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1. 发明申请

WO02085952A3 MODIFIED POLYMERS WITH A HIGH PROPORTION OF CIS-POSITION DOUBLE BONDS, METHOD FOR THE PRODUCTION AND USE THEREOF 审中-公开
标题翻译：改性聚合物与生产及其使用CIS永久双键，方法的比例高
公开(公告)号：WO02085952A3
公开(公告)日：2003-03-13
申请号：PCT/EP0204038
申请日：2002-04-11
申请人： BAYER AG , GRUEN MICHAEL , KNAUF THOMAS , BRAUBACH WILFRIED
发明人： GRUEN MICHAEL , KNAUF THOMAS , BRAUBACH WILFRIED
IPC分类号： B60C1/00 , C08C19/00 , C08C19/26 , C08C19/42 , C08F36/00 , C08C19/44
CPC分类号： C08C19/42 , C08C19/26
摘要： The invention relates to polymers which are modified along a polymer chain on the basis of conjugated dienes or conjugated dienes and vinyl aromatic compounds having a proportion of vinyl aromatic compounds of up to 60 wt. %, a proportion of cis-position double bonds of >/= 92 %, an average molecular weight of between 50 000 - 1 500 000 g/mol and a gel content of
摘要翻译：本发明沿着基于共轭二烯或具有高达60重量％，中的> / = 92％的顺式双键的含量乙烯基芳族化合物的含量的共轭二烯和乙烯基芳族化合物的聚合物链改性的聚合物涉及从50000至1,500,000克/摩尔的平均分子量的和

2. 发明申请

WO0216448A3 METALLIZED UNSATURATED POLYMER ANIONS, STABILIZED BY A COORDINATE BOND AND HAVING A LARGE PORTION OF CIS DOUBLE BONDS 审中-公开
标题翻译： METALLISIERTE BY配位键STABILIZED不饱和聚合物阴离子与CIS PERMANENT双键高比例的
公开(公告)号：WO0216448A3
公开(公告)日：2002-06-27
申请号：PCT/EP0109254
申请日：2001-08-10
申请人： BAYER AG , GRUEN MICHAEL , KNAUF THOMAS , BRAUBACH WILFRIED
发明人： GRUEN MICHAEL , KNAUF THOMAS , BRAUBACH WILFRIED
IPC分类号： C08F4/54 , C08C19/26 , C08F279/02 , C08F36/04 , C08F297/02
CPC分类号： C08F279/02 , C08C19/26 , C08F236/00 , C08F212/08
摘要： The invention relates to metallized unsaturated polymer anions, stabilized by a coordinate bond and having a large portion of cis double bonds. The invention further relates to a method for producing the same and to the use of said novel polymer anions in the production of graft polymers that are obtained by reacting the unsaturated polymer anions with anionically polymerizable nonpolar monomers. The graft polymers so obtained can be used for producing all sorts of shaped rubber bodies by corresponding vulcanization methods.
摘要翻译：本发明涉及金属化，通过协调结合用的顺式双键，它们的制备方法和通过与阴离子，非极性单体的不饱和聚合物的阴离子反应使用用于生产接枝聚合物聚合的新型聚合物阴离子的含量高，不饱和聚合物的阴离子稳定化的是。各种橡胶模制品的可通过适当的硫化从所得接枝来制备。

3. 发明专利

JP2003119223A COUPLED DIENE POLYMER MODIFIED WITH ELECTROPHILIC GROUP 审中-公开
公开(公告)号：JP2003119223A
公开(公告)日：2003-04-23
申请号：JP2002226260
申请日：2002-08-02
申请人： BAYER AG
发明人： GRUEN MICHAEL , KNAUF THOMAS , BRAUBACH WILFRIED
IPC分类号： C08F36/04 , C08C19/44 , C08F2/00 , C08F136/04 , C08F212/00 , C08L19/00
摘要： PROBLEM TO BE SOLVED: To provide a coupled polymer which has good processability and improved physical and dynamic characteristics and in which the coupling agent used exhibits no toxicity in processing. SOLUTION: The coupled polymer based on a conjugated diene or a conjugated diene and an aromatic vinyl compound, modified with an electrophilic group is produced by reacting a living anionic polymer based on the above-mentioned monomers with a functional organic compound containing at least three groups capable of reacting with the living anionic polymer and at least one group serving to modify the polymer in the molecule.

4. 发明专利

BR0113403A 未知
公开(公告)号：BR0113403A
公开(公告)日：2003-07-08
申请号：BR0113403
申请日：2001-08-10
申请人： BAYER AG
发明人： GRUEN MICHAEL , KNAUF THOMAS , BRAUBACH WILFRIED
IPC分类号： C08F4/54 , C08C19/26 , C08F279/02 , C08F8/00
摘要： The invention relates to metallized, unsaturated polymer anions stabilized by coordinate bonding and having a high proportion of cis double bonds, to a process for the preparation thereof and also to the use of the new polymer anions for the preparation of graft polymers that can be obtained by reaction of the unsaturated polymer anions with anionically polymerisable, non-polar monomers. From the graft polymers that are prepared in this way the most diverse rubber mouldings can be produced by appropriate vulcanization processes.

5. 发明专利

BR0205159A 未知
公开(公告)号：BR0205159A
公开(公告)日：2004-07-20
申请号：BR0205159
申请日：2002-12-10
申请人： BAYER AG
发明人： GRUEN MICHAEL , BRAUBACH WILFRIED
IPC分类号： C08J5/00 , C08C19/44 , C08F8/30 , C08F8/42 , C08F8/08
摘要： Modified conjugated diene or diene/vinylaromatic polymers with terminal functional groups derived from carbamoyl chlorides (I) or epoxy siloxanes (II) are new. Modified conjugated diene or diene/vinylaromatic polymers having a weight-average molecular weight (Mw) of more than 10000 and a polydispersity (Mn/Mw) of 1.3-5, with 40-100 mole% of terminal functional groups derived from carbamoyl chlorides of formula (I) or epoxy siloxanes of formula (II), are new: R1, R2 = H, 1-15C alkyl, 6-10C aryl, 5-10C cycloalkyl or (6-10C)aryl(1-4C)alkyl, or NR1R2 is a ring with 2-10 C atoms and 1-3 heteroatoms; R3-R7 = H, 1-15C alkyl, 6-10C aryl, 5-10C cycloalkyl, (6-10C)aryl(1-4C)alkyl or (CH2)pO(CH2)oQ; Q = oxiranyl; m, n, o, p = 1-12. An Independent claim is also included for production of the modified polymers by reacting conjugated dienes and optionally vinylaromatic compounds in an inert organic solvent in the presence of an alkali(ne earth) metal catalyst and reacting the product with (I) or (II) in an amount of 0.1-10 moles per mole of initiator.

6. 发明专利

CA2440585A1 HIGHLY BRANCHED DIENE POLYMERS 未知
公开(公告)号：CA2440585A1
公开(公告)日：2004-03-16
申请号：CA2440585
申请日：2003-09-12
申请人： BAYER AG
发明人： GRUEN MICHAEL , MUECKE SILVIA , WRANA CLAUS
IPC分类号： B60C1/00 , C08C19/44 , C08F8/00 , C08F36/04 , C08L15/00 , C08F236/06 , C08J5/00 , C08F2/06 , C08F12/06 , C08L9/06 , C08F212/08 , C08J3/24 , C08F4/42
摘要： The present invention relates to highly branched and coupled polymers based on conjugated dienes or on conjugated dienes and vinylaromatic compounds and on polyfunctional, organic compounds with at least four groups which are capabl e of coupling. Vulcanization products and shaped rubber articles of all types, in particular tires having an improved rolling resistance, can be produced from the highly branched diene polymers according to the present invention.

7. 发明专利

DE10151391A1 Modified polymer with cis double bonds based on conjugated dienes and vinyl aromatics useful for preparation of especially automobile tires, plastics, and golf balls has specific properties 未知
公开(公告)号：DE10151391A1
公开(公告)日：2002-10-24
申请号：DE10151391
申请日：2001-10-18
申请人： BAYER AG
发明人： GRUEN MICHAEL , KNAUF THOMAS , BRAUBACH WILFRIED
IPC分类号： C08C19/26 , C08C19/42 , C08F36/04 , C08F236/10
摘要： A polymer modified along the polymer chain based on conjugated dienes and vinyl aromatic compounds, up to 60 wt.% of which have \- 92% cis double bonds, and of mean weight average molecular weight Mw = 50,000 to 1,500,000, gel content

8. 发明专利

BR0304136A 未知
公开(公告)号：BR0304136A
公开(公告)日：2004-09-08
申请号：BR0304136
申请日：2003-09-15
申请人： BAYER AG
发明人： GRUEN MICHAEL , MUECKE SILVIA , WRANA CLAUS
IPC分类号： B60C1/00 , C08C19/44 , C08F8/00 , C08F36/04 , C08L15/00 , C08F297/00
摘要： Branched and coupled polymers are based on optionally conjugated dienes and vinyl aromatic compounds as well as polyfunctional organic compounds having at least 4 groups capable of coupling whereby at least 60% of the coupled polymers have a degree of branching of greater than 2 with the proviso that amount of polymer having at least 4-fold branching is greater than the amount having 3-fold branching. Branched and coupled polymers (I) are based on optionally conjugated dienes and vinyl aromatic compounds as well as polyfunctional organic compounds having at least 4 groups capable of coupling whereby the polymers (I) have a mol. wt. ratio (Mw/Mn) of 1.0-3.0, a weight average mol. wt. of 400,000-2,000,000, a glass transition temperature of -50 to -10degreesC, a 1,2-vinyl group content of 40-80% (with respect to diene groups), a degree of coupling of at least 45% whereby at least 60% of the coupled polymers (I) have a degree of branching of greater than 2 with the proviso that amount of polymer having at least 4-fold branching (with respect to 100 g polymer) is greater than the amount having 3-fold branching and the difference in solution viscosity before and after coupling is 100-400 (measured as a solution of 0.5 g polymer in 100 ml tolune at 25 degreesC using a Ubbelohde visometer). An Independent claim is included for a process for the production of polymers (I) by conventional polymerization of dienes with vinyl aromatic compounds in the presence of inert organic solvents and organic alkali metal compounds and reaction of the alkali metal terminated polymer anions that are formed with organic polyfunctional compounds that have at least 4 groups capable of coupling whereby the molar ratio of polyfunctional compounds to alkali-metal terminated polymer anions is 0.1-0.28:1.

9. 发明专利

BR0209112A 未知
公开(公告)号：BR0209112A
公开(公告)日：2004-07-13
申请号：BR0209112
申请日：2002-04-11
申请人： BAYER AG
发明人： GRUEN MICHAEL , KNAUF THOMAS , BRAUBACH WILFRIED
IPC分类号： B60C1/00 , C08C19/00 , C08C19/26 , C08C19/42 , C08F36/00 , C08C19/44
摘要： The present invention relates to polymers that are modified along the polymer chain and are based on conjugated dienes or conjugated dienes and vinyl-aromatic compounds having a content of vinyl-aromatic compounds of up to 60 wt. %, a content of cis-position double bonds of >=92%, a mean molecular weight of 50,000 to 1,500,000 g/mole and a gel content of

10. 发明专利

BR0203048A 未知
公开(公告)号：BR0203048A
公开(公告)日：2003-05-27
申请号：BR0203048
申请日：2002-08-05
申请人： BAYER AG
发明人： GRUEN MICHAEL , KNAUF THOMAS , BRAUBACH WILFRIED
IPC分类号： C08F36/04 , C08C19/44 , C08F2/00 , C08F136/04 , C08F212/00 , C08L19/00 , C08F297/04
摘要： A coupled and electrophilic group-modified polymer is claimed which is obtained by reaction of a specified polymer based on a conjugated diene (and optionally also vinylaromatics) with a polyfunctional compound containing ≥ 3 coupling groups and ≥ 1 electrophilic modifying group. A coupled and electrophilic group-modified polymer obtained by reaction of a polymer based on a conjugated diene (and optionally also vinylaromatics) with a polyfunctional compound containing ≥ 3 coupling groups and ≥ 1 electrophilic modifying group is such that (i) the polymer has mol. wt. distribution (Mw/Mn) 1.0-2.1, Mw ≥ 50,000, Tg -100 to -10 degrees C, a vinyl group content 5-90% (based on diene units and coupling number ≥ 2 and (ii) the amount of electrophilic modifying groups based on the amount of the alkali-terminated polymer anion intermediate used to prepare the product is 3-33 mol.%. An Independent claim is also included for the preparation of the coupled and modified polymer.

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