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    • 2. 发明申请
    • METHOD FOR ISOLATING POLYMETHYL ALKANOIC ACIDS AND FOR THE DISPOSAL OF THE RESULTING WASTES
    • 法分离polymethylolalkanoic和废物流的处置方法那里发生
    • WO0190040A3
    • 2002-05-23
    • PCT/EP0105816
    • 2001-05-21
    • BASF AGWEIGL HAGENEBEL KLAUSSCHULZ GERHARD
    • WEIGL HAGENEBEL KLAUSSCHULZ GERHARD
    • B01D9/02C07C51/285C07C51/43C07C51/47C07C59/105
    • C07C51/43C07C51/285C07C51/47C07C59/105
    • The invention relates to a method for isolating poly- or monomethyl alkanoic acids of the general formula (I), wherein R is the same or different and represents a substituted or unsubstituted hydrocarbon or a methylol group that is produced from the corresponding polymethylol alkanals or monomethylol alkanals of the general formula (II), wherein R has the meaning indicated above, by oxidation with an aqueous solution of hydrogen peroxide. The method further comprises the following steps: a) crystallization, followed by solid/liquid separation (B), thereby obtaining the acid as the first crystallized product (2a) and a mother liquor (3), b) producing in the mother liquor (3) another crystallized product (2b), and removing the resulting mother liquor (3) in another solid/liquid separation (C) from the crystallized product (2b), and c) disposing of the resulting acid-depleted mother liquor (3).
    • 本发明涉及一种用于聚分离的方法或monomethylolalkanoic通式(I)其中R是相同或不同的,并且是一个sustituierten或未取代烃基,或从相应的Polymethylolalkanalen羟甲基或monomethylolalkanals通式(II), 其中R具有上文所示的含义,由Oxdation制备与过氧化氢的水溶液,并且其中(a)一种结晶,接着进行固/液分离(B)中进行,并从该酸作为第一作物(2a)的 并且还母液得到(3),(b)在母液(3)还晶体(2b)中产生,并在进一步结晶(2b的另一个固/液分离(C)所得到的母液(3) )被分离,并且这样得到的,酸耗尽母液(3)设置。