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2. 发明授权

EP0792310B1 BIOLOGISCH ABBAUBARE POLYMERE, VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBARER FORMKÖRPER 失效
标题翻译：生物降解聚合物，方法的生产和使用，其用于制造生物可降解成型
公开(公告)号：EP0792310B1
公开(公告)日：2001-04-11
申请号：EP95925768.4
申请日：1995-06-27
申请人： BASF AKTIENGESELLSCHAFT
发明人： WARZELHAN, Volker , BRUCHMANN, Bernd , BOECKH, Dieter , SEELIGER, Ursula , YAMAMOTO, Motonori , BAUER, Peter
IPC分类号： C08G63/60 , C08G18/42 , C08G63/672
CPC分类号： C08G18/4676 , A01G24/00 , C05F17/009 , C08G18/4247 , C08G18/4286 , C08G63/60 , C08G63/672 , C08G2230/00 , C09K15/32 , Y02E50/343 , Y02P20/145 , Y02W30/43 , Y02W30/47

3. 发明公开

EP0802941A1 BIOLOGISCH ABBAUBARE POLYMERE, VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBARER FORMKÖRPER 失效
标题翻译： BIOLOGISCH ABBAUBARE POLYMERE，VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBERFORMKÖRPER
公开(公告)号：EP0802941A1
公开(公告)日：1997-10-29
申请号：EP96900924.0
申请日：1996-01-09
申请人： BASF AKTIENGESELLSCHAFT
发明人： WARZELHAN, Volker , SCHORNICK, Gunnar , BRAUN, Frank , SEELIGER, Ursula , YAMAMOTO, Motonori , BAUER, Peter
IPC分类号： C08G69 , C08G18 , C08G73 , C08J9 , C08K5 , C08L77 , C08L101 , C09J177 , D21H19
CPC分类号： C08G69/48 , C08G18/606 , C08G69/44 , C08G2230/00 , C08K5/353 , Y02W30/43 , C08L77/12
摘要： The invention concerns biologically degradable polyether ester amides P1 obtainable through reaction of a mixture consisting essentially of the following: (a1) a mixture consisting essentially of: 20-95 mol % adipic acid or ester-forming derivatives thereof or mixtures thereof, 5-80 mol % terephthalic acid or ester-forming derivatives thereof or mixtures thereof; 0.5 mol % of a compound containing sulphonate groups, the sum of the molar percentages being 100; (a2) a mixture of dihydroxy compounds consisting essentially of: (a21) 15-99,3 mol % of a dihydroxy compound chosen from the group comprising C2-C6 alkane diols and C5-C10 cycloalkane diols; (a22) 0.2-85 mol % of a dihydroxy compound containing ether functions, determined by formula I HO-[(CH2)n-O]m-H, wherein n is 2, 3 or 4 and m is an integer between 2 and 250, or mixtures thereof; (a23) 0.5-80 mol % of an amino-C2-C12 alkanol or an amino C5-C10 cycloalkanol; and (a24) 0-50 mol % of a diamino C1-C8 alkane; (a25) 0-50 mol % of a 2,2'-bisoxazoline. The invention also concerns other biologically degradable polymers and thermoplastic moulding materials, processes for manufacturing the same, the use thereof for producing biologically degradable moulded articles and adhesives, and biologically degradable moulded articles made from the polymers or moulding materials according to the invention.
摘要翻译：本发明涉及生物可降解的聚醚酯酰胺P1，其可通过基本上由以下组成的混合物反应获得：（a1）基本上由以下组成的混合物：20-95摩尔％的己二酸或其成酯衍生物或其混合物，5-80 摩尔％对苯二甲酸或其成酯衍生物或其混合物; 0.5摩尔％的含有磺酸盐基团的化合物，其摩尔百分数之和为100; （a2）主要由以下组分组成的二羟基化合物的混合物：（a21）15-99.3mol％的选自C2-C6链烷二醇和C5-C10环烷二醇的二羟基化合物; （a22）0.2-85mol％含醚官能团的二羟基化合物，由式I确定HO - [（CH2）nO] mH，其中n为2,3或4且m为2至250的整数，或者混合物物; （a23）0.5-80摩尔％的氨基-C2-C12链烷醇或氨基C5-C10环链烷醇; 和（a24）0-50摩尔％的二氨基C 1 -C 8烷烃; （a25）0-50摩尔％的2,2'-双恶唑啉。本发明还涉及其它生物可降解聚合物和热塑性模塑材料，其制造方法，其用于生产生物可降解模塑制品和粘合剂的用途，以及由本发明聚合物或模塑材料制成的生物可降解模塑制品。

4. 发明授权

EP0842221B1 THERMOPLASTISCHE FORMMASSEN AUF DER BASIS VON ETHYLENPOLYMERISATEN UND THERMOPLASTISCHEN POLYESTERN 失效
标题翻译：热塑性模塑化合物基于乙烯的聚合物和热塑性聚酯
公开(公告)号：EP0842221B1
公开(公告)日：2001-01-31
申请号：EP96927572.6
申请日：1996-07-22
申请人： BASF AKTIENGESELLSCHAFT
发明人： BAUER, Peter , SEELIGER, Ursula , FALLER, Uwe
IPC分类号： C08L23/04
CPC分类号： C08J5/18 , C08J2323/04 , C08L23/0815 , C08L67/00 , C08L2666/18
摘要： The present invention relates to thermoplastic moulding compounds containing as essential components: A) 95 to 99.99 wt.% of an ethylene polymer; and B) 0.01 to 5 wt.% of a thermoplastic polyester with a maximum melting point of 150 °C or below.

5. 发明公开

EP0986610A1 POLYMERMISCHUNG 失效
标题翻译：聚合物共混物
公开(公告)号：EP0986610A1
公开(公告)日：2000-03-22
申请号：EP98925619.3
申请日：1998-05-20
申请人： BASF AKTIENGESELLSCHAFT
发明人： BAUER, Peter , LUX, Martin , LILGE, Dieter
IPC分类号： C08L23/16
CPC分类号： C08L23/0815 , C08L23/06 , C08L2205/02 , C08L2666/04
摘要： The invention relates to polymer mixtures containing at least 85 wt pct ethylene/α-olefin copolymers (A) produced by metallocene catalysis and 1 to 15 wt pct essentially linear ethylene/α-olefin copolymers (B) produced with a different catalyst, in relation to the total mass of the polymer mixture.

6. 发明授权

EP0802941B1 BIOLOGISCH ABBAUBARE POLYMERE, VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBARER FORMKÖRPER 失效
公开(公告)号：EP0802941B1
公开(公告)日：1998-07-29
申请号：EP96900924.0
申请日：1996-01-09
申请人： BASF AKTIENGESELLSCHAFT
发明人： WARZELHAN, Volker , SCHORNICK, Gunnar , BRAUN, Frank , SEELIGER, Ursula , YAMAMOTO, Motonori , BAUER, Peter
IPC分类号： C08G69/44 , C08G18/60
CPC分类号： C08G69/48 , C08G18/606 , C08G69/44 , C08G2230/00 , C08K5/353 , Y02W30/43 , C08L77/12

7. 发明公开

EP0842221A1 THERMOPLASTISCHE FORMMASSEN AUF DER BASIS VON ETHYLENPOLYMERISATEN UND THERMOPLASTISCHEN POLYESTERN 失效
标题翻译：热塑性模塑化合物基于乙烯的聚合物和热塑性聚酯
公开(公告)号：EP0842221A1
公开(公告)日：1998-05-20
申请号：EP96927572.0
申请日：1996-07-22
申请人： BASF AKTIENGESELLSCHAFT
发明人： BAUER, Peter , SEELIGER, Ursula , FALLER, Uwe
IPC分类号： C08J5 , C08L23
CPC分类号： C08J5/18 , C08J2323/04 , C08L23/0815 , C08L67/00 , C08L2666/18
摘要： The present invention relates to thermoplastic moulding compounds containing as essential components: A) 95 to 99.99 wt.% of an ethylene polymer; and B) 0.01 to 5 wt.% of a thermoplastic polyester with a maximum melting point of 150 °C or below.

8. 发明公开

EP0809664A1 BIOLOGISCH ABBAUBARE POLYMERE, VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBARER FORMKÖRPER 失效
标题翻译： BIOLOGISCH ABBAUBARE POLYMERE，VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBERFORMKÖRPER
公开(公告)号：EP0809664A1
公开(公告)日：1997-12-03
申请号：EP96903976.0
申请日：1996-02-03
申请人： BASF AKTIENGESELLSCHAFT
发明人： WARZELHAN, Volker , PIPPER, Gunter , SEELIGER, Ursula , BAUER, Peter , PAGGA, Udo , YAMAMOTO, Motonori
IPC分类号： C08J5 , A61L15 , C08G63 , C08J9 , C08L67 , C08L101 , C09J167 , D21H19
CPC分类号： C08G63/91 , A61L15/26 , A61L15/62 , C08G63/20 , C08G63/60 , C08G63/668 , C08G63/672 , Y02W30/43 , C08L67/00
摘要： Biodegradable polyesters P1 obtainable through the reaction of a mixture consisting essentially of: (a1) a mixture consisting essentially of 35 to 95 mol.% adipic acid, ester-forming derivatives thereof or mixtures thereof, 5 to 65 mol.% terephthalic acid, ester-forming derivatives thereof or mixtures thereof, and 0 to 5 mol.% of a compound containing sulphonate groups, in which the sum of the individual mol percentages is 100; and (a2) a dihydroxy compound selected from the group consisting of C2-C6alkane diols and C5-C10cycloalkane diols, the molar ratio of (a1) to (a2) being in the range from 0.4:1 to 1.5:1, provided that the polyesters P1 have a molecular weight (Mn) in the range from 5000 to 50 000 g/mol, a viscosity index in the range from 30 to 350 g/ml (measured in o-dichlorobenzol/phenol (weight ratio 50/50), at a concentration of 0.5 wt.% polyesters P1 at a temperature of 25 °C) and a melting point in the range from 50 to 170 °C, and with the further provisos that from 0.01 to 5 mol.% related to the molar quantity of the component (a1) used of a compound D with at least three groups capable of ester formation are added to product the polyesters P1 and that the polyesters P1 contain both hydroxyl and carboxyl terminal groups, the molar ratio of carboxyl to hydroxyl terminal groups being greater than one. The invention also relates to further biodegradable polymers and thermoplastic casting compounds, process for their production, their use in the manufacture of biodegradable casting compounds and adhesives, biodegradable mouldings, foams and blends with starch obtainable from the polymers or casting compounds of the invention.
摘要翻译：通过基本上由以下组分组成的混合物反应可得到的生物可降解聚酯P1：（a1）基本上由35-95摩尔％己二酸，其成酯衍生物或其混合物组成的混合物，5-65摩尔％对苯二甲酸酯其形成的衍生物或其混合物，以及0-5摩尔％的含磺酸盐基团的化合物，其中各摩尔百分数之和为100; 和（a2）选自C2-C6烷烃二醇和C5-C10环烷烃二醇的二羟基化合物，（a1）与（a2）的摩尔比为0.4:1-1.5:1，条件是聚酯P1具有5000至50000g / mol的分子量（Mn），30至350g / ml的范围内的粘度指数（以邻二氯苯酚/苯酚（重量比50/50）测量），在25℃的温度下以0.5重量％的聚酯P1的浓度）和50-170℃的熔点，并且进一步的条件是0.01摩尔％至5摩尔％与摩尔量的具有至少三个能够形成酯的基团的化合物D所用的组分（a1）被添加到聚酯P1的产物中，并且聚酯P1同时含有羟基和羧基端基，羧基端基与羟基端基的摩尔比为大于一个。本发明还涉及进一步的可生物降解的聚合物和热塑性铸塑化合物，它们的生产方法，它们在制造可生物降解的浇铸化合物和粘合剂中的用途，可生物降解的模塑制品，泡沫材料和由本发明的聚合物或浇铸配混料可获得的淀粉共混物。

9. 发明公开

EP0792310A1 BIOLOGISCH ABBAUBARE POLYMERE, VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBARER FORMKÖRPER 失效
标题翻译： BIOLOGISCH ABBAUBARE POLYMERE，VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBERFORMKÖRPER
公开(公告)号：EP0792310A1
公开(公告)日：1997-09-03
申请号：EP95925768.0
申请日：1995-06-27
申请人： BASF AKTIENGESELLSCHAFT
发明人： WARZELHAN, Volker , BRUCHMANN, Bernd , BOECKH, Dieter , SEELIGER, Ursula , YAMAMOTO, Motonori , BAUER, Peter
IPC分类号： C08J9 , A01G9 , C05F17 , C08G18 , C08G63 , C08L1 , C08L67 , C08L75 , C08L101 , C09J167 , C09J175 , C09K15
CPC分类号： C08G18/4676 , A01G24/00 , C05F17/009 , C08G18/4247 , C08G18/4286 , C08G63/60 , C08G63/672 , C08G2230/00 , C09K15/32 , Y02E50/343 , Y02P20/145 , Y02W30/43 , Y02W30/47
摘要： Biodegradable polyether esters P1 obtainable by the reaction of a mixture consisting essentially of: (a1) a mixture essentially of 20 to 95 mol% adipic acid or ester-forming derivatives thereof or mixtures thereof, 5 to 80 mol% terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and 0 to 5 mol% of a sulphonate group-containing compounds in which the sum of the individual mol percentages is 100; and (a2) a mixture of dihydroxy compounds consisting essentially of (a21) 15 to 99 mol% of a dihydroxy compound selected from the group consisting of C2-C6 alkane diols and C5-C10 cycloalkane diols; (a22) 85 to 0.2 mol% of an ether function-containing dihydroxy compound as in formula I HO-[(CH2)n-O]m-H in which n is 2, 3 or 4 and m is a whole number from 2 to 250, or mixtures thereof, in which the molar ratio of (a1) to (a2) is in the range from 0.4:1 to 1.5:1 with the proviso that the polyether esters P1 have a molar weight (Mn) in the range from 5,000 to 80,000 g/mol, a viscosity index in the range from 30 to 450 g/ml (measured in o-dichlorobenzole/phenol (weight ratio 50/50) at a concentration of 0.5 wt.% polyether esters P1 at a temperature of 25 °C) and a melting point in the range from 50 to 200 °C, and with the further proviso that from 0.01 to 5 mol%, in relation to the molar quantity of the components (a1) used, of a compound D with at least three groups capable of ester formation are used to produce the polyether esters P1, and other biodegradable polymers and thermoplastic moulding compounds, process for their production and biodegradable mouldings, adhesives, foams and blends with starch obtainable from the polymers or moulding compounds of the invention.
摘要翻译：可生物降解的聚醚酯P1可通过基本上由以下组分组成的混合物反应获得：（a1）主要由20-95mol％己二酸或其成酯衍生物或其混合物组成的混合物，5-80mol％对苯二甲酸或酯形成其衍生物或其混合物，以及0-5mol％含磺酸盐基团的化合物，其中各个mol％的总和为100; （a2）基本上由（a21）15-99摩尔％选自C2-C6链烷二醇和C5-C10环链烷二醇的二羟基化合物组成的二羟基化合物的混合物; （a22）85至0.2摩尔％的式I的含醚官能团的二羟基化合物HO - [（CH2）nO] mH其中n为2,3或4且m为2至250的整数，或其中（a1）与（a2）的摩尔比在0.4:1至1.5:1的范围内，条件是聚醚酯P1的摩尔重量（Mn）为5,000至80,000 g / mol，粘度指数为30-450g / ml（在邻二氯苯甲醚/苯酚（重量比50/50）中测量，浓度为0.5重量％聚醚酯P1，温度为25℃ ），熔点为50-200℃，进一步条件是相对于所用组分（a1）的摩尔量，0.01-5摩尔％的化合物D具有至少三个用于形成酯的基团用于生产聚醚酯P1和其它可生物降解的聚合物和热塑性模塑化合物，它们的生产方法和可生物降解的模塑制品，粘合剂，泡沫塑料和与可从本发明的聚合物或模塑料获得的淀粉共混。

10. 发明授权

EP0927212B1 BIOLOGISCH ABBAUBARE POLYESTER 失效
标题翻译：可生物降解聚酯
公开(公告)号：EP0927212B1
公开(公告)日：2000-06-28
申请号：EP97943850.4
申请日：1997-09-19
申请人： BASF AKTIENGESELLSCHAFT
发明人： KOWITZ, Christoph , BAUER, Peter , BEIMBORN, Dieter, Bernhard , BRUCHMANN, Bernd , FALLER, Uwe , LAUN, Martin , PAGGA, Udo , PIPPER, Gunter , WARZELHAN, Volker
IPC分类号： C08G18/42
CPC分类号： C08G63/20 , C08G18/4216 , C08G18/7664 , C08G18/791 , C08G2170/20 , C08G2230/00 , Y10T428/2913

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