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1. 发明申请

WO1996020923A1 PROCESS FOR CONTINUOUSLY CLEANING RAW CAPROLACTAM MADE FROM 6-AMINO CAPRONITRILE 审中-公开
标题翻译：用于连续清洁方法OUT 6-氨基己腈生产ROH己内酰胺
公开(公告)号：WO1996020923A1
公开(公告)日：1996-07-11
申请号：PCT/EP1995005103
申请日：1995-12-22
申请人： BASF AKTIENGESELLSCHAFT
发明人： BASF AKTIENGESELLSCHAFT , RITZ, Josef , FISCHER, Rolf , SCHNURR, Werner , ACHHAMMER, Günther , LUYKEN, Hermann , FUCHS, Eberhard
IPC分类号： C07D201/16
CPC分类号： C07D201/16 , Y02P20/52
摘要： Cleaning raw caprolactam by hydration, subsequent treatment in an acid medium and final distillation in an alkaline medium, in which (a) 6-amino capronitrile is converted into raw caprolactam by reaction with water; (b) difficultly and easily boiling components are removed from the raw caprolactam from step (a); (c) the raw caprolactam from step (b) is treated with hydrogen at a temperature in the 50 to 150 DEG C range and a pressure in the 1.5 to 250 bar range in the presence of a hydration catalyst and, if desired, a solvent, to give a mixture A;(d1) mixture A is taken at a temperature in the 30 to 80 DEG C range and a pressure in the 1 to 5 bar range over an ion exchanger containing acid terminal groups to give a mixture B1 or (d2) mixture A is distilled in the presence of sulphuric acid, in which any solvent is removed before the addition of the sulphuric acid to give a mixture B2; and (e) mixture B1 or B2 is distilled in the presence of a base to yield pure caprolactam.
摘要翻译：通过氢化粗己内酰胺，在由碱性介质酸性介质中和随后的蒸馏后续处理的纯化的（a）6-氨基己腈通过与水到粗己内酰胺反应进行反应; （B）从粗己内酰胺从步骤（a）中分离的重和轻馏分; 在50至150℃下的范围内的温度（℃）从步骤（b）的粗己内酰胺和在加氢催化剂的存在下1.5至250巴的范围内的压力，并且如果需要的溶剂，用氢气以获得混合物 A; （D1）的混合物在30〜80℃的温度和1〜5巴以上的含末端酸基的离子交换剂的范围内的压力下，在溶剂A，导致得到混合物B1; 或（D2）的混合物A是在硫酸的存在下与硫酸的添加存在的任何溶剂除去的前蒸馏，从而得到混合物B2; 和（e）混合物B1或在碱的存在下混合物B2蒸馏以获得纯的己内酰胺。

2. 发明申请

WO1996020931A1 METHOD OF SIMULTANEOUSLY PREPARING CAPROLACTAM AND HEXAMETHYLENE DIAMINE 审中-公开
标题翻译：程序己内酰胺和己二胺的同时生产
公开(公告)号：WO1996020931A1
公开(公告)日：1996-07-11
申请号：PCT/EP1995005115
申请日：1995-12-22
申请人： BASF AKTIENGESELLSCHAFT
发明人： BASF AKTIENGESELLSCHAFT , ACHHAMMER, Günther , BASSLER, Peter , FISCHER, Rolf , FUCHS, Eberhard , LUYKEN, Hermann , SCHNURR, Werner , WITZEL, Tom
IPC分类号： C07D223/10
CPC分类号： C07C209/48 , C07D201/08
摘要： The invention concerns the simultaneous preparation of caprolactam and hexamethylene diamine from adipodinitrile, by the following steps: (a) the adipodinitrile is partially hydrogenated, producing a mixture substantially containing 6-aminocapronitrile, hexamethylene diamine, ammonia, adipodinitrile and hexamethylene imine (= "the mixture"); (b) the mixture obtained in step (a) is distilled, producing ammonia, as the forerunnings, and a residue I, in the presence of a compound A which is inert in the distillation conditions, the ammonia not being separated totally; (c) the residue I, substantially containing "the mixture", inert compound A and ammonia, the ammonia content being less than that of the mixture used in step (b), is subjected to a second distillation, producing a mixture of the inert compound A and ammonia, as the forerunnings, and a residue II; (d) the base II, substantially containing "the mixture" and inert compound A, is subjected to distillation in a third column, producing the inert compound A, as the forerunnings, and a residue III; (e) the base III, substantially containing "the mixture" and optionally an inert compound B, is subjected to distillation in a fourth column, producing forerunnings KP1, which substantially contain hexamethylene imine, optionally inert compound B and hexamethylene diamine, and a residue IV; (f) the forerunnings KP1 are subjected in a fifth column to distillation, producing forerunnings KP2, which substantially contain hexamethylene imine and optionally inert compound B, and a residue V, which substantially contains hexamethylene diamine with a degree of purity of at least 95 %, the forerunnings KP2 being fed to the third column or optionally only partially fed to the third column, and the rest being discarded; and (g) the residue IV, substantially containing 6-aminocapronitrile and adipodinitrile, is subjected in a sixth column to distillation, producing 6-aminocapronitrile with a degree of purity of at least 95 %, as forerunnings, and adiponitrile in the residue. The resultant 6-aminocapronitrile is cyclized to form caprolactam.
摘要翻译：同时制备的己内酰胺和己二胺己二腈从开始通过（a）己二腈被部分氢化以得到主要含6-氨基己腈，六亚甲基二胺，氨，己二腈和六亚甲基亚胺的混合物（=“混合物”），以及（b）中（a）使获得的蒸馏，得到氨作为顶部产物和塔底产物I，不被完全在惰性的蒸馏条件化合物下在存在分离，并且其中所述氨，和（c）的塔底产物I，基本上含有混合物 “共混物”，惰性的化合物和氨，氨含量大于所述混合物，将其在步骤（b）中使用的低，第二蒸馏以得到氨和惰性化合物的混合物作为塔顶产物和底部产物II，和（d）的塔底产物II，主要包含“共混物”和惰性的化合物 A，在第三列中，蒸馏，得到惰性的化合物A作为塔顶产物和塔底产物III，（E）的塔底产物III，基本上含有“共混物”，以及如果需要，一种惰性化合物B，下经受，在第四列中，蒸馏得到顶部产物KP1，基本上含有六亚甲基亚胺，如果需要惰性的化合物B和六亚甲基二胺，和塔底产物IV，（F）的塔顶产物KP1在第五列中，蒸馏，得到一顶部产物KP2，主要含有六亚甲基亚胺，并且如果需要的惰性化合物B 和底部产物V，以至少95％的纯度基本上六亚甲基二胺的含，被供应到所述第三塔的塔顶产物KP2或任选仅部分送入第三塔，其余部分被除去，和（g）塔底产物IV，主要含有 6-氨基己腈和Adipodinit RIL，进行，在第六列中，蒸馏，得到具有至少95％的纯度作为顶部产物和己二腈作为底部6-氨基己腈，和6-氨基己腈环化己内酰胺这样获得。

3. 发明申请

WO1996020165A1 PROCESS FOR PREPARING ALIPHATIC ALPHA,OMEGA-AMINONITRILES 审中-公开
标题翻译：用于生产脂肪族α，ω-氨基腈
公开(公告)号：WO1996020165A1
公开(公告)日：1996-07-04
申请号：PCT/EP1995004984
申请日：1995-12-16
申请人： BASF AKTIENGESELLSCHAFT
发明人： BASF AKTIENGESELLSCHAFT , SCHNURR, Werner , FISCHER, Rolf , BASSLER, Peter , HARDER, Wolfgang
IPC分类号： C07C253/30
CPC分类号： C07C253/30
摘要： Aliphatic alpha,omega-aminonitriles are prepared by partially hydrogenating aliphatic alpha,omega-dinitriles at an increased temperature and pressure in the presence of a base and an hydrogenation catalyst. Hydrogenation is carried out in the presence of ammonia and lithium hydroxide or a compound that releases lithium hydroxide during the hydrogenation process.
摘要翻译：脂族α，ω-二氨基腈通过氢化在氨和氢氧化锂的存在或化合物的在升高的温度和升高的压力下在碱氢化催化剂的存在和脂族α，ω-二腈的部分氢化的制剂，其氢氧化锂的氢化期间用品，执行。

4. 发明授权

EP1060158B1 VERFAHREN ZUR HERSTELLUNG VON ALIPHATISCHEN ALPHA-, OMEGA-DIAMINEN 有权
标题翻译：用于生产脂肪族α，ω-二胺类
公开(公告)号：EP1060158B1
公开(公告)日：2004-04-28
申请号：EP99937925.8
申请日：1999-02-23
申请人： BASF AKTIENGESELLSCHAFT
发明人： VOIT, Guido , FISCHER, Rolf , BASSLER, Peter , ANSMANN, Andreas , LUYKEN, Hermann , MERGER, Martin , OHLBACH, Frank , REHFINGER, Alwin
IPC分类号： C07C209/48 , C07C211/12
CPC分类号： C07C211/12 , B01J23/745 , C07C209/48
摘要： The invention relates to a method for producing aliphatic alpha-, omega-diamines by hydrogenating aliphatic alpha-, omega-dinitriles in the presence of a catalyst, characterised in that the catalyst used for the hydrogenation contains a) iron or a compound based on iron or mixtures thereof, b) 0.001 to 0.3 wt. % in relation to a) of a promoter based on 2, 3, 4 or 5 elements from the following group: aluminium, silicon, zirconium, titanium and vanadium and c) 0 to 0.3 wt. % in relation to a) of a compound based on an alkaline and/or alkaline earth metal.

5. 发明授权

EP1073620B1 VERFAHREN ZUR HERSTELLUNG VON 1,4-BUTANDIOL 有权
标题翻译：用于生产1,4-丁二醇
公开(公告)号：EP1073620B1
公开(公告)日：2003-07-09
申请号：EP99920693.1
申请日：1999-04-16
申请人： BASF AKTIENGESELLSCHAFT
发明人： FISCHER, Rolf , KAIBEL, Gerd , PINKOS, Rolf , RAHN, Ralf-Thomas
IPC分类号： C07C51/16 , C07C67/03 , C07C69/60 , C07C29/17 , C07D307/08 , C07D307/32
CPC分类号： C07D315/00 , C07C29/177 , C07D307/08 , C07C31/207
摘要： The invention relates to a method for producing 1,4-butanediol and possibly η-butyrolactone and tetrahydrofurane by oxidation of butane or benzol into a product flow containing maleic anhydride, absorption of maleic anhydride from the product flow by means of an inert, high-boiling solvent in an absorption stage, which yields a liquid absorption product, and esterification of said liquid absorption product with a C1-C5 esterification alcohol in an esterification step, yielding an esterification product containing the corresponding diester and high-boiling inert solvent. This is followed by hydrogenation of the esterification product, which results in an hydrogenation product containing the products 1,4-butanediol and optionally η-butyrolactone and tetrahydrofurane as well as the esterification alcohol. The hydrogenation product is separated by distillation into the products and the esterification alcohol and the esterification alcohol is returned to the esterification zone. Prior to hydrogenation the esterification product is separated by distillation under reduced pressured into the diester and the inert solvent, the inert solvent is returned to the absorption stage and the diester is hydrogenated in the liquid phase on a fixed-bed catalyst.

6. 发明授权

EP0931054B1 VERFAHREN ZUR ABTRENNUNG VON 2-AMINOMETHYLCYCLOPENTYLAMIN AUS EINER MISCHUNG ENTHALTEND HEXAMETHYLENDIAMIN UND 2-AMINOMETHYLCYCLOPENTYLAMIN 失效
标题翻译：方法分离共混含己二胺2 aminomethylcyclopentylamine和2 aminomethylcyclopentylamine
公开(公告)号：EP0931054B1
公开(公告)日：2003-05-28
申请号：EP97942889.3
申请日：1997-08-28
申请人： BASF AKTIENGESELLSCHAFT
发明人： LUYKEN, Hermann , REHFINGER, Alwin , BASSLER, Peter , VOIT, Guido , FISCHER, Rolf , MERGER, Martin , RUST, Harald
IPC分类号： C07C209/86
CPC分类号： C07C209/86 , C07C211/36 , C07C2601/08 , Y10S203/11 , C07C211/12
摘要： Process for the separation of 2-aminomethylcyclopentylamine from a mixture containing hexamethyldiamine and 2-aminomethylcyclopentylamine, characterized by the fact that the separation is carried out by means of distillation at a pressure of 1-300 mbars.

7. 发明授权

EP0815078B1 VERFAHREN ZUR HERSTELLUNG VON CAPROLACTAM 失效
标题翻译：用于生产己内酰胺
公开(公告)号：EP0815078B1
公开(公告)日：2003-04-02
申请号：EP96919688.0
申请日：1996-05-07
申请人： BASF AKTIENGESELLSCHAFT
发明人： FUCHS, Eberhard , MELDER, Johann-Peter , SCHNURR, Werner , FISCHER, Rolf
IPC分类号： C07D201/08 , C07D223/12
CPC分类号： C07D201/08 , C07D223/12
摘要： The production of caprolactam by reacting 6-amino capronitrile with water in the presence of catalysts, using an initial mixture of 6-amino capronitrile and the tetrahydroazepine derivative of formula (I), and reaction in the liquid phase in the presence of heterogeneous catalysts, and a process for producing tetrahydroazepine derivative (I) and its use for making caprolactam and polycaprolactam.

8. 发明授权

EP0983219B1 VERFAHREN ZUR HERSTELLUNG VON ALIPHATISCHEN ALKOHOLEN 失效
标题翻译：用于生产脂肪醇
公开(公告)号：EP0983219B1
公开(公告)日：2002-11-06
申请号：EP98925581.5
申请日：1998-05-12
申请人： BASF AKTIENGESELLSCHAFT
发明人： FISCHER, Rolf , PINKOS, Rolf , WULFF-DÖRING, Joachim
IPC分类号： C07C29/136 , B01J23/42 , B01J23/68
CPC分类号： C07C29/149 , B01J23/56 , B01J23/6567 , B01J23/89 , C07C31/12 , C07C31/207 , C07C31/125 , C07C31/20
摘要： The invention relates to a method for producing aliphatic alcohols by hydrogenating aliphatic carboxylic acids, anhydrides or esters thereof or lactones in the presence of a catalyst containing Pt and Re in metallic or oxidic form. Said catalyst also contains at least one other element from groups 5 to 12 and 14 and from the group of lanthanides of the periodic table of elements in metallic or oxidic form.

9. 发明授权

EP0912508B1 VERFAHREN ZUR HERSTELLUNG VON CAPROLACTAM AUS 6-AMINOCAPRONITRIL 失效
标题翻译：用于生产己内酰胺OFF 6-氨基己腈
公开(公告)号：EP0912508B1
公开(公告)日：2002-01-16
申请号：EP97935513.8
申请日：1997-07-07
申请人： BASF AKTIENGESELLSCHAFT
发明人： RITZ, Josef , ACHHAMMER, Günther , FISCHER, Rolf , FUCHS, Eberhard , VOIT, Guido
IPC分类号： C07D201/08 , C07D201/12 , C07D201/16
CPC分类号： C07D201/12 , C07D201/08
摘要： The invention concerns the preparation of caprolactam by cyclizing 6-aminocapronitrile in the presence of water at high temperature and optionally of a catalyst and a solvent by: a) separating from the reaction yield ('reaction yield I') of the cyclizing process caprolactam and all the components boiling higher than caprolactam ('high boilers'); b) treating the high boilers from step a) with phosphoric acid and/or polyphosphoric acid at a temperature ranging from 200 to 350 °C, obtaining reaction yield II; and c) separating the caprolactam resulting from reaction yield II of step b) and optionally 6-aminocapronitrile from unreacted 'high boilers' and the acid used.

10. 发明公开

EP1115715A1 VERFAHREN ZUR HERSTELLUNG VON TETRAHYDROFURAN 有权
标题翻译：用于生产四氢呋喃
公开(公告)号：EP1115715A1
公开(公告)日：2001-07-18
申请号：EP99947373.9
申请日：1999-09-16
申请人： BASF AKTIENGESELLSCHAFT
发明人： FISCHER, Rolf , LIANG, Shelue , PINKOS, Rolf
IPC分类号： C07D307/08
CPC分类号： C07D307/08 , Y02P20/582
摘要： The invention relates to a method for producing THF (tetrahydrofuran) by reacting a reaction mixture containing 1,4-butanediol on an acidic catalyst, said reaction mixture containing additional alcohols other than 1,4-butanediol and being essentially free from water.

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