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1. 发明专利

JP2001288182A METHOD FOR PRODUCING DIALKYLTHIOPHENE AND ALKYLENEDIOXYTHIOPHENE 失效
公开(公告)号：JP2001288182A
公开(公告)日：2001-10-16
申请号：JP2001092829
申请日：2001-03-28
申请人： BAYER AG
发明人： RAUCHSCHWALBE GUENTER , JONAS FRIEDRICH
IPC分类号： C07D495/06 , C07D333/32 , C07D495/04
摘要： PROBLEM TO BE SOLVED: To obtain a high-purity a dialokoxythiopene from a dialkoxythiophenedicarboxylic acid in a high yield. SOLUTION: The high-purity dialkoxythiophene and alkylenedioxythiophene are obtained in a high yield the by decarboxylation reaction of the dialkoxythiophenedicarboxylic acid and an alkylenedioxythiophenedicarboxylic acid, respectively. A solvent used in the reaction has a boiling point higher than that of the products and does not contain a nitrogen base.

2. 发明专利

JPH10107403A MANUFACTURE OF RIGID CIRCUIT AND FLEXIBLE CIRCUIT 失效
公开(公告)号：JPH10107403A
公开(公告)日：1998-04-24
申请号：JP25259297
申请日：1997-09-03
申请人： BAYER AG
发明人： WOLF GERHARD-DIETER , JONAS FRIEDRICH
IPC分类号： H05K3/10 , H05K3/18 , H05K3/42
摘要： PROBLEM TO BE SOLVED: To provide the manufacturing method of an electric conductive circuit having rigidity or flexibility. SOLUTION: In this manufacturing method, a supporting material, having a perforated part, is covered by a conductive polymer in which a bonding material can be contained, an electric plating preventing agent is coated in the form of negative picture, and the surface, having no electric plating preventing agent, is metal plated by electrode position in the form of positive picture of conductive track. The electric plating preventing agent is removed, and the conductive polymer is removed from the region, where metal plating is not provided or the conductive polymer is changed into a non-conductive form. As a result, a rigid or flexible circuit, consisting of conductive tracks which are electrically connected with each other on a flexible or rigid indication material, can be manufactured.

3. 发明专利

JP2003286336A Method for producing transparent electrically conductive layer, thus produced layer and its use 审中-公开
标题翻译：生产透明电导体层的方法，生产层及其使用方法
公开(公告)号：JP2003286336A
公开(公告)日：2003-10-10
申请号：JP2003038685
申请日：2003-02-17
申请人： Bayer Ag , バイエルアクチェンゲゼルシャフト
发明人： KIRCHMEYER STEPHAN , JONAS FRIEDRICH
IPC分类号： C08G61/12 , H01B5/14 , H01B13/00 , H05K1/09
CPC分类号： C08G61/126 , H05K1/09
摘要： PROBLEM TO BE SOLVED: To provide an electrically conductive layer particularly having a high electrical conductivity, and furthermore remarkably high transparency for various applications.
SOLUTION: The transparent electrically conductive layer particularly having a high electrical conductivity is produced by using a polymer to be produced by the chemical oxidation of an appropriate thiophene with the use of an iron (III) salt of an alicyclic sulfonic acid as the oxidizing agent.
COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：为了提供特别具有高导电性的导电层，并且对于各种应用而言还具有非常高的透明度。解决方案：特别是具有高导电性的透明导电层通过使用通过使用脂环族磺酸的铁（III）盐化学氧化合适的噻吩而制备的聚合物作为氧化剂。版权所有（C）2004，JPO

4. 发明申请

WO0045625A3 METHOD FOR THE DIRECT ELECTROPLATING OF THROUGH-HOLES IN PRINTED CIRCUIT BOARDS 审中-公开
标题翻译：程序对于通过印制电路板直接电
公开(公告)号：WO0045625A3
公开(公告)日：2002-06-13
申请号：PCT/EP0000256
申请日：2000-01-14
申请人： BAYER AG , KIRCHMEYER STEPHAN , JONAS FRIEDRICH
发明人： KIRCHMEYER STEPHAN , JONAS FRIEDRICH
IPC分类号： C25D7/00 , C25D5/34 , C25D5/56 , H05K3/42 , H05K3/46
CPC分类号： C25D5/56 , H05K3/424
摘要： The invention relates to a method for the direct electroplating of through holes in two-layer printed circuit boards and multilayer printed boards, consisting of the following steps: a) creation of holes in the copper-coated boards; b) oxidative pretreatment of the holes; c) possibly rinsing with water; c) treatment with an aqueous solution containing between 1 and 300 g/l phosphoric acid; e) treatment with a microemulsion containing one or more thiophenes of general formula (I) in which X is oxygen or a single bond and R and R independently of each other are hydrogen or a (C1-C4)-alkyl chain or together are a possibly substituted (C1-C4)-alkylene rest or a cyclohexylene-1,2 rest; f) treatment with sulphuric acid; g) possibly rinsing with water; and h) electrodeposition of copper.
摘要翻译：一个）的生产在铜层压板的孔，B）的孔的氧化预处理，c）如有必要，用水ð漂洗）治疗用水溶液：一种用于通过接触式双层印刷电路板和多层膜的直接电镀，包括以下工艺步骤过程含有1至300g /磷酸的L，E）与含有通式（I），其中X表示氧或单键中的一个或多个噻吩的微乳液处理，R <1>和R <2> 是氢或（C1-C4）烷基各自独立地是或一起形成任选取代的（C1-C4）亚烷基或亚环己基-1,2-自由基形式，f）与硫酸处理，g）如必要，用水冲洗铜，h）的电沉积。

5. 发明专利

CA2315682C SCREEN PRINTING PASTE FOR PRODUCING ELECTRICALLY CONDUCTIVE COATINGS 未知
公开(公告)号：CA2315682C
公开(公告)日：2006-10-03
申请号：CA2315682
申请日：1998-12-10
申请人： BAYER AG
发明人： JONAS FRIEDRICH , GUNTERMANN UDO
IPC分类号： H01B1/12 , H05B33/28 , B41F15/00 , C09D5/24 , C09D165/00 , G02F1/1362 , H01L51/50 , H05B33/14
摘要： The present invention relates to a screen printing paste having a viscosity of from 1 to 200 dPas, comprising a solution or dispersion of a conductive polymer and optionally binders, thickeners and fillers, and to the use thereof for the production of electrically conductive coatings.

6. 发明专利

ES2240731T3 NUEVAS DISPERSIONES DE POLITIOFENO. 未知
公开(公告)号：ES2240731T3
公开(公告)日：2005-10-16
申请号：ES02722144
申请日：2002-02-27
申请人： BAYER AG
发明人： JONAS FRIEDRICH , KIRCHMEYER STEPHAN
IPC分类号： H05B33/10 , C08G61/12 , C08J3/09 , H01B1/12 , H01G9/032 , H01L51/50 , H01M10/40
摘要： Procedimiento para la obtención de dispersiones o soluciones, que contienen complejos iónicos de politiofeno +An-, en disolventes orgánicos, caracterizado porque a) se añade un disolvente orgánico miscible con agua o una mezcla de disolventes orgánicos, miscibles con agua, a una dispersión o solución acuosa de complejos iónicos de politiofeno+ An-, significando politiofeno+ polímeros que contengan unidades recurrentes cargadas positivamente, al menos en parte, de la fórmula (I), en la que Y significa -(CH2)m-CR1R2(CH2)n- o un resto 1, 2- cicloalquileno con 3 a 8 átomos de carbono, substituido en caso dado y R1 y R2 significan, independientemente entre sí, hidrógeno, hidroximetilo, un resto alquilo con 1 a 20 átomos de carbono, en caso dado substituido o un resto arilo con 6 a 14 átomos de carbono, en caso dado substituido, y m, nson iguales o diferentes y significan un número desde 0 hasta 3, y donde An- significa un anión de un poliácido orgánico, o donde politiofeno+ An- significa polímeros que portan unidades recurrentes de la fórmula (II), en la que los anillos de tiofeno portan una carga positiva, al menos en parte y en la que Z significa -(CH2)m-CR3R4(CH2)n-, R3 significa hidrógeno o -(CH2)s-O-(CH2)p-SO3-M+, R4 significa -(CH2)s-O-(CH2)p-SO3-M+, m, nsignifica un número entero desde 0 hasta 3, M+ significa un catión, s significa un número entero desde 0 hasta 10, p significa un número entero desde 1 hasta 18 y b) se elimina agua de las mezclas resultantes.

7. 发明专利

HK1063641A1 Novel polythiophene dispersions 未知
公开(公告)号：HK1063641A1
公开(公告)日：2005-01-07
申请号：HK04106317
申请日：2004-08-24
申请人： BAYER AG
发明人： JONAS FRIEDRICH , KIRCHMEYER STEPHAN
IPC分类号： C08G61/12 , C08J3/09 , H05B33/10 , H01B1/12 , H01G9/032 , H01L51/50 , H01M10/40 , C08G , H01B
摘要： A process for the preparation of dispersions or solutions comprising polythiophene+An− ion complexes in anhydrous or low-water-content organic solvents, characterized in that at least one water-miscible organic solvent or a water-miscible solvent mixture is added to an aqueous dispersion or solution comprising optionally substituted polythiophenes, all or some of the water is removed, and the resultant dispersion or solution is, if desired, diluted with organic solvents.

8. 发明专利

DK1142888T3 未知
公开(公告)号：DK1142888T3
公开(公告)日：2004-12-06
申请号：DK01106444
申请日：2001-03-23
申请人： BAYER AG
发明人： RAUCHSCHWALBE GUENTER , JONAS FRIEDRICH
IPC分类号： C07D495/06 , C07D333/32 , C07D495/04
摘要： In the preparation of 3,4-dialkoxy- or 3,4-alkylenedioxy-thiophenes (I) or (II) by decarboxylation of the corresponding 3,4-dialkoxy- or 3,4-alkylene-dioxo-2,5-thiophene-dicarboxylic acids (III) or (IV), (i) decarboxylation is carried out in a solvent or diluent with a higher boiling point than (I) or (II), which is not an aromatic amine; and (ii) the end product is separated from this solvent or diluent by distillation. In the preparation of 3,4-dialkoxy- or 3,4-alkylenedioxy-thiophenes of formula (I) or (II) by decarboxylation of the corresponding 3,4-dialkoxy- or 3,4-alkylene-dioxo-2,5-thiophene-dicarboxylic acids of formula (III) or (IV): (i) decarboxylation is carried out in a solvent or diluent with a higher boiling point than (I) or (II), which is not an aromatic amine; and (ii) the end product is separated from this solvent or diluent by distillation. R , R = linear or branched 1-15 carbon (C) alkyl; X = optionally substituted -(CH2)n-; n = 1-12.

9. 发明专利

DE50103504D1 未知
公开(公告)号：DE50103504D1
公开(公告)日：2004-10-14
申请号：DE50103504
申请日：2001-03-23
申请人： BAYER AG
发明人： RAUCHSCHWALBE GUENTER , JONAS FRIEDRICH
IPC分类号： C07D495/06 , C07D333/32 , C07D495/04
摘要： In the preparation of 3,4-dialkoxy- or 3,4-alkylenedioxy-thiophenes (I) or (II) by decarboxylation of the corresponding 3,4-dialkoxy- or 3,4-alkylene-dioxo-2,5-thiophene-dicarboxylic acids (III) or (IV), (i) decarboxylation is carried out in a solvent or diluent with a higher boiling point than (I) or (II), which is not an aromatic amine; and (ii) the end product is separated from this solvent or diluent by distillation. In the preparation of 3,4-dialkoxy- or 3,4-alkylenedioxy-thiophenes of formula (I) or (II) by decarboxylation of the corresponding 3,4-dialkoxy- or 3,4-alkylene-dioxo-2,5-thiophene-dicarboxylic acids of formula (III) or (IV): (i) decarboxylation is carried out in a solvent or diluent with a higher boiling point than (I) or (II), which is not an aromatic amine; and (ii) the end product is separated from this solvent or diluent by distillation. R , R = linear or branched 1-15 carbon (C) alkyl; X = optionally substituted -(CH2)n-; n = 1-12.

10. 发明专利

DE10016723A1 未知
公开(公告)号：DE10016723A1
公开(公告)日：2001-10-11
申请号：DE10016723
申请日：2000-04-04
申请人： BAYER AG
发明人： RAUCHSCHWALBE GUENTER , JONAS FRIEDRICH
IPC分类号： C07D495/06 , C07D333/32 , C07D495/04 , C07D409/04
摘要： In the preparation of 3,4-dialkoxy- or 3,4-alkylenedioxy-thiophenes (I) or (II) by decarboxylation of the corresponding 3,4-dialkoxy- or 3,4-alkylene-dioxo-2,5-thiophene-dicarboxylic acids (III) or (IV), (i) decarboxylation is carried out in a solvent or diluent with a higher boiling point than (I) or (II), which is not an aromatic amine; and (ii) the end product is separated from this solvent or diluent by distillation. In the preparation of 3,4-dialkoxy- or 3,4-alkylenedioxy-thiophenes of formula (I) or (II) by decarboxylation of the corresponding 3,4-dialkoxy- or 3,4-alkylene-dioxo-2,5-thiophene-dicarboxylic acids of formula (III) or (IV): (i) decarboxylation is carried out in a solvent or diluent with a higher boiling point than (I) or (II), which is not an aromatic amine; and (ii) the end product is separated from this solvent or diluent by distillation. R , R = linear or branched 1-15 carbon (C) alkyl; X = optionally substituted -(CH2)n-; n = 1-12.

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