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    • 5. 发明专利
    • DE102005037294A1
    • 2007-02-15
    • DE102005037294
    • 2005-08-08
    • BASF AG
    • LANG NEVENSTROEFER ECKHARDSTAMMER ACHIMFRIESE THORSTENSIEGERT MARKUSHASSE HANSGRUETZNER THOMASBLAGOV SERGEJ
    • C07D323/06
    • The invention relates to an integrated process for preparing trioxane from formaldehyde in which, in a first step, a stream A 1 comprising water and formaldehyde and a recycle stream B 2 consisting substantially of water and formaldehyde are fed to a trioxane synthesis reactor in which the formaldehyde is converted to trioxane to obtain a product stream A 2 comprising trioxane, water and formaldehyde. Stream A 2 and a recycle stream D 1 comprising trioxane, water and formaldehyde are fed to a first distillation column and distilled at a pressure in the range from 0.1 to 2.5 bar to obtain a stream B 1 enriched in trioxane, and the stream B 2 consisting substantially of water and formaldehyde. Stream B 1 is fed to a second distillation column and distilled at a pressure in the range from 0.2 to 17.5 bar to obtain a product stream C 2 consisting substantially of trioxane, and a stream C 1 comprising trioxane, water and formaldehyde. Stream C 1 is fed to a third distillation column and distilled at a pressure in the range from 1 to 10 bar to obtain the recycle stream D 1 comprising trioxane, water and formaldehyde, and a stream D 2 consisting substantially of water.
    • 8. 发明专利
    • INTEGRATED METHOD FOR THE PREPARATION OF TRIOXANE FROM FORMALDEHYDE
    • CA2654892A1
    • 2007-12-21
    • CA2654892
    • 2007-06-11
    • BASF AG
    • LANG NEVENSTROEFER ECKHARDSIGWART CHRISTOPHSIEGERT MARKUS
    • C07D323/06
    • Integrated method for the preparation of trioxane from formaldehyde, comp rising the steps: a) introduction of a feeding flow A1 containing formaldehy de and water and a return flow B3 consisting essentially of formaldehyde and trioxane into a formaldehyde concentration unit, wherein said flows are sep arated into a formaldehyde-rich flow A2 and a flow A3 consisting essentially of water; b) introduction of a product flow C1, containing trioxane, water, and formaldehyde, a return flow E1 containing trioxane, water, and formalde hyde, and possibly flow A2 into a first low-pressure distillation column, wh erein said flows are distilled at a pressure of from 0.1 to 1.5 atmospheres, with a trioxane-enriched flow B1 containing predominantly trioxane, and als o water and formaldehyde, a slough removal flow B2 consisting essentially of formaldehyde and water, and the return flow B3 containing predominantly wat er, and also formaldehyde and trioxane removed as a side removal flow; c) in troduction of a slough removal flow B2 and possibly the flow A2 into a triox ane synthesis reactor, wherein said flows are allowed to react, and wherein the flow C1 containing trioxane, water, and formaldehyde is obtained; d) int roduction of a flow B1 into a mid-pressure distillation column, wherein said flow is distilled at a pressure of from 1.0 to3.0 atmospheres, wherein a lo w boiler stream D1 containing methanol, methylal, and methylformate,and a st ream D2 containing predominantly trioxane and also formaldehyde and water ar e obtained; e) introduction of a stream D2 into a high-pressure distillation column, wherein said stream is distilled at a pressure of from 2.5 to 10.0 atmospheres, wherein the return flow E1 contains trioxane, water, and formal dehyde, and a product flow E2 consisting essentially of trioxane is obtained ; wherein flow A2 can be introduced into either the low-pressure distillatio n column or into the trioxane-35 synthesis reactor, or into both.