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1. 发明申请

WO2005005495A2 OLEFIN POLYMERIZATION PROCESS 审中-公开
标题翻译： OLEFIN聚合方法
公开(公告)号：WO2005005495A2
公开(公告)日：2005-01-20
申请号：PCT/EP2004007061
申请日：2004-06-29
申请人： BASELL POLYOLEFINE GMBH , TONTI MARIA SILVIA , OBERHOFF MARKUS , FRAAIJE VOLKER , BACHMANN BERND
发明人： TONTI MARIA SILVIA , OBERHOFF MARKUS , FRAAIJE VOLKER , BACHMANN BERND
IPC分类号： C08F4/659 , C08F110/06 , C08F10/00
CPC分类号： C08F110/06 , C08F4/65912 , C08F4/65916 , Y10S526/904 , Y10S526/905 , C08F4/65927 , C08F2/06
摘要： A process for polymerizing one or more alpha-olefins of formula CH2=CHT wherein T is a hydrogen atom or a C1-C20 alkyl radical comprising the following steps: a) contacting in a continuous way one or more of said alpha olefins with a metallocene based catalyst system in a loop reactor, wherein: (i) the reaction is carried out in a liquid medium; (ii) the average residence time of the metallocene-based catalyst system is not more than 30 minutes; (iii) the temperature of the loop ranges from 25° to 70°C; in order to obtain a polymerization degree ranging from 60 to 500 g per gram of catalyst system; b) feeding in continuous the prepolymerized metallocene-based catalyst system obtained in step a) into a polymerization reactor C) polymerizing one or more alpha-olefins, the same or different from the alpha olefins used in step a), in the presence of said prepolymerized metallocene-based catalyst system.
摘要翻译：用于聚合一种或多种式CH 2 = CHT的α-烯烃的方法，其中T是氢原子或C 1 -C 20烷基，其包括以下步骤：a）以连续方式使一种或多种所述α-烯烃与茂金属其中：（i）反应在液体介质中进行; （ii）金属茂系催化剂体系的平均停留时间不超过30分钟; （iii）环路的温度范围为25°至70°C; 以获得每克催化剂体系60至500g的聚合度; b）将在步骤a）中获得的预聚合的茂金属基催化剂体系连续进料到聚合反应器中C）在所述的聚合反应器存在下聚合一种或多种与步骤a）中使用的α-烯烃相同或不同的α-烯烃，预聚金属茂系催化剂体系。

2. 发明申请

WO0196418A3 CATALYTIC SOLID SUPPORTED ON CALCINED HYDROTALCITE FOR OLEFINIC POLYMERISATION 审中-公开
标题翻译： ON用于烯烃聚合固体焙烧水滑石载体上的催化剂
公开(公告)号：WO0196418A3
公开(公告)日：2002-09-19
申请号：PCT/EP0106664
申请日：2001-06-13
申请人： BASELL POLYOLEFINE GMBH , FRAAIJE VOLKER , OBERHOFF MARKUS , PACZKOWSKI NICOLA , SCHOPF MARKUS , BIDELL WOLFGANG , WULFF-DOERING JOACHIM , MIHAN SHAHRAM
发明人： FRAAIJE VOLKER , OBERHOFF MARKUS , PACZKOWSKI NICOLA , SCHOPF MARKUS , BIDELL WOLFGANG , WULFF-DOERING JOACHIM , MIHAN SHAHRAM
IPC分类号： C08F4/02 , C08F4/60 , C08F4/605 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/646 , C08F4/655 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65922 , C08F110/06 , C08F2410/01 , Y10S526/904 , Y10S526/943 , C08F4/65916 , C08F4/025 , C08F2500/24 , C08F2500/18 , C08F2500/12
摘要： The invention relates to a catalytic solid for olefinic polymerisation, comprising A) at least one calcined hydrotalcite and B) at least one organic transition metal compound. The invention further relates to a catalyst system, comprising the catalytic solid, the use of the catalytic solid for the polymerisation or co-polymerisation of olefins and a method for the production of polyolefins by polymerisation or co-polymerisation of olefins in the presence of the catalytic solid.
摘要翻译：催化剂固体用于烯烃聚合，包括A）至少一种煅烧的水滑石，和B）至少一种有机过渡金属化合物，以及包含该催化剂的固体的催化剂体系，使用该催化剂的固体用于烯烃的聚合或共聚，并用于通过在烯烃的聚合或共聚合制备聚烯烃的方法存在下与催化剂固体。

3. 发明申请

WO0196417A3 CATALYST SYSTEM FOR CARRYING OUT OLEFIN POLYMERIZATION COMPRISING A CALCINED HYDROTALCITE SERVING AS A SUPPORTING MATERIAL 审中-公开
标题翻译：催化剂体系烯烃聚合通过煅烧水滑石作为载体材料
公开(公告)号：WO0196417A3
公开(公告)日：2002-09-19
申请号：PCT/EP0106663
申请日：2001-06-13
申请人： BASELL POLYOLEFINE GMBH , MIHAN SHAHRAM , SCHOPF MARKUS , FRAAIJE VOLKER , OBERHOFF MARKUS , PACZKOWSKI NICOLA , BIDELL WOLFGANG , WULFF-DOERING JOACHIM
发明人： MIHAN SHAHRAM , SCHOPF MARKUS , FRAAIJE VOLKER , OBERHOFF MARKUS , PACZKOWSKI NICOLA , BIDELL WOLFGANG , WULFF-DOERING JOACHIM
IPC分类号： C08F4/02 , C08F4/60 , C08F4/605 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/646 , C08F4/655 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F110/00 , C08F110/02
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65922 , C08F110/06 , C08F2410/01 , Y10S526/904 , Y10S526/943 , C08F4/65916 , C08F4/025 , C08F2500/24 , C08F2500/18 , C08F2500/12
摘要： The invention relates to a catalyst system for carrying out olefin polymerization. Said system comprises: A) at least one calcined hydrotalcite; B) at least one organotransition metal compound; C) optionally one or more cation-forming compounds, and; D) at least one organomagnesium compound.
摘要翻译：用于烯烃聚合，包括A）至少一种水滑石烧成体，B）至少一种有机过渡金属化合物，C）任选地一种或多种阳离子形成化合物和D）的至少一种有机镁化合物的催化剂体系。

4. 发明申请

WO2011147573A3 PROCESS FOR PREPARING A SUPPORTED CATALYST SYSTEM FOR OLEFIN POLYMERIZATION, THE CATALYST SYSTEM AND ITS USE 审中-公开
标题翻译：制备支持的烯烃聚合催化剂体系的方法，催化剂体系及其用途
公开(公告)号：WO2011147573A3
公开(公告)日：2012-12-06
申请号：PCT/EP2011002612
申请日：2011-05-26
申请人： BASELL POLYOLEFINE GMBH , FANTINEL FABIANA , MIHAN SHAHRAM , KARER RAINER , FRAAIJE VOLKER
发明人： FANTINEL FABIANA , MIHAN SHAHRAM , KARER RAINER , FRAAIJE VOLKER
IPC分类号： C08F210/16 , C08F4/02 , C08F4/6592 , C08F4/70
CPC分类号： C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61925 , C08L23/0815 , Y10S526/943 , C08F4/025 , C08F4/61904 , C08L2666/06 , C08F210/14 , C08F2500/17 , C08F4/7042
摘要： The invention refers to a process for preparing a supported catalyst system for the polymerization of olefins comprising at least one active catalyst component on a support, the process comprising A) impregnating a dry porous support component with a mixture comprising at least one precatalyst, at least one cocatalyst, and a first solvent, such that the total volume of the mixture is from 0.8 to 2.0 times the total pore volume of the support component, and B) thereafter, adding a second solvent in an amount of more than 1.5 times the total pore volume of the support component. The invention refers further to a catalyst system made by this process and the use of this catalyst system for polymerization or copolymerization of olefins.
摘要翻译：本发明涉及一种制备负载型催化剂体系的方法，所述催化剂体系包括在载体上包含至少一种活性催化剂组分的烯烃聚合，所述方法包括：A）至少将含有至少一种预催化剂的混合物浸渍在干多孔载体组分中，至少一种助催化剂和第一溶剂，使得混合物的总体积为载体组分的总孔体积的0.8-2.0倍，B）然后，加入第二种溶剂的总量的1.5倍以上载体组分的孔体积。本发明还涉及通过该方法制备的催化剂体系和该催化剂体系用于烯烃聚合或共聚的用途。

5. 发明申请

WO0148034A2 TRANSITION METAL COMPOUND, LIGAND SYSTEM, CATALYST SYSTEM AND THE USE OF THE LATTER FOR THE POLYMERISATION AND COPOLYMERISATION OF OLEFINS 审中-公开
标题翻译：过渡金属化合物，配体体系，催化剂体系和及其用途烯烃和共聚的聚合
公开(公告)号：WO0148034A2
公开(公告)日：2001-07-05
申请号：PCT/EP0012642
申请日：2000-12-13
申请人： BASELL POLYPROPYLEN GMBH , SCHOTTEK JOERG , OBERHOFF MARKUS , BINGEL CARSTEN , FISCHER DAVID , WEISS HORST , WINTER ANDREAS , FRAAIJE VOLKER
发明人： SCHOTTEK JOERG , OBERHOFF MARKUS , BINGEL CARSTEN , FISCHER DAVID , WEISS HORST , WINTER ANDREAS , FRAAIJE VOLKER
IPC分类号： C07F7/08 , C07F17/00 , C08F4/44 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16
CPC分类号： C08F210/16 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/06 , C08F210/06 , Y10S526/943 , C08F4/65927 , C08F2500/03 , C08F2500/18 , C08F2500/15 , C08F2500/17 , C08F210/08 , C08F2500/21 , C08F210/14 , C08F2/001
摘要： The invention relates to a method for polymerising olefins, in particular to a method for copolymerising propylene with additional olefins. The invention also relates to specially selected metallocenes, in particular to those types of metallocenes which have different substitutions in position 2 and position 4 on the indenyl ligand, to ligand systems, to highly active catalyst systems and to novel polypropylene copolymers. The inventive polymerisation takes place in the presence of the specially selected metallocenes.
摘要翻译：本发明在2位和4位上，配体体系，高活性的催化剂系统涉及一种方法，用于烯烃，特别是一种用于与其他的烯烃，特别是选择金属茂丙烯的共聚合方法的聚合反应，特别是那些具有在茚基不同的取代，以及新的聚丙烯共聚物是通过在聚合反应中特别选择金属茂的存在下进行。

7. 发明专利

AT403682T 未知
公开(公告)号：AT403682T
公开(公告)日：2008-08-15
申请号：AT03763826
申请日：2003-07-14
申请人： BASELL POLYOLEFINE GMBH
发明人： KRATZER ROLAND , FRAAIJE VOLKER
IPC分类号： C08F10/00 , B01J31/00 , C08F4/44 , C08F4/64 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/06 , C08F110/06
摘要： The present invention relates to a process for preparing a catalyst for olefin polymerization which is obtainable by bringing A) at least one organic transition metal compound, B) a mixture of at least two different organo metallic compounds and C) at least one cation-forming compound into contact with one another, wherein the organic transition metal compound A) is firstly brought into contact with the mixture of the organo metallic compounds B). In addition, the invention relates to the use of the catalyst for olefin polymerization, to catalysts obtainable by this process and to a process for the polymerization of olefins in which these catalysts are used.

8. 发明专利

BR0317318A 未知
公开(公告)号：BR0317318A
公开(公告)日：2005-11-08
申请号：BR0317318
申请日：2003-12-16
申请人： BASELL POLYOLEFINE GMBH
发明人： GREGORIUS HEIKE , FRAAIJE VOLKER , LUTRINGSHAUSER MANFRED
IPC分类号： C08F4/642 , C08F4/6592 , C08F10/00 , C08F110/06
摘要： The present invention relates to a process for preparing a catalyst solid for olefin polymerization, comprising a finely divided support, an aluminoxane and a metallocene compound, which comprises: a) firstly combining the finely divided support with the aluminoxane and subsequently b) adding the reaction product of a metallocene compound with at least one organometallic compound to the modified support, catalyst solids obtainable by this process, catalyst systems comprising these catalyst solids, their use for the polymerization of olefins and a process for the polymerization of olefins.

9. 发明专利

DE69831139D1 未知
公开(公告)号：DE69831139D1
公开(公告)日：2005-09-15
申请号：DE69831139
申请日：1998-03-05
申请人： BASELL POLYOLEFINE GMBH
发明人： BINGEL CARSTEN , GOERES MARKUS , FRAAIJE VOLKER , WINTER ANDREAS
IPC分类号： C07D333/16 , A61K20060101 , C07B37/04 , C07C20060101 , C07C1/20 , C07C1/22 , C07C13/465 , C07C45/67 , C07C45/68 , C07C49/67 , C07C49/683 , C07C49/697 , C07C49/755 , C07C221/00 , C07C225/22 , C07C303/30 , C07C309/65 , C07D20060101 , C07D213/50 , C07D307/46 , C07D333/22 , C07F20060101 , C07F7/00 , C07F7/08 , C07F17/00 , C08F20060101 , C08F4/619 , C08F4/6192 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/06
摘要： A process for the preparation of indanones of the formula II from indanones of the formula I or of indanones of the formula IIa from indanones of the formula Ia comprises reacting an indanone of the formula I or Ia with a coupling component.

10. 发明专利

AU782996B2 Transition metal compound, ligand system, catalyst system and the use of the latter for the polymerisation and copolymerisation of olefins 未知
公开(公告)号：AU782996B2
公开(公告)日：2005-09-15
申请号：AU2511001
申请日：2000-12-13
申请人： BASELL POLYOLEFINE GMBH
发明人： SCHOTTEK JORG , OBERHOFF MARKUS , BINGEL CARSTEN , FISCHER DAVID , WEISS HORST , WINTER ANDREAS , FRAAIJE VOLKER , KRATZER ROLAND
IPC分类号： C07F7/08 , C07F17/00 , C08F4/44 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F4/642
摘要： Novel bridged cyclopentadienyl compounds and corresponding metallocene catalysts are claimed. Bridged cyclopentadienyl compounds (I) are of formula (1). [Image] R 3>, R 4>, R 6>, R 50>H, 1-20C hydrocarbon, preferably 1-18C alkyl, 2-20C alkenyl, 3-15C alkylalkenyl, 6-18C aryl, 5-18C heteroaryl, 7-20C arylalkyl, 7-20C alkylaryl, optionally fluorinated; R 5>isobutyl, isopropyl, isopentyl, isohexyl, cyclopentyl or cyclohexyl; R 20>, R 21>=6-18C aryl, optionally substituted, 5-18C heteroaryl, 7-20C arylalkyl, fluorinated 6-18C aryl or 7-20C arylalkyl and two R 20> or R 21> groups may form a mono- or polycyclic ring system, optionally substituted whereby R 20> and R 21> are not simultaneously naphthyl, phenyl, phenanthrenyl or anthracenyl as well as mixtures of naphthyl and phenyl; Q : 4-24C aryl, a heteroaryl that with the cyclopentadienyl ring forms azapentalene, thiopentalene or phosphapentalene, optionally substituted by R 20>; Z=0-3; l : 0-4, preferably 1; B : a bridging structural element; M : Ti, Zr or Hf, preferably Zr; x : halogen, preferably chlorine, alkyl, preferably methyl or phenolate, optionally substituted. Independent claims are included for: (i) metallocene compounds (II) of formula (2), excluding rac-Me 2Si[2-i-Pr-4-(1-naphthyl)ind)(2'-Me-4'-phInd)ZrCl 2, rac-Me 2Si[2-i-Pr-4-(1-naphthyl)ind)(2'-Me-4',5'-benzind)]ZrCl 2, rac-Me 2Si[2-i-Pr-4-(1-naphthyl)ind)[2'-Me-4',5'-benzind)]ZrCl 2, rac-Me 2Si[2-i-Pr-4-(1-naphthyl)ind)(2'-Me-4'',5'-benzind)]ZrCl 2, rac-Me 2Si[2-i-Pr-4-phenylind)(2'-ethyl-4'-phind)]Zrcl 2, rac-Me 2Si[2-i-Pr-4-(1-naphthyl)ind)(2'-ethyl-4'-PhInd)]Zrcl 2, rac-MeSi[2-i-Pr-4-Phind)(2'-Me-4'-PhInd)]ZrCl 2 and rac-MeSi[2-i-Pr-4-(1-naphthyl)ind)(2'-ethyl-4',5'-benzind)]ZrCl 2; (ii) a catalyst system (III) comprising a metallocene compound (II), at least one cocatalyst and/or at least one support; (iii) a process for the production of a polyolefin by polymerization of an olefin in the presence of the metallocene compounds (II); (iv) propylene homo- or copolymers prepared using the metallocene compound (II).

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