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    • 3. 发明申请
    • SOLID STATE POLYMERIZATION PROCESS FOR POLYESTER
    • 聚酯固体状态聚合方法
    • WO2009000708A1
    • 2008-12-31
    • PCT/EP2008/057640
    • 2008-06-18
    • CIBA HOLDING INC.THOMPSON, Thomas FriendANDREWS, Stephen MarkODORISIO, Paul Angelo
    • THOMPSON, Thomas FriendANDREWS, Stephen MarkODORISIO, Paul Angelo
    • C08G63/16C08G63/80C08G63/85
    • C08G63/85C08G63/183C08G63/80C08G63/87
    • Disclosed is a method for increasing the solid state polymerization (SSP) rates of organic titanate catalyzed polyester. The method comprises in a first step, reacting a dicarboxylic acid or a C 1 -C 4 dicarboxylic diester with a diol at a suitable temperature and pressure to effect esterification or transesterification to prepare a precondensate and in a second step, reacting the precondensate to effect polycondensation at a suitable temperature and pressure to prepare a high molecular weight polyester and in a third step, further increasing the molecular weight and viscosity of the polyester under SSP conditions of a suitable temperature and pressure, where an organic titanate is added in the first step or in the second step as a reaction catalyst, and where a phosphinic acid compound is added in the first step, in the second step or just prior to the third step. The phosphinic acid compound is for example diisooctyl phosphinic acid. The polyester product exhibits low aldehyde formation during melt processing steps as well as excellent color.
    • 公开了增加有机钛酸酯催化聚酯的固态聚合(SSP)速率的方法。 该方法包括在第一步骤中,在合适的温度和压力下使二羧酸或C 1 -C 4二羧酸二酯与二醇反应以进行酯化或酯交换以制备预缩合物,并且在第二步中,使预缩合物与 合适的温度和压力以制备高分子量聚酯,并且在第三步中,在合适的温度和压力的SSP条件下进一步提高聚酯的分子量和粘度,其中在第一步中加入有机钛酸盐或在 作为反应催化剂的第二步骤,其中在第一步骤,第二步骤或第三步骤之前加入次膦酸化合物。 次膦酸化合物例如是二异辛基次膦酸。 聚酯产品在熔融加工步骤中表现出低醛形成以及优异的颜色。