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    • 8. 发明专利
    • Method for applying integrated pre-treatment layers, comprises applying cross linkable preparation containing e.g. corrosion protection agent, on metallic surface and thermally- and/or photochemically cross linking the layer
    • DE102005061317A1
    • 2007-06-21
    • DE102005061317
    • 2005-12-20
    • BASF AG
    • GOETHLICH ALEXANDERVANDERMEULEN GUIDOHICKL MARKUSDORNBUSCH MICHAELWITTELER HELMUTFERNANDEZ GONZALEZ MONICA
    • C09D5/08B05D7/16C09D5/12C09D5/46C09D175/06
    • Method for applying integrated pre-treatment layers with a thickness of 1-25 mu m, comprises applying cross linkable preparation on the metallic surface and thermally- and/or photochemically cross linking the layer, where the preparation contains e.g. corrosion protection agent, which is a copolymer from (a) monoethylenic unsaturated hydrocarbon, (b) 4-8C monoethylenic unsaturated dicarboxylic acid and (c) other ethylenic unsaturated monomers. Method for applying integrated pre-treatment layers with a thickness of 1-25 mu m to metallic surfaces, comprises applying a cross linkable preparation (A) on the metallic surface and thermally- and/or photochemically cross linking the applied layer, where (A) contains at least 20-70 wt.% of at least one thermal and/or photochemical cross linkable binder system, 20-70 wt.% of at least fine particle-inorganic fillers with an average particle size of less than 10 mu m, 0.25-40 wt.% of at least one corrosion protection agent and optionally a solvent, where the corrosion protection agent is at least a copolymer, obtained from (a) 70-30 mol.% of at least a monoethylenic unsaturated hydrocarbon (a1) and/or at least one monomer (monoethylenic unsaturated hydrocarbons modified with functional groups X 1> (a2) and vinylethers (a3)), (b) 30-70 mol.% of at least 4-8C monoethylenic unsaturated dicarboxylic acid, its anhydride and/or derivatives (where the derivatives are esters of dicarboxylic acids with alcohols of formula (HO-R 1>-X 2> n), amides, imides with ammonia and/or amines of formula (HR 2>N-R 1>-X 2> n)) and (c) 0-10 mol.% of other ethylenic unsaturated monomers, which are different from (a) and (b), but are copolymerizable with (a) and (b), where the quantities in each case are referred to the total quantity of all monomer units in the copolymer. R 1>(n+1)-value of 1-40C hydrocarbons, optionally substituted with non-adjacent C-atoms and O and/or N; R 2>H, 1-10C hydrocarbon group or -(R 1>-X 2> n); n : 1-3; and X 2>a functional group. Independent claims are included for: (1) a molded article with a metallic surface, which is coated with an integrated pretreatment layer with a thickness of 1-25 mu m obtained by the above procedure; and (2) a preparation (A) for applying integrated pretreatment layers on metallic surfaces.
    • 10. 发明专利
    • Method for applying corrosion protection layer on metallic surfaces comprises treating the surface with a formulation having binding agent, pigment and/or filler and corrosion protecting agent, which is a thioamide group containing compound
    • DE102005004292A1
    • 2006-08-03
    • DE102005004292
    • 2005-01-28
    • BASF AG
    • FERNANDEZ GONZALEZ MONICAHICKL MARKUSMOCK-KNOBLAUCH CORDULAESSIG MANFREDHENNIG INGOLF
    • C09D5/08B05D7/14C09D5/12C09D5/46
    • Method for applying corrosion protection layer on a metallic surface comprises treating the surface with a formulation containing at least one binding agent, a pigment and/or a filler and a corrosion protecting agent, which is at least one thioamide group containing compounds. Method for applying corrosion protection layer on a metallic surface comprises treating the surface with a formulation containing at least one binding agent, a pigment and/or a filler and a corrosion protecting agent, which is at least one thioamide group of formula -C(S)NR 1>R 2> containing compounds such as thioamide compound (D1) of formula R 4> n-R 3>-C(S)NR 1>R 2> or thioamide (D2) with at least two thioamide group. n : 1-5; R 1>, R 2>H or optionally substituted 1-20C alkyl; R 3>(n+1)-valenced 1-30C hydrocarbon; and R 4>functional group. Independent claims are included for: (1) a method for applying an integrated pretreating layer on metallic surface comprising treating the metallic surface with a crosslinkable preparation, containing a binding agent, a crosslinkable component, where the crosslinkable group is bounded with the binding agent and/or additionally a crosslinker is used, a pigment and/or filler, a corrosion protecting agent and optionally a solute, and crosslinking the applied layer, where the amount of the binding agent is 20-70 wt.%, filler contains 20-70 wt.% of at least one inorganic fine particulate fillers with an average particle size of less than 10 mu m, and the corrosion protecting agent contains 0.25-10 wt.% of thioamide group containing compounds, where the wt.% relate to the sum of all components except the solute; (2) a polymer comprising at least two terminally and/or laterally positioned thioamide group of formula -C(S)NR 1>R 2>; (3) integrated pretreating layer on a metallic surface of steel, zinc or its alloy or aluminum or its alloy obtained by the method; (4) metallic surface comprising the integrated pretreating layer; (5) a strip metal from steel containing a coating from zinc or its alloy comprising the surface; (6) a preparation, for applying corrosion protection layer on metallic surface, comprising at least one binding agent, a pigment and/or a filler and a corrosion protecting agent, which is at least one thioamide group of formula -C(S)NR 1>R 2> containing compounds such as thioamide compound (D1) of formula R 4> n-R 3>-C(S)NR 1>R 2> or thioamide (D2) with at least two thioamide group; and (7) a preparation, for applying an integrated pretreating layer on metallic surface, comprising a binding agent, a crosslinkable component, where the crosslinkable group is bounded with the binding agent and/or additionally a crosslinker is used, a pigment and/or filler, a corrosion protecting agent and optionally a solute, where the amount of the binding agent is 20-70 wt.%, filler contains 20-70 wt.% of at least one inorganic fine particulate fillers with an average particle size of less than 10 mu m, and the corrosion protecting agent contains 0.25-10 wt.% of thioamide group containing compounds, where the wt.% relate to the sum of all components except the solute.