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1. 发明申请

WO2009024549A3 PROCESS AND APPARATUS FOR OXIDIZING ORGANIC COMPOUNDS 审中-公开
标题翻译：方法和装置氧化有机化合物
公开(公告)号：WO2009024549A3
公开(公告)日：2009-04-30
申请号：PCT/EP2008060786
申请日：2008-08-18
申请人： BASF SE , TELES JOAQUIM HENRIQUE , OEHLENSCHLAEGER STEFFEN , GUMLICH KAI , SCHAEFER MARTIN , LAMM STEPHAN , BERG STEFAN , NILLES MICHAEL , SCHILDBERG HANS-PETER , JOHN TILO , ZEHNER PETER
发明人： TELES JOAQUIM HENRIQUE , OEHLENSCHLAEGER STEFFEN , GUMLICH KAI , SCHAEFER MARTIN , LAMM STEPHAN , BERG STEFAN , NILLES MICHAEL , SCHILDBERG HANS-PETER , JOHN TILO , ZEHNER PETER
IPC分类号： C07C51/235 , C07C53/122 , C07C53/126
CPC分类号： C07C51/235 , Y02P20/582 , C07C53/126 , C07C53/122
摘要： The invention relates to a process for oxidizing at least one organic substance with oxygen, comprising the following steps: a) adding the at least one organic substance, in the form of a liquid, and an oxygen-containing gas stream to a first reaction stage, to form a reaction mixture, at least some of the oxygen reacting with the organic compound to form a reaction product, b) adding the reaction mixture from the first reaction stage to an adiabatically operated reaction stage, in which the unreacted organic substance undergoes at least partial further reaction to form the product. The invention additionally relates to an apparatus for implementing the process.
摘要翻译：本发明涉及一种用于用氧气氧化的至少一种有机物质，所述方法包括以下步骤：a）加成作为液体和在第一反应阶段接触以形成反应混合物的含氧气体流的至少一个有机物质，其中，至少与所述的氧的一部分反应有机化合物的反应产物，b）将来自第一反应阶段的反应混合物中的绝热操作反应阶段，其中进一步至少部分地发生反应的未反应的有机物质的产品。此外，本发明涉及一种装置，用于执行该方法。

2. 发明申请

WO2009024446A3 PROCESS AND DEVICE FOR THE OXIDATION OF ORGANIC COMPOUNDS 审中-公开
标题翻译：方法和装置氧化有机化合物
公开(公告)号：WO2009024446A3
公开(公告)日：2009-05-07
申请号：PCT/EP2008060121
申请日：2008-08-01
申请人： BASF SE , TELES JOAQUIM HENRIQUE , GUMLICH KAI , SCHAEFER JOCHEN , OEHLENSCHLAEGER STEFFEN , LAMM STEPHAN , MERTEN ROLAND , SCHAEFER MARTIN , GROB RUEDIGER , EMNET UWE
发明人： TELES JOAQUIM HENRIQUE , GUMLICH KAI , SCHAEFER JOCHEN , OEHLENSCHLAEGER STEFFEN , LAMM STEPHAN , MERTEN ROLAND , SCHAEFER MARTIN , GROB RUEDIGER , EMNET UWE
IPC分类号： C07C51/235 , B01J8/22 , C07C53/124 , C07C53/126 , C07C53/128
CPC分类号： C07C51/235 , C07C53/124 , C07C53/128 , C07C53/122 , C07C53/126
摘要： The invention relates to a process for the oxidation of organic compounds with oxygen in which, in a first step, the organic compound and at least some of the oxygen required for the oxidation are charged to a first reaction zone, where the first reaction zone is operated isothermally and back-mixed, and in a second step the reaction mixture from the first reaction zone is passed to a second reaction zone, where the second reaction zone is operated adiabatically. The invention further relates to a reactor for carrying out the process comprising at least one isothermal (3, 5) and one adiabatic (7) reaction zone which are arranged in a reactor jacket (8), where each isothermal reaction zone (3, 5) is configured in the form of a jet loop reactor and the adiabatic reaction zone (7) is configured as bubble column.
摘要翻译：本发明涉及一种方法，用于与氧的有机化合物的氧化，其中在第一步骤中的有机化合物和至少所需的氧的氧化的一部分在第一反应区中添加，其中，所述第一反应区等温运行和返混，并且在第二步骤中，从所述第二反应区绝热操作的第一反应区的反应混合物供入第二反应区。本发明还涉及一种用于执行该方法的反应器，其包括至少一个等温（3,5）和绝热（7）反应区被布置在反应器容器（8）中，每个等温反应区（3,5）中的一个形式喷射回路反应器被设计和绝热反应区（7）被设计为泡罩塔。

3. 发明申请

WO2011020878A3 METHOD FOR PRODUCING 4-PENTENOIC ACID 审中-公开
标题翻译：用于生产4-戊
公开(公告)号：WO2011020878A3
公开(公告)日：2011-09-15
申请号：PCT/EP2010062098
申请日：2010-08-19
申请人： BASF SE , TELES JOAQUIM HENRIQUE , SCHELPER MICHAEL , GUMLICH KAI , CHABANAS MATHIEU , MUELLER CHRISTIAN , MEIER ANTON
发明人： TELES JOAQUIM HENRIQUE , SCHELPER MICHAEL , GUMLICH KAI , CHABANAS MATHIEU , MUELLER CHRISTIAN , MEIER ANTON
IPC分类号： C07C51/235 , C07C57/03
CPC分类号： C07C51/235 , C07C57/03
摘要： The invention relates to a method for producing 4-pentenoic acid, at least comprising the oxidation of a mixture (G) containing 4-pentenal, 3-methyl-2-butanone and cyclopentene oxide and to the use of a mixture (G) containing 4-pentenal, 3-methyl-2-butanone and cyclopentene oxide for producing 4-pentenoic acid. The invention also relates to the mixture (G) which is obtained as an auxiliary product from the oxidation of cyclopentene to cyclopentanone by means of dinitrogen monoxide.
摘要翻译：本发明涉及一种方法，用于4-戊烯酸的制备中，至少包含以下的混合物的含有4-戊烯醛，3-甲基-2-丁酮含有氧化（G），和环戊烯氧化物，以及使用的混合物（G）-4-戊烯醛，3- 甲基-2-丁酮和4-戊烯酸的制备环戊烯氧化物。在本发明的上下文中，环戊烯氧化成环戊酮的副产物的混合物（G）优选通过一氧化二氮的方法而获得。

4. 发明申请

WO2008071632A2 METHOD FOR ISOLATING N2O 审中-公开
标题翻译：隔离N2O的方法
公开(公告)号：WO2008071632A2
公开(公告)日：2008-06-19
申请号：PCT/EP2007063510
申请日：2007-12-07
申请人： BASF SE , BAUMANN DIETER , ROESSLER BEATRICE , TELES JOAQUIM HENRIQUE
发明人： BAUMANN DIETER , ROESSLER BEATRICE , TELES JOAQUIM HENRIQUE
IPC分类号： C01B21/22 , B01D53/14 , B01D53/56 , C07C45/28 , C07C49/00
CPC分类号： C01B21/22 , B01D53/1406 , B01D53/1418 , B01D53/77 , B01D2257/402 , Y02C20/10 , Y02P20/153
摘要： The present invention relates to a method for purifying a gas mixture G-0 containing nitrous oxide, comprising at least the bringing of the gas mixture G-0 into contact with a solvent mixture (I) containing at least 50% by weight of water with respect to the total solvent mixture (I), wherein the pH of the solvent mixture (I) ranges from 3.5 to 8.0, the desorption of a gas mixture G-1 from a composition (A), the bringing into contact of the gas mixture G-1 with a solvent mixture (II) containing at least 50% by weight of water with respect to the total solvent mixture (II), wherein the pH of the solvent mixture (II) ranges from 2.0 to 8.0, and the desorption of a gas mixture G-2 from a composition (B), wherein the pH in each case relates to a measurement with a glass electrode. The invention also relates to the use of gas mixtures obtained by the method according to the invention, as oxidizing agents for olefins.
摘要翻译：本发明涉及一种用于净化的气体混合物G-0包括一氧化二氮，至少包括基于总溶剂混合物（I），其中，所述气体混合物G-0与包含至少50重量％水的溶剂混合物（I）接触范围从3.5到8.0，气体混合物G-1的从组合物中的脱附的溶剂混合物（I）的pH值（a）中，含有至少50的气体混合物G-1与溶剂的混合物（II）的接触重量基于总溶剂混合物（II），其中，所述溶剂混合物（II）的中的2.0的区域中的pH值至8.0，并混合气体G-2的从组合物中（B）解吸％的水，其中每种情况下的pH都指用玻璃电极测量，以及通过根据本发明的方法可获得的气体混合物作为用于烯烃的氧化剂的用途。

5. 发明申请

WO2010083978A3 TUBE BUNDLE REACTOR FOR NON-CATALYZED OR HOMOGENOUSLY CATALYZED REACTIONS 审中-公开
标题翻译：管式反应器非催化或均匀催化反应
公开(公告)号：WO2010083978A3
公开(公告)日：2011-01-06
申请号：PCT/EP2010000280
申请日：2010-01-19
申请人： BASF SE , TELES JOAQUIM HENRIQUE , RESCH PETER , RUPPEL WILHELM , WEGERLE ULRIKE , GERLINGER WOLFGANG , ROESSLER-FEIGEL BEATRICE , MEIER ANTON , MUELLER CHRISTIAN
发明人： TELES JOAQUIM HENRIQUE , RESCH PETER , RUPPEL WILHELM , WEGERLE ULRIKE , GERLINGER WOLFGANG , ROESSLER-FEIGEL BEATRICE , MEIER ANTON , MUELLER CHRISTIAN
IPC分类号： B01J19/24 , B01J19/00
CPC分类号： B01J19/2425 , B01J4/001 , B01J19/006 , B01J2219/00085 , B01J2219/00166 , F28D7/16 , F28F9/0265 , F28F9/0275 , F28F9/0278 , Y02P20/582
摘要： The invention relates to a tube bundle reactor having a flat feed dome. Alternatively, the discharge dome can also be designed flat. The flat design reduces the reaction heat developing in the hood in reaction types that take place not only in the tube bundle (non-catalyzed reactions and reactions with homogenously distributed catalyst). Undesired reactions that already take place in the dome due to accumulated heat are thus heavily suppressed, whereby greater selectivity in temperature-sensitive reactions is achieved. Additionally, the temperature distribution within the domes can be precisely controlled. The tube bundle reactor comprises a tube bundle that has a feed end connected to a feed dome of the tube bundle reactor, wherein the feed dome is designed in a flat shape having a cross-sectional surface at the feed end and an inner volume, and the ratio of the inner volume to the cross-sectional surface is less than 0.35 m. The invention is furthermore implemented by a method for operating a tube bundle reactor, comprising: introducing a reactant mixture into a tube bundle and converting at least a portion of the reactant mixture into a product inside the tube bundle. The introduction step comprises: feeding the reactant mixture into an inner space of a feed dome of the tube bundle reactor and forwarding the reactant mixture into a feed end of the tube bundle in the form of a fluid flow. The fluid flow has a cross-sectional surface upon entering the feed end and the inner space of the feed dome through which the fluid flows has an inner volume; wherein the ratio of the inner volume to the cross-sectional surface is less than 0.35 m.
摘要翻译：本发明涉及一种具有平面供应罩管束反应器。可替换地，放电罩可以制成平的。扁平设计降低导致反应类型，发生不仅在Rohbündel（未催化的反应和反应以均匀地分布催化剂）罩反应热。其特征在于，由此更高的选择性与对温度敏感的反应实现的是那些已经在罩发生不希望的反应，由于积热，强烈抑制。此外，该罩内的温度分布可以被精确地控制。包括具有进料端，其连接到所述管束反应器的供给罩管束管束反应器中，与在进料端的内部容积的横截面面积和扁平形状的供给罩构造，并且内部容积的横截面面积的比例为小于0， 35米。引入在管束中的反应物混合物，并且至少在管束内的反应混合物的一部分反应，以一个产品：此外，本发明是通过一种用于操作管束反应器的方法，包括的手段来实现。放电，其包括：供给所述反应物混合物进入管束反应器的供给罩的内和反应物混合物通入在流体流的形式管束的一个进给端。流体流动的横截面面积，因为它进入的进料端和通过其流体流流，具有内部容积的供给机罩的内部; 其中内部体积与横截面面积的比例为小于0.35微米。

6. 发明申请

WO2012055716A3 METHOD FOR THE PRODUCTION OF 1-METHYL-1-ALKOXYCYCLOPENTANES 审中-公开
标题翻译：制备1-甲基-1-烷氧基环戊烷的方法
公开(公告)号：WO2012055716A3
公开(公告)日：2012-08-30
申请号：PCT/EP2011068060
申请日：2011-10-17
申请人： BASF SE , LANVER ANDREAS , EBEL KLAUS , KLOPSCH RAINER , BERTLEFF WERNER , DEHN RICHARD , TELES JOAQUIM HENRIQUE , KRONEMAYER HELMUT , SCHREMS MARCUS GEORG
发明人： LANVER ANDREAS , EBEL KLAUS , KLOPSCH RAINER , BERTLEFF WERNER , DEHN RICHARD , TELES JOAQUIM HENRIQUE , KRONEMAYER HELMUT , SCHREMS MARCUS GEORG
IPC分类号： C07C5/29 , C07C13/12 , C07C41/06 , C07C43/184
CPC分类号： C07C41/06 , C07C1/24 , C07C5/29 , C07C2521/08 , C07C2527/173 , C07C2601/08 , C07C2601/10 , C07C43/184 , C07C13/12 , C07C13/20
摘要： The invention relates to a method for the production of cyclopentane derivatives of formula (I), in which R represents a C1-C10 alkyl group, characterized in that cyclohexanol or cyclohexene or mixtures of both compounds are reacted to 1-methyl-1-cyclopentene (first stage), a C1-C10 alkanol being added subsequently to the double bond of the 1-methyl-1-cyclopentene (second stage).
摘要翻译：其中R为C1至C10烷基的式（I）环戊烷衍生物的制备方法，其特征在于将环己醇或环己烯或两种化合物的混合物转化为1-甲基-1-环戊烯（第一阶段）然后在1-甲基-1-环戊烯的双键中加入C1至C10链烷醇（第二步）。

7. 发明申请

WO2010023211A2 PROCESS FOR PREPARING CYCLIC KETONES 审中-公开
标题翻译：用于生产环酮
公开(公告)号：WO2010023211A2
公开(公告)日：2010-03-04
申请号：PCT/EP2009060956
申请日：2009-08-26
申请人： BASF SE , TELES JOAQUIM HENRIQUE , RUPPEL WILHELM , WEGERLE ULRIKE , MEIER ANTON , GENGER THOMAS , SCHELPER MICHAEL , RESCH PETER
发明人： TELES JOAQUIM HENRIQUE , RUPPEL WILHELM , WEGERLE ULRIKE , MEIER ANTON , GENGER THOMAS , SCHELPER MICHAEL , RESCH PETER
IPC分类号： C07C45/33 , C07C49/11
CPC分类号： C07C45/28 , C07C45/82 , C07C2601/08 , Y02P20/582 , C07C49/403 , C07C49/395 , C07C49/413
摘要： The present invention relates to a process for preparing at least one monocyclic ketone having 4 to 20 carbon atoms by reacting a mixture G1 comprising at least one monocyclic olefin having 4 to 20 carbon atoms with a mixture G2 comprising at least dinitrogen monoxide, this reaction being carried out adiabatically.
摘要翻译：本发明涉及一种方法，用于由混合物G1包括4至20个碳原子的至少一种单环烯烃与含有至少一氧化二氮的混合物G2使具有碳原子数4〜20的至少一个单环酮的制备方法，所述反应在绝热下进行。

8. 发明申请

WO2008145656A3 PRODUCTS, THE USE THEREOF IN THE TREATMENT OF TEXTILES, AND THE PRODUCTION THEREOF 审中-公开
标题翻译：产品，它们在纺织和生产治疗
公开(公告)号：WO2008145656A3
公开(公告)日：2009-03-19
申请号：PCT/EP2008056500
申请日：2008-05-27
申请人： BASF SE , WEYRAUCH JAN PHILIPP , TELES JOAQUIM HENRIQUE , REICHERT JUERGEN
发明人： WEYRAUCH JAN PHILIPP , TELES JOAQUIM HENRIQUE , REICHERT JUERGEN
IPC分类号： C07D309/22 , D06M13/137
CPC分类号： C07D309/22 , D06M13/148 , D06M13/352 , D06M2200/20
摘要： Products, obtained by reacting of at least one compound of the common formula I with at least one compound of the common formula II under acidic conditions, wherein the variables are defined as follows: a is selected from whole numbers in the range from 0 to 2, n is chosen from whole numbers in the range from 1 to 4, R1 is chosen from C1-C4-alkyl, R2, R3 and R4 are identical or different and are selected from hydrogen and C1-C8-alkyl.
摘要翻译：由通式I在酸性条件下通式II的至少一种化合物，其中各变量的定义如下的至少一种化合物反应得到的产品：一个从在范围的整数中选择从零到2，n是选自整数范围从1到4，R 1选自C1-C4烷基，R2，R3和R4相同或不同，选自氢和C1-C8烷基。

9. 发明申请

WO2012055754A3 METHOD FOR THE PRODUCTION OF 1-METHYLCYCLOPENTANE DERIVATIVES 审中-公开
标题翻译：制备1-甲基环戊烷衍生物的方法
公开(公告)号：WO2012055754A3
公开(公告)日：2012-08-30
申请号：PCT/EP2011068328
申请日：2011-10-20
申请人： BASF SE , LANVER ANDREAS , EBEL KLAUS , KLOPSCH RAINER , BERTLEFF WERNER , DEHN RICHARD , TELES JOAQUIM HENRIQUE , KRONEMAYER HELMUT , SCHREMS MARCUS GEORG
发明人： LANVER ANDREAS , EBEL KLAUS , KLOPSCH RAINER , BERTLEFF WERNER , DEHN RICHARD , TELES JOAQUIM HENRIQUE , KRONEMAYER HELMUT , SCHREMS MARCUS GEORG
IPC分类号： C07C17/08 , C07C5/29 , C07C13/12 , C07C23/08 , C07C29/04 , C07C35/06 , C07C41/06 , C07C43/184
CPC分类号： C07C17/08 , C07C1/20 , C07C5/29 , C07C29/04 , C07C41/06 , C07C2601/10 , Y02P20/127 , C07C23/08 , C07C13/12 , C07C43/184 , C07C35/06
摘要： The invention relates to a method for the production of 1-methylcyclopentene by the thermal reaction of cyclohexanol or cyclohexene or mixtures of both compounds to 1-methylcyclopentene, characterized in that the obtained byproducts 3-methylcyclopentene and 4-methylcyclopentene (double bond isomers of 1-methylcyclopentene) are fed back to the reaction.
摘要翻译：一种用于通过环己醇或环己烯，或两种化合物1-甲基环戊烯的混合物的热反应制备1-甲基环戊烯的方法，其特征在于，所得的3-甲基环戊烯和4-甲基环戊烯（1-甲基环戊烯的双键）的副产物被循环到反应中。

10. 发明申请

WO2009106621A8 METHOD FOR PRODUCING OLEFINICALLY UNSATURATED CARBONYL COMPOUNDS BY OXIDATIVE DEHYDROGENATION OF ALCOHOLS 审中-公开
标题翻译：受理并醇氧化脱氢制不饱和羰基烯
公开(公告)号：WO2009106621A8
公开(公告)日：2010-09-16
申请号：PCT/EP2009052383
申请日：2009-02-27
申请人： BASF SE , LIMBACH MICHAEL , TELES JOAQUIM HENRIQUE , ABDALLAH RADWAN , MAEURER TORSTEN , JOHANN THORSTEN
发明人： LIMBACH MICHAEL , TELES JOAQUIM HENRIQUE , ABDALLAH RADWAN , MAEURER TORSTEN , JOHANN THORSTEN
IPC分类号： C07C45/38 , C07C45/39 , C07C47/21
CPC分类号： C07C29/56 , C07C45/38 , C07C33/03 , C07C47/21
摘要： The invention relates to a method for producing olefinically unsaturated carbonyl compounds by oxidative dehydrogenation in an oxygen-containing atmosphere on a supported catalyst which contains gold and optionally additional noble metals, at temperatures in the range of 50 to 240°C.
摘要翻译：一种制备烯属不饱和羰基化合物的通过氧化脱氢在含氧上的负载型催化剂的气氛中，黄金和其他可能的贵金属方法包括在温度范围从50至240℃

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