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    • 4. 发明申请
    • METHOD FOR PRODUCING RANDOM RADICAL COPOLYMERS AND CORRESPONDING ACTIVE INGREDIENT COMPOSITIONS OBTAINABLE THEREFROM
    • 用于生产统计自由基共聚物和那些可活性化合物
    • WO2010063672A3
    • 2010-08-05
    • PCT/EP2009066042
    • 2009-11-30
    • BASF SETUERK HOLGERDIELEMANN CEDRICBOHRMANN HANS-GUENTERKOLTZENBURG SEBASTIAN
    • TUERK HOLGERDIELEMANN CEDRICBOHRMANN HANS-GUENTERKOLTZENBURG SEBASTIAN
    • C08F2/04A01N25/04C08F220/58
    • A01N25/10A01N43/653A01N47/24C08F2/04C08F2/06C08F220/06C08F220/18C08F220/56C08F220/58A01N2300/00
    • The invention relates to a method for producing random radical copolymers, characterized by the following steps: a) dissolving by heating a) at least one olefinically unsaturated sulfonic acid of formula (I); wherein n is 0 to 10; X represents O or NR5; R1 represents hydrogen or methyl; R2, R3 independently represent hydrogen or C1 to C6 alkyl and R5 represents hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, wherein the aryl groups can be mono- or polysubstituted, the salts thereof or mixtures of acid and salts and b) at least two structurally distinct olefinically unsaturated monomers of formula (II), wherein Y represents O or NR7; R5 represents hydrogen or methyl; R6 represents alkyl, hydroxyalkyl, (di)alkylaminoalkyl or (di)alkylaminoaryl and R7 represents hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, and c) optionally one or more olefinically unsaturated monomers which can be structurally distinct from components (a) and (b), and at least one initiator, either (i) in a solvent mixture which contains water and a solvent having a boiling point below 140°C and being soluble in water, or (ii) in one or more pure alcohols, and polymerizing said mixture in solution, the copolymer formed also remaining dissolved. The copolymers obtainable according to the above method are suitable as formulation adjuvants in agrochemical active ingredient compositions.
    • 一种用于无规自由基共聚物的制备方法的特征在于:a)式(I),其中n为0至10中的至少一个烯属不饱和磺酸; X是O或NR5; R1是氢或甲基; R2,R3独立地是氢或C1-C6烷基和R5是氢,烷基,芳基,烷基,芳基烷基,烷氧基烷基,芳氧基烷基,烷氧基芳基,羟烷基,(二)烷基氨基烷基,(二)烷基氨基芳基,(二)芳基氨基,Alkylarylaminoalkyl或alkylarylaminoaryl ,其中该芳基基团可以被取代一次或多次,平均它们的盐或酸和盐,和b)至少两种结构不同的式(II),其中Y是O或NR 7的烯属不饱和单体的混合物; R5是氢或甲基; R 6是烷基,羟烷基,(二)烷基氨基烷基或(二)烷基氨基芳基,并且R 7是氢,烷​​基,芳基,烷基,芳基烷基,烷氧基烷基,芳氧基烷基,烷氧基芳基,羟烷基,(二)烷基氨基烷基,(二)烷基氨基芳基,(二)芳基氨基,Alkylarylaminoalkyl 平均值或alkylarylaminoaryl,其中该芳基基团可以被取代一次或多次,和c)任选的一种或多种烯属不饱和单体,其在结构上是从组分(a)和(b)是不同的,d)至少一种引发剂无论是在(I) 溶剂混合物包含水和具有140℃以下的沸点的水溶性有机溶剂,溶解或(ii)在通过加热和聚合在溶液中,其中所形成的共聚物也溶解溶解一种或多种纯的醇。 通过该方法获得的共聚物适合作为农业化学活性成分组合物中的制剂助剂。
    • 8. 发明申请
    • METHOD AND DEVICE FOR ANALYZING THE HARDENING OF HARDENABLE FORMULATIONS
    • 方法和设备进行调查固化固化配方
    • WO03029784A2
    • 2003-04-10
    • PCT/EP0210910
    • 2002-09-27
    • BASF AGSCHROF WOLFGANGMUELLER THORSTENKOLTZENBURG SEBASTIANKRONER MATTHIASLEHMANN STEPHANHADELER JOACHIM
    • SCHROF WOLFGANGMUELLER THORSTENKOLTZENBURG SEBASTIANKRONER MATTHIASLEHMANN STEPHANHADELER JOACHIM
    • G01N11/00G01N3/00G01N3/06G01N3/42
    • G01N3/42G01N2203/0092G01N2203/0682
    • The invention relates to a method for combined analysis of the hardening of hardenable liquid or viscous formulations, wherein (a) n hardenable formulations are provided in parallel in n containers, and (b) at least one degree of hardening is determined for each of the n formulations, wherein a measuring tip is inserted into the formulation with a determined amount of force and the maximum penetration depth thus obtained is taken as a measure of the degree of hardening of said formulations, and (c) one or several parameters characterizing the hardening kinetics are determined for a respective composition of the formulations from the measured values for the depths of penetration at various times after the production of the formulations . Preferably, steps (a) - (c) are carried out on several occasions and by analyzing the large number of individual values of the parameters characterizing the hardening characteristics thus obtained, it is possible to ascertain the dependency of the characteristic parameter(s) in relation to the composition of the formulations, whereupon the composition of the formulations can be optimized with regard to the hardening behavior thereof.
    • 本发明涉及一种方法,用于在其中设置在平行于正固化配方可固化液体或粘性制剂的固化的组合研究ÑBehäitern的(a)和(b)固化的程度anjeder所述n制剂至少一次测定, 通过测量末端以一定的力刺穿制剂和达到制剂的固化度的最大穿透深度AIS度量被测量,和制备所述制剂的后(c)对于每个由用于在不同时间的穿透深度的测量值的制剂的组合物的 或固化参数的动力学的多个特征被确定第二十 根据所述步骤(a)(c)是优选进行多次,它是由这样获得的大量的一种或硬化参数的动力学特性的个体值的分析来确定是的函数,或制剂的组合物的特征参数 由此制剂的组合物可以相对于它们的固化行为进行优化。