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    • 3. 发明申请
    • PIPERAZINE COMPOUNDS WITH A HERBICIDAL ACTION
    • 用除草活性的哌嗪化合物
    • WO2008152073A3
    • 2009-02-12
    • PCT/EP2008057329
    • 2008-06-11
    • BASF SEHUPE EIKESEITZ THOMASWITSCHEL MATTHIASSONG DSCHUNMOBERG WILLIAM KARLPARRA RAPADO LILIANASTELZER FRANKVESCOVI ANDREANEWTON TREVOR WILLIAMREINHARD ROBERTSIEVERNICH BERNDGROSSMANN KLAUSEHRHARDT THOMASRACK MICHAELKIBLER ELMAR
    • HUPE EIKESEITZ THOMASWITSCHEL MATTHIASSONG DSCHUNMOBERG WILLIAM KARLPARRA RAPADO LILIANASTELZER FRANKVESCOVI ANDREANEWTON TREVOR WILLIAMREINHARD ROBERTSIEVERNICH BERNDGROSSMANN KLAUSEHRHARDT THOMASRACK MICHAELKIBLER ELMAR
    • C07D241/08A61K31/495C07D403/10C07D407/10C07D409/10C07D413/10C07D417/10
    • C07D241/08C07D403/10C07D407/10C07D409/10C07D413/10C07D417/10
    • The invention relates to piperazine compounds of the following defined general formula (I) and to their use as herbicides. The invention also relates to crop protection agents and to a method for combating undesired plant growth. In formula (I), the variables are defined as follows: R1 is selected from halogen, cyano, nitro, Z-C(=O)-R11, phenyl and a 5- or 6-membered heterocyclic group that has 1, 2, 3 or 4 heteroatoms, selected from O, N and S as ring atoms, wherein phenyl and the heterocyclic group are unsubstituted or have 1, 2, 3 or 4 substituents R1a; Z stands for a covalent bond or a CH2 group; R11 represents hydrogen, C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C5-C6 cycloalkenyl, C2-C6 alkynyl and similar; R2 represents hydrogen, halogen, nitro, cyano, C1-C4 alkyl, C1-C4 haloalkyl, C2- C4 alkenyl, C1-C4 alkoxy, C1-C4 haloalkoxy, benzyl or a group S(O) nR21, wherein R21 stands for C1-C4 alkyl or C1-C4 haloalkyl and n stands for 0, 1 or 2; R3 represents hydrogen or halogen; R4 represents C1-C4 alkyl, C3- C4 alkenyl or C3-C4 alkynyl; R5 represents hydrogen, C1-C4 alkyl, C3-C4 alkenyl, C3-C4 alkynyl or a group (=O)R51, wherein R51 stands for hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy or C1-C4 haloalkoxy; R6 stands for C1-C4 alkyl, C1-C4 hydroxy alkyl or C1-C4 haloalkyl; R7, R8 stand, independently of one another, for hydrogen, OH, C1-C4 alkoxy, C1-C4 haloalkyoxy, C1-C4 alkyl or C1-C4 haloalkyl; R9, R10 are selected, independently of one another, from hydrogen, halogen, CN, NO2, C1-C4 alkyl, C1-C4 haloalkyl, C2-C4 alkenyl, C1-C4alkoxy and C1-C4 haloalkoxy.
    • 本发明涉及如以下通式(I)中所定义的哌嗪化合物及其作为除草剂的用途。 本发明还涉及组合物用于作物保护和打击不需要的植物生长的方法。 在式(I)中,变量具有以下含义:R 1选自卤素,氰基,硝基,ZC(= O)-R 11,苯基中的含有1,2,3或4的5-或6-元杂环基团 由具有杂原子作为环原子,其中苯基和杂环基团是未取代的或具有O,N和S的1,2,3或4个具有取代基R1A; Z是共价键或CH 2基团; R11是氢,C1-C6烷基,C3-C6环烷基,C2-C6烯基,C5-C6环烯基,C2-C6炔基等; R2是氢,卤素,硝基,氰基,C1-C4烷基,C1-C4卤代烷基,C2-C4链烯基,C1-C4烷氧基,C1-C4卤代烷氧基,苄基或基团S(O)NR21, 其中R 21代表C1-C4烷基或C1-C4卤代烷基,n为0,1或2; R3是氢或卤素; R4是C1-C4烷基,C3-C4链烯基或C3-C4炔基; R5是氢,C1-C4烷基,C3-C4链烯基,C3-C4炔基或基团C(= O)R51,其中R51是氢,C1-C4烷基,C1-C4卤代烷基,C1 C4烷氧基或C1-C4卤代烷氧基; R6是C1-C4烷基,C1-C4羟烷基或C1-C4卤代烷基; R7,R8独立地为氢,OH,C1-C4烷氧基,C1-C4 Haloalkyoxy,C1-C4烷基或C1-C4卤代烷基; 和R9,R10独立地选自氢,卤素,CN,NO2,C1-C4烷基,C1-C4卤代烷基,C2-C4链烯基,C1-C4烷氧基和C1-C4卤代烷氧基中选择。
    • 4. 发明申请
    • PIPERAZINE COMPOUNDS WITH A HERBICIDAL ACTION
    • 用除草活性的哌嗪化合物
    • WO2008152072A3
    • 2009-02-12
    • PCT/EP2008057328
    • 2008-06-11
    • BASF SEHUPE EIKESEITZ THOMASWITSCHEL MATTHIASSONG DSCHUNMOBERG WILLIAM KARLPARRA RAPADO LILIANASTELZER FRANKVESCOVI ANDREANEWTON TREVOR WILLIAMREINHARD ROBERTSIEVERNICH BERNDGROSSMANN KLAUSEHRHARDT THOMASRACK MICHAELKIBLER ELMAR
    • HUPE EIKESEITZ THOMASWITSCHEL MATTHIASSONG DSCHUNMOBERG WILLIAM KARLPARRA RAPADO LILIANASTELZER FRANKVESCOVI ANDREANEWTON TREVOR WILLIAMREINHARD ROBERTSIEVERNICH BERNDGROSSMANN KLAUSEHRHARDT THOMASRACK MICHAELKIBLER ELMAR
    • C07D241/08A01N43/60
    • C07D241/08A01N43/60
    • The invention relates to piperazine compounds of the following defined general formula (I) and to their use as herbicides. The invention also relates to crop protection agents and to a method for combating undesired plant growth. In formula (I): R1 is selected from halogen, cyano, nitro, Z-C(=O)-R12, phenyl and a 5- or 6-membered heterocyclic group that has 1, 2, 3 or 4 heteroatoms, selected from O, N and S as ring atoms, wherein phenyl and the heterocyclic group are unsubstituted or have 1, 2, 3 or 4 substituents R1a; Z stands for a covalent bond or a CH2 group; R12 represents hydrogen, C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6alkenyl, C5-C6 cycloalkenyl, C2-C6alkynyl and similar; R2 represents hydrogen, halogen, nitro, cyano, C1-C4alkyl, C1-C4 haloalkyl, C2- C4 alkenyl, C1-C4 alkoxy, C1-C4haloalkoxy, benzyl or a group S(O) nR21, wherein R21 stands for C1-C4 alkyl or C1-C4 haloalkyl and n stands for 0, 1 or 2; R3 represents hydrogen or halogen; R4 represents C1-C4 alkyl, C3- C4 alkenyl or C3-C4 alkynyl; R5 represents hydrogen, C1-C4alkyl, C3-C4 alkenyl, C3-C4 alkynyl or a group (=O)R51, wherein R51 stands for hydrogen, C1-C4alkyl, C1-C4 haloalkyl, C1-C4 alkoxy or C1-C4 haloalkoxy; R6 stands for C1-C4alkyl, C1-C4 hydroxy alkyl or C1-C4haloalkyl; R7, R8 stand, independently of one another, for hydrogen, OH, C1-C4 alkoxy, C1-C4 haloalkyoxy, C1-C4 alkyl or C1-C4 haloalkyl; R9, R10 are selected, independently of one another, from hydrogen, halogen, CN, NO2, C1-C4 alkyl, C1-C4 haloalkyl, C2-C4 alkenyl, C1-C4 alkoxy and C1-C4 haloalkoxy; and R11 represents hydrogen or C1-C4 alkyl. The invention also relates to the agriculturally suitable salts of said compounds.
    • 本发明涉及如以下通式(I)中所定义的哌嗪化合物及其作为除草剂的用途。 本发明还涉及组合物用于作物保护和打击不需要的植物生长的方法。 R 1选自卤素,氰基,硝基,ZC(= O)-R 12,苯基和选择的5-或6-元杂环基团含有选自O,N和S的1,2,3或4个杂原子 作为环原子,其中苯基和杂环基团是未取代的或有1个,2个,3个或4个取代基R1A有; Z是共价键或CH 2基团; R12是氢,C1-C6烷基,C3-C6环烷基,C2-C6烯基,C5-C6环烯基,C2-C6炔基等; R2是氢,卤素,硝基,氰基,C1-C4烷基,C1-C4卤代烷基,C2-C4链烯基,C1-C4烷氧基,C1-C4卤代烷氧基,苄基或基团S(O)NR21, 其中R 21代表C1-C4烷基或C1-C4卤代烷基,n为0,1或2; R3是氢或卤素; R4是C1-C4烷基,C 3 -C 4 - 烯基或C 3 -C 4炔基; R5是氢,C1-C4烷基,C3-C4链烯基,C3-C4炔基或基团C(= O)R51,其中R51是氢,C1-C4烷基,C1-C4卤代烷基,C1 C4烷氧基或C1-C4卤代烷氧基; R6是C1-C4烷基,C1-C4-HydroxyalkyloderC1-C4卤代烷基; R7,R8独立地为氢,OH,C1-C4烷氧基,C1-C4 Haloalkyoxy,C1-C4烷基或C1-C4卤代烷基; R9,R10独立地选自氢,卤素,CN,NO2,C1-C4烷基,C1-C4卤代烷基,C2-C4链烯基,C1-C4烷氧基和C1-C4卤代烷氧基中选择; 和R11是氢或C1-C4烷基; 以及这些化合物的农业上适用的盐。
    • 5. 发明申请
    • SYNERGISTICALLY ACTING HERBICIDAL MIXTURES
    • 协同作用除草混合物
    • WO2004008849A3
    • 2004-05-13
    • PCT/EP0307992
    • 2003-07-22
    • BASF AGO'NEAL WILLIAM BKIBLER ELMARWESTBERG DAN EWITSCHEL MATTHIASVANTIEGHEM HERVE R
    • O'NEAL WILLIAM BKIBLER ELMARWESTBERG DAN EWITSCHEL MATTHIASVANTIEGHEM HERVE R
    • A01N43/80A01N43/10A01N43/56A01N43/647A01N43/70A01N43/713A01N43/88A01N47/36
    • A01N43/56A01N47/36A01N61/00A01N43/70A01N43/10A01N43/88A01N2300/00
    • A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula (I) in which the variables have the following meanings: R , R are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R is a optionally substituted heterocyclic radical se-lected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydro-isoxazol-4-yl and 4,5-dihydroisoxazol-5-yl; R is hydrogen, halogen or alkyl; R is alkyl; R is hydrogen or alkyl; or one of its environmentally compatible salts; and B) the compound of formula (II) or one of its environmentally compatible salts; and C) at least one further herbicidal compound from the group of the acetolactate synthase inhibitors (ALS), lipid biosynthesis inhibitors and photosynthesis inhibitors; in a synergistically effective amount. Compositions comprising these mixtures, processes for the prepa-ration of these compositions, and their use for controlling undesired plants.
    • 一种协同除草混合物,其包含A)至少一种式(I)的3-杂环基取代的苯甲酰基衍生物,其中所述变量具有以下含义:R 1,R 3为卤素,烷基,卤代烷基,烷氧基, 卤代烷氧基,烷硫基,烷基亚磺酰基或烷基磺酰基; R 2是选自以下的任选取代的杂环基:异恶唑-3-基,异恶唑-4-基,异恶唑-5-基,4,5-二氢异恶唑-3-基,4,5-二氢 - 异恶唑-4-基和4,5-二氢异恶唑-5-基; R 4是氢,卤素或烷基; R 5是烷基; R 6是氢或烷基; 或其环境相容的盐之一; 和B)式(II)化合物或其与环境相容的盐之一; 和C)来自乙酰乳酸合酶抑制剂(ALS),脂质生物合成抑制剂和光合作用抑制剂的至少一种另外的除草化合物; 协同有效量。 包含这些混合物的组合物,这些组合物的制备方法以及它们用于防治不期望的植物的用途。
    • 6. 发明申请
    • SYNERGISTICALLY ACTING HERBICIDAL MIXTURES
    • 协同作用除草混合物
    • WO2004010779A3
    • 2004-05-06
    • PCT/EP0308114
    • 2003-07-24
    • BASF AGKIBLER ELMARO'NEAL WILLIAM BWITSCHEL MATTHIASVANTIEGHEM HERVE RWESTBERG DAN E
    • KIBLER ELMARO'NEAL WILLIAM BWITSCHEL MATTHIASVANTIEGHEM HERVE RWESTBERG DAN E
    • A01N25/02A01N43/40A01N43/70A01N43/80A01N43/90
    • A01N43/40A01N43/56A01N43/80A01N43/90A01N61/00A01N43/70A01N2300/00
    • A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula (I) see paper versionin which the variables have the following meanings: R1, R3 are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a optionally substituted heterocyclic radical selected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-di-hydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl;R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) at least the compound of formula (IIa) see paper versionor one of its environmentally compatible salts; and, if desired, orthe compound of formula (IIb) see paper versionor one of its environmentally compatible salts; in a synergistically effective amount; and, if desired, C) at least one further herbicidal compound; in a synergistically effective amount. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling un-desired plants.
    • 一种协同除草混合物,其包含A)至少一种式(I)的3-杂环基取代的苯甲酰基衍生物,见变种具有以下含义的论文版本:R1,R3为卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基, 烷基亚磺酰基或烷基磺酰基; R2是任选取代的杂环基团,其选自异恶唑-3-基,异恶唑-4-基,异恶唑-5-基,4,5-二氢异恶唑-3-基,4,5-二氢异恶唑-4-基, 吡啶基和4,5-二氢异恶唑-5-基; R 4是氢,卤素或烷基; R5是烷基; R6是氢或烷基; 或其环境相容的盐之一; 和B)至少式(IIa)化合物参见试纸版其环境相容的盐之一; 并且如果需要,或式(IIb)化合物参见试纸版其环境相容的盐之一; 协同有效量; 并且如果需要,C)至少一种另外的除草化合物; 协同有效量。 包含这些混合物的组合物,这些组合物的制备方法及其用于控制​​不需要的植物的用途。
    • 7. 发明申请
    • NON-AQUEOUS ACTIVE INGREDIENT CONCENTRATES HAVING AN HERBICIDAL EFFECT
    • 具有除草效果的非水活性浓缩物
    • WO2008015279A3
    • 2008-08-07
    • PCT/EP2007058091
    • 2007-08-03
    • BASF SEKRAPP MICHAELBERGHAUS RAINERBRATZ MATTHIASKIBLER ELMARVANTIEGHEM HERVE R
    • KRAPP MICHAELBERGHAUS RAINERBRATZ MATTHIASKIBLER ELMARVANTIEGHEM HERVE R
    • A01N25/32A01N43/10A01N43/78A01N43/80
    • A01N43/56A01N25/02A01N25/30A01N43/10A01N43/80A01N2300/00
    • The present invention relates to active ingredient concentrates having an herbicidal effect, comprising: a) 10 to 100 g/L of at least one 4-benzoyl-substituted pyrazol compound of the formula (I), wherein R 1 , R 3 independently of each other stand for hydrogen, halogen, hethyl, halogen methyl, methoxy, halogen methoxy, methylthio, methyl sulfinyl, or methyl sulfonyl; R 2 stands for a 5-membered heterocyclic residue, which is unsubstituted, or carries 1, 2, 3, or 4 substituents, which are selected from halogen, C 1 -C 6 -alkyl, C 1 -C 4 -akoxy, C 1 -C 4 -halogen alkyl, C 1 -C 4 -halogen alkoxy, and C 1 -C 4 -alkylthio; R 4 stands for hydrogen, halogen, or methyl; R 5 stands for C 1 -C 6 -alkyl, C 3 -C 6 -cycloalkyl, or C 3 -C 6 -cycloalkylmethyl; and R 6 stands for hydrogen, or C 1 -C 4 -Alkyl; or one of its salts used in agriculture, b) 200 to 700 g/L 2-chlorine-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)-acetamide, and 25 c) 10 to 200 g/L of at least a surface-active substance S, which is selected from a mixture of at least one anionic surface-active compound, and at least one non-ionic surface-active compound, wherein the components a), b), and c) are dissolved in an organic solvent mixture, which comprises at least 95 wt.-%, based on the solvent mixture, of d1) at least one aprotic polar organic solvent, which has a miscibility with water at 25°C and 1 bar of at least 50 g/l, and d2) at least one organic solvent, which has a solubility in water at 25°C and 1 bar of less than 5 g/l.
    • 本发明涉及活性化合物浓缩物具有含有除草活性:1)10至100克/升式(I)其中R 1 ,R 3 <中的至少一种4-苯甲酰基取代的吡唑化合物的 独立地表示氢,卤素,甲基,卤代甲基,甲氧基,卤代甲氧基,甲硫基,甲基亚磺酰基或甲基磺酰基; R 2是未取代的或带有1,2,3或4个取代基的5元杂环基,所述取代基是卤素,C 1 -C 4烷基, 6 烷基,C 1 -C 4 -Akoxy,C 1 -C 4 - 卤代烷基,C 1 -C 4卤代烷氧基和C 1 -C 4烷硫基; R 4是氢,卤素或甲基; R 5,C 1 -C 6烷基,C 3 -C 6,C 6,C 6, 环烷基或C 3 -C 6环烷基甲基; 和R 6是氢或C 1 -C 4烷基;并且R 6是氢或C 1 -C 4烷基。 或其农业上有用的盐中的一种,B)为200〜700 2-氯-N-(2,4-二甲基-3-噻吩基)-N-(2-甲氧基-1-甲基乙基)乙酰胺克/升,和25℃下 )10至200克C)在有机溶剂混合物中的)/ L的至少一种表面活性剂S,其选自至少一种阴离子表面活性化合物和至少一种非离子表面活性化合物的混合物,其中所述组分存在于溶液中选择的),和b,所述 至少95重量%,基于溶剂混合物,从d1)至少一种非质子极性有机具有与水的混溶性,在25℃和溶剂1巴包含至少50克/升的,和d2)至少一种有机溶剂, 其在25℃和1巴下在水中具有小于5g / l的溶解度。