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    • 3. 发明专利
    • DE59710873D1
    • 2003-11-27
    • DE59710873
    • 1997-05-02
    • BAYER AG
    • WILMES DRBAUMBACH DRNACHTKAMP DRKOENIG DRDEARTH RANDALLBOCK DRWIECZORREK DIPL-ING
    • C03C17/32C08G18/08C08G18/12C08G18/64C08G18/70C08G18/75C08G18/79C08G18/80C09D175/04
    • Aqueous polyurethane coatings - contain a binder comprising (a) water-soluble or dispersible polyol component, (b) water-soluble or dispersible polyisocyanate component with capped isocyanate groups and (c) optional standard auxiliary agents and additives. The ratio of capped isocyanate groups in (b) to hydroxyl groups in (a) is at least 0.8:1.Component (a) comprises the following : (A1) 20-60 wt.% polyisocyanate comprising at least 50 wt.% 4,4`-diisocyanatodicyclohexyl methane and the rest other organic polyisocyanates with molecular weights of 140-1500 ; (B1) 20-65 wt.% one or more polyether polyols with hydroxy values of 25-350 mg KOH/g substance ; (C1) 2-12 wt.% (potential) anionic chain extender comprising at least one compound containing one or more groups which can react with NCO groups and at least one group which may be at least partially neutralised and can form salts ; (D1) 0-12 wt.% non-ionic hydrophilic chain extender, comprising at least one mono- or bifunctional ( relative to an isocyanate addition reaction) compound containing one or more hydrophilic polyether chains ; (E1) 0-15 wt.% one or more alcohols containing 2-4 hydroxyl groups and having molecular weights of 62-250 ; (F1) 0-15 wt.% one or more (cyclo)aliphatic polyamines containing 2-4 amino groups and having molecular weights of 60-300 ; (G1) 0-30 wt.% one or more (cyclo)aliphatic polyamine polyhydroxy compounds containing a total of 2-4 amino and hydroxyl groups and having molecular weights of 61-300 ; and (H1) 0-15 wt.% one or more mono- or bifunctional (relative to an isocyanate addition reaction) stabiliser component containing 1-2 hydrazide groups and having molecular weights of 70-300. Component (b) comprises : (A2) 40-80 wt.% polyisocyanate with an isocyanurate group content (calculated as C3N3O3 ; molecular weight = 26) of 2-30 wt.%, derived from diisocyanates molecular weights of 140-350 ; (B2) 5-30 wt.% one or more monofunctional (relative to an isocyanate addition reaction) capping agent for isocyanate groups ; (C2) 0-15 wt.% (potential) anionic chain extender comprising at least one compound containing one or more groups which can react with NCO groups and at least one group which may be at least partially neutralised and can form salts ; (D2) 5-30 wt.% non-ionic hydrophilic chain extender, comprising at least one mono- or bifunctional (relative to an isocyanate addition reaction) compound containing one or more hydrophilic polyether chains ; (E2) 0-15 wt.% one or more alcohols containing 2-4 hydroxyl groups and having molecular weights of 62-250 ; (F2) 0-15 wt.% one or more (cyclo)aliphatic polyamines containing 2-4 amino groups and having molecular weights of 60-300 ; and (G2) 0.5-15 wt.% one or more mono- or bifunctional (relative to an isocyanate addition reaction) stabiliser component containing 1-2 hydrazide groups and having molecular weights of 70-300. Also claimed is the preparation of these coating materials.