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1. 发明申请

WO2008015170A2 PROCESS FOR REGENERATING RUTHENIUM CATALYSTS FOR THE HYDROGENATION OF BENZENE 审中-公开
标题翻译：再生钌催化剂用于苯甲酸加氢的方法
公开(公告)号：WO2008015170A2
公开(公告)日：2008-02-07
申请号：PCT/EP2007057758
申请日：2007-07-27
申请人： BASF AG , HENKELMANN JOCHEM , BECKER MICHAEL , SCHOENHERR MICHAEL , RUPPEL WILHELM , WEGERLE ULRIKE , STAECK BIANCA
发明人： HENKELMANN JOCHEM , BECKER MICHAEL , SCHOENHERR MICHAEL , RUPPEL WILHELM , WEGERLE ULRIKE , STAECK BIANCA
IPC分类号： B01J23/46 , B01J38/04 , C07C5/10
CPC分类号： B01J38/04 , B01J23/40 , B01J23/462 , B01J23/75 , B01J23/755 , B01J23/96 , C07C5/10 , C07C2523/46 , Y02P20/584 , Y10S585/906 , C07C13/18
摘要： The present application describes a process for regenerating a ruthenium catalyst for the hydrogenation of benzene, which comprises flushing the catalyst with inert gas in a regeneration step until the original or part of the original activity is attained.
摘要翻译：本申请描述了用于苯加氢的钌催化剂的再生方法，包括在再生步骤中用惰性气体吹扫催化剂直至达到原始或部分原始活性。

2. 发明专利

ES2112591T3 未知
公开(公告)号：ES2112591T3
公开(公告)日：1998-04-01
申请号：ES95113509
申请日：1995-08-29
申请人： BASF AG
发明人： RUPPEL WILHELM DR , WEGERLE ULRIKE , TENTEN ANDREAS DR , HAMMON ULRICH DR
IPC分类号： B01J8/06 , B01J21/02 , B01J23/16 , B01J23/28 , C07B61/00 , C07C51/25 , C07C57/04 , C07C57/055
摘要： A process for the catalytic gas-phase oxidation of acrolein to acrylic acid in a multiple contact tube fixed-bed reactor through whose space surrounding the contact tubes only one heat-exchange medium circuit is passed, at elevated temperature on catalytically active multimetal oxides with an acrolein conversion for a single pass of >/=95 mol % and an acrylic acid formation selectivity of >/=90 mol %, which comprises firstly passing the heat-exchange medium through the multiple contact tube fixed-bed reactor longitudinally, considered over the reaction container as a whole, to the contact tubes in cocurrent to the reaction-gas mixture and secondly superposing a transverse flow within the reaction container by means of an arrangement of successive baffles along the contact tubes which leaves passage cross sections free, so as to give a meandrous flow of the heat-exchange medium, seen in longitudinal section through the contact tube bundle, and setting the flow rate of the circulated heat-exchange medium so that its temperature rises by from 2 DEG to 10 DEG C. between the point of entry into the reactor and the point of exit out of the reactor.

3. 发明专利

DE59500906D1 未知
公开(公告)号：DE59500906D1
公开(公告)日：1997-12-04
申请号：DE59500906
申请日：1995-08-29
申请人： BASF AG
发明人： RUPPEL WILHELM DR , WEGERLE ULRIKE , TENTEN ANDREAS DR , HAMMON ULRICH DR
IPC分类号： B01J23/88 , B01J8/06 , B01J21/02 , B01J23/16 , B01J23/887 , B01J27/132 , B01J27/192 , C07B61/00 , C07C45/35 , C07C47/22
摘要： A gas-phase mixture of propene and oxygen is catalytically oxidized by passing a reactant gas mixture comprising propene and oxygen through a plurality of catalyst containing contact tubes in a fixed bed reactor and simultaneously passing only one heat-exchange medium at elevated temperature over the exterior surfaces of the contact tubes in a longitudinal flow pattern which is cocurrent with the direction of flow of the reactants through said tube; simultaneously superposing a transverse flow on said longitudinal flow of heat exchange medium by means of an arrangement of successive baffles along the contact tubes which leave passage cross-sections free, thereby resulting in a meandrous flow of the heat-exchange medium through the reactor and setting the flow rate of said heat-exchange medium so that its temperature between the point of entry of the medium into the reactor and its point of exit increases by 2 DEG to 10 DEG C.; and obtaining product acrolein at a selectivity >/=85 mol % from the reactor at a single pass propene conversion >/=90 mol %.

4. 发明专利

DE4023239A1 未知
公开(公告)号：DE4023239A1
公开(公告)日：1992-01-23
申请号：DE4023239
申请日：1990-07-21
申请人： BASF AG
发明人： MARTAN HANS DR , WEGERLE ULRIKE , RUPPEL WILHELM DR , RIEKERT LOTHAR PROF DR , BECKER DIETER , KOTTER MICHAEL DR
IPC分类号： B01J23/88 , B01J23/887 , B01J27/19 , B01J27/192 , C07B61/00 , C07C45/35 , C07C47/22

5. 发明专利

CZ294400B6 Acrolein catalytic oxidation process to acrylic acid in a gaseous phase 未知
公开(公告)号：CZ294400B6
公开(公告)日：2004-12-15
申请号：CZ229495
申请日：1995-09-07
申请人： BASF AG
发明人： RUPPEL WILHELM DR , WEGERLE ULRIKE , TENTEN ANDREAS DR , HAMMON ULRICH DR
IPC分类号： B01J23/28 , B01J8/06 , B01J21/02 , B01J23/16 , C07B61/00 , C07C51/25 , C07C57/04 , C07C57/055
摘要： In the present invention, there is described a process for the catalytic gas-phase oxidation of acrolein to acrylic acid in a multiple contact tube fixed-bed reactor through whose space surrounding the contact tubes only one heat-exchange medium circuit is passed, at elevated temperature on catalytically active multimetal oxides with an acrolein conversion for a single pass and an acrylic acid formation selectivity, which comprises firstly passing the heat-exchange medium through the multiple contact tube fixed-bed reactor longitudinally, considered over the reaction container as a whole, to the contact tubes in co-current to the reaction-gas mixture and secondly superposing a transverse flow within the reaction container by means of an arrangement of successive baffles along the contact tubes which leaves passage cross sections free, so as to give a meandrous flow of the heat-exchange medium, seen in longitudinal section through the contact tube bundle, and setting the flow rate of the circulated heat-exchange medium so that its temperature rises by from 2 to 10 degC.

6. 发明专利

CZ9502294A3 ACROLEIN CATALYTIC OXIDATION PROCESS TO ACRYLIC ACID IN A GASEOUS PHASE 未知
公开(公告)号：CZ9502294A3
公开(公告)日：1996-03-13
申请号：CZ229495
申请日：1995-09-07
申请人： BASF AG
发明人： RUPPEL WILHELM DR , WEGERLE ULRIKE , TENTEN ANDREAS DR , HAMMON ULRICH DR
IPC分类号： B01J23/28 , B01J8/06 , B01J21/02 , B01J23/16 , C07B61/00 , C07C51/25 , C07C57/055
CPC分类号： B01J8/067 , B01J2208/00212 , C07C51/252 , C07C57/04

7. 发明专利

DE59101073D1 未知
公开(公告)号：DE59101073D1
公开(公告)日：1994-04-07
申请号：DE59101073
申请日：1991-07-11
申请人： BASF AG
发明人： MARTAN HANS DR , WEGERLE ULRIKE , RUPPEL WILHELM DR , RIEKERT LOTHAR PROF DR , BECKER DIETER , KOTTER MICHAEL DR
IPC分类号： B01J23/88 , B01J23/887 , B01J27/19 , B01J27/192 , C07B61/00 , C07C45/35 , C07C47/22

8. 发明专利

CZ294399B6 Process of catalytic oxidation of propylene to acrolein in gaseous phase 未知
公开(公告)号：CZ294399B6
公开(公告)日：2004-12-15
申请号：CZ229395
申请日：1995-09-07
申请人： BASF AG
发明人： RUPPEL WILHELM DR , WEGERLE ULRIKE , TENTEN ANDREAS DR , HAMMON ULRICH DR
IPC分类号： B01J23/88 , B01J8/06 , B01J21/02 , B01J23/16 , B01J23/887 , B01J27/132 , B01J27/192 , C07B61/00 , C07C45/35 , C07C47/22
摘要： In the present invention, there is described a process of catalytic oxidation of propylene to acrolein in gaseous phase wherein a gas-phase mixture of propene and oxygen is catalytically oxidized by passing a reactant gas mixture comprising propene and oxygen through a plurality of catalyst containing contact tubes in a fixed bed reactor and simultaneously passing only one heat-exchange medium at elevated temperature over the exterior surfaces of the contact tubes in a longitudinal flow pattern which is co-current with the direction of flow of the reactants through said tube; simultaneously superposing a transverse flow on said longitudinal flow of heat exchange medium by means of an arrangement of successive baffles along the contact tubes which leave passage cross-sections free, thereby resulting in a meandrous flow of the heat-exchange medium through the reactor and setting the flow rate of said heat-exchange medium so that its temperature between the point of entry of the medium into the reactor and its point of exit increases by 2 to 10 degC.

9. 发明专利

CZ9502293A3 PROCESS OF CATALYTIC OXIDATION OF PROPYLENE TO ACROLEINE IN GASEOUS PHASE 未知
公开(公告)号：CZ9502293A3
公开(公告)日：1996-04-17
申请号：CZ229395
申请日：1995-09-07
申请人： BASF AG
发明人： RUPPEL WILHELM DR , WEGERLE ULRIKE , TENTEN ANDREAS DR , HAMMON ULRICH DR
IPC分类号： B01J23/88 , B01J8/06 , B01J21/02 , B01J23/16 , B01J23/887 , B01J27/132 , B01J27/192 , C07B61/00 , C07C45/35 , C07C47/22
CPC分类号： B01J27/192 , B01J8/067 , B01J23/8876 , B01J2208/00212 , B01J2208/00221 , B01J2219/00777 , C07C45/35 , C07C47/22

10. 发明专利

CZ229395A3 PROCESS OF CATALYTIC OXIDATION OF PROPYLENE TO ACROLEINE IN GASEOUS PHASE 未知
公开(公告)号：CZ229395A3
公开(公告)日：1996-04-17
申请号：CZ229395
申请日：1995-09-07
申请人： BASF AG
发明人： RUPPEL WILHELM DR , WEGERLE ULRIKE , TENTEN ANDREAS DR , HAMMON ULRICH DR
IPC分类号： B01J23/88 , B01J8/06 , B01J21/02 , B01J23/16 , B01J23/887 , B01J27/132 , B01J27/192 , C07B61/00 , C07C45/35 , C07C47/22
摘要： A gas-phase mixture of propene and oxygen is catalytically oxidized by passing a reactant gas mixture comprising propene and oxygen through a plurality of catalyst containing contact tubes in a fixed bed reactor and simultaneously passing only one heat-exchange medium at elevated temperature over the exterior surfaces of the contact tubes in a longitudinal flow pattern which is cocurrent with the direction of flow of the reactants through said tube; simultaneously superposing a transverse flow on said longitudinal flow of heat exchange medium by means of an arrangement of successive baffles along the contact tubes which leave passage cross-sections free, thereby resulting in a meandrous flow of the heat-exchange medium through the reactor and setting the flow rate of said heat-exchange medium so that its temperature between the point of entry of the medium into the reactor and its point of exit increases by 2 DEG to 10 DEG C.; and obtaining product acrolein at a selectivity >/=85 mol % from the reactor at a single pass propene conversion >/=90 mol %.

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