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1. 发明申请

WO2012126797A2 USE OF OLIGOMERIC CARBODIIMIDES AS STABILIZERS 审中-公开
标题翻译：使用稳定剂低聚碳化二亚胺
公开(公告)号：WO2012126797A2
公开(公告)日：2012-09-27
申请号：PCT/EP2012054550
申请日：2012-03-15
申请人： BASF SE , SMIT THEO , POTTIE LAURENCE , SCHILLO SIMONE , FRENZ VOLKER , MEER ROELOF VAN DER
发明人： SMIT THEO , POTTIE LAURENCE , SCHILLO SIMONE , FRENZ VOLKER , MEER ROELOF VAN DER
IPC分类号： C07C267/00 , C07C271/00
CPC分类号： C07C267/00 , C07D207/404 , C07D223/10 , C07D263/14 , C07D263/22
摘要： The invention relates to the use of oligomeric carbodiimides containing at least one heterocyclic end group as stabilizers for polymers. The oligomeric carbodiimides can be compounds of the general formula (I), in which A1, A2 are identical or different and represent hydrocarbon groups with 2 to 20 carbon atoms independently of each other; B1, B2 are identical or different and represent heterocycles, C1-C30 alcohols, poyletherols, polyesterols, amines, polyetheramines, polyesteramines, thioalcohols, polyetherthiols, polyesterthiols independently of each other; R1, R2 are identical or different and represent (A) independently of each other; and n represents a whole number ranging from 2 to 100; wherein A1, A2, B1 and B2 can each be substituted with C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkinyl, C1-C20 alkoxy, carbonyl oxygen (=O), or halogen at any position with the proviso that at least one substituent of B1 or B2 is a heterocyclic end group. The invention further relates to methods for stabilizing polymers against hydrolysis using oligomeric carbodiimides.
摘要翻译：使用含有至少一个杂环端基低聚碳二亚胺，作为稳定剂用于聚合物。其中低聚碳化二亚胺可以是通式（I）化合物，其中A1，A2，彼此独立地，相同或不同，是具有2至20个碳原子，B1，B2彼此独立地，相同或不同，杂环，C1-C30醇的烃基， Poyletherole，聚酯多元醇，胺，聚醚，聚酯胺，硫醇，Polyetherthiole，Polyesterthiole，R1，R2彼此独立地，相同或不同，（A）中，n为整数2至100，并且其中A1，A2，B1和B2 在每种情况下通过C1-C20烷基，C2-C20链烯基，C2-C20炔基，C1-C20烷氧基，羰基氧（= O）或卤素的任何位置可被取代，其条件是至少一个取代基是B1或B2的杂环端基。此外，对于通过低聚碳二亚胺稳定对抗水解的聚合物的方法。

2. 发明申请

WO2012098149A3 PROCESS FOR PRODUCING A COMPOSITE MATERIAL 审中-公开
标题翻译：用于生产复合材料
公开(公告)号：WO2012098149A3
公开(公告)日：2013-01-17
申请号：PCT/EP2012050690
申请日：2012-01-18
申请人： BASF SE , LANGE ARNO , COX GERHARD , DYLLICK-BRENZINGER RAINER , GRONWALD OLIVER , SMIT THEO
发明人： LANGE ARNO , COX GERHARD , DYLLICK-BRENZINGER RAINER , GRONWALD OLIVER , SMIT THEO
IPC分类号： C08G79/00 , C08G8/28 , C08G79/02
CPC分类号： C08G79/00 , C07F5/04 , C07F5/05 , C07F5/069 , C07F7/006 , C07F7/045 , C07F7/184 , C07F7/21 , C07F9/09 , C08G8/28 , C08G77/60 , C08G79/02 , C08K3/36 , C08K2003/2241
摘要： The present invention relates to a process for producing composite materials which consist essentially of a) at least one oxidic phase and b) at least one organic polymer phase, by copolymerizing - at least one compound A selected from aryloxy metallates, aryloxy semimetallates and aryloxy esters of non-metals which form oxo acids and are different from carbon and nitrogen, with - at least one compound B selected from formaldehyde and formaldehyde equivalents, in a reaction medium which is essentially anhydrous, the compound B being used in an amount such that the molar ratio of formaldehyde to the aryloxy groups in the compound A is at least 0.9:1.
摘要翻译：本发明涉及一种用于生产基本上由a）至少一种氧化物相的复合材料; 其下的至少一种化合物B - 和b）由有机聚合物相的，至少，通过共聚 - 至少一种化合物A，所述下Aryloxymetallaten，Aryloxyhalbmetallaten和含氧酸非金属，它们是由碳和氮不同，被选择的Aryloxyestern形成，具有甲醛和甲醛等价物被选择时，在反应介质中基本上不含水，在使用中，其量使得所述芳氧基中的化合物甲醛的摩尔比至少为0.9的化合物B：1。

3. 发明公开

KR20180008544A 산소 이동 차단을 위한 종이 기재상의 아크릴레이트 폴리머를 가진 코팅층의 용도 审中-公开
标题翻译：在纸基材上使用具有丙烯酸酯聚合物的涂层以阻止氧气转移
公开(公告)号：KR20180008544A
公开(公告)日：2018-01-24
申请号：KR20177035296
申请日：2016-05-13
申请人： BASF SE
发明人： SEYFFER HERMANN , CIMPEANU CARMEN ELENA , SMIT THEO , VELING NICO , SCHMIDT THUEMMES JUERGEN , LAWRENZ DIRK , BLUM RAINER
IPC分类号： D21H19/12 , D21H19/20 , D21H19/22 , D21H19/54 , D21H19/58 , D21H21/14 , D21H27/10 , D21H27/18
CPC分类号： D21H27/10 , D21H19/12 , D21H19/20 , D21H19/22 , D21H19/54 , D21H19/58 , D21H21/14 , D21H27/18
摘要： 본발명은코팅된종이기판을통해산소이동차단을위한종이기판상의코팅층의용도에관한것으로, 여기에서종이기판상의코팅층은, 하기의단계를포함하는, 방법으로수득가능하고: (a) 표면을가진종이기판을제공하는단계, (b) 제공된종이기판의표면상에수성코팅물을도포하는단계, 및 (c) 도포된수성코팅물을구비한종이기판을건조시켜코팅된종이기판을수득하는단계, 여기에서수성코팅물은, 제1 분해된전분의존재하에, 항상 100인, 전체모노머의중량부의총계를기준으로적어도 25 중량부의 C-C알킬아크릴레이트또는 C-C알킬메타크릴레이트의라디칼개시에멀젼중합에의해수득가능한, 폴리머 P의수성분산물을함유한다. 추가로, 모노머의중합이후첨가되는, 폴리머 P 및추가사카라이드의수성분산물을포함하는코팅물로수득가능한코팅된종이기판에관한것이다. 또한, 폴리머 P 및추가사카라이드의수성분산물을포함하는코팅물로수득가능한코팅된종이기판의제조방법에관한것이다.
摘要翻译：本发明涉及在纸基材上涂覆涂层以阻止通过涂布纸基材的氧气流动，其中纸基材上的涂层可通过包括以下步骤的方法获得：（a）（B）在所提供的纸基材的表面上施加水性涂层;以及（c）用所施加的水性涂层干燥纸基材以获得涂布纸基材。其中水性涂层包含基于总单体在第一降解淀粉存在下的总重量份数的至少25重量份的丙烯酸C烷基酯或甲基丙烯酸C烷基酯，其中P 1和P 2分别是P 1和P 2。此外，本发明涉及一种可用包含聚合物P和另外的糖的聚合物产物的涂层获得的涂布纸基材，其在单体聚合后加入。本发明还涉及一种制造涂布纸基材的方法，该涂布纸基材可用包含聚合物P和另外的糖的水基产品的涂层获得。

4. 发明公开

KR20180008543A 산소 이동 차단을 위한 종이 기판상의 스티렌-부타디엔 코폴리머를 가진 코팅층의 용도 审中-公开
标题翻译：在纸基材上使用具有苯乙烯 - 丁二烯共聚物的涂层以阻止氧气转移
公开(公告)号：KR20180008543A
公开(公告)日：2018-01-24
申请号：KR20177035295
申请日：2016-05-13
申请人： BASF SE
发明人： SEYFFER HERMANN , CIMPEANU CARMEN ELENA , SMIT THEO , VELING NICO , SCHMIDT THUEMMES JUERGEN , LAWRENZ DIRK , BLUM RAINER
IPC分类号： D21H19/20 , C08F220/06 , C08F236/10 , C08L3/02 , C09D109/06 , C09D125/10 , D21H19/22 , D21H19/54 , D21H27/10 , D21H27/18
CPC分类号： D21H19/20 , C08F236/10 , C09D109/06 , C09D125/10 , D21H19/22 , D21H19/54 , D21H27/10 , D21H27/18 , C08F220/06 , C08L3/02
摘要： 본발명은코팅된종이기판을통한산소이동을차단하기위한종이기판상의코팅층의용도에관한것으로, 여기에서종이기판상의코팅층은, (a) 표면을가진종이기판을제공하는단계, (b) 제공된종이기판의표면상에수성코팅물을도포하는단계, 및 (c) 도포된수성코팅물을가진종이기판을건조시켜코팅된종이기판을수득하는단계를포함하는방법에의해수득가능하고, 수성코팅물은, 제1 분해된전분의존재하에, 항상 100인전체모노머의중량부의총계를기준으로, 적어도 40 중량부의스티렌및 22 내지 49 중량부의부타디엔및 선택적으로다른모노머의라디칼개시에멀젼중합에의해수득가능한, 코폴리머 P의수성분산물을함유한다. 추가로, 본발명은코폴리머 P의수성분산물및 모노머의중합이후첨가되는추가의사카라이드를포함하는코팅물로수득가능한코팅된종이기판에관한것이다. 또한, 본발명은코폴리머 P의수성분산물및 추가의사카라이드를포함하는코팅물로수득가능한코팅된종이기판의제조방법에관한것이다.
摘要翻译：本发明涉及使用对纸基材为通过涂布纸基材的纸基材上阻断氧运输，涂层本文中，（a）提供具有表面的纸基材的涂层，（b）设置在（c）用所施加的水性涂层干燥纸基材以获得涂布的纸基材，其中水性涂料在纸基材的表面上施加水基涂层水，首先在降解淀粉，总是100的存在，基于重量份总的所有单体的至少40重量份的苯乙烯和22至49重量份的丁二烯和，可选地，由其它单体的自由基引发的乳液聚合得到可能是共聚物P的数量组分的产物。此外，本发明涉及一种涂布纸基材，该涂布纸基材可用包含共聚物P的水基产品和在单体聚合后添加的另外的糖的涂层获得。本发明还涉及一种制备涂布纸基材的方法，所述涂布纸基材可用包含共聚物P和另外的糖的水基产品的涂层获得。

5. 发明专利

CA3005068A1 AQUEOUS COMPOSITIONS BASED ON POLYALKENAMERS 未知
公开(公告)号：CA3005068A1
公开(公告)日：2017-05-18
申请号：CA3005068
申请日：2016-11-11
申请人： BASF SE
发明人： SMIT THEO , NEGRETE HERRERA NORMA LIDIA , DAHMEN STEFAN , STURM BERNHARD , MUELLER KEVIN , HAEBERLE KARL
IPC分类号： C08G61/08 , C08F4/00 , C09D5/00 , C09D165/00
摘要： The invention relates to aqueous compositions containing a) at least one polymer PALK in the form of dispersed polymer particles, wherein the polymer PALK can be obtained by the ring-opening metathesis polymerization of at least one cyclic olefin monomer and b) at least one polymer P2 in the form of dispersed polymer particles, wherein the polymer P2 does not have an olefenically unsaturated C-C bond and has repeating units which have at least one polar group. The aqueous compositions are suitable in particular for producing films and barrier coatings which have a very good barrier effect against gases such as air, oxygen, nitrogen, argon, and carbon dioxide, in particular against oxygen and oxygen-containing gases such as air. At the same time, the films and coatings have very good mechanical properties, in particular a high elongation at break while having a good tear strength.

6. 发明专利

ES2584416T3 Material de caucho con material de barrera de copolímeros de cicloolefina 未知
公开(公告)号：ES2584416T3
公开(公告)日：2016-09-27
申请号：ES13745639
申请日：2013-08-02
申请人： BASF SE
发明人： SMIT THEO , MÜLLER KEVIN , DAHMEN STEFAN , NEGRETE HERRERA NORMA LIDIA , STURM BERNHARD
IPC分类号： C08G61/08 , C09D165/00
摘要： Uso de un copolímero para reducir la permeabilidad a los gases de material de caucho, en el que el copolímero se puede preparar mediante polimerización de metátesis con apertura de anillo de a) por lo menos un primer monómero de olefina seleccionado del grupo que consiste en monómeros de olefina cíclica con por lo menos un doble enlace C-C endocíclico, en donde en una posición alfa con respecto al doble enlace no está presente ningún átomo de carbono terciario que lleve un átomo de hidrógeno, y b) por lo menos un segundo monómero de olefina seleccionado del grupo que consiste en monómeros de olefina cíclica con un doble enlace C-C endocíclico, en donde en por lo menos una posición alfa con respecto al doble enlace está presente un átomo de carbono terciario que lleva un átomo de hidrógeno, en donde el copolímero está oxidado al menos en parte, y en donde el copolímero no está preparado, o lo está con menos del 1 % en moles con respecto a la suma de los monómeros, a partir de monómeros de olefina policíclica con al menos dos dobles enlaces C-C.

7. 发明专利

IN3735CHN2014A ADDITIVES FOR STABILIZING POLYCONDENSATES WITH RESPECT TO HYDROLYSIS 未知
公开(公告)号：IN3735CHN2014A
公开(公告)日：2015-09-04
申请号：IN3735CHN2014
申请日：2014-05-16
申请人： BASF SE
发明人： POTTIE LAURENCE , SMIT THEO , SCHILLO SIMONE , FRENZ VOLKER , DER MEER ROELOF VAN
IPC分类号： C08K5/00
摘要： The invention relates to a mixture containing at least one multi functional chain extender with at least three reactive groups as well as at least one monofunctional or difunctional hydrolytic stabiliser said chain extender and hydrolytic stabilisers reacting with the end groups of polymers when the polymers are in a melted or solid state with a chemical bond being formed. The invention also relates to the use of such mixtures as stabilisers for polymers and to a method for the stabilisation of polymers against losses in molecular weight in which an effective amount of such a mixture is added to the polymer.

8. 发明专利

CA2880775A1 RUBBER MATERIAL WITH BARRIER MATERIAL MADE OF CYCLOOLEFIN COPOLYMERS 未知
公开(公告)号：CA2880775A1
公开(公告)日：2014-02-20
申请号：CA2880775
申请日：2013-08-02
申请人： BASF SE
发明人： SMIT THEO , MULLER KEVIN , DAHMEN STEFAN , NEGRETE HERRERA NORMA LIDIA , STURM BERNHARD
IPC分类号： C08G61/08 , C09D165/00
摘要： The use of a certain copolymer is described for reducing the gas-permeability of rubber material. A rubber material provided with a barrier material in the form of the copolymer is also described. The copolymer can be produced via ring-opening metathesis polymerization of a) one first olefin monomer selected from the group consisting of cyclic olefin monomers having at least one endocyclic C-C double bond, where no tertiary carbon atom bearing a hydrogen atom is present in alpha-position to the double bond, and b) one second olefin monomer selected from the group consisting of cyclic olefin monomers having one endocyclic C-C double bond, where a tertiary carbon atom bearing a hydrogen atom is present in at least one alpha-position to the double bond, where the copolymer has been oxidized at least to some extent, where the amount of polycyclic olefin monomers used to produce the copolymer with at least two C-C double bonds is zero or less than 1 mol%, based on the entirety of the monomers.

9. 发明专利

PL2723565T3 Powlekane folie polimerowe o właściwościach bariery tlenowej 未知
公开(公告)号：PL2723565T3
公开(公告)日：2015-08-31
申请号：PL12730870
申请日：2012-06-18
申请人： BASF SE
发明人： PIETSCH INES , WEISS AXEL , MICHL KATHRIN , PREISHUBER-PFLÜGL PETER , SMIT THEO
IPC分类号： B32B27/08 , B32B27/36 , B65D81/34 , C09D4/06 , C09D133/00

10. 发明专利

ES2538854T3 Láminas de polímero revestidas con propiedades de barrera frente a oxígeno 未知
公开(公告)号：ES2538854T3
公开(公告)日：2015-06-24
申请号：ES12730870
申请日：2012-06-18
申请人： BASF SE
发明人： PIETSCH INES , WEISS AXEL , MICHL KATHRIN , PREISHUBER-PFLÜGL PETER , SMIT THEO
IPC分类号： B32B27/08 , B32B27/36 , B65D81/34 , C09D4/06 , C09D133/00
摘要： Lámina de polímero revestida, que puede fabricarse mediante el revestimiento de una lámina de polímero con una composición acuosa, que contiene A) un polímero obtenido mediante polimerización por radicales, que se compone del 10 al 80 % en peso de al menos un compuesto, seleccionado de anhídridos de ácido etilénicamente insaturados y ácidos dicarboxílicos etilénicamente insaturados, cuyos grupos ácido carboxílico pueden formar un grupo anhídrido, y B) al menos una alcanolamina con al menos dos grupos hidroxilo.

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