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    • 3. 发明申请
    • COMPOUNDS WITH ISOCYANATE GROUPS AND MASKED GROUPS REACTIVE IN RELATION TO ISOCYANATES
    • 与异氰酸酯化合物封端的和异氰酸酯 - 反应性基团
    • WO1997023536A1
    • 1997-07-03
    • PCT/EP1996005634
    • 1996-12-16
    • BASF AKTIENGESELLSCHAFTBRUCHMANN, BerndRENZ, HansMOHRHARDT, Günter
    • BASF AKTIENGESELLSCHAFT
    • C08G18/80
    • C07D317/14C07D319/06C08G18/2805C08G18/2825C08G18/2865C08G18/2875C08G18/32C09D175/00
    • Compounds with isocyanate groups and masked groups reactive in relation to isocyanates, of the formula (I), in which R , R , R , X and Y have the following meaning: R , R are hydrogen, C1- to C10-alkyl, C6- to C10-aryl, C7- to C10-aralkyl or R and R form together C3- to C10-alkane diyl; X, Y are -O-, -S-, (a), in which R is hydrogen, a C1- to C20-alkyl group which is optionally interrupted by oxygen atoms in the ether function, a C6 to C10-aryl group or a C7- to C10-aralkyl group; R is a C1- to C10-alkane diyl group which forms a 4 to 7-membered ring along with the unit -X-CR R -Y-, in which either in the unit R one of the hydrogen atoms or in the unit (b), the radical R is replaced by an allophanate group (R ), in which R is a divalent, aliphatic, alicyclic, araliphatic or aromatic C2- to C20-hydrocarbon unit, and R is a simple bond or a divalent, aliphatic, alicyclic, araliphatic or aromatic C1- to C20-hydrocarbon unit or a mono or poly- (C2- to C4-alkylene oxide) unit, and R is a carbamoyl (c) radical or a biuret group (R ), in which one of the radicals R is hydrogen and the other radical has the same meaning as R , or a biuret group (R ) in which one of the radicals R has the same meaning as R and the other has the same meaning as R , or a thioallophanate group (R ).
    • 具有化合物的异氰酸酯基和封端的式(I)中R <1>,R <2>,R <3>中,X和Y具有如下含义的异氰酸酯 - 反应性基团,R <1>,R <2>是氢 ,C1至C10烷基,C6至C10芳基,C7-C10芳烷基,或R <1>和R <2>一起形成C3〜C10的烷二基,X,Y是-O - , - S - 中,(a),其中R <4>表示氢,C1至C20烷基,其任选地通过在醚官能氧原子间隔,C6至C10芳基或C7〜C10的芳烷基,R <3 > C1至C10烷二<1> [R <2> -Y-与部分-X-CR 4至7元环时,一起其中或者装置R <3>的一个氢原子 或单元(b)中,基团R <4>通过脲基甲酸酯基团(R ),其中R <5>是一个二价脂族,脂环族,芳脂族或芳族C 2至C 20烃基部分,R <6 >单键或二价脂族,alicyclis 澈,芳脂族或芳族C1〜C20的烃单元或单或聚(C 2至C 4亚烷基氧)部分,R <7>为氨基甲酰基(C)指,或缩二脲基团(R <磅> )其中,R中的一个<8>为氢且另一个基团的含义与R <7>,或缩二脲基团(R ),其中R中的一个<9>具有相同的含义 是为R <7>,而另一个具有的含义与R <1>,或更换的thioallophanate基(R )相同。
    • 6. 发明申请
    • BIODEGRADABLE POLYMERS, PROCESS FOR THEIR PRODUCTION AND THEIR USE IN PRODUCING BIODEGRADABLE MOULDINGS
    • 生物降解聚合物,方法的生产和使用,其用于制造生物可降解成型
    • WO1996015173A1
    • 1996-05-23
    • PCT/EP1995002491
    • 1995-06-27
    • BASF AKTIENGESELLSCHAFTWARZELHAN, VolkerSCHORNICK, GunnarBRUCHMANN, BerndSEELIGER, UrsulaYAMAMOTO, MotonoriBAUER, Peter
    • BASF AKTIENGESELLSCHAFT
    • C08G63/20
    • C08L3/02C08G18/4216C08G18/4219C08G18/4277C08G18/428C08G18/4286C08G18/4676C08G18/6659C08G63/20C08G63/60C08G2230/00C08L75/06C09D167/00C09K17/52Y02A40/284Y10S525/938Y10T428/31547Y10T428/31786Y10T428/31794C08L2666/02C08L2666/26C08L2666/36
    • Biodegradable polyesters P1 obtainable by the reaction of a mixture consisting essentially of (a1) a mixture essentially of 35 to 95 mol% adipic acid or ester-forming derivatives thereof or mixtures thereof, 5 to 65 mol% terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and 0 to 5 mol% of a sulphonate group-containing compound in which the sum of the individual mol percentages is 100, and (a2) a dihydroxy compound selected from the group consisting of C2-C6 alkane diols and C5-C10 cycloalkane diols, in which the molar ratio of (a1) and (a2) is in the range from 0.4:1 to 1.5:1, provided that the polyester P1 have a molecular weight (Mn) in the range from 5000 to 50,000 g/mol, a viscosity index in the range from 30 to 350 g/ml (measured in o-dichlorobenzole/phenol (in a ratio by weight of 50/50) at a concentration of 0.5 wt.% polyester P1 at a temperature of 25 DEG C) and a melting point in the range from 50 to 170 DEG C, and with the further proviso that from 0.01 to 5 mol% in relation to the molar quantity of the component (a1) used of compound D with at least three groups capable of forming esters are used to produce the polyesters P1, and other biodegradable polymers and thermoplastic moulding compounds and adhesives, biodegradable mouldings, foams and blends with starch obtainable from the polymers or moulding compounds of the invention.
    • 可生物降解聚酯P1由基本上由混合物反应获得(A1)基本上35由〜95摩尔%的己二酸或它们的酯形成性衍生物或者它们的混合物,5〜65摩尔%的对苯二甲酸或其酯形成性衍生物的混合物 或其混合物,和0〜5摩尔%磺酸酯化合物的,单独的摩尔百分比的总和为100摩尔%,和(a2)选自C2-C6烷二醇和C5-C10组成的组中的二羟基化合物 -cycloalkanediols,其中的(a1)至(A2)在0.4的范围内的摩尔比:1至1.5:1种选择,条件是所述聚酯P1具有分子量(Mn)的范围为5000至50000,条件 克/摩尔,在范围在聚酯P1 0.5重量%的浓度在25℃的温度的粘度数从30至350微克/毫升(邻二氯苯测定/苯酚(50/50重量比) C)和熔点 包含50至170℃,并与进一步的条件是从0.01〜5摩尔%,基于组分(a1)的摩尔量,一化合物D与能够形成酯的至少三个基团为生产 聚酯P1中使用的以及其它可生物降解的聚合物和热塑性模塑组合物,其制备方法,它们用于制备可生物降解的模制品和粘合剂,可生物降解的模制品,泡沫的用途,并与本发明的聚合物或模塑组合物获得的淀粉的共混物。
    • 7. 发明申请
    • BIODEGRADABLE POLYMERS, PROCESS FOR THEIR PRODUCTION AND THEIR USE IN PRODUCING BIODEGRADABLE MOULDINGS
    • 生物降解聚合物,方法的生产和使用,其用于制造生物可降解成型
    • WO1996015174A1
    • 1996-05-23
    • PCT/EP1995002492
    • 1995-06-27
    • BASF AKTIENGESELLSCHAFTWARZELHAN, VolkerBRUCHMANN, BerndBOECKH, DieterSEELIGER, UrsulaYAMAMOTO, MotonoriBAUER, Peter
    • BASF AKTIENGESELLSCHAFT
    • C08G63/60
    • C08G18/4676A01G24/00C05F17/009C08G18/4247C08G18/4286C08G63/60C08G63/672C08G2230/00C09K15/32Y02E50/343Y02P20/145Y02W30/43Y02W30/47
    • Biodegradable polyether esters P1 obtainable by the reaction of a mixture consisting essentially of: (a1) a mixture essentially of 20 to 95 mol% adipic acid or ester-forming derivatives thereof or mixtures thereof, 5 to 80 mol% terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and 0 to 5 mol% of a sulphonate group-containing compounds in which the sum of the individual mol percentages is 100; and (a2) a mixture of dihydroxy compounds consisting essentially of (a21) 15 to 99 mol% of a dihydroxy compound selected from the group consisting of C2-C6 alkane diols and C5-C10 cycloalkane diols; (a22) 85 to 0.2 mol% of an ether function-containing dihydroxy compound as in formula I HO-[(CH2)n-O]m-H in which n is 2, 3 or 4 and m is a whole number from 2 to 250, or mixtures thereof, in which the molar ratio of (a1) to (a2) is in the range from 0.4:1 to 1.5:1 with the proviso that the polyether esters P1 have a molar weight (Mn) in the range from 5,000 to 80,000 g/mol, a viscosity index in the range from 30 to 450 g/ml (measured in o-dichlorobenzole/phenol (weight ratio 50/50) at a concentration of 0.5 wt.% polyether esters P1 at a temperature of 25 DEG C) and a melting point in the range from 50 to 200 DEG C, and with the further proviso that from 0.01 to 5 mol%, in relation to the molar quantity of the components (a1) used, of a compound D with at least three groups capable of ester formation are used to produce the polyether esters P1, and other biodegradable polymers and thermoplastic moulding compounds, process for their production and biodegradable mouldings, adhesives, foams and blends with starch obtainable from the polymers or moulding compounds of the invention.
    • 通过基本上由的混合物反应得到的可生物降解的聚醚酯P1(a1)的基本上由20〜95摩尔%的己二酸或它们的酯形成性衍生物或者它们的混合物,5〜80摩尔%的对苯二甲酸或其酯形成性衍生物的混合物 或其混合物,和0〜5摩尔%磺酸酯化合物的,单独的摩尔百分比的总和为100摩尔%,和(a2)基本上由(A21)的二羟基化合物为15〜99.8的混合物 摩尔%(A22)选自C2-C6烷二醇和C5-C10-环烷二醇的组中选择的二羟基化合物,为85〜0.2摩尔%的含有醚官能团的二羟基化合物中的和根据式I HO - [(CH 2) 否] mH的,提供了其中n是2,3或4,m为2至250的整数,或它们的混合物,其中(a1)至(A2)的范围为0.4的摩尔比:1至 1.5:1种选择,其中M assgabe该聚醚酯P1具有的范围内的分子量(Mn)为5000〜80000克/摩尔,在30至450范围内的粘度数克/毫升(邻二氯苯/苯酚测量(50/50重量比)在 具有0.5重量%聚醚酯P1的在25℃的温度下)的浓度和在50至200℃的范围内的熔点,并与进一步的条件是从0.01〜5%(摩尔) 基于组分(a1)的摩尔量,与能够对聚醚酯P1的所用的制备,酯形成至少三个基团以及其它可生物降解的聚合物和热塑性模塑组合物,涉及它们的制备方法,它们用于制备可生物降解的成型品中使用的化合物D的 和粘合剂,可生物降解的模制品,泡沫和从本发明的聚合物或模塑组合物与淀粉的共混物获得的。