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    • 1. 发明申请
    • HALOGEN-FREE, PHOSPHOROUS-CONTAINING, FLAME-PROTECTED POLYMER FOAMS
    • 无卤素,无磷阻燃聚合物泡沫
    • WO2011095540A2
    • 2011-08-11
    • PCT/EP2011051550
    • 2011-02-03
    • BASF SEHAHN KLAUSKRIHA OLAFBELLIN INGOSPIES PATRICKFUCHS SABINEDEGLMANN PETERMASSONNE KLEMENSDENECKE HARTMUTFLECKENSTEIN CHRISTOPHJANSSENS GEERTHOFMANN MAXIMILIANDOERING MANFREDMICHAEL CIESIELSKIWAGNER JOCHEN
    • HAHN KLAUSKRIHA OLAFBELLIN INGOSPIES PATRICKFUCHS SABINEDEGLMANN PETERMASSONNE KLEMENSDENECKE HARTMUTFLECKENSTEIN CHRISTOPHJANSSENS GEERTHOFMANN MAXIMILIANDOERING MANFREDMICHAEL CIESIELSKIWAGNER JOCHEN
    • C08J9/00
    • C08J9/0038C08J9/0066C08J2325/04C08K5/53
    • The invention relates to a polymer foam having a density in the range between 5 and 120 kg/m3, containing a) a polymer component, containing at least one styrene polymer, b) 0.1 to 5 parts by weight (relative to 100 parts by weight of component a)) of a flame retardant mixture, containing b1) at least one phosphorus compound of formula (I) having a phosphorus content in the range between 5 and 80% by weight, relative to the phosphorus compound, (X1)s =PR1R2R3 (I), where the symbols and indices in formula (I) have the following meanings: R1 is C1-C16-alkyl, C1-C10-hydroxyalkyl, C2-C16-alkenyl, C1-C16-alkoxy, C2-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9, COR10, COOR11, CONR12R13; R2 is C1-C16-alkyl, C1-C10-hydroxyalkyl, C2-C16-alkenyl, C1-C16-alkoxy, C2-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryl-C1-C16-alkyl,C6-C10-aryl-C1-C16-alkoxy, SR9, COR10, COOR11, CONR12R13;R3 is H, SH, SR4, OH, OR5 or a group 30 -(Y1)n-[P(= X2)uR6 -(Y2)n]m-P(= X3)tR7R8; or two groups R1, R2, R3 together with the phosphorus atom to which they are bound form a ring system; X1, X2 and X3 are independently of each other identically or differently O or S; Y1, Y2 are identically or differently O or S; R4, R5, R9, R10, R11, R12,R13 are identically or differently C1-C12-alkyl, C3-C8-cycloalkyl, which is unsubstituted or substituted by one or more C1-C4-alkyl groups, C2-C12-alkenyl, C2-C12-alkinyl, C6-C10-aryl or C6-C10-aryl C1-C4-alkyl; R6, R7, R8 are independently of each other identically or differently C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9, COR10, COOR11, CONR12R13; n is 1, if Y1 or Y2 is O, and 1, 2, 3, 4, 5, 6, 7 or 8, if Y1 or Y2 is S; m is a whole number between 0 and 100; s, t and u are independently of each other 0 or 1; and b2) elementary sulphur.
    • 阻燃剂混合物,其包含b1的一)),其包括含有至少一种苯乙烯聚合物的聚合物组分,B)(基于具有在5〜120千克/米3范围内的密度,A聚合物泡沫)0.1至5重量份每100重量份组分的) 在式(I)具有在5的范围内的磷含量到80重量%的至少一种磷化合物,基于磷化合物(X1)S = PR1R2R3(I),其中,在式(I)中的符号和指数具有以下含义 有:R1是C1-C16烷基,C1-C10羟基烷基,C2-C16烯基,C1-C16烷氧基,C2-C16-链烯氧基,C3-C10环烷基,C3-C10环烷氧基,C6-C10 芳基,C6-C10芳氧基,C6-C10芳基C1-C16烷基,C6-C10芳基C1-C16烷氧基,SR9,COR 10,COOR 11,CONR 12 R 13; R2是C1-C16烷基,C1-C10羟基烷基,C2-C16烯基,C1-C16烷氧基,C2-C16-链烯氧基,C3-C10环烷基,C3-C10环烷氧基,C6-C10芳基, C6-C10芳基C1-C16烷基,C6-C10芳基C1-C16烷氧基,SR9,COR 10,COOR 11,CONR 12 R 13; R 3是H,SH,SR 4,OH,OR 5或Gruppe30 - (Y1) N- [P(= X2)UR6 - (Y2)N] MP(= X3)tR7R8;或两个基团R1,R2,与磷原子R3一起形成它们所连接形成环系统; X 1,X 2和X 3相同或不同且彼此独立地为O或S; Y1,Y2是相同或不同的O或S; R4,R5,R9,R10,R11,R12,R13为相同或不同的C1-C12烷基,C3-C8环烷基,其未被取代或者被一个或多个C1-C4烷基取代,C2-C12链烯基, C 2 -C 12炔基,C 6 -C 10芳基或C 6 -C 10芳基-C 1 -C 4烷基; R6,R7,R8是相同的或彼此独立地C1-C16烷基,C1-C16链烯基,C1-C16烷氧基,C1-C16-链烯氧基,C3-C10环烷基,C3-C10环烷氧基,C6-C10的不同 芳基,C6-C10芳氧基,C6-C10芳基C1-C16烷基,C6-C10芳基C1-C16烷氧基,SR9,COR 10,COOR 11,CONR 12 R 13; 如果Y1或Y2是O,n是1,如果Y1或Y1是1,则为1,2,3,4,5,6,7或8。 Y2是S; m是0至100的整数; s,t和u独立地为0或1; 和b2)元素硫。
    • 2. 发明申请
    • METHOD FOR PRODUCING EXPANDABLE GRANULATES CONTAINING POLYLACTIC ACID
    • 生产可膨胀含聚丙烯酸颗粒的方法
    • WO2011086030A2
    • 2011-07-21
    • PCT/EP2011050129
    • 2011-01-06
    • BASF SEFUESL ANDREASSAMPATH BANGARUHOFMANN MAXIMILIANBELLIN INGONALAWADE SAMEERHAHN KLAUSKUENKEL ANDREASLOOS ROBERT
    • FUESL ANDREASSAMPATH BANGARUHOFMANN MAXIMILIANBELLIN INGONALAWADE SAMEERHAHN KLAUSKUENKEL ANDREASLOOS ROBERT
    • C08L67/04C08J9/16
    • C08J9/127C08J9/0061C08J9/16C08J9/18C08J2333/14C08J2367/02C08J2367/04C08J2463/00C08J2467/02C08L33/068C08L67/02C08L67/04C08L2666/02
    • The invention relates to a method for producing expandable granulates containing polylactic acid, comprising the following steps: a) melting and mixing the constituents i) between 50 and 99.9 wt. %, relative to the total weight of constituents i) to iii), of polylactic acid, ii) between 0 and 49.9 wt. %, relative to the total weight of constituents i) to iii), of at least one other polymer, iii) between 0.1 and 2 wt. %, relative to the total weight of constituents i) to iii), of a diepoxide or polyepoxide, and iv) between 0 and 10 wt. % of at least one additive, b) mixing v) between 3 and 7 wt. %, relative to the total weight of constituents i) to iv), of an organic blowing agent, into the melted polymer mass, by means of a static or dynamic mixer, at a temperature of at least 40°C, c) discharging the mixture via a nozzle plate with boreholes having a maximum on the nozzle outlet diameter of 1.5 mm, and d) granulating the melted mass containing the blowing agent directly behind the nozzle plate, under water, at a pressure of between 1 and 20 bar. The invention also relates to expandable granulates containing polylactic acid, that can be obtained according to said method, and to special expandable granulates containing polylactic acid, and between 3 and 7 wt. % of an organic blowing agent, preferably n-pentane, and especially preferably iso-pentane. The invention also relates to a preferred method for producing expandable granulates containing polylactic acid and a blowing agent, with a low bulk density.
    • 本发明涉及一种用于制备可膨胀含聚乳酸的颗粒的方法,包括步骤:a)熔化并混合各组分ⅰ)50〜99.9重量%,基于组分的总重量,I至III),聚乳酸二 )0至49.9重量%,基于组分的总重量,i至iii)中,一种或多种其它聚合物,ⅲ)从0.1至2重量%,基于组分的总重量,i至iii)中, 二环氧化物或聚环氧化物和iv)0至10重量%的一种或多种添加剂%,b)将v)的3至7重量%,基于组分的总重量的I至IV)有机发泡剂到聚合物熔体借助于 在至少40℃的温度下的静态或动态混合器,c)通过用造粒孔,其直径在模出口至多1.5毫米,和d)的模板排出吹直接熔融超过管芯板未剂含有 在1到20巴范围内的压力下进行。 此外,本发明涉及通过该方法和特殊可膨胀含聚乳酸的颗粒与3〜7重量的有机发泡剂的重量%,优选正戊烷和更优选异戊烷的比例获得的可膨胀的含聚乳酸的颗粒。 此外,本发明涉及制备具有低堆积密度的含推进剂的可膨胀聚乳酸颗粒的优选方法。
    • 9. 发明申请
    • MICROWAVE-ASSISTED SETTING OF SHAPED CERAMIC/FOAM BODIES
    • 形状陶瓷/泡沫体的微波辅助设置
    • WO2010076170A2
    • 2010-07-08
    • PCT/EP2009067079
    • 2009-12-14
    • BASF SENEHLS BENJAMINSCHMIED BERNHARDMAHN ULRIKEHAHN KLAUSWIELAND PETRAFUCHS SABINEULANOVA TATIANAFRANCIS TIMOTHYBAUMGAERTNER KLAUS-MARTINMUEGGE HORST
    • NEHLS BENJAMINSCHMIED BERNHARDMAHN ULRIKEHAHN KLAUSWIELAND PETRAFUCHS SABINEULANOVA TATIANAFRANCIS TIMOTHYBAUMGAERTNER KLAUS-MARTINMUEGGE HORST
    • C08J9/232B01J19/12B27N3/00B29C35/08B29C44/10C08J9/236
    • C08J9/236B29C35/0805B29C67/205B29C2035/0855C08J9/232H05B6/80H05B2206/046
    • The invention relates to a method for the production of shaped foam bodies, comprising: provision of a composition having foam particles and binder; introduction of the composition into a space which is bounded on at least one side by a pressing surface; and exertion of pressure onto the composition by means of the pressing surface. The method further irradiation of microwaves through the pressing surface into the composition, while pressure is being exerted onto the composition. The invention furthermore relates to a device for carrying out the method according to the invention, having: at least one pressing surface and a counterbearing surface lying opposite, between which a space extends which is adapted to receive a composition of foam particles and binder. The pressing surface and counterbearing surface adjoin the space directly. The device further comprises at least one stiff layer which locally or entirely is essentially transparent for microwaves and has a surface facing toward the space, which is connected to the pressing surface in such a way as to transmit force. The device also comprises a microwave radiator unit which is arranged on a side of the stiff layer remote from the space and is aligned relative to the space in order to irradiate microwaves into the space through the stiff layer. Lastly, the invention relates to a microwave radiator unit for the heat treatment of foam compositions. The microwave radiator unit comprises a multiplicity of microwave antennas which are arranged in a plane array and at least two of which are connected through a distributor device to a common microwave signal source, which feeds the at least two antennas.
    • 本发明涉及一种用于生产成型泡沫体的方法,其包括:提供具有泡沫颗粒和粘合剂的组合物; 将组合物引入由至少一侧通过挤压表面界定的空间中; 并借助于挤压表面对组合物施加压力。 该方法进一步将微波通过压制表面照射到组合物中,同时将压力施加到组合物上。 本发明还涉及一种用于执行根据本发明的方法的装置,该装置具有:至少一个压制表面和一个相对的承载表面,在所述承载表面之间延伸有空间,该空间适于接收泡沫颗粒和粘合剂的组合物。 按压表面和承重表面直接连接空间。 该装置进一步包括至少一个局部或完全对于微波来说基本上透明的刚性层,并且具有面向该空间的表面,该表面以这样的方式连接到按压表面以便传递力。 该装置还包括微波辐射器单元,该微波辐射器单元布置在刚性层的远离该空间的一侧上,并相对于该空间对齐,以便通过该刚性层将微波辐射到该空间中。 最后,本发明涉及用于泡沫组合物的热处理的微波辐射器单元。 微波辐射器单元包括多个微波天线,微波天线以平面阵列布置,并且其中至少两个微波天线通过分配器装置连接到公共微波信号源,该微波信号源馈送至少两个天线。