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    • 3. 发明申请
    • RYLENE MONOIMIDE DERIVATES AND USE THEREOF AS PHOTOSENTIZERS IN SOLAR CELLS AND PHOTODETECTORS
    • 芳基单酰胺衍生物及其作为光电剂在太阳能电池和光电子体中的用途
    • WO2013118068A1
    • 2013-08-15
    • PCT/IB2013/050996
    • 2013-02-07
    • BASF SEMAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V.BASF (CHINA) COMPANY LIMITED
    • BENEDITO, Flavio LuizBRUDER, IngmarERK, PeterPSCHIRER, Neil GregorySEND, RobertMÜLLEN, KlausWONNEBERGER, HenrikeLI, Chen
    • C09K11/06H01L31/0256H01L31/04H01L51/42
    • H01L51/0053C07D471/04C07D491/04C09B5/62C09B57/001H01G9/2031H01G9/2059H01L51/0061H01L51/0072Y02E10/52Y02E10/549
    • The present invention relates to compounds of the formulae Ia,Ib and Ic in which R are identical or different aryloxy, arylthio, hetaryloxy, hetarylthio, aryl, diarylamino or dialkylamino radicals, n when m is 0: 0, 1, 2 or 3, when m is 1: 0, 1, 2, 3, 4 or 5, m is 0 or 1, A is -COOM, -SO 3 M or -PO 3 M, M is hydrogen, an alkali metal cation or [NR'] 4+ , R' is hydrogen or alkyl, where the R' radicals may be the same or different, B is C 1 -C 6 -alkylene or 1,4-phenylene, where the phenylene radical may be 2 mono-or polysubstituted by alkyl, nitro, cyano and/or halogen, L is a chemical single bond or a bridge of the formula -(Het)Ar-or –(Het)Ar-(Het)Ar- which may be mono-or polysubstituted by phenyl, alkyl, alkoxy, alkylthio and/or -NR 4 R 5 and in which (Het)Ar is aryl or hetaryl which may be fused to saturated or unsaturated 5-to 18-membered rings which maycomprise heteroatoms, where, in the case of two (Het)Ar, these may be the same or different, q is 0 or 1, R 1 , R 2 are each independently radicals of the formula IIa, IIb or IIc R 3 is phenyl, alkyl, alkoxy, alkylthio or -NR 6 R 7 , X is C(R 8 R 9 ) 2 , NR 10 , oxygen or sulfur, R 4 to R 10 are each independently hydrogen, alkyl whose carbon chain may be interrupted by one or more -O-, -S-, -CO-, -SO- and/or -SO 2 -moieties, or aryl or hetaryl, each of which may be mono-or polysubstituted by alkyl, alkoxy and/or alkylthio, p is 0, 1, 2, 3, 4 or 5, Y is NR 11 or sulfur, and R 11 is hydrogen, alkyl whose carbon chain may be interrupted by one or more -O-, -S-, -CO-, -SO- and/or -SO 2 -moieties, or aryl, hetaryl, aralkyl or hetaralkyl. The present invention further relates to the use of compounds of the formulae Ia, Ib and Ic or mixtures of compounds of the formulae Ia, Ib and Icand/or isomers thereof or mixtures of isomers of the compounds of the formulae Ia, Ib and Ic as photosensitizers in solar cells and photodetectors, and to solar cells and photodetectors comprising compounds of the formulae Ia, Ib and Ic or mixtures of compounds of the formulae Ia, Ib and Ic and/or isomers thereof or mixtures of isomers of the compounds of the formulae Ia, Ib and Ic as photosensitizers.
    • 本发明涉及式Ia,Ib和Ic的化合物,其中R是相同或不同的芳氧基,芳硫基,杂芳氧基,杂芳硫基,芳基,二芳基氨基或二烷基氨基,当m为0:0,1,2或3时, 当m为1:0,1,2,3,4或5时,m为0或1,A为-COOM,-SO3M或-PO3M,M为氢,碱金属阳离子或[NR'] 4+, R'是氢或烷基,其中R'基可以相同或不同,B是C 1 -C 6 - 亚烷基或1,4-亚苯基,其中亚苯基可以是被烷基,硝基,氰基单取代或多取代的2 和/或卤素,L是化学单键或式 - (Het)Ar-或 - (Het)Ar-(Het)Ar-的桥,其可以被苯基,烷基,烷氧基,烷硫基单 - 或多取代 和/或-NR4R5,其中(Het)Ar是芳族或杂芳基,其可以与可能是杂原子的饱和或不饱和的5至18元环稠合,其中在两(Het)Ar的情况下,这些可以是 相同或不同,q为0或1,R1,R2各自独立地为自由基 式IIa,IIb或IIc中的R 3是苯基,烷基,烷氧基,烷硫基或-NR 6 R 7,X是C(R 8 R 9)2,NR 10,氧或硫,R 4至R 10各自独立地是氢,其碳链可以是 被一个或多个-O - , - S-,-CO-,-SO-和/或-SO 2 - 基团间隔,或芳基或杂芳基,其中每一个可以被烷基,烷氧基和/或烷硫基单或多取代 ,p为0,1,2,3,4或5,Y为NR 11或硫,R 11为氢,碳链可被一个或多个-O - , - S - , - CO - , - SO - 和/或-SO 2 - 基团,或芳基,杂芳基,芳烷基或杂烷基。 本发明还涉及式Ia,Ib和Ic化合物或式Ia,Ib和Ic化合物或其异构体的混合物或式Ia,Ib和Ic化合物的异构体混合物的用途, 太阳能电池和光电检测器中的光敏剂,以及包含式Ia,Ib和Ic化合物或式Ia,Ib和Ic化合物和/或其异构体的化合物或其混合物或式的化合物的异构体混合物的太阳能电池和光电探测器 Ia,Ib和Ic作为光敏剂。
    • 4. 发明公开
    • RYLENE MONOIMIDE DERIVATES AND USE THEREOF AS PHOTOSENTIZERS IN SOLAR CELLS AND PHOTODETECTORS
    • RONLENMONOIMIDDERIVATE UND VERWENDUNG DAVON ALS光敏剂在SOLARZELLEN UND PHOTODETEKTOREN
    • EP2812412A1
    • 2014-12-17
    • EP13747029.0
    • 2013-02-07
    • BASF SEMax-Planck-Gesellschaft zur Förderung der Wissenschaften e.V.
    • BENEDITO, Flavio LuizBRUDER, IngmarERK, PeterPSCHIRER, Neil GregorySEND, RobertMÜLLEN, KlausWONNEBERGER, HenrikeLI, Chen
    • C09K11/06H01L31/0256H01L31/04H01L51/42
    • H01L51/0053C07D471/04C07D491/04C09B5/62C09B57/001H01G9/2031H01G9/2059H01L51/0061H01L51/0072Y02E10/52Y02E10/549
    • The present invention relates to compounds of the formulae Ia,Ib and Ic in which R are identical or different aryloxy, arylthio, hetaryloxy, hetarylthio, aryl, diarylamino or dialkylamino radicals, n when m is 0: 0, 1, 2 or 3, when m is 1: 0, 1, 2, 3, 4 or 5, m is 0 or 1, A is -COOM, -SO
      3 M or -PO
      3 M, M is hydrogen, an alkali metal cation or [NR']
      4+ , R' is hydrogen or alkyl, where the R' radicals may be the same or different, B is C
      1 -C
      6 -alkylene or 1,4-phenylene, where the phenylene radical may be 2 mono-or polysubstituted by alkyl, nitro, cyano and/or halogen, L is a chemical single bond or a bridge of the formula -(Het)Ar-or –(Het)Ar-(Het)Ar- which may be mono-or polysubstituted by phenyl, alkyl, alkoxy, alkylthio and/or -NR
      4 R
      5 and in which (Het)Ar is aryl or hetaryl which may be fused to saturated or unsaturated 5-to 18-membered rings which maycomprise heteroatoms, where, in the case of two (Het)Ar, these may be the same or different, q is 0 or 1, R
      1 , R
      2 are each independently radicals of the formula IIa, IIb or IIc R
      3 is phenyl, alkyl, alkoxy, alkylthio or -NR
      6 R
      7 , X is C(R
      8 R
      9 )
      2 , NR
      10 , oxygen or sulfur, R
      4 to R
      10 are each independently hydrogen, alkyl whose carbon chain may be interrupted by one or more -O-, -S-, -CO-, -SO- and/or -SO
      2 -moieties, or aryl or hetaryl, each of which may be mono-or polysubstituted by alkyl, alkoxy and/or alkylthio, p is 0, 1, 2, 3, 4 or 5, Y is NR
      11 or sulfur, and R
      11 is hydrogen, alkyl whose carbon chain may be interrupted by one or more -O-, -S-, -CO-, -SO- and/or -SO
      2 -moieties, or aryl, hetaryl, aralkyl or hetaralkyl. The present invention further relates to the use of compounds of the formulae Ia, Ib and Ic or mixtures of compounds of the formulae Ia, Ib and Icand/or isomers thereof or mixtures of isomers of the compounds of the formulae Ia, Ib and Ic as photosensitizers in solar cells and photodetectors, and to solar cells and photodetectors comprising compounds of the formulae Ia, Ib and Ic or mixtures of compounds of the formulae Ia, Ib and Ic and/or isomers thereof or mixtures of isomers of the compounds of the formulae Ia, Ib and Ic as photosensitizers.
    • 本发明涉及式Ia,Ib和Ic的化合物,其中R是相同或不同的芳氧基,芳硫基,苯氧基,杂芳硫基,芳基,二芳基氨基或二烷基氨基,n当m是0:0,1,2或3时, 当m为1:0,1,2,3,4或5时,m为0或1,A为-COOM,-SO3M或-PO3M,M为氢,碱金属阳离子或[NR'] 4+, R'是氢或烷基,其中R'可以相同或不同,B是C 1 -C 6 - 亚烷基或1,4-亚苯基,其中亚苯基可以是被烷基,硝基,氰基单取代或多取代的2 和/或卤素,L是化学单键或式 - (Het)Ar-或 - (Het)Ar-(Het)Ar-的桥,其可以被苯基,烷基,烷氧基,烷硫基单 - 或多取代 和/或-NR4R5,其中(Het)Ar是芳族或杂芳基,其可以与可能是杂原子的饱和或不饱和的5至18元环稠合,其中在两(Het)Ar的情况下,这些可以是 相同或不同,q为0或1,R 1,R 2各自独立地为自由基 式IIa,IIb或IIc的式中R3是苯基,烷基,烷氧基,烷硫基或-NR6R7,X是C(R8R9)2,NR10,氧或硫,R4至R10各自独立地是氢,碳链可以是 被一个或多个-O - , - S-,-CO-,-SO-和/或-SO 2 - 基团间隔,或芳基或杂芳基,其中每一个可以被烷基,烷氧基和/或烷硫基单或多取代 ,p为0,1,2,3,4或5,Y为NR 11或硫,R 11为氢,碳链可被一个或多个-O - , - S - , - CO - , - SO - 和/或-SO 2 - 基团,或芳基,杂芳基,芳烷基或杂烷基。 本发明还涉及式Ia,Ib和Ic化合物或式Ia,Ib和Ic化合物或其异构体的混合物或式Ia,Ib和Ic化合物的异构体混合物的用途, 太阳能电池和光电检测器中的光敏剂以及包含式Ia,Ib和Ic化合物或式Ia,Ib和Ic化合物和/或其异构体的化合物或其混合物或式的化合物的混合物的太阳能电池和光电探测器或式 Ia,Ib和Ic作为光敏剂。
    • 7. 发明申请
    • OPTICAL DETECTOR
    • 光学检测器
    • WO2016092454A1
    • 2016-06-16
    • PCT/IB2015/059411
    • 2015-12-07
    • BASF SEBASF (CHINA) COMPANY LIMITED
    • SEND, RobertBRUDER, IngmarVALOUCH, SebastianIRLE, StephanTHIEL, Erwin
    • G01C3/06
    • G01J1/4228G01C3/06G01J1/08G01J1/44G01S5/16G01S7/4816G01S11/12G01S17/023G01S17/46G02B7/32
    • An optical detector(110) is disclosed, comprising: at least one optical sensor(122) adapted to detect a light beam(120) and to generate at least one sensor signal, wherein the optical sensor(122) has at least one sensor region(124), wherein the sensor signal of the optical sensor(122) exhibits a non-linear dependency on an illumination of the sensor region(124) by the light beam (120) with respect to a total power of the illumination; at least one image sensor(128) being a pixelated sensor comprising a pixel matrix(174) of image pixels(176), wherein the image pixels(176) are adapted to detect the light beam(120) and to generate at least one image signal, wherein the image signal exhibits a linear dependency on the illumination of the image pixels(176) by the light beam(1,6) with respect to the total power of the illumination; and at least one evaluation device(132), the evaluation device(132) being adapted to evaluate the sensor signal and the image signal. In a particularly preferred embodiment, the non-linear dependency of the sensor signal on the total power of the illumination of the optical sensor(122) is expressible by a non-linear function comprising a linear part and a non-linear part, wherein the evaluation device(132) is adapted to determine the linear part and/or the non-linear part of the non-linear function by evaluating both the sensor signal and the image signal. Herein, the evaluation device(132), preferably, comprises a processing circuit(136) being adapted to provide a difference between the sensor signal and the image signal for determining the non-linear part of the non-linear function.
    • 公开了一种光学检测器(110),包括:适于检测光束(120)并产生至少一个传感器信号的至少一个光学传感器(122),其中所述光学传感器(122)具有至少一个传感器区域 (124),其中所述光学传感器(122)的传感器信号相对于所述照明的总功率对所述光束(120)的所述传感器区域(124)的照明呈现非线性依赖性; 至少一个图像传感器(128)是像素化传感器,其包括图像像素(176)的像素矩阵(174),其中图像像素(176)适于检测光束(120)并且生成至少一个图像 信号,其中所述图像信号相对于所述照明的总功率表现出由所述光束(1,6)对所述图像像素(176)的照明的线性依赖性; 和至少一个评估装置(132),评估装置(132)适于评估传感器信号和图像信号。 在特别优选的实施例中,传感器信号对光学传感器(122)的照明的总功率的非线性依赖性可由包括线性部分和非线性部分的非线性函数表示,其中, 评估装置(132)适于通过评估传感器信号和图像信号来确定非线性函数的线性部分和/或非线性部分。 这里,评估装置(132)优选地包括处理电路(136),其适于提供传感器信号和图像信号之间的差异,用于确定非线性函数的非线性部分。
    • 8. 发明申请
    • VERIFICATION DEVICE, VERIFICATION SYSTEM AND METHOD FOR VERIFYING THE IDENTITY OF AN ARTICLE
    • 验证设备,验证系统和验证文章标识的方法
    • WO2015159247A1
    • 2015-10-22
    • PCT/IB2015/052769
    • 2015-04-16
    • BASF SEBASF (CHINA) COMPANY LIMITED
    • SEND, RobertBRUDER, IngmarIRLE, StephanTHIEL, Erwin
    • G07D7/20
    • G07D7/12B42D25/21B42D25/378G07D7/121H01G9/2059H01L51/42
    • A verification device (110) for verifying the identity of an article (114) is disclosed. The verification device (110) comprises: at least one illumination source (116) for illuminating at least one safety mark (124) of the article (114) with at least one light beam (122); at least one detector (118) adapted for detecting after an interaction of the light beam (122) with the safety mark (124), the detector (118) having at least one optical sensor (128), wherein the optical sensor (128) has at least one sensor region (130), wherein the optical sensor (128) is designed to generate at least one sensor signal in a manner dependent on an illumination of the sensor region (130) by the light beam (122), wherein the sensor signal, given the same total power of the illumination,is dependent on a beam cross-section of the light beam (122) in the sensor region (130); and at least one evaluation device (120) adapted for evaluating the sensor signal and for verifying the identity of the article (114) on the basis of the sensor signal. Further, a verification system (112), a method for verifying the identity of an article (114) and a use of an optical sensor (128) for verifying the identity of an article (114) are disclosed.
    • 公开了一种用于验证物品(114)的身份的验证装置(110)。 验证装置(110)包括:用至少一个光束(122)照射物品(114)的至少一个安全标记(124)的至少一个照明源(116); 至少一个检测器(118)适于在所述光束(122)与所述安全标记(124)的相互作用之后检测,所述检测器(118)具有至少一个光学传感器(128),其中所述光学传感器(128) 具有至少一个传感器区域(130),其中所述光学传感器(128)被设计成以取决于由所述光束(122)照射所述传感器区域(130)的方式产生至少一个传感器信号,其中, 给定相同的照明总功率的传感器信号取决于传感器区域(130)中的光束(122)的光束横截面; 以及适于基于所述传感器信号来评估所述传感器信号和用于验证所述物品(114)的身份的至少一个评估装置(120)。 此外,公开了一种验证系统(112),用于验证物品(114)的身份的方法和用于验证物品(114)的身份的光学传感器(128)的使用。
    • 9. 发明申请
    • DATA READOUT DEVICE FOR READING OUT DATA FROM A DATA CARRIER
    • 用于从数据载体读取数据的数据读出设备
    • WO2015150989A1
    • 2015-10-08
    • PCT/IB2015/052233
    • 2015-03-26
    • BASF SEBASF (CHINA) COMPANY LIMITED
    • SEND, RobertBRUDER, IngmarIRLE, StephanTHIEL, Erwin
    • G11B7/135
    • G11B7/13G11B7/1362G11B2007/0013
    • A data readout device (114) for reading out data from at least one data carrier (112) having data modules (116) located at least two different depths within the at least one data carrier (112) is disclosed. The data readout device (114) comprises: -at least one illumination source (122) for directing at least one light beam (124) onto the data carrier (112); -at least one detector (130) adapted for detecting at least one modified light beam modified by at least one of the data modules (116), the detector (130) having at least one optical sensor (132), wherein the optical sensor (132)has at least one sensor region (134), wherein the optical sensor (132)is designed to generate at least one sensor signal in a manner dependent on an illumination of the sensor region (134)by the modified light beam, wherein the sensor signal, given the same total power of the illumination,is dependent on a beam cross-section of the modified light beam in the sensor region (134); and -at least one evaluation device (136) adapted for evaluating the at least one sensor signal and for deriving data stored in the at least one data carrier (112) from the sensor signal. Further, a data storage system (110), a method for reading out data from at least one data carrier (112) and a use of an optical sensor (132) for reading out data are disclosed.
    • 公开了一种用于从至少一个数据载体(112)读出数据的数据读出装置(114),该数据载体(112)具有位于至少一个数据载体(112)内的至少两个不同深度的数据模块(116)。 数据读出装置(114)包括:至少一个照明源(122),用于将至少一个光束(124)引导到数据载体(112)上; - 至少一个检测器(130),其适于检测由数据模块(116)中的至少一个修改的至少一个修改的光束,所述检测器(130)具有至少一个光学传感器(132),其中所述光学传感器 132)具有至少一个传感器区域(134),其中所述光学传感器(132)被设计成以取决于所述修改的光束的所述传感器区域(134)的照明的方式产生至少一个传感器信号,其中, 给定相同的照明总功率的传感器信号取决于传感器区域(134)中修改的光束的光束横截面; 以及 - 至少一个评估装置(136),其适于评估所述至少一个传感器信号并且用于从所述传感器信号导出存储在所述至少一个数据载体(112)中的数据。 此外,公开了一种数据存储系统(110),用于从至少一个数据载体(112)读出数据的方法和用于读出数据的光学传感器(132)的使用。