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    • 3. 发明申请
    • REACTIVE DYES, PROCESSES FOR THEIR PREPARATION AND THEIR USE
    • 反应性染料及其制备方法及其使用
    • WO2009053238A3
    • 2009-12-17
    • PCT/EP2008063373
    • 2008-10-07
    • HUNTSMAN ADV MAT SWITZERLANDTZIKAS ATHANASSIOSVERDUGO THOMASROENTGEN GEORG
    • TZIKAS ATHANASSIOSVERDUGO THOMASROENTGEN GEORG
    • C09B62/503C09B62/465C09B67/22
    • C09B62/5033C09B62/465C09B67/004
    • Reactive dyes of the formula (1) in which Q1 is hydrogen, halogen or a radical of the formula (2a) or (2b),R1, R2 and R3 independently of one another are hydrogen or C1-C4alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato, and R1 in formula (1) and R1 in formula (2a) have identical or different meanings and R2 in formula (1) and R2 in formula (2a) have identical or different meanings, (R4)0-1 and (R5)0-1 independently of one another are 0 or 1 identical or different substituents from the group consisting of C1-C4alkyl, C1-C4alkoxy, halogen and sulfo, A is hydrogen or C1-C4alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato, phenyl which is unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, carbamoyl, sulfo or halogen, phenyl-C1-C2alkylene which is unsubstituted or substituted in the phenyl ring by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, sulfo, carbamoyl or halogen, or C5-C7cycloalkyl which is unsubstituted or substituted by C1-C4alkyl, B is a C2-C12alkylene radical which can be interrupted by 1, 2 or 3 members from the group consisting of -NH-, -N(CH3)- or -O- and is unsubstituted or substituted by hydroxyl, sulfo, sulfato, cyano or carboxyl, a C5-C7cycloalkylene radical or C1-C2alkylene-C5-C7cycloalkylene radical which are unsubstituted or substituted in the cycloalkylring by C1C4alkyl,C1C2alkylenephenylene radical or phenylene radical which are unsubstituted or substituted in the phenyl ring by C1C4alkyl, C1C4alkoxy, C2-C4alkanoylamino, sulfo, halogen or carboxyl, V1 and V2 independently of one another are halogen, T is a radical of the formula -CO-(CH2)m-SO2-Y (3a), -CO-CH(HaI)-CH2-HaI (3b) or -CO-C(HaI)=CH2 (3c), Hal is halogen, X is hydroxyl or Y, Y is vinyl or a radical -CH2-CH2-U and U is a group which can be split off under alkaline conditions, and m is the number 2, 3 or 4. are suitable for dyeing widely varying fibre materials, in particular cellulosic fibre materials, and produce dyeings with good allround properties.
    • 其中Q1是氢,卤素或式(2a)或(2b)的基团的式(1)的反应性染料是R 1,R 2和R 3彼此独立的氢或C 1 -C 4烷基,其未被取代或被 羟基,磺基,羧基或硫酸根,式(1)中的R 1和式(2a)中的R 1具有相同或不同的含义,式(1)中的R 2和式(2a)中的R 2具有相同或不同的含义, 0-1和(R5)0-1彼此独立地是0或1个与C1-C4烷基,C1-C4烷氧基,卤素和磺基基团相同或不同的取代基,A是氢或未被取代的C 1 -C 4烷基 被羟基,磺基,羧基或硫酸根取代的苯基,未被取代或被C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 4烷酰基氨基,羟基,羧基,氨基甲酰基,磺基或卤素取代的苯基,未取代或取代的苯基-C 1 -C 2亚烷基 C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 4烷酰基氨基,羟基,羧基,磺基,氨基甲酰基的苯环 1或卤素,或未被取代或被C 1 -C 4烷基取代的C 5 -C 7环烷基,B为C2-C12亚烷基,其可以被-NH-,-N(CH 3) - 或-O-,并且是未取代的或被羟基,磺基,硫酸基,氰基或羧基取代的C 5 -C 7亚环烷基或C 1 -C 2亚烷基-C 5 -C 7亚环烷基,其未被取代或被被C 1 -C 4烷基,C 1 -C 2亚烷基亚苯基或亚苯基取代的环烷基 C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 4烷酰基氨基,磺基,卤素或羧基,V 1和V 2彼此独立地在苯环中被取代或取代的基团是卤素,T是式-CO-(CH 2)m - SO2-Y(3a),-CO-CH(HaI)-CH2-HaI(3b)或-CO-C(HaI)= CH2(3c),Hal是卤素,X是羟基或Y,Y是乙烯基或 基团-CH 2 -CH 2 -U和U是在碱性条件下可以分离的基团,m是2,3或4号,适用于广泛变化的纤维的染色 特别是纤维素纤维材料,并产生具有良好全面性能的染色。
    • 5. 发明申请
    • REACTIVE DYES, THEIR PREPARATION AND THEIR USE
    • 活性染料,它们的制备和它们的用途
    • WO2007017425A3
    • 2007-04-05
    • PCT/EP2006064937
    • 2006-08-02
    • HUNTSMAN ADV MAT SWITZERLANDCHRISTNACHER HUBERT JEAN LUCTZIKAS ATHANASSIOSROENTGEN GEORG
    • CHRISTNACHER HUBERT JEAN LUCTZIKAS ATHANASSIOSROENTGEN GEORG
    • C09B62/04C09B62/515C09D11/02
    • C09B62/043C09B62/4416Y10S8/918
    • Reactive dyes of formula (1), wherein B is an aliphatic bridging member, R 1 is C 1 -C 4 alkyl, halogen or an -SO 2 -Z radical, R 2 and R 3 are each independently of the other C 1 -C 4 alkoxy, R 4 , R 5 and R 6 are each independently of the others hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, k and q are each independently of the other the number O or 1 , p is the number O, 1 or 2, X 1 and X 2 are each independently of the other halogen, and T is halogen, a non-fibre-reactive substituent or a fibre-reactive radical of formula (2a), (2b), (2c), (2d), (2e) or (2f), wherein (R 7 ) 0-2 denotes from O to 2 identical or different substituents from the group halogen, C 1 -C 4 alkyl, C 1 C 4 alkoxy and sulfo, Z is vinyl or a -CH 2 -CH 2 -U radical and U is a group that is removable under alkaline conditions, Q is a -CH(Hal)-CH 2 -HaI or -C(Hal)=CH 2 group and Hal is halogen, or T is a radical of formula (3), wherein R 1 , R 2 , R 3 , R 4 , k, p and q each have the definitions given above, are suitable especially for dyeing cotton and yield dyeings having good all-round fastness properties.
    • 式(1)的活性染料,其中B是脂族桥连成员,R 1是C 1 -C 4烷基,卤素或 -SO 2 -Z基团,R 2 SUB 3和R 3各自独立于另一个C 1 -C 1 -C R 4,R 5,R 5,和R 6各自独立地为氢或未被取代的或被取代的 C 1 -C 4烷基,k和q各自独立地是数字0或1,p是数字0,1或2,X (2a),(2b)的非纤维反应性取代基或纤维反应性基团的卤素,其中R 1和X 2各自独立于其它卤素,并且T为卤素, ,(2c),(2d),(2e)或(2f),其中(R 7)0-2表示O至2个相同或不同的 基团卤素,C 1 -C 4烷基,C 1 -C 4烷氧基和磺基,Z为乙烯基或 -CH 2 SUB-2 -U基团,并且U是基团 在碱性条件下可除去,Q为-CH(Hal)-CH 2 -Hal或-C(Hal)= CH 2 SUB基团,Hal为卤素或T为 式(3)的基团,其中R 1,R 2,R 3,R 4,k,k, ,p和q各自具有上面给出的定义,特别适用于具有良好的全面牢度性能的染色棉和产量染色。
    • 6. 发明申请
    • RED REACTIVE DYES, THEIR PREPARATION AND THEIR USE
    • 红色反应性染料及其制备及其使用
    • WO2008017615A3
    • 2008-11-27
    • PCT/EP2007057873
    • 2007-07-31
    • HUNTSMAN ADV MAT SWITZERLANDROENTGEN GEORGFEKETE LASZLO
    • ROENTGEN GEORGFEKETE LASZLO
    • C09B62/44C09D11/00D06P1/38
    • C09B62/4415C09D11/17C09D11/18C09D11/32C09D11/328D06P1/382D06P3/663D06P5/30
    • Reactive dyes of formula (1) wherein R1 and R2 independently of one another are hydrogen or unsubstituted or substituted C1- C4alkyl, D is a radical of a diazo component of the formula (2a) or (2b) X1 and X2 independently of one another are halogen, T is a fibre-reactive radical of the formula (3a) -NH-(CH2)2-3-SO2-Z, (3b) -NH-(CH2)2-3-O-(CH2)2-3-SO2-Z, (3c), (3d), (3e), (3f) or (3g), (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a -CH2-CH2-U radical and U is a group that is removable under alkaline conditions, Q is a -CH(Hal)-CH2-Hal or -C(Hal)=CH2 group, Hal is halogen, n is the number 0, 1 or 2, and m and q are independently of one another the number 0 or 1, are suitable for dyeing cellulosic or amide-group-containing fibre materials.
    • 式(1)的反应性染料,其中R 1和R 2彼此独立地是氢或未取代的或取代的C 1 -C 4烷基,D是式(2a)或(2b)的重氮组分的基团,X 1和X 2彼此独立地 T是具有式(3a)-NH-(CH2)2-3-SO2-Z,(3b)-NH-(CH2)2-3-O-(CH2)2- 3-SO 2 -Z,(3c),(3d),(3e),(3f)或(3g),(R3)0-2表示0-2个与卤素,C 1 -C 4烷基, C1-C4烷氧基和磺基,Z是乙烯基或-CH2-CH2-U基团,U是在碱性条件下可除去的基团,Q是-CH(Hal)-CH 2 - Hal或-C(Hal)= CH 2 基团,Hal是卤素,n是数字0,1或2,m和q彼此独立地是数字0或1,适用于染色含纤维素或含酰胺基的纤维材料。
    • 9. 发明申请
    • MIXTURES OF FIBRE-REACTIVE DYES AND THEIR USE IN A METHOD FOR DI- OR TRICHROMATIC DYEING OR PRINTING
    • 纤维反应性染料的混合物及其在二色或三色染色或印刷方法中的用途
    • WO2011101185A9
    • 2012-03-29
    • PCT/EP2011050397
    • 2011-01-13
    • HUNTSMAN ADV MAT SWITZERLANDTZIKAS ATHANASSIOSROENTGEN GEORGCASARTELLI MARCOCODEMO REMOLANDRE JEAN-FRANCOIS
    • TZIKAS ATHANASSIOSROENTGEN GEORGCASARTELLI MARCOCODEMO REMOLANDRE JEAN-FRANCOIS
    • C09B67/22C09B62/513D06P1/38D06P3/66
    • C09B62/513C09B62/4413C09B62/4415C09B67/0042C09B67/0047C09B67/0052D06P1/38D06P3/663Y10S8/917Y10S8/918Y10S8/919Y10S8/924Y10S8/926
    • Dye mixtures, comprising at least one red dyeing dye of the formula (1) and at least one blue, yellow, orange or brown dyeing dye from the group of the formulae (2), (3), (4), (5) and (6), wherein B is an aliphatic bridging member, R1, R3 and R8 are each independently of the others hydrogen or C1-C4alkyl, R2, R4, R5, R9, R11, R12, R13, R14, R15 and R16 are each independently of the others hydrogen, C1-C4alkyl, C1-C4alkoxy or sulfo, R6 and R10 are each independently of the other amino or C1-C4alkyl, (R7)j denotes j identical or different substituents selected from the group C2-C4alkanoylamino, ureido, C1-C4alkyl and C1-C4alkoxy, (R17)i denotes i identical or different substituents selected from the group C2-C4alkanoylamino, ureido, sulfo, C1-C4alkyl and C1-C4alkoxy, X1, X2, X3, X4, X5 and X6 are each independently of the others halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, Z1, Z2 and Z3 are each independently of the others a fibre-reactive group of the formula -SO2-Y8, (7a) or -NH-CO-(CH2)2-3-SO2-Y9 (7b), Y1, Y2, Y3, Y4, Y5, Y6, Y7, Y8 and Y9 are each independently of the others vinyl or a radical -CH2-CH2-U and U is a group removable under alkaline conditions, i, j, k and l are each independently of the other the number 0, 1 or 2, m is the number 1 or 2, n and u are each independently of the other the number 1, 2 or 3, p and q are each independently of the other the number 0 or 1, r and s are each independently of the other the number 0 or 1, and t is the number 0, 1 or 2, and the sum of r, s and t is 2 or 3 are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
    • 包含至少一种式(1)的红染色剂和至少一种式(2),(3),(4),(5)的基团的蓝,黄,橙或棕染色染料的染料混合物, 和(6)其中B是脂族桥连构件,R 1,R 3和R 8各自独立地为氢或C 1 -C 4烷基,R 2,R 4,R 5,R 9,R 11,R 12,R 13,R 14,R 15和R 16为 各自独立地为氢,C 1 -C 4烷基,C 1 -C 4烷氧基或磺基,R 6和R 10各自独立地为其它氨基或C 1 -C 4烷基,(R 7)j表示相同或不同的选自C 2 -C 4烷酰基氨基, 脲基,C 1 -C 4烷基和C 1 -C 4烷氧基,(R 17)i表示相同或不同的选自C 2 -C 4烷酰基氨基,脲基,磺基,C 1 -C 4烷基和C 1 -C 4烷氧基,X 1,X 2,X 3,X 4,X 5和 X 6各自独立地为卤素,3-羧基吡啶-1-基或3-氨基甲酰基吡啶-1-基,Z1,Z2和Z3各自独立地为式-SO2-Y8的纤维反应性基团( 7A) 或-NH-CO-(CH2)2-3-SO2-Y9(7b),Y1,Y2,Y3,Y4,Y5,Y6,Y7,Y8和Y9各自独立地为乙烯基或基团-CH2- CH2-U和U是在碱性条件下可除去的基团,i,j,k和l各自独立于数字0,1或2中的另一个,m是数字1或2,n和u各自独立地为 数字1,2或3中的另一个,p和q各自独立于数字0或1中的另一个,r和s各自独立于数字0或1中的另一个,并且t是数字0,1或2, r,s和t的总和为2或3,特别适用于纤维素纤维材料的二色或三色染色或印花,并且具有良好的再现性和良好的全面牢固性能的产量染色或印花。