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    • 4. 发明申请
    • PROCESS FOR PREPARING AROMATIC ALDEHYDES
    • 用于生产芳香醛
    • WO1996005161A1
    • 1996-02-22
    • PCT/EP1995003167
    • 1995-08-10
    • BASF AKTIENGESELLSCHAFTFISCHER, RolfIRGANG, MatthiasSCHNURR, WernerWULFF-DÖRING, Joachim
    • BASF AKTIENGESELLSCHAFT
    • C07C45/41
    • C07C45/41B01J23/10C07C67/313C07C69/76
    • A process is disclosed for preparing aromatic aldehydes having the general formula (I), in which R , R , R , R and R stand for hydrogen, C1-C6 alkyl, C3-C8 cycloalkyl, aryl, hydroxy, C1-C4 alkoxy, phenoxy, C7-C12 alkylphenyl, C7-C12 phenylalkyl, amino, methylamino, dimethylamino or halogen and R may also stand for formyl or COOR , and R stands for hydrogen, C1-C6 alkyl, C3-C8 cycloalkyl, aryl, C7-C12 alkylphenyl or C7-C12 phenylalkyl. For that purpose, aromatic carboxylic acid or their esters having the general formula (II), in which R , R , R , R , R and R have the above meanings or R , R , R and R have the above meanings and R and R form together a -CH2- bridge, are reacted with hydrogen in the gaseous phase at temperatures from 200 to 450 DEG C and pressures from 0.1 to 20 bars in the presence of a catalyst whose catalytically active mass contains 80 to 99.9 % by weight zirconium oxide and 0.1 to 20 % by weight of one or several lanthanide elements.
    • 一种用于制备通式(I)中R <1>,R <2>,R <3>,R <4>和R <5>为氢,C1-C6烷基,C3的芳香醛过程 至C8环烷基,芳基,羟基,C1至C4烷氧基,苯氧基,C7-C12烷基苯基,C7-C12苯基烷基,氨基,甲氨基,二甲氨基或卤素,并且R <1>另外甲酰基或COOR <6 > - [R <6>为氢,C1-C6烷基,C3至C8环烷基,芳基,C7至C12烷基苯基或C 7至C 12苯基烷基,意思是说,在其中一个芳族羧酸或它们的通式的酯 (II)其中R <1>,R <2>,R <3>,R <4>,R <5>和R <6>具有上述定义,或其中R <2>,R <3 >,R <4>和R <5>具有上文给出的含义且R <6>和R <1>一起在200温度下,以450℃和0的压力形成-CH 2桥,与在气相中氢 1至20巴在催化剂其催化活性组合物包括存在从80至99.9重量%氧化锆和0.1至20重量的一个或% 含有镧系元素的多个元件,进行反应。
    • 6. 发明申请
    • PROCESS FOR PREPARING A HYDROGENATION CATALYST
    • 用于生产加氢催化剂
    • WO1997012673A1
    • 1997-04-10
    • PCT/EP1996004203
    • 1996-09-26
    • BASF AKTIENGESELLSCHAFTHEINEKE, DanielRIEKER, Christopher, WilliamOOSTVOGELS, JozefPOSTELMANS, DanySCHNEIDER, Heinz-WalterTHOME, AlfredACHHAMMER, Günther
    • BASF AKTIENGESELLSCHAFT
    • B01J23/42
    • B01J23/42B01J23/96B01J37/16C01B21/1418Y02P20/584
    • The invention relates to a hydrogenation catalyst by the reduction from platinum in the stage of oxidation of +4 (Pt (IV)) with a selective reducing agent in an acidic aqueous medium in the presence of a carbon-containing carrier to platinum in the stage of oxidation +2 (Pt (II)), subsequent poisoning of the platinum thus obtained with a sulphur-containing selective reducing agent, and subsequent reduction of the platinum thus partially poisoned to form metallic platinum (Pt(0)) and subsequent processing as known per se in that (a) Pt (II) is partially poisoned with a sulphur-containing selective reducing agent, wherein the sulphur-containing selective reduction agent is used in an amount which corresponds to from 15 to 70 mol % of the amount of the sulphur-containing selective reducing agent which might be needed to reduce Pt(IV) to Pt (II), provided that the amount of Pt (IV) corresponds to the amount of Pt (II) used and to be poisoned, and subsequently the partially poisoned Pt (II) is reduced with an alkali metal formate to Pt (0); or (b) platinum in the stage of oxidation of greater than +2 is partially poisoned and subsequently or simultaneously reduced with an alkali metal formate to Pt (0). The invention also relates to a hydrogenation catalyst, use of the hydrogenation catalyst for preparing hydroxylammonium salts, a process for the preparation of hydroxylammonium salts, and a process for regenerating platinum-containing hydrogenation catalysts.
    • 通过在的氧化态还原铂的制备氢化催化剂4(铂(IV)),与在碳质载体的存在下,铂的氧化态+2(铂(II))的酸性水性介质中的选择性还原剂,随后中毒 如此所得载铂用选择性还原剂,之后减少从而部分中毒铂成金属铂含硫铂(Pt(0)),并且向其中随后以常规方式后处理通过(a)铂(II)与含硫选择性还原剂反应 部分中毒,被使用,在其对应于从15到70%(摩尔),将在顺序的Pt(IV),以铂(II),以减少所需要的选择性还原剂含硫的量的,提供的量的含硫选择性还原剂 的Pt的量(IV)对应于到,插入的Pt(II)的中毒的量,然后将 部分中毒的Pt(II)与碱金属与Pt减少(0),或(b)铂在大于2部分中毒和随后或同时用碱金属降低到的Pt(0)以及氢化催化剂的氧化状态,使用氢化催化剂 对于羟铵盐的制备,处理用于羟铵盐的制备和用于再生铂的氢化催化剂的方法。