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1. 发明申请

WO2015014826A1 REVERSE-PHASE POLYMERISATION PROCESS 审中-公开
标题翻译：反相聚合方法
公开(公告)号：WO2015014826A1
公开(公告)日：2015-02-05
申请号：PCT/EP2014/066255
申请日：2014-07-29
申请人： BASF SE
发明人： HASCHICK, Robert , JELICIC, Aleksandra , BARRATT, John, Scott , HESSE, Pascal , SOETJE, Oliver , FONSECA ZEPEDA, Gabriela, Eugenia , KEELAPANDAL RAMAMOORTHY, Shankara Narayanan , LANGLOTZ, Björn
IPC分类号： C08F2/32 , C08F20/56
CPC分类号： C08F220/56 , B01J19/123 , B01J19/24 , B01J2219/0869 , B01J2219/1203 , B01J2219/24 , C08F2/32 , C08F220/06 , C08F220/20 , C08F226/10 , C08F2220/382 , C08F2220/385 , C08F220/34
摘要： A reverse-phase suspension polymerisation process for the manufacture of polymer beads comprising forming aqueous monomer beads comprising an aqueous solution of water-soluble ethylenically unsaturated monomer or monomer blend and polymerising the monomer or monomer blend to form polymer beads while suspended in a non-aqueous liquid, and recovering polymer beads, in which the process comprises, providing in a vessel (1) a volume (2) of non-aqueous liquid wherein the volume of non-aqueous liquid extends between at least one polymer bead discharge point (3) and at least one monomer feed point (4), feeding the aqueous monomer or monomer blend through orifices (5) into, or onto, the non-aqueous liquid to form aqueous monomer beads, allowing the aqueous monomer beads to flow towards the polymer bead discharge point subjecting the aqueous monomer beads to polymerisation conditions to initiate polymerisation to form polymerising beads, wherein the polymerising beads have formed polymer beads when they reach the polymer bead discharge point, removing a suspension of the polymer beads in non-aqueous liquid from the vessel at the polymer bead discharge point and recovering water soluble or water swellable polymer beads from the suspension. The invention also relates to the apparatus suitable for carrying out a reverse-phase suspension polymerisation and polymer beads obtainable by the process or employing the apparatus.
摘要翻译：一种用于制备聚合物珠粒的反相悬浮聚合方法，包括形成包含水溶性烯属不饱和单体或单体共混物的水溶液的含水单体珠粒，并将单体或单体共混物聚合以形成聚合物珠粒，同时悬浮在非水性液体和回收的聚合物珠，其中该方法包括在容器（1）中提供非水性液体的体积（2），其中非水性液体的体积在至少一个聚合物珠粒排出点（3）和至少一个单体进料点（4），通过孔（5）将含水单体或单体共混物进料到非水性液体中或其上，以形成含水单体珠，使单体水单体流向聚合物珠粒放电点使含水单体珠粒聚合条件以引发聚合以形成聚合珠粒，其中聚合珠粒已形成聚合物珠粒当它们到达聚合物珠粒排放点时，在聚合物珠粒排出点处从容器中除去非水液体中的聚合物珠子的悬浮液并从悬浮液中回收水溶性或水可溶胀的聚合物珠粒。本发明还涉及适用于进行反相悬浮聚合的装置和可通过该方法获得的聚合物珠粒，或采用该装置。

2. 发明申请

WO2016120818A1 TRANSPORTATION OF POLYMERIC BEAD PRODUCTS 审中-公开
标题翻译：聚合物珠粒产品的运输
公开(公告)号：WO2016120818A1
公开(公告)日：2016-08-04
申请号：PCT/IB2016/050428
申请日：2016-01-28
申请人： BASF SE , BASF (CHINA) COMPANY LIMITED
发明人： BARRATT, John , JELICIC, Aleksandra , HASCHICK, Robert , SOETJE, Oliver
IPC分类号： C08F2/32 , C08F20/56
CPC分类号： C08F2/32 , C08F20/56 , C08F220/56 , C08F220/34
摘要： Transportation of Polymeric Bead Products A method of transportation of a polymer product from a first location to a second location in which the transportation comprises at least one of the group consisting of: (a) conveyance in a vehicle for at least 50 km; and/or (b) conveyance in at least one conduit in which the polymer product comprises water soluble or water swellable polymer beads, wherein the water soluble or water swellable polymer beads are obtainable by a process comprising a reverse-phase suspension polymerisation comprising forming aqueous monomer beads of an aqueous solution comprising water-soluble ethylenically unsaturated monomer or monomer blend and polymerising the monomer or monomer blend, to form polymer beads while suspended in a non-aqueous liquid, and recovering polymer beads, in which the process comprises providing in a vessel (1) a volume (2) of non-aqueous liquid wherein the volume of non-aqueous liquid extends between at least one polymer bead discharge point (3) and at least one monomer feed point (4), feeding the aqueous monomer or monomer blend through orifices (5) into, or onto, the non- aqueous liquid to form aqueous monomer beads, allowing the aqueous monomer beads to flow towards the polymer bead discharge point initiating polymerisation of the aqueous monomer beads to form polymerising beads, wherein the polymerising beads have formed polymer beads when they reach the polymer bead discharge point, removing a suspension of the polymer beads in non-aqueous liquid from the vessel at the polymer bead discharge point and recovering, water soluble or water swellable polymer beads from the suspension, in which the aqueous monomer or monomer blend and/or the orifices is/are vibrated such that the frequency multiplied by the weight average droplet diameter is between 150 and 800 mm/s. The method enables polymer product transported to a second location to have a narrow particle size distribution and reduced fines or dust content.
摘要翻译：聚合物珠产品的运输聚合物产品从第一位置运输到第二位置的方法，其中运输包括以下组中的至少一个：（a）在车辆中运输至少50公里; 和/或（b）至少一个导管中的输送，其中聚合物产物包含水溶性或水可溶胀聚合物珠，其中水溶性或水可溶胀聚合物珠可通过包含形成水溶性包含水溶性烯属不饱和单体或单体共混物的水溶液的单体珠，并聚合单体或单体共混物，以形成聚合物珠，同时悬浮在非水性液体中，并回收聚合物珠，其中该方法包括提供容器（1）非水液体的体积（2），其中非水性液体的体积在至少一个聚合物珠粒排放点（3）和至少一个单体进料点（4）之间延伸，进料含水单体或通过孔（5）将单体共混物加入到非水液体中或在非水液体上形成含水单体珠，使含水单体珠流向聚合物珠粒排出物 Ge点引发含水单体珠的聚合以形成聚合珠，其中聚合珠当它们到达聚合物珠粒排放点时已经形成聚合物珠粒，在聚合物珠粒上从容器中除去聚合物珠粒在非水性液体中的悬浮液排出点和从悬浮液中回收的水溶性或水可溶胀的聚合物珠粒，其中水性单体或单体混合物和/或孔口被振动，使得乘以重量平均液滴直径的频率在150和800mm之间 /秒。该方法使得聚合物产物运输到第二位置具有窄的粒度分布和减少的细粉或粉尘含量。

3. 发明申请

WO2015014825A1 REVERSE-PHASE POLYMERISATION PROCESS 审中-公开
标题翻译：反相聚合方法
公开(公告)号：WO2015014825A1
公开(公告)日：2015-02-05
申请号：PCT/EP2014/066252
申请日：2014-07-29
申请人： BASF SE
发明人： HESSE, Pascal , JELICIC, Aleksandra , FONSECA ZEPEDA, Gabriela Eugenia , HASCHICK, Robert , KEELAPANDAL RAMAMOORTHY, Shankara Narayanan , NAYLOR, Gareth Ian , BARRATT, John Scott , SOETJE, Oliver , LIEVRE, Marcel , RAINAU, Florian , LEBKÜCHER, Mark
IPC分类号： C08F2/32 , C08F20/56
CPC分类号： C08F2/32 , B01J19/10 , B01J2219/0888 , B01J2219/24 , C08F2/01 , C08F220/06 , C08F220/20 , C08F220/56 , C08F226/10 , C08F2220/382 , C08F2220/385 , C08F220/34
摘要： A reverse-phase suspension polymerisation process for the manufacture of polymer beads comprising forming aqueous monomer beads comprising an aqueous solution of water-soluble ethylenically unsaturated monomer or monomer blend and polymerising the monomer or monomer blend, to form polymer beads while suspended in a non-aqueous liquid, and recovering polymer beads, in which the process comprises providing in a vessel (1) a volume (2) of non-aqueous liquid wherein the volume of non-aqueous liquid extends between at least one polymer bead discharge point (3) and at least one monomer feed point (4), feeding the aqueous monomer or monomer blend through orifices (5) into, or onto, the non-aqueous liquid to form aqueous monomer beads, allowing the aqueous monomer beads to flow towards the polymer bead discharge point initiating polymerisation of the aqueous monomer beads to form polymerising beads, wherein the polymerising beads form polymer beads when they reach the polymer bead discharge point, removing a suspension of the polymer beads in non-aqueous liquid from the vessel at the polymer bead discharge point and recovering, water soluble or water swellable polymer beads from the suspension, in which the aqueous monomer or monomer blend and/or the orifices is/are vibrated such that the frequency multiplied by the weight average droplet diameter is between 150 and 800 mm/s. The invention also relates to the apparatus suitable for carrying out a reverse-phase suspension polymerisation and polymer beads obtainable by the process or employing the apparatus. Furthermore, the invention also relates to polymer beads having a weight mean particle size in the range of 0.05 to 5 mm which are held in a container in an amount of at least 300 kg having a standard deviation of particle size less than 20%. In addition, the invention also provides polymer beads having a weight mean particle size in the range 0.05 to 5 mm having a standard deviation of particle size less than 20% and having an amount of residual acrylamide of less than 500 ppm.
摘要翻译：一种用于制造聚合物珠粒的反相悬浮聚合方法，包括形成包含水溶性烯键式不饱和单体或单体共混物的水溶液的含水单体珠，并聚合单体或单体共混物，以形成聚合物珠粒，水性液体和回收的聚合物珠粒，其中该方法包括在容器（1）中提供非水性液体的体积（2），其中非水性液体的体积在至少一个聚合物珠粒排出点（3）和至少一个单体进料点（4），通过孔（5）将含水单体或单体共混物进料到非水性液体中或其上，以形成含水单体珠，使单体水单体流向聚合物珠粒引发单体珠水聚合形成聚合珠，其中聚合珠形成聚合物珠，当它们到达聚合物珠粒放电po 在聚合物珠粒排出点处从容器中除去聚合物小珠在非水性液体中的悬浮液，并从悬浮液中回收水溶性或水可溶胀的聚合物珠，其中单体或单体混合物和/或孔被振动，使得乘以重量平均液滴直径的频率在150和800mm / s之间。本发明还涉及适用于进行反相悬浮聚合的装置和可通过该方法获得的聚合物珠粒，或采用该装置。此外，本发明还涉及重量平均粒径在0.05至5mm范围内的聚合物珠，其以至少300kg的量保持在容器中，其具有小于20％的粒度的标准偏差。此外，本发明还提供了重均粒径在0.05-5mm范围内的聚合物珠，其粒径的标准偏差小于20％，残留丙烯酰胺的量小于500ppm。

4. 发明申请

WO2016120819A1 REVERSE-PHASE POLYMERISATION PROCESS INCORPORATING A MICROFLUIDIC DEVICE 审中-公开
标题翻译：合并微流控器件的反相聚合工艺
公开(公告)号：WO2016120819A1
公开(公告)日：2016-08-04
申请号：PCT/IB2016/050429
申请日：2016-01-28
申请人： BASF SE , BASF (CHINA) COMPANY LIMITED
发明人： HASCHICK, Robert , JELICIC, Aleksandra , FONSECA ZEPEDA, Gabriela Eugenia , RECKMANN, Anna , HOLTZE, Christian , STRUBEL, Bernd
IPC分类号： C08F2/32 , C08F20/56
CPC分类号： C08F2/32 , B01J19/0093 , B01J2219/00833 , B01J2219/00894 , C08F20/34 , C08F120/34
摘要： A reverse-phase suspension polymerization process for the manufacture of polymer beads comprising forming aqueous monomer beads of an aqueous solution comprising water-soluble ethylenically unsaturated monomer or monomer blend, polymerizing the monomer or monomer blend to form polymer beads while suspended in a non-aqueous liquid, and recovering polymer beads, comprises providing a volume of non-aqueous liquid (2) in a vessel (1), where the volume of non-aqueous liquid extends between at least one polymer bead discharge point(3) and at least one monomer feed point (4), generating monomer micro-volumes in at least one microfluidic device (5), said monomer micro-volumes being separated by none-aqueous liquid in at least one first microfluidic channel (6), feeding the monomer micro-volumes through the at least one first microfluidic channel (6) towards the at least one monomer feed point (4) at which the monomer micro-volumes enter into or onto the volume (2) of non-aqueous liquid and form aqueous monomer droplet, allowing the aqueous monomer droplets to flow towards the polymer bead discharge point, initiating polymerization of the aqueous monomer droplets to form polymerizing beads.
摘要翻译：一种用于制备聚合物珠粒的反相悬浮聚合方法，其包括形成包含水溶性烯属不饱和单体或单体共混物的水溶液的含水单体珠粒，将单体或单体共混物聚合以形成聚合物珠粒，同时悬浮在非水性液体和回收的聚合物珠粒包括在容器（1）中提供一定体积的非水性液体（2），其中非水性液体的体积在至少一个聚合物珠粒排出点（3）和至少一个单体进料点（4），在至少一个微流体装置（5）中产生单体微量，所述单体微量体在至少一个第一微流体通道（6）中由非水性液体分离，通过至少一个第一微流体通道（6）的体积朝向至少一个单体进料点（4），在该单体进料点处，单体微量体积进入非水性液体的体积（2）或其上 m含水单体液滴，使含水单体液滴流向聚合物珠粒排放点，引发含水单体液滴的聚合形成聚合珠粒。

5. 发明申请

WO2016120817A1 PREPARATION OF AQUEOUS SOLUTIONS OR DISPERSIONS OF POLYMERIC BEAD PRODUCTS 审中-公开
标题翻译：聚合物珠粒产品的水溶液或分散体的制备
公开(公告)号：WO2016120817A1
公开(公告)日：2016-08-04
申请号：PCT/IB2016/050427
申请日：2016-01-28
申请人： BASF SE , BASF (CHINA) COMPANY LIMITED
发明人： BARRATT, John , JELICIC, Aleksandra , HASCHICK, Robert , SOETJE, Oliver
IPC分类号： C08L33/00
CPC分类号： C08L33/02 , C08L33/26
摘要： Preparation of Aqueous Solutions or Dispersions of Polymeric Bead Products A method of forming an aqueous solution or an aqueous dispersion of a polymer product com- prising providing the polymer product; feeding the polymer product to a polymer hydration make-up unit; combining the polymer product with an aqueous liquid; and hydrating the polymer product to form the aqueous solution or aqueous dispersion of the poly- mer product, in which the polymer product comprises water-soluble or water swellable polymer beads, wherein the water soluble or water swellable polymer beads are obtainable by a process com- prising a reverse-phase suspension polymerisation comprising forming aqueous monomer beads of an aqueous solution comprising water-soluble ethylenically unsaturated monomer or monomer blend and polymerising the monomer or monomer blend, to form polymer beads while sus- pended in a non-aqueous liquid, and recovering polymer beads, in which the process comprises providing in a vessel (1) a volume (2) of non-aqueous liquid wherein the volume of non-aqueous liquid extends between at least one polymer bead discharge point (3) and at least one monomer feed point (4), feeding the aqueous monomer or monomer blend through orifices (5) into, or onto, the non- aqueous liquid to form aqueous monomer beads, allowing the aqueous monomer beads to flow towards the polymer bead discharge point initiating polymerisation of the aqueous monomer beads to form polymerising beads, wherein the polymerising beads have formed polymer beads when they reach the polymer bead discharge point, removing a suspension of the polymer beads in non-aqueous liquid from the vessel at the poly- mer bead discharge point and recovering, water soluble or water swellable polymer beads from the suspension, in which the aqueous monomer or monomer blend and/or the orifices is/are vibrated such that the frequency multiplied by the weight average droplet diameter is between 150 and 800 mm/s. The method enables aqueous solutions or aqueous dispersions of water soluble or water swellable polymer product to be made at a consistent concentration and for the so formed aqueous solutions or dispersions to be consistently dosed into systems to be treated.
摘要翻译：聚合物珠产品的水溶液或分散体的制备形成聚合物产物的水溶液或水分散体的方法，包括提供聚合物产物; 将聚合物产物加入到聚合物水合补充单元中; 将聚合物产物与水性液体组合; 并且使聚合物产物水合以形成聚合物产物的水溶液或水分散体，其中聚合物产物包含水溶性或水可溶胀的聚合物珠，其中水溶性或水可溶胀的聚合物珠可通过工艺com - 提供反相悬浮聚合，包括形成包含水溶性烯属不饱和单体或单体共混物的水溶液的水性单体珠，并聚合单体或单体共混物，以形成聚合物珠，同时悬浮在非水性液体中，和回收聚合物珠粒，其中该方法包括在容器（1）中提供非水液体体积（2），其中非水性液体的体积在至少一个聚合物珠粒排放点（3）和至少一个聚合物珠粒排出点一个单体进料点（4），通过孔口（5）将含水单体或单体共混物进料到非水液体中或其上，以形成含水单体珠粒，允许使含水单体珠流向聚合物珠粒排出点，引发含水单体珠的聚合以形成聚合珠，其中聚合珠在达到聚合物珠粒排出点时形成聚合物珠，除去聚合物珠的悬浮液在聚合物珠粒排出点处的容器中的非水性液体和从悬浮液中回收水溶性或水可溶胀的聚合物珠粒，其中水性单体或单体混合物和/或孔口被振动，使得频率乘以重量平均液滴直径在150和800mm / s之间。该方法使水溶液或水溶胀性聚合物产物的水溶液或水分散体以一致的浓度制备，并且使得如此形成的水溶液或分散体一致地加入待处理的体系中。

6. 发明申请

WO2017076784A1 REVERSE-PHASE POLYMERISATION PROCESS 审中-公开
标题翻译：反相聚合工艺
公开(公告)号：WO2017076784A1
公开(公告)日：2017-05-11
申请号：PCT/EP2016/076185
申请日：2016-10-31
申请人： BASF SE
发明人： LANG, Ortmund , JELICIC, Aleksandra , SCHUSTER, Thomas , SOETJE, Oliver , JECK, Sandra , HASCHICK, Robert , BRINGMANN, Tobias
IPC分类号： C08F2/32 , C08F220/56
CPC分类号： C08F2/32 , B01J4/002 , B01J19/123 , B01J19/242 , B01J19/243 , B01J2219/00094 , B01J2219/185 , B01J2219/1923 , B01J2219/1943 , C08F220/56 , C08F220/06
摘要： The present invention relates to a reverse-phase suspension polymerisation process for the manufacture of polymer beads comprising forming aqueous monomer beads of an aqueous solution comprising water-soluble ethylenically unsaturated monomer or monomer blend and polymerising the monomer or monomer blend to form polymer beads while suspended in a nonaqueous liquid, recovering polymer beads, and then cleaning the non-aqueous liquid in which the process comprises providing the non-aqueous liquid in a vessel (1), forming a suspension of monomer beads from the aqueous monomer or monomer blend in the non-aqueous liquid, initiating polymerisation to form polymerising beads, removing a suspension of the polymer beads in non-aqueous liquid from the vessel and recovering, water soluble or water swellable polymer beads from the suspension, in which the non-aqueous liquid contains impurities which comprise particles, and then subjecting the non-aqueous liquid from the suspension to a cleaning stage, in which the cleaning stage provides a cleaned non-aqueous liquid suitable for use in a reverse-phase suspension polymerisation process, which cleaning stage comprises subjecting the non-aqueous liquid to a pre-heating step, passing the preheated non-aqueous liquid through a helical tube evaporator thereby forming a mixture of liquid and gas, releasing the resulting mixture of liquid and gas into a gas-liquid separator vessel, and subsequently forming a liquid stream containing solids and a cleaned non-aqueous liquid stream. The invention also relates to an apparatus suitable for carrying out the process of the invention and also to polymeric products obtainable by the process.
摘要翻译：本发明涉及用于制造聚合物珠粒的反相悬浮聚合方法，其包括形成包含水溶性烯属不饱和单体或单体混合物的水溶液的含水单体珠粒，并使所述单体聚合或在悬浮于非水液体中时形成聚合物珠粒，回收聚合物珠粒，然后清洁非水液体，其中该方法包括在容器（1）中提供非水液体，从而形成单体珠粒悬浮液含水单体或单体在非水液体中混合，引发聚合形成聚合珠粒，从容器中除去聚合物珠粒在非水液体中的悬浮液，并从悬浮液中回收水溶性或水溶胀性聚合物珠粒，其中非水液体含有包含颗粒的杂质，然后将悬浮液中的非水液体进行处理清洁阶段，其中清洁阶段提供适用于反相悬浮聚合工艺的清洁的非水性液体，该清洁阶段包括使非水液体经受预热步骤，使预热的非水性液体通过，将含水液体通过螺旋管式蒸发器从而形成液体和气体的混合物，将得到的液体和气体混合物释放到气液分离器容器中，随后形成含有固体和清洁的非水液体流的液体流。本发明还涉及适用于实施本发明方法的设备，并且还涉及通过该方法可获得的聚合物产品。

7. 发明申请

WO2015014824A1 REVERSE-PHASE POLYMERISATION PROCESS 审中-公开
标题翻译：反相聚合方法
公开(公告)号：WO2015014824A1
公开(公告)日：2015-02-05
申请号：PCT/EP2014/066251
申请日：2014-07-29
申请人： BASF SE
发明人： BARRATT, John, Scott , JELICIC, Aleksandra , HESSE, Pascal , SOETJE, Oliver , HASCHICK, Robert , FONSECA ZEPEDA, Gabriela, Eugenia , KEELAPANDAL RAMAMOORTHY, Shankara, Narayanan , JECK, Sandra , KUHN, Jelan
IPC分类号： C08F2/32 , B01D29/00 , C08F20/56 , C08J11/02
CPC分类号： C08F265/04 , B01D29/00 , B01J19/24 , B01J2219/24 , C08F2/32 , C08F220/06 , C08F220/20 , C08F220/56 , C08F226/10 , C08F2220/382 , C08F2220/385 , C08J3/12 , C08J11/02 , C08J2351/00 , C08F220/34
摘要： A reverse-phase suspension polymerisation process for the manufacture of polymer beads comprising forming aqueous monomer beads of an aqueous solution comprising water-soluble ethylenically unsaturated monomer or monomer blend and polymerising the monomer or monomer blend to form polymer beads while suspended in a non-aqueous liquid, recovering polymer beads, and then cleaning the non-aqueous liquid in which the process comprises providing the non-aqueous liquid in a vessel (1), forming a suspension of monomer beads from the aqueous monomer or monomer blend in the non-aqueous liquid, initiating polymerisation to form polymerising beads, removing a suspension of the polymer beads in non-aqueous liquid from the vessel and recovering, water soluble or water swellable polymer beads from the suspension, in which the non-aqueous liquid contains impurities which comprise particles, and then transferring the non-aqueous liquid from the suspension to a cleaning stage, in which the cleaning stage provides a cleaned non-aqueous liquid suitable for use in a reverse-phase suspension polymerisation process, which cleaning stage comprises removing particles from the non-aqueous liquid in at least one filtration step. The invention also relates to the apparatus suitable for carrying out a reverse-phase suspension polymerisation and polymer beads obtainable by the process or employing the apparatus. The invention further relates to a cleaned non-aqueous liquid obtainable by the process.
摘要翻译：一种用于制造聚合物珠粒的反相悬浮聚合方法，包括形成包含水溶性烯键式不饱和单体或单体共混物的水溶液的含水单体珠粒，并将单体或单体共混物聚合以形成聚合物珠粒，同时悬浮于非水性液体，回收聚合物珠粒，然后清洗非水液体，其中该方法包括在容器（1）中提供非水性液体，从非水性单体或单体共混物形成单体珠粒悬浮液液体，引发聚合以形成聚合珠，从容器中除去聚合物小珠在非水液体中的悬浮液，并从悬浮液中回收水溶性或水可溶胀的聚合物珠，其中非水性液体含有包含颗粒的杂质，然后将非水性液体从悬浮液转移到清洁阶段，其中清洗步骤 e提供适用于反相悬浮聚合方法的清洁的非水性液体，该清洗阶段包括在至少一个过滤步骤中从非水性液体中除去颗粒。本发明还涉及适用于进行反相悬浮聚合的装置和可通过该方法获得的聚合物珠粒，或采用该装置。本发明还涉及通过该方法可获得的清洁的非水性液体。

8. 发明公开

EP3027661A1 REVERSE-PHASE POLYMERISATION PROCESS 审中-公开
标题翻译：反相聚合工艺
公开(公告)号：EP3027661A1
公开(公告)日：2016-06-08
申请号：EP14744840.1
申请日：2014-07-29
申请人： BASF SE
发明人： BARRATT, John Scott , JELICIC, Aleksandra , HESSE, Pascal , SOETJE, Oliver , HASCHICK, Robert , FONSECA ZEPEDA, Gabriela Eugenia , KEELAPANDAL RAMAMOORTHY, Shankara Narayanan , JECK, Sandra , KUHN, Jelan
IPC分类号： C08F2/32 , B01D29/00 , C08F20/56 , C08J11/02
CPC分类号： C08F265/04 , B01D29/00 , B01J19/24 , B01J2219/24 , C08F2/32 , C08F220/06 , C08F220/20 , C08F220/56 , C08F226/10 , C08F2220/382 , C08F2220/385 , C08J3/12 , C08J11/02 , C08J2351/00 , C08F220/34
摘要： A reverse-phase suspension polymerisation process for the manufacture of polymer beads comprising forming aqueous monomer beads of an aqueous solution comprising water-soluble ethylenically unsaturated monomer or monomer blend and polymerising the monomer or monomer blend to form polymer beads while suspended in a non-aqueous liquid, recovering polymer beads, and then cleaning the non-aqueous liquid in which the process comprises providing the non-aqueous liquid in a vessel (1), forming a suspension of monomer beads from the aqueous monomer or monomer blend in the non-aqueous liquid, initiating polymerisation to form polymerising beads, removing a suspension of the polymer beads in non-aqueous liquid from the vessel and recovering, water soluble or water swellable polymer beads from the suspension, in which the non-aqueous liquid contains impurities which comprise particles, and then transferring the non-aqueous liquid from the suspension to a cleaning stage, in which the cleaning stage provides a cleaned non-aqueous liquid suitable for use in a reverse-phase suspension polymerisation process, which cleaning stage comprises removing particles from the non-aqueous liquid in at least one filtration step. The invention also relates to the apparatus suitable for carrying out a reverse-phase suspension polymerisation and polymer beads obtainable by the process or employing the apparatus. The invention further relates to a cleaned non-aqueous liquid obtainable by the process.
摘要翻译：用于制造聚合物珠粒的反相悬浮聚合方法包括形成包含水溶性烯属不饱和单体或单体共混物的水溶液的含水单体珠粒，并将单体或单体共混物聚合以形成聚合物珠粒，同时将其悬浮于非水液体，回收聚合物珠粒，然后清洗非水液体，其中该方法包括在容器（1）中提供非水液体，由含水单体或单体混合物形成单体珠粒悬浮于非水溶液液体，引发聚合形成聚合珠粒，从容器中除去聚合物珠粒在非水液体中的悬浮液，并从悬浮液中回收水溶性或水溶胀性聚合物珠粒，其中非水液体含有包含颗粒，然后将非水液体从悬浮液转移到清洁阶段，其中清洁阶段 e提供适用于反相悬浮聚合工艺的清洁过的非水液体，该清洁阶段包括在至少一个过滤步骤中从非水液体中除去颗粒。本发明还涉及适用于进行反相悬浮聚合的设备和可通过该方法或使用该设备获得的聚合物珠粒。本发明还涉及通过该方法可获得的清洁过的非水液体。

9. 发明公开

EP3250614A1 REVERSE-PHASE POLYMERISATION PROCESS INCORPORATING A MICROFLUIDIC DEVICE 审中-公开
标题翻译：采用微流体装置的反相聚合工艺
公开(公告)号：EP3250614A1
公开(公告)日：2017-12-06
申请号：EP16742871.3
申请日：2016-01-28
申请人： BASF SE
发明人： HASCHICK, Robert , JELICIC, Aleksandra , FONSECA ZEPEDA, Gabriela Eugenia , RECKMANN, Anna , HOLTZE, Christian , STRUBEL, Bernd
IPC分类号： C08F2/32 , C08F20/56
CPC分类号： C08F2/32 , B01J19/0093 , B01J2219/00833 , B01J2219/00894 , C08F20/34 , C08F120/34
摘要： Disclosed herein is a polymerization process involving the steps of generating monomer micro-volumes in a microfluidic device, feeding the monomer micro-volumes through the at least one first microfluidic channel towards a monomer feed point at which the monomer micro-volumes enter into or onto a volume of a non-aqueous liquid and form aqueous monomer droplets, allowing the aqueous monomer droplets to flow towards a polymer bead discharge point, initiating polymerisation of the aqueous monomer droplets to form polymerising beads, removing a suspension of the polymer beads in the non-aqueous liquid from the vessel at the polymer bead discharge point, and recovering water soluble or water swellable polymer beads from the suspension. The present disclosure also includes an apparatus for performing the polymerization process and water soluble or water swellable polymer beads obtained by the polymerization process.

10. 发明公开

EP3027662A1 REVERSE-PHASE POLYMERISATION PROCESS 审中-公开
标题翻译： UMKEHRPHASEN-POLYMERISATIONSPROZESS
公开(公告)号：EP3027662A1
公开(公告)日：2016-06-08
申请号：EP14747573.5
申请日：2014-07-29
申请人： BASF SE
发明人： HASCHICK, Robert , JELICIC, Aleksandra , BARRATT, John Scott , HESSE, Pascal , SOETJE, Oliver , FONSECA ZEPEDA, Gabriela Eugenia , KEELAPANDAL RAMAMOORTHY, Shankara Narayanan , LANGLOTZ, Björn
IPC分类号： C08F2/32 , C08F20/56
CPC分类号： C08F220/56 , B01J19/123 , B01J19/24 , B01J2219/0869 , B01J2219/1203 , B01J2219/24 , C08F2/32 , C08F220/06 , C08F220/20 , C08F226/10 , C08F2220/382 , C08F2220/385 , C08F220/34
摘要： A reverse-phase suspension polymerisation process for the manufacture of polymer beads comprising forming aqueous monomer beads comprising an aqueous solution of water-soluble ethylenically unsaturated monomer or monomer blend and polymerising the monomer or monomer blend to form polymer beads while suspended in a non-aqueous liquid, and recovering polymer beads, in which the process comprises, providing in a vessel (1) a volume (2) of non-aqueous liquid wherein the volume of non-aqueous liquid extends between at least one polymer bead discharge point (3) and at least one monomer feed point (4), feeding the aqueous monomer or monomer blend through orifices (5) into, or onto, the non-aqueous liquid to form aqueous monomer beads, allowing the aqueous monomer beads to flow towards the polymer bead discharge point subjecting the aqueous monomer beads to polymerisation conditions to initiate polymerisation to form polymerising beads, wherein the polymerising beads have formed polymer beads when they reach the polymer bead discharge point, removing a suspension of the polymer beads in non-aqueous liquid from the vessel at the polymer bead discharge point and recovering water soluble or water swellable polymer beads from the suspension. The invention also relates to the apparatus suitable for carrying out a reverse-phase suspension polymerisation and polymer beads obtainable by the process or employing the apparatus.
摘要翻译：一种用于制备聚合物珠粒的反相悬浮聚合方法，其包括形成包含水溶性烯属不饱和单体或单体共混物的水溶液的含水单体珠粒，并将单体或单体共混物聚合以形成聚合物珠粒，同时悬浮在非水性液体和回收的聚合物珠粒，其中该方法包括在容器（1）中提供非水性液体的体积（2），其中非水性液体的体积在至少一个聚合物珠粒排出点（3）和至少一个单体进料点（4），通过孔口（5）将含水单体或单体共混物进料到非水性液体中或其上，以形成含水单体珠粒，使含水单体珠流向聚合物珠粒排出点使含水单体珠粒聚合条件以引发聚合以形成聚合珠粒，其中聚合珠粒已形成聚合物珠粒当它们到达聚合物珠粒排放点时，在聚合物珠粒排放点处从容器中除去聚合物小珠在非水性液体中的悬浮液，并从悬浮液中回收水溶性或水可溶胀聚合物珠粒。本发明还涉及适用于进行反相悬浮聚合的装置和通过该方法或使用该装置可获得的聚合物珠。

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