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1. 发明申请

WO1994003547A1 PAINT COMPOSITION 审中-公开
标题翻译：涂料组合物
公开(公告)号：WO1994003547A1
公开(公告)日：1994-02-17
申请号：PCT/EP1993002065
申请日：1993-08-03
申请人： BASF LACKE + FARBEN AG , NOF CORPORATION , TAKESHI, Hayakawa , KISHIO, Shibato
发明人： BASF LACKE + FARBEN AG , NOF CORPORATION
IPC分类号： C09D143/04
CPC分类号： C09D143/04 , C08G18/4063 , C08G18/61 , C08L2666/14 , C08L2666/28 , C08L2666/44
摘要： Paint compositions containing (A) a vinyl type copolymer obtained by polymerizing (i) specific silicone type vinyl monomers 1-50 % by weight, (ii) vinyl monomers containing hydroxyl groups 5-60 % by weight, and (iii) other vinyl monomers 5-80 % by weight, (B) specific hydroxyl-group-containing silicone type compounds, and (C) a hardening agent that allows reaction with hydroxyl groups. Paint films can be formed which have excellent water-repellence and oil-repellence, and in which there is no lowering of water-repellence or oil-repellence when they are exposed for long periods in natural environments.
摘要翻译：通过聚合（i）1-50重量％的特定硅酮型乙烯基单体得到的（A）乙烯基类共聚物，（ⅱ）含有5-60重量％羟基的乙烯基单体和（ⅲ）其它乙烯基单体 5-80重量％，（B）特定的含羟基的有机硅类化合物，和（C）能够与羟基反应的硬化剂。可以形成具有优异的拒水性和拒油性的油漆膜，并且当在自然环境中长时间暴露时，不会降低拒水性或拒油性。

2. 发明申请

WO1998002495A1 HEAT-HARDENABLE PAINT COMPOSITIONS 审中-公开
标题翻译：热复合油漆组合物
公开(公告)号：WO1998002495A1
公开(公告)日：1998-01-22
申请号：PCT/EP1997003375
申请日：1997-06-27
申请人： BASF LACKE + FARBEN AG , NOF CORPORATION , SHIBATOH, Kishio , NUKITA, Akito , LÜER, Ingo
发明人： BASF LACKE + FARBEN AG , NOF CORPORATION
IPC分类号： C09D201/06
CPC分类号： C08G18/4063 , C08G18/4291 , C08G18/7893 , C08G18/80
摘要： To obtain paint compositions with which it is possible to form paint films which have excellent acid resistance, weather resistance and heat resistance and which also have excellent yellowing resistance. A heat hardenable paint composition which contains (A) polyol which has in each molecule two or more sterically protected secondary hydroxyl groups, being polyol obtained by means of an esterification reaction of an epoxy group containing compound which has one epoxy group and which does not have a polymerizable unsaturated bond and a carboxyl group containing compound which has two or more carboxyl groups; and (B) 1,3,5-triazine-2,4,6-tris-carbamic acid ester which can be represented by the general formula C3N3(NHCOOR)3 or an oligomer thereof, wherein the mol ratio secondary hydroxyl groups originating from the aforementioned (A) component : NHCOOR groups originating from the aforementioned (B) component in the composition is from 1:3 to 3:1. (In said formula, R represents an alkyl group which has from 1 to 20 carbon atoms, an aryl group which has from 6 to 20 carbon atoms or an aralkyl group which has from 7 to 20 carbon atoms.)
摘要翻译：为了获得可以形成耐酸性，耐候性和耐热性优异并且耐黄变性优异的漆膜的油漆组合物。一种热硬化性涂料组合物，其含有（A）在各分子中具有两个或多个空间保护的仲羟基的多元醇，其为通过具有一个环氧基且不具有一个环氧基的含环氧基的化合物的酯化反应得到的多元醇可聚合不饱和键和具有两个或更多个羧基的含羧基化合物; 和（B）可以由通式C3N3（NHCOOR）3表示的1,3,5-三嗪-2,4,6-三氨基甲酸酯或其低聚物，其中源自上述（A）成分：由组合物中的上述（B）成分起源的NHCOOR基团为1:3〜3:1。（式中，R表示碳原子数1〜20的烷基，碳原子数6〜20的芳基或碳原子数7〜20的芳烷基。）

3. 发明申请

WO1996034064A1 THERMOSET PAINT COMPOSITIONS 审中-公开
标题翻译：热固性涂料组合物
公开(公告)号：WO1996034064A1
公开(公告)日：1996-10-31
申请号：PCT/EP1996001633
申请日：1996-04-19
申请人： BASF LACKE + FARBEN AG , NOF CORPORATION , HAYAKAWA, Takeshi , SHIBATO, Kishio , MONMA, Yasuhiro
发明人： BASF LACKE + FARBEN AG , NOF CORPORATION
IPC分类号： C09D175/04
CPC分类号： C08G18/6279 , C08G18/4063 , C08G18/6229 , C08G18/6233 , C09D175/04 , C08L2666/16
摘要： Thermoset paint compositions with which paint films can be formed which have excellent acid resistance, abrasion resistance and adhesion, and with which the water repelling properties and staining resistance can be retained for a longer period of time than with the conventional fluorine resin based paint films, are obtained. Constitution: Thermoset paint film compositions which contain (a) from 20 to 80 % by weight of fluorine containing copolymer, comprising fluoro-olefin and vinyl based monomer, of which the solubility parameter value is from 9.0 to 10.5 and the hydroxy group value is within the range from 60 to 150 mgKOH/g; (b) from 20-80 % by weight of vinyl based (co)polymer, comprising vinyl based monomer which contains at least 10 % by weight of monomer which can be repesented by formula (1), of which the solubility parameter is from 9.0 to 10.5 and the hydroxy group value is within the range from 60 to 150 mgKOH/g; (c) from 5 to 40 % by weight of alkyl etherified melanine resin; and (d) from 2 to 40 % by weight of blocked polyisocyanate compound, and with which the glass transition temperature of the paint film after hardening is at least 50 DEG C. In formula (1), R to R each independently represent H or methyl group, i is 0-2, j is 0 or 1, k is 0-3, m is 0-3 and n is 0-10.
摘要翻译：可以形成具有优异的耐酸性，耐磨性和粘合性的耐油性涂料组合物，并且耐久性能和耐污染性能比常规氟树脂基涂料膜更长时间地保持，获得。结构：热固性漆膜组合物，其含有（a）20〜80重量％的含氟共聚物，包含氟代烯烃和乙烯基类单体，溶解度参数值为9.0-10.5，羟基值在范围为60至150 mgKOH / g; （b）20-80重量％的乙烯基（共）聚合物，其包含含有至少10重量％可通过式（1）重新反应的单体的乙烯基类单体，其溶解度参数为9.0 至10.5，羟基值在60〜150mgKOH / g的范围内; （c）5至40重量％的烷基醚化的蜜胺树脂; 和（d）2-40重量％的封端多异氰酸酯化合物，硬化后漆膜的玻璃化转变温度至少为50℃。在式（1）中，R 1至R 5 各自独立地表示H或甲基，i为0-2，j为0或1，k为0-3，m为0-3，n为0-10。

4. 发明申请

WO1996005261A1 WATER DISPERSIBLE ACRYLIC BASED GRAFT COPOLYMERS, A METHOD OF MANUFACTURE AND AQUEOUS PAINTS 审中-公开
标题翻译：水分散型丙烯酸共聚物，制造方法和水性涂料
公开(公告)号：WO1996005261A1
公开(公告)日：1996-02-22
申请号：PCT/EP1995003122
申请日：1995-08-05
申请人： BASF LACKE + FARBEN AG , NOF CORPORATION , MATSUKURA, Yoshiaki , TANIGUCHI, Hitochi , SAKAI, Atsuhiro , KAWAMURA, Yoshiaki
发明人： BASF LACKE + FARBEN AG , NOF CORPORATION
IPC分类号： C09D155/00
CPC分类号： C09D155/005
摘要： To obtain aqueous paints with which paint films which have excellent paint film properties such as water resistance and resistance to chemical attack, and excellent finished appearance can be obtained, and which have excellent painting operability and storage stability. An unsaturated bond-containing acrylic based copolymer (a) obtained by reacting an acrylic based copolymer (a1) of acid value 35-120 mg.KOH/gram, hydroxy group value 50-150 mg.KOH/gram, glass transition temperature -20 - +50 DEG C and number average molecular weight 4500-9000 and an unsaturated monomer mixture (a2), which has functional groups which can react with hydroxy groups, in a mol ratio of a2/a1 = 0.4-1.5, and a monomer composition (b) compounded in such a way that the acid value is not more than 15 and the hydroxy group value is 50-150 are reacted in the proportions by weight of a/b = 10/90 - 60/40 to produce a water dispersible acrylic based graft copolymer which has an acid value of 10-30, a hydroxy group value of 50-150, a glass transition temperature of -20 - +50 DEG C and number average molecular weight 10000-100000, in which side chains comprising the aforementioned b are graft polymerized on the main chains comprising the aforementioned a, and this copolymer is dispersed in an aqueous medium and an aqueous paint is obtained.
摘要翻译：为了获得具有优异的油漆膜性能如耐水性和耐化学腐蚀性以及优异的外观的涂料的水性涂料，并且具有优异的喷涂操作性和储存稳定性。通过酸值35-120mg.KOH /克的丙烯酸类共聚物（a1），羟基值为50-150mg.KOH /克，玻璃化转变温度-20℃反应获得的不饱和键的丙烯酸类共聚物（a） - + 50℃和数均分子量为4500-9000的不饱和单体混合物（a2）和具有可与羟基反应的官能团的不饱和单体混合物（a2）以a2 / a1 = 0.4-1.5的摩尔比和单体组成（b）以酸值不超过15，羟基值为50-150的比例以a / b = 10/90〜60/40的重量比进行反应，得到水分散性丙烯酸系接枝共聚物，其酸值为10-30，羟基值为50-150，玻璃化转变温度为-20- +50℃，数均分子量为10000-100000，其中包含上述b在包含上述a的主链上被接枝聚合，并且该共聚物被分散 d在水性介质中，得到水性涂料。

5. 发明申请

WO1998007796A1 HEAT-HARDENABLE PAINT COMPOSITIONS 审中-公开
标题翻译：热复合油漆组合物
公开(公告)号：WO1998007796A1
公开(公告)日：1998-02-26
申请号：PCT/EP1997004111
申请日：1997-07-29
申请人： BASF LACKE + FARBEN AG , NOF CORPORATION , NUKITA, Akito , SHIBATO, Kishio , LÜER, Ingo
发明人： BASF LACKE + FARBEN AG , NOF CORPORATION
IPC分类号： C09D157/00
CPC分类号： C09D175/04 , C08G18/6229 , C08G18/7893 , C08L61/32 , C09D133/066 , C08L2666/14
摘要： The invention relates to a heat-hardenable paint composition which contains (A) vinyl based copolymer of hydroxyl group value from 20 to 200 mg KOH/g, being a copolymer of from 5 to 70 wt.% hydroxyl group containing vinyl based monomer which can be represented by general formula (1) and from 95 to 30 wt.% other vinyl based monomer (a-2), and (B) 1,3,5-triazine-2,4,6-triscarbamic acid ester which can be represented by general formula (2): C3N3(NHCOOR)3 or an oligomer thereof, in which the mol ratio of hydroxyl groups originating from the aforementioned (A) component: NHCOOR groups originating from the aforementioned (B) component in the composition is from 1:3 to 3:1. In general formula (1), X , X and X each independently represent a hydrogen atom or a methyl group. Moreover j is an integer of value from 0 to 2, m is an integer of value from 3 to 5, and n is an integer of value from 0 to 5. However, j and n cannot both be 0. In general formula (2), R represents an alkyl group which has from 1 to 20 carbon atoms, an aryl group which has from 6 to 20 carbon atoms or an aralkyl group which has from 7 to 20 carbon atoms, and these groups may be the same or different.
摘要翻译：本发明涉及一种热硬化性涂料组合物，它含有（A）羟基值为20-200mg KOH / g的乙烯基共聚物，为含有5-70％（重量）羟基的乙烯基类单体的共聚物，它可以由通式（1）表示，95〜30重量％的其它乙烯基类单体（a-2）和（B）1,3,5-三嗪-2,4,6-三氨基甲酸酯由上述（A）成分衍生的上述（B）成分中衍生的上述（A）成分的NHCOOR基团的摩尔比来自组成中的（C）N 3（NHCOOR）3或其低聚物 1：3到3：1。在通式（1）中，X 1，X 2和X 3各自独立地表示氢原子或甲基。此外，j为0〜2的整数，m为3〜5的整数，n为0〜5的整数。然而，j，n均不能为0。在通式（2）中，），R表示碳原子数1〜20的烷基，碳原子数6〜20的芳基或碳原子数7〜20的芳烷基，这些基可以相同也可以不同。

6. 发明申请

WO1997022672A1 THERMOSETTING PAINT COMPOSITION 审中-公开
标题翻译：热固性涂料组合物
公开(公告)号：WO1997022672A1
公开(公告)日：1997-06-26
申请号：PCT/EP1996005160
申请日：1996-11-22
申请人： BASF LACKE + FARBEN AG , NOF CORPORATION , MORI, Souichi , MONMA, Yasuhiro , SHIBATOH, Kishio
发明人： BASF LACKE + FARBEN AG , NOF CORPORATION
IPC分类号： C09D175/00
CPC分类号： C09D175/00 , C08G18/6229 , C08G18/6233 , C08G18/807 , C08K5/005 , C08L75/00 , C08L2666/16 , C08L2666/28
摘要： To offer thermosetting paint compositions resistant to yellowing to brass, which give paint films of excellent resistance to yellowing due to brass, low-temperature curability, weather resistance, resistance to yellowing after stoving, acid resistance, scratch resistance, solvent resistance, adhesion and appearance. Thermosetting paint compositions, which are thermosetting paint compositions which are resistant to yellowing due to brass, characterized in that the paint-film-forming components include (A) a compound which has per molecule at least 2 functional groups which can react with an isocyanate group, at 49.6-90 wt.%, (B) a blocked isocyanate which has per molecule at least 2 isocyanate groups blocked by an azole blocking agent, at 9.6-50 wt.%, (C) an ultraviolet absorber and/or free radical scavenger, at 0.2-5 wt.%, (D) an organotin compound at 0.1-3 wt.%, and (E) an amino resin at 0.1-30 wt.%.
摘要翻译：提供耐黄变黄色的热固性涂料组合物，其得到黄铜耐黄变性优异的漆膜，耐候性，耐候性，耐烤后黄变性，耐酸性，耐刮擦性，耐溶剂性，粘合性和外观。热固性涂料组合物是由于黄铜而耐黄变的热固性涂料组合物，其特征在于，成膜组分包括（A）每分子具有至少2个可与异氰酸酯基团反应的官能团的化合物，49.6-90重量％，（B）每分子具有至少2个被唑类封闭剂封闭的异氰酸酯基团的封端异氰酸酯，（9.6）重量％，（C）紫外线吸收剂和/或自由基清除剂，为0.2-5重量％，（D）0.1-3重量％的有机锡化合物，和（E）0.1-30重量％的氨基树脂。

7. 发明申请

WO1997031983A1 COLORED METALLIC PAINT COMPOSITIONS AND PAINTED OBJECTS 审中-公开
标题翻译：彩色金属涂料组合物和涂饰物品
公开(公告)号：WO1997031983A1
公开(公告)日：1997-09-04
申请号：PCT/EP1997000608
申请日：1997-02-10
申请人： BASF LACKE + FARBEN AG , NOF CORPORATION , SAKAI, Naoya , FUJIMORI, Eiji , SAKANIWA, Shinichi , ISHII, Katsuaki
发明人： BASF LACKE + FARBEN AG , NOF CORPORATION
IPC分类号： C09D05/36
CPC分类号： C09D5/36
摘要： To obtain a colored metallic paint with which a colored metallic paint film which has excellent features and with which a change in color is produced according to differences in the viewing angle can be formed using the usual cheap pigments without compounding special glitter materials. A paint composition which contains, per 100 parts by weight of a film forming binder (A), from 0.1 to 15 parts by weight of metallic powder (B), from 0.1 to 10 parts by weight of a first colored pigment (C) of primary particle size from 0.01 to 0.2 mu m which is selected from among the group comprising the phthalocyanine, perylene, indanthrone, azomethine, benzimidazolone, quinacridone, anthraquinone, diketopyrolopyrrole and dioxazine based pigments, and from 0.5 to 50 parts by weight of a second colored pigment (D) of primary particle size from 0.1 to 2 mu m selected from among the group comprising the diketopyrolopyrrole, quinacridone, pyrazolone, naphthol AS, iron oxide and complex metal oxide based pigments, where the primary particle size of the pigment (C) is relatively smaller than that of the pigment (D), and there is a complementary color relationship between the pigments (C) and (D).
摘要翻译：为了获得具有优异特征并且根据视角的差异产生颜色变化的着色金属漆膜的彩色金属涂料，可以使用通常的廉价颜料形成，而不需要混合特殊的闪光材料。一种涂料组合物，其包含相对于成膜粘合剂（A）每100重量份，0.1〜15重量份的金属粉末（B），0.1〜10重量份的第一着色颜料（C）一次粒径为0.01〜0.2μm，选自酞菁，苝，阴丹酮，偶氮甲碱，苯并咪唑酮，喹吖啶酮，蒽醌，二酮咯吡咯和二恶嗪类颜料，以及0.5〜50重量份的第二有色颜料（C）的一次粒径为0.1〜2μm的颜料（D），选自二酮基吡咯并吡咯，喹吖啶酮，吡唑啉酮，萘酚AS，氧化铁和复合金属氧化物系颜料，（D）相对较小，颜料（C）和（D）之间存在互补的颜色关系。

8. 发明申请

WO1997022421A1 METHOD FOR FORMING A PAINT FILM, AND PAINTED OBJECT 审中-公开
标题翻译：形成涂膜的方法和涂漆对象
公开(公告)号：WO1997022421A1
公开(公告)日：1997-06-26
申请号：PCT/EP1996005166
申请日：1996-11-22
申请人： BASF LACKE + FARBEN AG , NOF CORPORATION , FURUUCHI, Kazuyoshi , MORI, Souichi
发明人： BASF LACKE + FARBEN AG , NOF CORPORATION
IPC分类号： B05D07/00
CPC分类号： B05D7/532 , B05D7/542
摘要： To offer a method for forming paint films of outstanding acid resistance, finished appearance, water resistance and adhesion, etc., even when a water-based base finishing coat and solvent-based top finishing coat are painted wet-on-wet. A method for forming a paint film by a method for forming a hardened paint film in which a water-based thermosetting base finishing coat is painted onto the surface of an object to be painted, a thermosetting top coat is painted on top of this wet-on-wet, and the paint films are hardened at the same time, in which the aforementioned top coat which contains as a primary resin a copolymer which is a copolymer of a vinyl monomer which has a ring structure and other vinyl monomer(s) in which the proportion of vinyl monomer having a ring structure in the total quantity of monomers is 20-50 wt.%, and the proportion of other vinyl monomer(s) is 80-50 wt.%, and which has a glass transition temperature of 0-60 DEG C, a solubility parameter of 9.0-11.0 and a weight-average molecular weight of 4000-30,000.
摘要翻译：为了提供一种形成具有优异的耐酸性，成品外观，耐水性和粘附性等的涂膜的方法，即使将水性基底涂层和溶剂型顶涂层涂在湿润湿润上。通过用于形成硬化漆膜的方法来形成漆膜的方法，其中将水性热固性基底饰面涂布在待涂漆物体的表面上，将热固性顶涂层涂在该湿 - 并且涂膜同时硬化，其中上述顶涂层包含作为主要树脂的共聚物，该共聚物是具有环结构的乙烯基单体和其它乙烯基单体的共聚物其中单体总量中具有环结构的乙烯基单体的比例为20-50重量％，其它乙烯基单体的比例为80-50重量％，玻璃化转变温度为 0-60℃，溶解度参数为9.0-11.0，重均分子量为4000-30,000。

9. 发明申请

WO1997022420A1 METHOD FOR FORMING A PAINT FILM, AND A PAINTED OBJECT 审中-公开
标题翻译：形成涂膜的方法和涂漆物体
公开(公告)号：WO1997022420A1
公开(公告)日：1997-06-26
申请号：PCT/EP1996005159
申请日：1996-11-22
申请人： BASF LACKE + FARBEN AG , NOF CORPORATION , FURUUCHI, Kazuyoshi , MORI, Souichi
发明人： BASF LACKE + FARBEN AG , NOF CORPORATION
IPC分类号： B05D07/00
CPC分类号： B05D7/532 , B05D7/542 , Y10T428/31515 , Y10T428/31573 , Y10T428/31855 , Y10T428/31909
摘要： To form paint films of outstanding acid resistance, finished appearance, water resistance, adhesion and bending resistance by coating a base finishing coat and top finishing coat wet-on-wet. A method for forming a paint film by a method for forming a thermosetting paint film in which a solvent-based thermosetting base finishing coat is painted onto the surface of an object to be painted, a thermosetting top finishing coat is painted on top of this wet-on-wet, and the paint films are hardened at the same time, in which the aforementioned top finishing coat which contains as a primary resin a copolymer which is a copolymer of a vinyl monomer which has a ring structure and other vinyl monomers in which the proportion of vinyl monomer having a ring structure in the total quantity of monomers is 20-50 wt.%, and the proportion of other vinyl monomer(s) is 80-50 wt.%, and which has a glass transition temperature of 0-60 DEG C, a solubility parameter of 9.0-11.0 and a weight-average molecular weight of 4000-30,000.
摘要翻译：通过涂布底漆和顶涂层湿润湿法，形成具有优异耐酸性，成品外观，耐水性，粘合性和耐弯曲性的漆膜。通过用于形成热固性漆膜的方法来形成漆膜的方法，其中将溶剂型热固性基底涂层涂在待涂漆物体的表面上，将热固性顶部精整涂层涂在该湿的顶部并且漆膜同时硬化，其中上述顶涂层包含作为主要树脂的共聚物，其是具有环结构的乙烯基单体和其它乙烯基单体的共聚物，其中其中在单体总量中具有环结构的乙烯基单体的比例为20-50重量％，其它乙烯基单体的比例为80-50重量％，玻璃化转变温度为0 -60℃，溶解度参数为9.0-11.0，重均分子量为4000〜30000。

10. 发明申请

WO1996005260A1 WATER-DISPERSIBLE ACRYLIC GRAFT COPOLYMER, METHOD FOR MAKING IT AND WATER-BASED PAINT 审中-公开
标题翻译：水分散丙烯酸共聚物，其制备方法和水性涂料
公开(公告)号：WO1996005260A1
公开(公告)日：1996-02-22
申请号：PCT/EP1995003145
申请日：1995-08-08
申请人： BASF LACKE + FARBEN AG , NOF CORPORATION , MATSUKURA, Yoshiaki , TANIGUCHI, Hitoshi , SAKAI, Atsuhiro , KAWAMURA, Yoshiaki
发明人： BASF LACKE + FARBEN AG , NOF CORPORATION
IPC分类号： C09D151/00
CPC分类号： C09D151/003 , C08F265/04
摘要： To obtain paint films with outstanding paint film performance traits such as water resistance and chemical resistance, etc., and outstanding finished appearance, and to obtain water-based paints which are easy to apply and have outstanding storage stability. An acrylic copolymer of acid number 35-120 mg KOH/g, hydroxyl group number 50-150 mg KOH/g, glass transition temperature -20 to +50 DEG C and number average molecular mass 4500-9000, comprising a copolymer of alpha , beta -ethylenic unsaturated monomers (a), and a monomer combination including an alpha , beta -ethylenic unsaturated monomer containing a glycidal group and an alpha , beta -etylenic unsaturated monomer containing a hydroxyl group to give an acid number of
摘要翻译：为了获得具有优异的漆膜性能特征如耐水性和耐化学性等的漆膜，并且具有优异的成品外观，并且获得易于涂覆并且具有优异的储存稳定性的水性涂料。酸值35-120mg KOH / g，羟基数50-150mg KOH / g，玻璃化转变温度-20至+50℃，数均分子量4500-9000的丙烯酸共聚物，包含α， β-烯属不饱和单体（a），以及包含含有缩水甘油基的α，β-亚乙烯基不饱和单体和含有羟基的α，β-亚乙烯基不饱和单体以产生酸值为15mg的单体组合 KOH / g，羟基数为50〜150mg KOH / g（b），在一个阶段中以规定的比例反应，制成水分散性丙烯酸接枝共聚物，其酸值为10〜30mgKOH / g，羟基数为50-150mg KOH / g，玻璃化转变温度为-20至+50℃，数均分子量为10,000-100,000，通过将由上述（b）形成的侧链接枝至来自上述（a）的主链，该接枝共聚物分散在水性药物中 ium获得水性油漆。

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