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    • 1. 发明申请
    • AQUEOUS, ALKALINE, CYANIDE-FREE BATH FOR ELECTRODEPOSITING ZINC AND ZINC ALLOY COATINGS
    • 碱性水,氰化物坏的锌及锌合金镀层电隔离
    • WO2007045650A3
    • 2007-06-14
    • PCT/EP2006067495
    • 2006-10-17
    • BASF AGHEIDENFELDER THOMASNEUMANN JESSICAWITTELER HELMUTHERRERA TABOADA LIDCAY
    • HEIDENFELDER THOMASNEUMANN JESSICAWITTELER HELMUTHERRERA TABOADA LIDCAY
    • C25D3/22C25D3/56
    • C25D3/22C25D3/565
    • The invention relates to aqueous, alkali, cyanide-free baths containing: I) a zinc ion source and, optionally, a source for additional metal ions; II) at least one cationic polycondensation product that can be obtained by the condensation of i) non-cyclic amine (A1), produced by reacting mono(N,N-dialkylaminoalkyl)amine (A1a) with a bifunctional compound (A1b), selected from the group consisting of urea, thio urea, dialkyl carbonates, aliphatic and aromatic dicarboxylic acids and aliphatic and aromatic diisocyanates with a molar ratio of (A1a) to (A1b) ranging from 1.2: 1 to 2.1: 1 or; ii) of a mixture (A2) consisting of at least one non-cyclic amine (A1) and of at least one cyclic amine (A3) with a molar ratio (A1) to (A3) ranging from 10:1 to 1:10 with at least one bifunctional compound (B) selected from the group consisting of halomethyloxiranes and bisepoxides and, provided that at least one cyclic amine (A3) is condensed, with the alkylene dihalogenide and dihalogen alkylether having a molar ratio (B) to (A1) or (B) to (A2) ranging from 0.6: 1 to 1.3: 1.
    • 本发明涉及含有I)的锌离子源和任选的其它金属离子源,水,碱性无氰浴II)由I的缩合)由单声道的反应(N,N制备的非环状胺(A1)获得的至少一种阳离子缩聚产物 二烷基氨基烷基)胺(A1A)(具有1.2选自脲,硫脲,二烷基碳酸酯,脂肪族中选出的双官能化合物A1B)和芳族二羧酸和脂族和芳族二异氰酸酯(摩尔比A1A)至(A1B):1 至2.1:(1:1的混合物,或ii)10的至少一个非环状胺A1)和至少一种环状胺(A3)(以摩尔比A1)至(A3)的A2)(1:1〜1:10具有至少 条件是至少一个环胺(A3)中冷凝选自卤代甲基和双环氧化物和,所述亚烷基二卤化物的选择的双官能化合物(B) 和(B)与(A1)或(B)与(A2)的摩尔比为0.6:1至1.3:1的二卤代烷基醚。