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1. 发明申请

WO2015121785A1 GRAPHENE NANORIBBONS WITH CONTROLLED ZIG-ZAG EDGE AND COVE EDGE CONFIGURATION 审中-公开
标题翻译：具有控制的ZIG-ZAG边缘和COVE边缘配置的石墨纳米尼
公开(公告)号：WO2015121785A1
公开(公告)日：2015-08-20
申请号：PCT/IB2015/050951
申请日：2015-02-09
申请人： BASF SE , EMPA- EIDGENÖSSISCHE MATERIALPRÜFUNGS- UND FORSCHUNGSANSTALT , MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. , BASF (CHINA) COMPANY LIMITED
发明人： SCHWAB, Matthias Georg , MÜLLEN, Klaus , FENG, Xinliang , YANG, Bo , DUMSLAFF, Tim , FASEL, Roman , RUFFIEUX, Pascal , LIU, Jia , CAI, Jinming , SANCHEZ-SANCHEZ, Carlos , LIU, Junzhi
IPC分类号： C07C15/20 , C01B31/04 , C08G61/10 , B82Y40/00
CPC分类号： C08G61/10 , C01B32/184 , C01B2204/06 , C07C15/20 , C07C25/22 , C08G2261/312 , C08G2261/314 , C08G2261/72 , C08G2261/724
摘要： Provided are graphene nanoribbons with controlled zig-zag edge and cove edge configuration and methods for preparing such graphene nanoribbons. The nanoribbons are selected from the following formulae.
摘要翻译：提供了具有可控曲折边缘和凸缘边缘配置的石墨烯纳米带以及用于制备这种石墨烯纳米带的方法。纳米带选自下列公式。

2. 发明申请

WO2013175342A1 GRAPHENE NANORIBBONS WITH CONTROLLED MODIFICATIONS 审中-公开
标题翻译：具有控制修饰的石墨纳米级
公开(公告)号：WO2013175342A1
公开(公告)日：2013-11-28
申请号：PCT/IB2013/053886
申请日：2013-05-13
申请人： BASF SE , EMPA , MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. , BASF SCHWEIZ AG , BASF (CHINA) COMPANY LIMITED
发明人： FASEL, Roman , RUFFIEUX, Pascal , MÜLLEN, Klaus , CAI, Jinming , FENG, Xinliang , BERGER, Reinhard
IPC分类号： B82B3/00
CPC分类号： C07D403/10 , B82Y30/00 , B82Y40/00 , C01B32/182 , C01B32/184 , C01B2204/06 , C01B2204/065 , C07D209/56 , C07D215/18 , C07D237/26 , C07D239/72
摘要： The present invention relates to a graphene nanoribbon, comprising a repeating unit which comprises at least one modification,wherein the modification is selected from a heteroatomic substitution, a vacancy, a sp 3 hybridization, a Stone-Wales defect, an inverse Stone-Wales defect, a hexagonal sp 2 hybridized carbon network ring size modification, and any combination thereof.
摘要翻译：本发明涉及石墨烯纳米棒，其包含重复单元，其包含至少一个修饰，其中所述修饰选自杂原子取代，空位，sp3杂交，石 - 威尔斯缺陷，反石 - 威尔斯缺陷，六角形sp2杂化碳网络环尺寸修改，以及它们的任何组合。

3. 发明申请

WO2013093756A1 POLYMERIC PRECURSORS FOR PRODUCING GRAPHENE NANORIBBONS AND METHODS FOR PREPARING THEM 审中-公开
标题翻译：用于生产石墨纳米粒的聚合物前体及其制备方法
公开(公告)号：WO2013093756A1
公开(公告)日：2013-06-27
申请号：PCT/IB2012/057377
申请日：2012-12-17
申请人： BASF SE , MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. , BASF CHINA COMPANY LIMITED , SCHWAB, Matthias Georg , NARITA, Akimitsu , FENG, Xinliang , MÜLLEN, Klaus
发明人： SCHWAB, Matthias Georg , NARITA, Akimitsu , FENG, Xinliang , MÜLLEN, Klaus
IPC分类号： C01B31/04 , C01B31/02
CPC分类号： C01B31/0446 , B82Y30/00 , B82Y40/00 , C01B32/184 , C07C49/683 , C08F2/00 , C08F138/00 , C08G61/10 , C08G2261/1412 , C08G2261/312 , C08G2261/364 , C08G2261/46 , C08G2261/91 , C08G2261/92 , C08G2261/95 , C08L65/00 , H01B1/04 , Y10S977/734 , Y10S977/842 , Y10S977/932
摘要： An oligophenylene monomer of general formula (I) wherein R 1 and R 2 are independently of each other H, halogene, -OH, -NH 2 , -CN, -NO 2 or a linear or branched, saturated or unsaturated C 1 -C 40 hydrocarbon residue, which can be substituted 1-to 5-fold with halogene (F, Cl, Br, I), -OH, -NH 2 , -CN and/or -NO 2 , and wherein one or more CH 2 -groups can be replaced by -O-or -S-, or an optionally substituted aryl, alkylaryl or alkoxyaryl residue; and m represents 0, 1 or 2.
摘要翻译：通式（I）的低聚苯乙烯单体，其中R 1和R 2彼此独立地为H，卤素，-OH，-NH 2，-CN，-NO 2或直链或支链，饱和或不饱和的C 1 -C 40烃残基，其可以是用卤素（F，Cl，Br，I），-OH，-NH 2，-CN和/或-NO 2取代1至5倍，并且其中一个或多个CH 2基团可以被-O-或 - S-或任选取代的芳基，烷基芳基或烷氧基芳基; m表示0,1或2。

4. 发明申请

WO2014097015A1 GRAPHENE-BASED IN-PLANE SUPERCAPACITORS 审中-公开
标题翻译：基于石墨的内置超级计算机
公开(公告)号：WO2014097015A1
公开(公告)日：2014-06-26
申请号：PCT/IB2013/060269
申请日：2013-11-20
申请人： BASF SE , MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. , BASF SCHWEIZ AG , BASF (CHINA) COMPANY LIMITED
发明人： SCHWAB, Matthias Georg , MÜLLEN, Klaus , FENG, Xinliang , WU, Zhong-Shuai
IPC分类号： H01G11/84 , H01G11/26 , H01G11/32 , B32B7/00 , B32B37/00
CPC分类号： H01G11/84 , H01G11/26 , H01G11/32 , Y02E60/13
摘要： The present invention relates to a process for preparing a supercapacitor, comprising the following steps: (a) preparing a graphene film on a substrate S1, (b) optionally transferring the graphene film to a substrate S2, which is different from the substrate S1, (c) preparing in-plane graphene electrodes of interdigital structure and at least one current collector of interdigital structure by (c1) providing a mask on the graphene film, wherein the mask has a mask pattern which leaves at least one graphene area of interdigital structure uncovered, (c2) applying the current collector onto the graphene area of interdigital structure and removing the mask, (c3) removing the parts of the graphene film which are not covered by the current collector, (d)adding an electrolyte such that the electrolyte is in contact with the in-plane graphene electrodes of interdigital structure.
摘要翻译：本发明涉及制备超级电容器的方法，包括以下步骤：（a）在衬底S1上制备石墨烯膜，（b）任选地将石墨烯膜转移到与衬底S1不同的衬底S2上，（c）通过（c1）在所述石墨烯膜上提供掩模来制备叉指结构的面内石墨烯电极和至少一个叉指结构的集电器，其中所述掩模具有留下至少一个叉指结构的石墨烯区域的掩模图案（c2）将集电体施加到叉指结构的石墨烯区域并除去掩模，（c3）除去未被集电体覆盖的石墨烯膜的部分，（d）添加电解质，使得电解质与交叉指向结构的面内石墨烯电极接触。

5. 发明申请

WO2014076634A1 POLYMERIC PRECURSORS FOR PRODUCING GRAPHENE NANORIBBONS AND SUITABLE OLIGOPHENYLENE MONOMERS FOR PREPARING THEM 审中-公开
标题翻译：用于生产石墨纳米粒子的聚合物前体和适用的制备他们的二乙烯基单体
公开(公告)号：WO2014076634A1
公开(公告)日：2014-05-22
申请号：PCT/IB2013/060075
申请日：2013-11-12
申请人： BASF SE , MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. , BASF (CHINA) COMPANY LIMITED
发明人： MÜLLEN, Klaus , FENG, Xinliang , CAI, Jinming , RUFFIEUX, Pascal , FASEL, Roman , NARITA, Akimitsu
IPC分类号： C07C15/14 , C07C15/12 , C07C15/20 , C07C15/30 , C07C25/18 , C07C309/66 , C07C245/20 , C01B31/04 , C08G61/10
CPC分类号： C08G61/121 , B82Y40/00 , C01B32/182 , C01B32/184 , C01B2204/06 , C01B2204/22 , C07C25/18 , C08G61/10 , C08G2261/148 , C08G2261/312 , C08G2261/314 , C08G2261/414 , C08G2261/72 , C08G2261/91 , C08G2261/92 , C08G2261/95 , H01L51/102 , H01L51/441 , H01L51/5206 , H01L51/5221
摘要： The invention relates to oligophenylene monomers of general formula I, wherein R 1 is H, halogene, -OH, -NH 2 , -CN,-NO 2 , or a linear or branched, saturated or un-saturated C 1 -C 40 hydrocarbon residue, which can be substituted 1-to 5-fold with halogene (F, Cl, Br, I), -OH, -NH 2 , -CN and/or -NO 2 , and wherein one or more CH 2 -groups can be replaced by -O-, -S-, -C(O)O-, -O-C(O)-, -C(O)-, -NH-or – NR 3 -, wherein R 3 is an optionally substituted C 1 -C 40 hydrocarbon residue, or an optionally substituted aryl, alkylaryl, alkoxyaryl, alkanoyl or aroyl residue; R 2a and R 2b are H, or optionally one or more of the pairs of adjacent R 2a /R 2b is joined to form a single bond in a six-membered carbocycle; m is an integer of from 0 to 3; n is 0 or 1; and X is halogene or trifluoromethylsulfonate, and Y is H; or X is H, and Y is halogene or trifluoromethylsulfonate. The invention further relates to polymeric precursors as well as methods for preparing graphene nanoribbons from the oligophenylene monomers and the polymeric precur- sors.
摘要翻译：本发明涉及通式I的低聚苯乙烯单体，其中R 1是H，卤素，-OH，-NH 2，-CN，-NO 2或直链或支链，饱和或不饱和的C 1 -C 40烃残基，其可以是用卤素（F，Cl，Br，I），-OH，-NH 2，-CN和/或-NO 2取代1至5倍，并且其中一个或多个CH 2 - 可以被-O - ， - S，-C（O）O-，-OC（O） - ， - C（O） - ， - NH-或-NR 3 - ，其中R 3是任选取代的C 1 -C 40烃残基或任选取代的芳基，烷基芳基，烷氧基芳基，烷酰基或芳酰基残基; R2a和R2b是H或任选的一对或多个相邻的R 2a / R 2b结合形成六元碳环中的单键; m为0〜3的整数; n为0或1; X为卤素或三氟甲基磺酸盐，Y为H; 或X为H，Y为卤素或三氟甲磺酸酯。本发明还涉及聚合物前体以及从低聚苯乙烯单体和聚合物前体制备石墨烯纳米带的方法。

6. 发明申请

WO2013061258A1 GRAPHENE NANORIBBON PRECURSORS AND MONOMERS SUITABLE FOR PREPARATION THEREOF 审中-公开
标题翻译：石墨纳米比亚前驱物和适合其制备的单体
公开(公告)号：WO2013061258A1
公开(公告)日：2013-05-02
申请号：PCT/IB2012/055845
申请日：2012-10-24
申请人： BASF SE , MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. , BASF (CHINA) COMPANY LIMITED , SCHWAB, Matthias Georg Schwab , MUELLEN, Klaus , FENG, Xinliang , DOESSEL, Lukas
发明人： SCHWAB, Matthias Georg Schwab , MUELLEN, Klaus , FENG, Xinliang , DOESSEL, Lukas
IPC分类号： C07C15/14 , C01B31/04
CPC分类号： C08G61/10 , B82Y30/00 , B82Y40/00 , C01B32/184 , C01B2204/06 , C01B2204/065 , C07C15/14 , C07C17/30 , C07C25/18 , C08G2261/1412 , C08G2261/148 , C08G2261/312 , C08G2261/314 , C08G2261/412 , H01L51/0045 , H01L51/0558 , H01L51/102
摘要： Provided are graphene nanoribbon precursors comprising repeated units of the general formula (I) in which R 1 , R 2 are each H, halogen, -OH, -NH 2 , -CN, -NO 2 or a hydrocarbyl radical which has 1 to 40 carbon atoms and may be linear or branched, saturated or unsaturated and mono- or poly-substituted by halogen (F, CI, Br, I), -OH, -NH 2 , -CN, and/or -NO 2 , where one or more CH 2 groups may also be replaced by -O-, -S-, -C(O)O-, -O-C(O)-, -C(O)-, -NH- or -NR-, in which R is an optionally substituted C 1 C 40 -hydrocarbyl radical, or an optionally substituted aryl, alkylaryl or alkoxyaryl radical. (I).
摘要翻译：提供了包含通式（I）的重复单元的石墨烯纳米纤维前体，其中R 1，R 2各自为H，卤素，-OH，-NH 2，-CN，-NO 2或具有1至40个碳原子的烃基，是直链或支链的，饱和或不饱和的，被卤素（F，Cl，Br，I），-OH，-NH 2，-CN和/或-NO 2单取代或多取代，其中一个或多个CH 2基团也可以被-O - ， - S - ， - C（O）O-，-OC（O） - ， - C（O） - ， - NH-或-NR-取代，其中R是任选取代的C 1 -C 40 - 烃基或任选取代的芳基，烷基芳基或烷氧基芳基。（一世）。

7. 发明申请

WO2014097032A1 EDGE HALOGENATION OF GRAPHENE MATERIALS 审中-公开
标题翻译：石墨材料的边缘蚀刻
公开(公告)号：WO2014097032A1
公开(公告)日：2014-06-26
申请号：PCT/IB2013/060563
申请日：2013-12-02
申请人： BASF SE , MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. , BASF SCHWEIZ AG , BASF (CHINA) COMPANY LIMITED
发明人： HINTERMANN, Tobias , MÜLLEN, Klaus , FENG, Xinliang , TAN, Yuan-Zhi
IPC分类号： C01B31/00 , C01B31/02 , C01B31/30
CPC分类号： H01L29/1606 , C01B32/192 , C01B32/194 , C07C17/02 , H01B1/04
摘要： The present invention relates to a process for edge-halogenation of a graphene material; wherein the graphene material, which is selected from graphene, a graphene nanoribbon, a graphene molecule, or a mixture thereof, is reacted with a halogen- donor compound in the presence of a Lewis acid, so as to obtain an edge-halogenated graphene material.
摘要翻译：本发明涉及石墨烯材料的边缘卤化方法; 其中选自石墨烯，石墨烯纳米棒，石墨烯分子或其混合物中的石墨烯材料在路易斯酸存在下与卤素给体化合物反应，以获得边缘卤化石墨烯材料。

8. 发明申请

WO2013132388A1 AEROGEL BASED ON DOPED GRAPHENE 审中-公开
标题翻译：基于DOPED GRAPHENE的AIRGEL
公开(公告)号：WO2013132388A1
公开(公告)日：2013-09-12
申请号：PCT/IB2013/051542
申请日：2013-02-26
申请人： BASF SE , MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. , BASF (CHINA) COMPANY LIMITED
发明人： SCHWAB, Matthias Georg , MÜLLEN, Klaus , FENG, Xinliang , WU, Zhong-Shuai
IPC分类号： C01B31/04 , C01B31/00
CPC分类号： H01G11/24 , B82Y30/00 , B82Y40/00 , C01B32/182 , C01B32/192 , H01G11/32 , H01G11/36 , H01G11/56 , H01M4/90 , H01M4/96 , Y02E60/13
摘要： The present invention relates to an aerogel based on doped graphene, a method for producing said aerogel and the use of said aerogel, for example, as an electrode or a catalyst. Furthermore, the present invention relates to electrodes, all solid-state supercapacitors (ASSS) or catalysts based on said aerogel.The present invention also relates to doped graphene, which can be obtained as an intermediate in the production of the aerogel based on doped graphene using graphene oxide as starting material.
摘要翻译：本发明涉及一种基于掺杂石墨烯的气凝胶，一种制备所述气凝胶的方法和所述气凝胶的使用，例如电极或催化剂。此外，本发明涉及电极，所有固态超级电容器（ASSS）或基于所述气凝胶的催化剂。本发明还涉及掺杂石墨烯，其可以作为基于掺杂石墨烯生产气凝胶的中间体而获得使用氧化石墨烯作为原料。

9. 发明申请

WO2013061256A1 OLIGOPHENYLENE MONOMERS AND POLYMERIC PRECURSORS FOR PRODUCING GRAPHENE NANORIBBONS 审中-公开
标题翻译：邻苯二甲酸单体和聚合物前驱体用于生产石墨纳米粒子
公开(公告)号：WO2013061256A1
公开(公告)日：2013-05-02
申请号：PCT/IB2012/055843
申请日：2012-10-24
申请人： BASF SE , MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. , BASF (CHINA) COMPANY LIMITED , IVANOVICI, Sorin , SCHWAB, Matthias Georg Schwab , FENG, Xinliang , MÜLLEN, Klaus
发明人： IVANOVICI, Sorin , SCHWAB, Matthias Georg Schwab , FENG, Xinliang , MÜLLEN, Klaus
IPC分类号： C07C15/14 , C07C15/12 , C07C15/20 , C07C15/28 , C07C15/30 , C07C25/18 , C07C309/66 , C07C245/20 , C01B31/04 , C08G61/10
CPC分类号： C01B31/0446 , B82Y30/00 , B82Y40/00 , C01B32/182 , C01B32/184 , C01B2204/06 , C01B2204/065 , C07C17/093 , C07C17/263 , C07C17/30 , C07C17/361 , C07C25/18 , C07C2603/42 , C07C2603/54 , C08G61/10 , C08G2261/148 , C08G2261/312 , C08G2261/412 , Y10S977/734 , Y10S977/842 , C07C25/22 , C07C25/24
摘要： Oligophenylene monomers for the synthesis of polymeric precursors for the preparation of graphene nanoribbons, the polymeric precursors, and methods for preparing them, as well as methods for preparing the graphene nanoribbons from the polymeric precursors and the monomers are provided.
摘要翻译：提供用于合成制备石墨烯纳米带的聚合物前体的亚乙基单体，聚合物前体及其制备方法，以及从聚合物前体和单体制备石墨烯纳米带的方法。

10. 发明申请

WO2010000670A1 HIGH PERFORMANCE SOLUTION PROCESSABLE SEMINCONDUCTOR BASED ON DITHIENO [2,3-D:2',3'-D']BENZO[1,2-B:4,5-B'] DITHIOPHENE 审中-公开
标题翻译：基于DITHIENO [2,3-D：2'，3'-D'] BENZO [1,2-B：4,5-B']二氢苯的高性能溶液可处理的SEMINCONUCTOR
公开(公告)号：WO2010000670A1
公开(公告)日：2010-01-07
申请号：PCT/EP2009/057985
申请日：2009-06-25
申请人： BASF SE , MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. , KASTLER, Marcel , KOEHLER, Silke , MUELLEN, Klaus , GAO, Peng , BECKMANN, Dirk , FENG, Xinliang
发明人： KASTLER, Marcel , KOEHLER, Silke , MUELLEN, Klaus , GAO, Peng , BECKMANN, Dirk , FENG, Xinliang
IPC分类号： C07D495/12
CPC分类号： H01L51/0074 , C07D495/22 , C09K11/06 , C09K2211/1011 , C09K2211/1092 , G02B2006/12069 , H01L51/0545 , H01L51/5048 , H05B33/10 , H05B33/14 , Y02E10/549
摘要： Dithienobenzodithiophenes of general formula (I) in which R 1 to R 6 are each independently selected from a) H, b) halogen, c) -CN, d) -NO 2 , e) - OH, f) a C 1-20 alkyl group, g) a C 2-20 alkenyl group, h) a C 2-20 alkynyl group, i) a C 1-20 alkoxy group, j) a C 1-20 alkylthio group, k) a C 1-20 haloalkyl group, I) a -Y- C 3-10 cycloalkyl group, m) a -Y-C 6-14 aryl group, n) a -Y-3-12 membered cyclo- heteroalkyl group, or o) a -Y-5-14 membered heteroaryl group, wherein each of the C 1-20 alkyl group, the C 2-20 alkenyl group, the C 2-20 alkynyl group, the C 3-10 cycloalkyl group, the C 6-14 aryl group, the 3-12 membered cyc- loheteroalkyl group, and the 5-14 membered heteroaryl group is optionally substituted with 1 -4 R 7 groups, wherein R 1 and R 3 and R 2 and R 4 may also together form an aliphatic cyclic moiety, Y is independently selected from divalent a C 1-6 alkyl group, a divalent C 1 - 6 haloalkyl group, or a covalent bond; and m is independently selected from 0, 1, or 2. The invention also relates to the use of the dithienobenzodithiophenes according to any of claims 1 to 4 as semiconductors or charge transport materials, as thin-film transistors (TFTs), or in semiconductor components for organic light-emitting diodes (OLEDs), for photovoltaic components or in sensors, as an electrode material in batteries, as optical waveguides or for electrophotography applications.
摘要翻译：通式（I）的二噻吩并苯并二噻吩，其中R 1至R 6各自独立地选自a）H，b）卤素，c）-CN，d）-NO 2，e）-OH，f）C 1-20烷基，）C2-20烯基，h）C2-20炔基，i）C1-20烷氧基，j）C1-20烷硫基，k）C1-20卤代烷基，I）a -Y- C3-10环烷基，m）a-Y-C6-14芳基，n）a -Y-3-12元环杂烷基，或o）-Y-5-14元杂芳基，其中各 C 1-20烷基，C 2-20烯基，C 2-20炔基，C 3-10环烷基，C 6-14芳基，3-12元环杂烷基，和5-14 任选被1-4个R 7基团取代，其中R 1和R 3以及R 2和R 4也可以一起形成脂族环状部分，Y独立地选自二价C 1-6烷基，二价C 1-6卤代烷基，或共价键; 并且m独立地选自0,1或2.本发明还涉及根据权利要求1至4中任一项所述的二噻吩并苯并噻吩作为半导体或电荷传输材料，作为薄膜晶体管（TFT）或半导体用于有机发光二极管（OLED）的组件，用于光伏组件或传感器，作为电池中的电极材料，作为光波导或电子照相应用。

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