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1. 发明申请

WO9932429A3 METHOD FOR PRODUCING SECONDARY AMINES FROM NITRILES AND PRIMARY AMINES 审中-公开
标题翻译：用于生产仲胺由伯胺和腈
公开(公告)号：WO9932429A3
公开(公告)日：1999-08-26
申请号：PCT/EP9808248
申请日：1998-12-16
申请人： BASF AG , FUCHS EBERHARD , BREITSCHEIDEL BORIS , OHLBACH FRANK , STEFFEN FRANK , HUNGER JUERGEN
发明人： FUCHS EBERHARD , BREITSCHEIDEL BORIS , OHLBACH FRANK , STEFFEN FRANK , HUNGER JUERGEN
IPC分类号： C07C209/48 , C07C211/08 , C07C211/34
CPC分类号： C07C209/48 , C07C2601/14 , C07C211/08 , C07C211/34
摘要： The invention relates to a method for producing amines of general formula (I) X(-CH2-NHR)n in which R independently represents C1-200-alkyl, C3-8-cycloalkyl, C4-20-alkyl cycloalkyl, C4-20-cylcoalkyl alkyl, C2-20-alkoxyalkyl, aryl, C7-20-alkylaryl, C7-20-aryl alkyl, C2-8-hyrodoxyalkyl, C2-8-mercaptoalkyl, C8-20-aryloxyalkyl or jointly represents a saturated or unsaturated C2-6-alkylene chain which is optionally substituted singly to triply by C1-4-alkyl and is optionally interrupted by oxygen or nitrogen. X is a C1-20-alkyl, C2-20-alkenyl or C3-8-cycloalkyl with n free valances optionally substituted by C1-20-alkyl, C3-8-cycloalkyl, C4-20-alkyl cycloalkyl, C4-20-cycloalkyl alkyl, C2-20-alkoxyalkyl, aryl, C7-20-alkylaryl, C7-20-aryl alkyl, C1-20-alkoxy, hydroxy, C1-20-hyrodoxyalkyl, amino, C1-20-alkyl amino, C2-20-dialkyl amino, C2-12-alkenyl amino, C3-8-cycloalkyl amino, aryl amino, diaryl amino, aryl-C1-8-alkyl amino, halogen, mercapto, C2-20-alkenyloxy, C3-8-cycloalkoxy, aryloxy, and C2-8-alkoxycarbonyl, and n is a whole number from 1 to 4. The amines are produced by reacting nitriles of general formula (II) X(-CN)n in which X and n have the above mentioned meanings with primary amines of general formula (III) H2NR in which R has the above mentioned meanings, and with hydrogen at temperatures ranging from 50 to 250 DEG C and pressure ranging from 5 to 350 bar in the presence of a catalyst containing Pd, whereby the catalyst comprises 0.1 to 10 wt. % Pd on a carrier, said wt. % being relative to the total weight of the catalyst.
摘要翻译：一种制备通式的胺（I）X（CH 2 NHR）n，其中R独立地C1-200烷基，C 3-8环烷基，C 4-20烷基环烷基，C 4-20环烷基烷基，C2过程 20烷氧基烷基，芳基，C7-20烷基芳基，C7-20芳烷基，C2-8羟基烷基，C2-8巯基烷基，C 8-20芳氧基烷基或一起任选地被单取代由C 1-4 - 烷基取代的三取代饱和或不饱和，任选地被氧或氮C 2-6亚平均X是任选被C 1-20烷基取代的，C 3-8环烷基，C 4-20烷基环烷基，C 4-20环烷基烷基，C 2-20烷氧基烷基中断芳基，C7-20烷基芳基，C7-20芳烷基，C1-20烷氧基，羟基，C 1-20羟基烷基，氨基，C 1-20烷基氨基，C 2-20二烷基氨基，C 2-12 - 烯基，C3 8环烷基氨基，芳氨基，二芳基氨基，芳基-C 1-8 - 烷基氨基，卤素，巯基，C 2-20链烯氧基，C 3-8 - 环烷氧基，芳氧基，C2-8烷氧羰基取代的C 1-20 - 烷基，C 2-20 - 链烯基或C 3-8 - 环烷基，其中n自由价并且n是从1到4的整数，通过使通式腈（II）X（-CN）n，其中X和n具有以上给出的含义，与通式的伯胺（III）H 2 NR ，其中R具有上述含义，并在温度为50至5〜350巴的含Pd催化剂的存在下250℃，氢气压力，其中，基于所述催化剂的总重量计所述催化剂为0.1〜10重量包含.-在支撑％的Pd。

2. 发明申请

WO2005123821A3 CYCLOHEXANE POLYCARBOXYLIC ACID DERIVATIVES CONTAINING ADJUVANTS 审中-公开
标题翻译： TOOLS含CYCLOHEXANPOLYCARBONSÄUREDERIVATE
公开(公告)号：WO2005123821A3
公开(公告)日：2006-09-08
申请号：PCT/EP2005006682
申请日：2005-06-21
申请人： BASF AG , STORZUM UWE , BREITSCHEIDEL BORIS
发明人： STORZUM UWE , BREITSCHEIDEL BORIS
IPC分类号： C08K5/12 , C07C67/303 , C07C69/75
CPC分类号： C08K5/12 , C07C67/303 , C07C69/75
摘要： Use of 1,2-cyclohexane dicarboxylic acid esters selected from the group consisting of 1,2-diisobutylcyclohexane dicarboxylic acid esters, 1,2-Di-(2-ethylhexyl)-cyclohexane dicarboxylic acid esters and 1,2-diisononylcyclohexane dicarboxylic acid esters in adjuvants or as adjuvants selected from the group consisting of the following; auxiliary flowing agents, auxiliary film forming agents, de-foamers, foam-preventing agents, wetting agents, coalescing agents and emulsifiers; lubricants selected from lubricating oils, lubricating greases and lubricating pastes; auxiliary calendering agents; auxiliary rheology agents, quenchers for chemical reactions; phlegmatizing agents; pharmaceutical products; softeners in adhesives; impact resistance modifiers and standardizing agents, in addition to surfactant compositions, auxiliary calendering agents, auxiliary rheology agents, quenchers for chemical reactions, phlegmatizing agents, pharmaceutical products, softeners in adhesives, impact resistance modifiers and standardizing agents containing cyclohexane polycarboxylic acid derivatives.
摘要翻译：使用1,2-环己烷二选自1,2-Diisobutylcyclohexandicarbonsäureester组成的组中，选自1,2-二 - （2-乙基己基）-cyclohexandicarbonsäureester和1,2-Diisononylcyclohexandicarbonsäureester在赋形剂或作为一种辅助由以下组成的下列佐剂：从流，成膜助剂，消泡剂，消泡剂，润湿剂，聚结剂和乳化剂选择的表面活性剂组合; 从润滑油，润滑油脂和润滑膏选择润滑剂; Kalandrierhilfsmitteln; 流变助剂，淬灭剂进行化学反应; 脱敏剂; 医药产品; 增塑剂的粘合剂; 抗冲改性剂和增量剂，以及表面活性组合物Kalandrierhilfsmittel，流变剂，猝灭剂进行化学反应，减敏剂，药物产品，在粘合剂中的增塑剂; 抗冲改性剂和包含Cyclohexanpolycarbonsäurederivate致动装置。

3. 发明申请

WO2008006834A3 USE OF IMIDAZOLE COMPOUNDS AS PLASTICISERS 审中-公开
标题翻译：咪唑化合物用作软件制造商
公开(公告)号：WO2008006834A3
公开(公告)日：2008-03-06
申请号：PCT/EP2007057058
申请日：2007-07-10
申请人： BASF AG , BERGNER EIKE JOHANNES , EBEL KLAUS , WEIGL HAGEN , BREITSCHEIDEL BORIS , HOLZMANN JUERGEN
发明人： BERGNER EIKE JOHANNES , EBEL KLAUS , WEIGL HAGEN , BREITSCHEIDEL BORIS , HOLZMANN JUERGEN
IPC分类号： C08K5/3445 , C07D233/54 , C08L27/06
CPC分类号： C07D233/58 , C08K5/3445 , C08L27/06
摘要： The invention relates to the use of an imidazole compound of formula (I) as a plasticiser for polyvinyl chloride, in which formula: R 1 represents hydrogen, alkyl, cycloalkyl, aryl or aralkyl, the last three named groups being unsubstituted, or substituted by alkyl; and R 2 represents alkyl, cycloalkyl, aryl or aralkyl, the last three named groups being unsubstituted, or substituted by alkyl and the R 2 group having at least 7 carbon atoms.
摘要翻译：使用式（I）作为聚氯乙烯（I）增塑剂的咪唑化合物进行说明，其中R ^{1 是氢，烷基，环烷基，芳基或芳烷基，其中最后三个提到的基团是未取代的或者被烷基取代的可以被替代; 且R ^{2 是烷基，环烷基，芳基或芳烷基，其中最后三个提到的基团可以是未取代或由烷基取代，并且R ^{2 具有至少7个碳原子。}}}

4. 发明申请

WO2010069796A3 INSECTICIDAL POLYMER COMPOSITION 审中-公开
标题翻译：杀虫剂聚合物组合物
公开(公告)号：WO2010069796A3
公开(公告)日：2010-11-25
申请号：PCT/EP2009066491
申请日：2009-12-07
申请人： BASF SE , BREITSCHEIDEL BORIS , ISHAQUE MICHAEL , HARMSEN SVEN , WAGNER JOCHEN
发明人： BREITSCHEIDEL BORIS , ISHAQUE MICHAEL , HARMSEN SVEN , WAGNER JOCHEN
IPC分类号： A01N25/10 , A01N25/34 , A01N53/00 , A01P7/04
CPC分类号： A01N25/10 , A01N25/18 , A01N53/00 , C08K5/0016 , C08K5/0058 , A01N2300/00
摘要： The present invention relates to a polymer composition comprising a polymer, a plasticizer, and an insecticide and/or an insect repellent. Further, it relates to a process for the preparation of a molding comprising heat-molding the polymer composition. The invention also relates to a plasticizer composition comprising an insecticide and/or an insect repellent, and a plasticizer. Additionally, it relates to a molding comprising the polymer composition, and to a use of the molding for the control of insects.
摘要翻译：本发明涉及包含聚合物，增塑剂和杀虫剂和/或驱虫剂的聚合物组合物。此外，它涉及一种用于制备包括热成型聚合物组合物的模制品的方法。本发明还涉及包含杀虫剂和/或驱虫剂和增塑剂的增塑剂组合物。另外，它涉及一种包含聚合物组合物的模制品，并涉及该模制品用于防治昆虫的用途。

5. 发明专利

CA2127435A1 COBALT CATALYSTS 未知
公开(公告)号：CA2127435A1
公开(公告)日：1995-02-01
申请号：CA2127435
申请日：1994-07-05
申请人： BREITSCHEIDEL BORIS , POLANEK PETER , IRGANG MATTHIAS , PETERSEN HERMANN , LINDEN GERD , VOIT GUIDO , WITZEL TOM
发明人： BREITSCHEIDEL BORIS , POLANEK PETER , IRGANG MATTHIAS , PETERSEN HERMANN , LINDEN GERD , VOIT GUIDO , WITZEL TOM
IPC分类号： B01J23/889 , B01J27/185 , B01J27/187 , B01J37/08 , C07B61/00 , C07C209/48 , C07C209/50 , C07C211/36 , B01J23/84 , C07C221/00 , C07C225/14
摘要： Cobalt catalysts of the disclosure: Cobalt catalysts whose catalytically active material comprises from 55 to 98 wt%of cobalt, from 0.2 to 15 wt% of phosphorus, from 0.2 to 15wt% of manganese, and from 0.2 to 15 wt% of alkali metal, calculated as oxide, In which the catalyst material is calcined in a first step at final temperatures of from 550.degree. to 750.degree.C and in a second step at final temperatures of from 800.degree. to 1000.degree.C, and a process for the hydrogenation of organic nitriles and/or imines, in which the novel cobalt catalyst is used.

6. 发明专利

CA2170555C PREPARATION OF 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE 未知
公开(公告)号：CA2170555C
公开(公告)日：2006-06-27
申请号：CA2170555
申请日：1996-02-28
申请人： VOIT GUIDO , WITZEL TOM , BREITSCHEIDEL BORIS , HARDER WOLFGANG , LUYKEN HERMANN , PAUL AXEL , ROS KARL-HEINZ , WAHL PETER
发明人： VOIT GUIDO , WITZEL TOM , BREITSCHEIDEL BORIS , HARDER WOLFGANG , LUYKEN HERMANN , PAUL AXEL , ROS KARL-HEINZ , WAHL PETER
IPC分类号： B01J23/46 , C07C211/36 , B01J23/75 , B01J23/755 , C07B61/00 , C07C209/48
摘要： A process for the preparation of 3-aminomethyl-3,5,5- trimethylcyclohexylamine from 3-cyano-3,5,5-trimethyl- cyclohexanone in three spatially separated reaction spaces, which comprises a) reacting the 3-cyano-3,5,5-trimethylcyclohexanone with excess ammonia on acidic metal-oxide catalysts in a first reaction space at from 20 to 150.degree.C and from 50 to 300 bar, b) hydrogenating the resultant reaction products using hydrogen in a second reaction space in the presence of excess ammonia on hydrogenation catalysts, with or without basic components or on neutral or basic supports at from 50 to 100.degree.C and at from 50 to 300 bar, and c) hydrogenating the resultant reaction products in the presence of hydrogen in a third reaction space on hydrogenation catalysts, with or without basic components or on neutral or basic supports at from 110 to 160.degree.C and at from 150 to 300 bar.

7. 发明专利

CA2175271C COBALT CATALYSTS FOR THE HYDROGENATION OF NITRILES AND/OR IMINES 未知
公开(公告)号：CA2175271C
公开(公告)日：2007-06-19
申请号：CA2175271
申请日：1996-04-29
申请人： BREITSCHEIDEL BORIS , POLANEK PETER , VOIT GUIDO , WITZEL TOM , LINDEN GERD , HESSE MICHAEL
发明人： BREITSCHEIDEL BORIS , POLANEK PETER , VOIT GUIDO , WITZEL TOM , LINDEN GERD , HESSE MICHAEL
IPC分类号： B01J27/187 , B01J23/75 , B01J23/78 , B01J23/889 , B01J27/185 , C07B61/00 , C07C209/44 , C07C209/48 , C07C209/52 , C07C211/03 , C07C211/36
摘要： Cobalt catalysts whose catalytically active composition comprises from 55 to 98 % by weight of cobalt, from 0.2 to 15 % by weight of phosphorus, from 0.2 to 1.5 % by weight of manganese and from 0.05 to 5 % by weight of alkali metal, calculated as oxide, are prepared by calcining the catalyst composition, reducing it at final temperatures of from 200 to 400.degree.C in a stream of hydrogen and subsequently surface-oxidizing it by treatment in a stream of air at final temperatures of from 20 to 60.degree.C and can be used in a process for hydrogenating organic nitriles and/or imines.

8. 发明专利

CA2197109C HYDROGENATION OF AROMATIC COMPOUNDS IN WHICH AT LEAST ONE HYDROXYL GROUP IS BONDED TO AN AROMATIC RING 未知
公开(公告)号：CA2197109C
公开(公告)日：2006-07-04
申请号：CA2197109
申请日：1997-02-07
申请人： RUHL THOMAS , BREITSCHEIDEL BORIS , RUTTER HEINZ , WETTLING THOMAS , HENKELMANN JOCHEM
发明人： RUHL THOMAS , BREITSCHEIDEL BORIS , RUTTER HEINZ , WETTLING THOMAS , HENKELMANN JOCHEM
IPC分类号： B01J23/46 , B01J23/89 , C07B61/00 , C07C29/20 , C07C35/08 , C07C35/21 , C07C41/20 , C07C43/196
摘要： A process for hydrogenating aromatic compounds in which at least one hydroxyl group is bonded to an aromatic ring comprises bringing at least one of these compounds into contact with free hydrogen in the presence of a catalyst, wherein the catalyst comprises ruthenium and, if desired, at lea st one metal of transition groups I, VII and VIII in an amount of from 0.01 to 30% by weight, preferably from 0.2 to 15 % by weight, based on the total weight of the catalyst, applied to a support, where the support has a mean pore diameter of at least 0.1 .mu.m, preferably at least 0.5 .mu.m, and a surface area of at most 15 m2/g, preferably at most 10 m2/g.

9. 发明专利

CA2255235A1 PREPARATION OF 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE HAVING A CIS/TRANS ISOMER RATIO OF AT LEAST 70:30 未知
公开(公告)号：CA2255235A1
公开(公告)日：1999-06-18
申请号：CA2255235
申请日：1998-12-15
申请人： ROS KARL-HEINZ , BREITSCHEIDEL BORIS , WITZEL TOM , VOIT GUIDO , LUYKEN HERMANN , WAHL PETER
发明人： ROS KARL-HEINZ , BREITSCHEIDEL BORIS , WITZEL TOM , VOIT GUIDO , LUYKEN HERMANN , WAHL PETER
IPC分类号： C07C209/26 , C07C209/48 , C07C209/52 , C07C211/36
摘要： A process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine having a cis/trans isomer ratio of at least 70:30 by a) imination of 3-cyano-3,5,5-trimethylcyclohexanone with ammonia in the presence of an imination catalyst at temperatures of from 20.degree. to 150.degr ee.C and pressures of from 1.5 to 30 MPa to form 3-cyano-3,5,5-trimethylcyclohexanone imine followed by b) hydrogenation of the 3-cyano-3,5,5-trimethylcyclohexanone imine in the presence of ammonia over a catalyst containing copper and/or a Group VIII metal at a temperature of from 80.degree. to 160.degree.C and under a pressure o f from 5 to 30 MPa, wherein the catalytic hydrogenation of the 3-cyano-3,5,5-trimethylcyclohexanone imine is carried out in the presence of an acid used in an amount such as to giv e an acid number of from 0.1 to 2, based on 3-cyano-3,5,5-trimethylcyclohexanone used.

10. 发明专利

CA2170555A1 PREPARATION OF 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE 未知
公开(公告)号：CA2170555A1
公开(公告)日：1996-09-04
申请号：CA2170555
申请日：1996-02-28
申请人： VOIT GUIDO , WITZEL TOM , BREITSCHEIDEL BORIS , HARDER WOLFGANG , LUYKEN HERMANN , PAUL AXEL , ROBETA KARL HEINZ , WAHL PETER
发明人： VOIT GUIDO , WITZEL TOM , BREITSCHEIDEL BORIS , HARDER WOLFGANG , LUYKEN HERMANN , PAUL AXEL , ROBETA KARL-HEINZ , WAHL PETER
IPC分类号： B01J23/46 , B01J23/75 , B01J23/755 , C07B61/00 , C07C209/48 , C07C211/36
摘要： A process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine from 3-cyano-3,5,5-trimethyl-cyclohexanone in three spatially separated reaction spaces, which comprises a) reacting the 3-cyano-3,5,5-trimethylcyclohexanone with excess ammonia on acidic metal-oxide catalysts in a first reaction space at from 20 to 150.degree.C and from 50 to 300 bar, b) hydrogenating the resultant reaction products using hydrogen in a second reaction space in the presence of excess ammonia on hydrogenation catalysts, with or without basic components or on neutral or basic supports at from 50 to 100.degree.C and at from 50 to 300 bar, and c) hydrogenating the resultant reaction products in the presence of hydrogen in a third reaction space on hydrogenation catalysts, with or without basic components or on neutral or basic supports at from 110 to 160.degree.C and at from 150 to 300 bar.

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