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    • 4. 发明申请
    • PIPERAZINE COMPOUNDS WITH A HERBICIDAL ACTION
    • 用除草活性的哌嗪化合物
    • WO2008152072A3
    • 2009-02-12
    • PCT/EP2008057328
    • 2008-06-11
    • BASF SEHUPE EIKESEITZ THOMASWITSCHEL MATTHIASSONG DSCHUNMOBERG WILLIAM KARLPARRA RAPADO LILIANASTELZER FRANKVESCOVI ANDREANEWTON TREVOR WILLIAMREINHARD ROBERTSIEVERNICH BERNDGROSSMANN KLAUSEHRHARDT THOMASRACK MICHAELKIBLER ELMAR
    • HUPE EIKESEITZ THOMASWITSCHEL MATTHIASSONG DSCHUNMOBERG WILLIAM KARLPARRA RAPADO LILIANASTELZER FRANKVESCOVI ANDREANEWTON TREVOR WILLIAMREINHARD ROBERTSIEVERNICH BERNDGROSSMANN KLAUSEHRHARDT THOMASRACK MICHAELKIBLER ELMAR
    • C07D241/08A01N43/60
    • C07D241/08A01N43/60
    • The invention relates to piperazine compounds of the following defined general formula (I) and to their use as herbicides. The invention also relates to crop protection agents and to a method for combating undesired plant growth. In formula (I): R1 is selected from halogen, cyano, nitro, Z-C(=O)-R12, phenyl and a 5- or 6-membered heterocyclic group that has 1, 2, 3 or 4 heteroatoms, selected from O, N and S as ring atoms, wherein phenyl and the heterocyclic group are unsubstituted or have 1, 2, 3 or 4 substituents R1a; Z stands for a covalent bond or a CH2 group; R12 represents hydrogen, C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6alkenyl, C5-C6 cycloalkenyl, C2-C6alkynyl and similar; R2 represents hydrogen, halogen, nitro, cyano, C1-C4alkyl, C1-C4 haloalkyl, C2- C4 alkenyl, C1-C4 alkoxy, C1-C4haloalkoxy, benzyl or a group S(O) nR21, wherein R21 stands for C1-C4 alkyl or C1-C4 haloalkyl and n stands for 0, 1 or 2; R3 represents hydrogen or halogen; R4 represents C1-C4 alkyl, C3- C4 alkenyl or C3-C4 alkynyl; R5 represents hydrogen, C1-C4alkyl, C3-C4 alkenyl, C3-C4 alkynyl or a group (=O)R51, wherein R51 stands for hydrogen, C1-C4alkyl, C1-C4 haloalkyl, C1-C4 alkoxy or C1-C4 haloalkoxy; R6 stands for C1-C4alkyl, C1-C4 hydroxy alkyl or C1-C4haloalkyl; R7, R8 stand, independently of one another, for hydrogen, OH, C1-C4 alkoxy, C1-C4 haloalkyoxy, C1-C4 alkyl or C1-C4 haloalkyl; R9, R10 are selected, independently of one another, from hydrogen, halogen, CN, NO2, C1-C4 alkyl, C1-C4 haloalkyl, C2-C4 alkenyl, C1-C4 alkoxy and C1-C4 haloalkoxy; and R11 represents hydrogen or C1-C4 alkyl. The invention also relates to the agriculturally suitable salts of said compounds.
    • 本发明涉及如以下通式(I)中所定义的哌嗪化合物及其作为除草剂的用途。 本发明还涉及组合物用于作物保护和打击不需要的植物生长的方法。 R 1选自卤素,氰基,硝基,ZC(= O)-R 12,苯基和选择的5-或6-元杂环基团含有选自O,N和S的1,2,3或4个杂原子 作为环原子,其中苯基和杂环基团是未取代的或有1个,2个,3个或4个取代基R1A有; Z是共价键或CH 2基团; R12是氢,C1-C6烷基,C3-C6环烷基,C2-C6烯基,C5-C6环烯基,C2-C6炔基等; R2是氢,卤素,硝基,氰基,C1-C4烷基,C1-C4卤代烷基,C2-C4链烯基,C1-C4烷氧基,C1-C4卤代烷氧基,苄基或基团S(O)NR21, 其中R 21代表C1-C4烷基或C1-C4卤代烷基,n为0,1或2; R3是氢或卤素; R4是C1-C4烷基,C 3 -C 4 - 烯基或C 3 -C 4炔基; R5是氢,C1-C4烷基,C3-C4链烯基,C3-C4炔基或基团C(= O)R51,其中R51是氢,C1-C4烷基,C1-C4卤代烷基,C1 C4烷氧基或C1-C4卤代烷氧基; R6是C1-C4烷基,C1-C4-HydroxyalkyloderC1-C4卤代烷基; R7,R8独立地为氢,OH,C1-C4烷氧基,C1-C4 Haloalkyoxy,C1-C4烷基或C1-C4卤代烷基; R9,R10独立地选自氢,卤素,CN,NO2,C1-C4烷基,C1-C4卤代烷基,C2-C4链烯基,C1-C4烷氧基和C1-C4卤代烷氧基中选择; 和R11是氢或C1-C4烷基; 以及这些化合物的农业上适用的盐。
    • 5. 发明申请
    • PIPERAZINE COMPOUNDS WITH A HERBICIDAL ACTION
    • 用除草活性的哌嗪化合物
    • WO2008152073A3
    • 2009-02-12
    • PCT/EP2008057329
    • 2008-06-11
    • BASF SEHUPE EIKESEITZ THOMASWITSCHEL MATTHIASSONG DSCHUNMOBERG WILLIAM KARLPARRA RAPADO LILIANASTELZER FRANKVESCOVI ANDREANEWTON TREVOR WILLIAMREINHARD ROBERTSIEVERNICH BERNDGROSSMANN KLAUSEHRHARDT THOMASRACK MICHAELKIBLER ELMAR
    • HUPE EIKESEITZ THOMASWITSCHEL MATTHIASSONG DSCHUNMOBERG WILLIAM KARLPARRA RAPADO LILIANASTELZER FRANKVESCOVI ANDREANEWTON TREVOR WILLIAMREINHARD ROBERTSIEVERNICH BERNDGROSSMANN KLAUSEHRHARDT THOMASRACK MICHAELKIBLER ELMAR
    • C07D241/08A61K31/495C07D403/10C07D407/10C07D409/10C07D413/10C07D417/10
    • C07D241/08C07D403/10C07D407/10C07D409/10C07D413/10C07D417/10
    • The invention relates to piperazine compounds of the following defined general formula (I) and to their use as herbicides. The invention also relates to crop protection agents and to a method for combating undesired plant growth. In formula (I), the variables are defined as follows: R1 is selected from halogen, cyano, nitro, Z-C(=O)-R11, phenyl and a 5- or 6-membered heterocyclic group that has 1, 2, 3 or 4 heteroatoms, selected from O, N and S as ring atoms, wherein phenyl and the heterocyclic group are unsubstituted or have 1, 2, 3 or 4 substituents R1a; Z stands for a covalent bond or a CH2 group; R11 represents hydrogen, C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C5-C6 cycloalkenyl, C2-C6 alkynyl and similar; R2 represents hydrogen, halogen, nitro, cyano, C1-C4 alkyl, C1-C4 haloalkyl, C2- C4 alkenyl, C1-C4 alkoxy, C1-C4 haloalkoxy, benzyl or a group S(O) nR21, wherein R21 stands for C1-C4 alkyl or C1-C4 haloalkyl and n stands for 0, 1 or 2; R3 represents hydrogen or halogen; R4 represents C1-C4 alkyl, C3- C4 alkenyl or C3-C4 alkynyl; R5 represents hydrogen, C1-C4 alkyl, C3-C4 alkenyl, C3-C4 alkynyl or a group (=O)R51, wherein R51 stands for hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy or C1-C4 haloalkoxy; R6 stands for C1-C4 alkyl, C1-C4 hydroxy alkyl or C1-C4 haloalkyl; R7, R8 stand, independently of one another, for hydrogen, OH, C1-C4 alkoxy, C1-C4 haloalkyoxy, C1-C4 alkyl or C1-C4 haloalkyl; R9, R10 are selected, independently of one another, from hydrogen, halogen, CN, NO2, C1-C4 alkyl, C1-C4 haloalkyl, C2-C4 alkenyl, C1-C4alkoxy and C1-C4 haloalkoxy.
    • 本发明涉及如以下通式(I)中所定义的哌嗪化合物及其作为除草剂的用途。 本发明还涉及组合物用于作物保护和打击不需要的植物生长的方法。 在式(I)中,变量具有以下含义:R 1选自卤素,氰基,硝基,ZC(= O)-R 11,苯基中的含有1,2,3或4的5-或6-元杂环基团 由具有杂原子作为环原子,其中苯基和杂环基团是未取代的或具有O,N和S的1,2,3或4个具有取代基R1A; Z是共价键或CH 2基团; R11是氢,C1-C6烷基,C3-C6环烷基,C2-C6烯基,C5-C6环烯基,C2-C6炔基等; R2是氢,卤素,硝基,氰基,C1-C4烷基,C1-C4卤代烷基,C2-C4链烯基,C1-C4烷氧基,C1-C4卤代烷氧基,苄基或基团S(O)NR21, 其中R 21代表C1-C4烷基或C1-C4卤代烷基,n为0,1或2; R3是氢或卤素; R4是C1-C4烷基,C3-C4链烯基或C3-C4炔基; R5是氢,C1-C4烷基,C3-C4链烯基,C3-C4炔基或基团C(= O)R51,其中R51是氢,C1-C4烷基,C1-C4卤代烷基,C1 C4烷氧基或C1-C4卤代烷氧基; R6是C1-C4烷基,C1-C4羟烷基或C1-C4卤代烷基; R7,R8独立地为氢,OH,C1-C4烷氧基,C1-C4 Haloalkyoxy,C1-C4烷基或C1-C4卤代烷基; 和R9,R10独立地选自氢,卤素,CN,NO2,C1-C4烷基,C1-C4卤代烷基,C2-C4链烯基,C1-C4烷氧基和C1-C4卤代烷氧基中选择。
    • 9. 发明申请
    • HERBICIDAL COMPOSITION COMPRISING GLYPHOSATE, GLUFOSINATE OR THEIR SALTS
    • 包含糖苷,谷氨酸盐或其盐的除草组合物
    • WO2009141367A2
    • 2009-11-26
    • PCT/EP2009056105
    • 2009-05-20
    • BASF SESIEVERNICH BERNDMOBERG WILLIAM KARLSIMON ANJAWALTER HELMUTEVANS RICHARD R
    • SIEVERNICH BERNDMOBERG WILLIAM KARLSIMON ANJAWALTER HELMUTEVANS RICHARD R
    • A01N57/20A01N33/18A01N43/10A01N43/50A01N43/70A01N43/80
    • A01N43/80A01N33/18A01N37/40A01N43/10A01N43/40A01N43/50A01N43/54A01N43/68A01N43/76A01N43/84A01N57/20A01N43/70A01N43/86A01N61/00A01N2300/00
    • The present invention relates to a herbicidal compositon which comprises: a) at least one herbicide A selected from glyphosate, glufosinate and their salts, and b) a herbicide B which is 3-[5-(difluoromethoxy)-1 -methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone]. The present invention relates in particular to a herbicidal composition comprising: a) at least one herbicide A selected from glyphosate, glufosinate and their salts, b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol- 4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone], and c) at least one further herbicide C, which is selected from the herbicide groups C.1 to C.8: C.1 herbicides of the group of acetolactat synthase inhibitors (ALS inhibitors), C.2 herbicides of the group of protoporphyrinogen oxidase inhibitors (PPO inhibitors), C.3 herbicides of the group of auxines, C.4 herbicides of the group of 4-hydroxyphenyl-pyruvate-dioxygenase inhibitors (HPPD inhibitors), C.5 herbicides of the group of phytoene desaturase inhibitors (PDS inhibitors), C.6 herbicides of the group of photosystem Il inhibitors (PSII inhibitors), C.7 herbicides of the group of microtubulin inhibitors, and C.8 herbicides of the group of inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors).
    • 本发明涉及除草组合物,其包含:a)至少一种选自草甘膦,草铵膦及其盐的除草剂A,和b)除草剂B,其为3- [5-(二氟甲氧基)-1-甲基-3- (三氟甲基)吡唑-4-基甲基磺酰基] -4,5-二氢-5,5-二甲基-1,2-恶唑[通用名:pyroxasulfone]。 本发明特别涉及除草组合物,其包含:a)至少一种选自草甘膦,草铵膦及其盐的除草剂A,b)除草剂B,其为3- [5-(二氟甲氧基)-1-甲基-3- (三氟甲基)吡唑-4-基甲基磺酰基] -4,5-二氢-5,5-二甲基-1,2-恶唑[通用名:pyroxasulfone],和c)至少一种另外的除草剂C,其选自除草剂 组C.1至C.8:丙酰乳糖合成酶抑制剂(ALS抑制剂)组的C.1除草剂,原卟啉原氧化酶抑制剂(PPO抑制剂)组的C.2除草剂,营养素组的C.3除草剂 ,4-羟基苯基 - 丙酮酸 - 双加氧酶抑制剂(HPPD抑制剂)组的C.4除草剂,八氢番茄红素去饱和酶抑制剂(PDS抑制剂)组的C.5除草剂,光系统II抑制剂组的C.6除草剂 PSII抑制剂),微管蛋白抑制剂组的C.7除草剂和抑制剂组的C.8除草剂 的非常长链脂肪酸(VLCFA抑制剂)的合成。