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1. 发明申请

WO2004050724A1 PROCESS FOR PREPARING 1-BUTENE POLYMERS 审中-公开
标题翻译：制备1-丁烯聚合物的方法
公开(公告)号：WO2004050724A1
公开(公告)日：2004-06-17
申请号：PCT/EP2003/012236
申请日：2003-11-03
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , CASCIO INGURGIO, Antonio
发明人： RESCONI, Luigi , CASCIO INGURGIO, Antonio
IPC分类号： C08F10/08
CPC分类号： C08F10/08 , C07F17/00 , C08F4/65912 , C08F110/08 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/20 , C08F2500/03
摘要： A process for obtaining 1-butene polymers optionally containing up to 30% by mol of ethylene, propylene or an alpha-olefin of formula CH 2 =CHZ, wherein Z is a C 3 -C 10 alkyl group s, comprising the step of contacting under polymerization conditions 1-butene and optionally ethylene, propylene or said alpha-olefin, in the presence of a catalyst system obtainable by contacting: a) a metallocene compound of formula (I): R 3 R 2 R 4 0 R~ Rs MXp LLR 6 R 5 R' O R 2 R 4 (I) wherein: M is an atom of a transition metal belonging to group 3, 4, 5, 6 or to the lanthanide or actinide groups in the Periodic Table of the Elements; p is an integer from 0 to 3; X, is a hydrogen atom, a halogen atom, or a hydrocarbon group; R 1 is a hydrocarbon group; RZ, R 3 and R 6 are hydrogen atoms or hydrocarbon groups; R 4 and R 5 join to form a condensed saturated or unsaturaded 4-7 membered ring; and L is a divalent bridging group; and b) an alumoxane or a compound able to form an alkylmetallocene cation.
摘要翻译：一种获得任选含有至多30摩尔％乙烯，丙烯或式CH 2 = CHZ的α-烯烃（其中Z为C 3 -C 10烷基）的1-丁烯聚合物的方法，包括在聚合条件下接触的步骤 1-丁烯和任选的乙烯，丙烯或所述α-烯烃，在催化剂体系存在下可通过以下方式获得：a）式（I）的茂金属化合物：R 3 R 2 R 4 R 〜Rs MXp LLR 6 R 5 R'OR 2 R 4（I）其中：M是属于第3,4,5,6族的过渡金属的原子或镧系元素或锕系元素小组在元素周期表中; p是0至3的整数; X是氢原子，卤素原子或烃基; R 1是烃基; R 3，R 3和R 6是氢原子或烃基; R 4和R 5连接形成稠合的饱和或不饱和4-7元环; L是二价桥基; 和b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

2. 发明申请

WO2006117285A1 PROCESS FOR THE POLYMERIZATION OF ALPHA OLEFINS 审中-公开
标题翻译： ALPHA OLEFINS聚合方法
公开(公告)号：WO2006117285A1
公开(公告)日：2006-11-09
申请号：PCT/EP2006/061545
申请日：2006-04-12
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , GUIDOTTI, Simona , SANTORIELLO, Iolanda
发明人： RESCONI, Luigi , GUIDOTTI, Simona , SANTORIELLO, Iolanda
IPC分类号： C08F10/00 , C08F4/6592 , C07F17/00 , C07F7/08
CPC分类号： C07F7/0818 , C07F17/00 , C08F4/65912 , C08F10/00 , C08F10/08 , C08F110/06 , C08F110/08 , C08F210/08 , Y10S526/943 , C08F4/65927 , C08F2/02 , C08F2500/17 , C08F210/16
摘要： A process for preparing 1-butene polymers, comprising polymerizing 1-butene or copolymerizing 1-butene with ethylene, propylene or an alpha-olefin of formula CHT 2 =CHT wherein T is a C 3 -C 10 alkyl group, in the presence of a catalyst system obtainable by contacting: A) a metallocene compound belonging to formula (I): wherein M is zirconium titanium or hafnium; X, equal to or different from each other, is a hydrogen atom, a halogen atom, a a hydrocarbon radical, optionally containing heteroatoms; R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 are hydrogen atoms, or C 1 -C 4O hydrocarbon radicals optionally containing heteroatoms; R 1 , R 2 and R 3 , are linear or branched, C 1 -C 2o -alkyl radicals, optionally containing heteroatoms; B) a Jumoxane or a compound capable of forming an alkyl metallocene cation; and optionally C) organo aluminum compound.
摘要翻译：一种制备1-丁烯聚合物的方法，包括将1-丁烯或1-丁烯与乙烯，丙烯或式CHT 2 CH = CHT的α-烯烃聚合，其中T是C 3 在可以通过下述方法获得的催化剂体系存在下进行：A）属于式（I）的茂金属化合物：其中M是锆钛或铪; X，彼此相同或不同，是氢原子，卤素原子，烃基，任选地含有杂原子; R 4，R 5，R 6，R 7，R 8， R 9，R 10，R 11，R 12和R 13是氢原子或任选含有杂原子的C 1 -C 40烃基; R 1，R 2和R 3是直链或支链的C 1 -C 2 O 任选地含有杂原子的烷基; B）可以形成烷基茂金属阳离子的Jumoxane或化合物; 和任选的C）有机铝化合物。

3. 发明申请

WO2006005648A1 METALLOCENE COMPOUNDS, LIGANDS USED IN THEIR PREPARATION, PREPARATION OF 1-BUTENE POLYMERS AND 1-BUTENE POLYMERS THEREFROM 审中-公开
标题翻译：金属化合物，其制备中使用的配体，1-丁烯聚合物的制备和其中的1-保加利亚聚合物
公开(公告)号：WO2006005648A1
公开(公告)日：2006-01-19
申请号：PCT/EP2005/052486
申请日：2005-05-31
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , MORHARD, Friederike
发明人： RESCONI, Luigi , MORHARD, Friederike
IPC分类号： C08F10/08
CPC分类号： C07D495/04 , C07D333/78 , C07F7/08 , C07F17/00 , C08F4/65912 , C08F10/00 , C08F10/08 , C08F110/08 , C08F210/08 , C08F2420/06 , C08F4/65927 , C08F2500/17 , C08F2500/15 , C08F2500/11 , C08F210/16 , C08F210/06 , C08F210/14
摘要： A process for preparing 1-butene polymers comprising polymerizing 1-butene and optionally ethylene, propylene or higher alpha-olefin, in the présence of a catalyst system obtainable by contacting: a) metallocene compound of formula (I): wherein: M is a transition metal; p is an integer from 0 to 3; X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group; L is a divalent CI - C40 hydrocarbon radical; R 1 is a C 1 -C 40 hydrocarbon radical; T', is a moiety of formula (Ha) or (IIb): wherein R 2 and R 3 , are C 1 -C 40 hydrocarbon radicals or they can form together a C 3 -C 7 membered ring; R 4 is C 1 -C 40 hydrocarbon radicals; T 2 and T 3 , are a moiety of formula (IIla) wherein R 6 and R 7 , equal to or different from each other, are hydrogen atoms or C 1 -C 40 hydrocarbon radicals; R 5 is a hydrogen atom or a C 1 -C 40 hydrocarbon radicals; with the proviso that if T 1 is a moiety of formula (Ila) at least one between T 2 and T 3 is a moiety of formula (I1Tb), and if T 1 is a moiety of formula (IIb) at least one between T 2 and T 3 is a moiety of formula (IIIa); b) at least an alumoxane or a compound able to form an alkylmetallocene cation
摘要翻译：一种制备1-丁烯聚合物的方法，其包括聚合1-丁烯和任选的乙烯，丙烯或更高级的α-烯烃，催化剂体系可通过使下列物质接触而获得：a）式（I）的茂金属化合物：其中：M为过渡金属; p是0至3的整数; X相同或不同，是氢原子，卤素原子或烃基; L是二价Cl

4. 发明申请

WO2005105865A1 PROCESS FOR THE PREPARATION OF ATACTIC 1-BUTENE POLYMERS 审中-公开
标题翻译：制备单层1-丁烯聚合物的方法
公开(公告)号：WO2005105865A1
公开(公告)日：2005-11-10
申请号：PCT/EP2005/004506
申请日：2005-04-25
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , GUIDOTTI, Simona
发明人： RESCONI, Luigi , GUIDOTTI, Simona
IPC分类号： C08F10/08
CPC分类号： C08F10/08 , C08F4/65912 , C08F110/08 , C08F210/02 , C08F210/08 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/03 , C08F2500/20 , C08F2500/15 , C08F210/06 , C08F210/16
摘要： A process for obtaining atactic 1-butene polymer optionally containing at least one comonomer selected from ethylene, propylene or an alpha-olefin of formula CH2=CHR, wherein R is a linear or branched C3-C 20 alkyl group, comprising the step of polymerizing 1-butene and optionally ethylene, propylene or said alpha-olefin, in the presence of a catalyst system obtainable by contacting: a) at least one metallocene compound of formula (I) in its meso or meso-like form wherein M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group; L is a divalent C 1 -C 40 hydrocarbon radical optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; R' and R 2 , are C 1 -C 40 hydrocarbon radicals; T, equal to or different from each other, is a moiety of formula (IIa) or (Ilb) wherein R 3 is a C I -C 40 hydrocarbon radical; R 4 and R 6 , are hydrogen atoms or C 1 -C 40 hydrocarbon radicals; R 5 is a C I -C 40 hydrocarbon radical; R 7 and R 8 , equal to or different from each other, are hydrogen atoms or C 1 -C 40 hydrocarbon radicals; and b) an alumoxane or a compound capable of forming an alkyl metallocene cation.
摘要翻译：获得任选含有选自乙烯，丙烯或式CH 2 = CHR的α-烯烃的至少一种共聚单体的无规性1-丁烯聚合物的方法，其中R是直链或支链C 3 -C 20烷基，其包括聚合1 丁烯和任选的乙烯，丙烯或所述α-烯烃在催化剂体系的存在下，可通过以下步骤获得： - ）至少一种其中间或内消旋形式的式（I）金属茂化合物，其中M是过渡金属; p是0至3的整数; X相同或不同，是氢原子，卤素原子或烃基; L是任选含有属于元素周期表第13-17族的杂原子的二价C 1 -C 40烃基; R'和R 2是C1-C40烃基; T为相同或不同的式（IIa）或（IIb）的部分，其中R 3为C 1 -C 40烃基; R 4和R 6是氢原子或C 1 -C 40烃基; R 5是C 1 -C 40烃基; R 7和R 8彼此相同或不同，是氢原子或C 1 -C 40烃基; 和b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

5. 发明申请

WO2002100908A1 PROCESS FOR THE POLYMERIZATION OF 1-BUTENE 审中-公开
标题翻译： 1-BOTENE聚合方法
公开(公告)号：WO2002100908A1
公开(公告)日：2002-12-19
申请号：PCT/EP2002/006574
申请日：2002-06-11
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi
发明人： RESCONI, Luigi
IPC分类号： C08F10/08
CPC分类号： C08F110/08 , C08F4/65912 , C08F10/08 , C08F210/08 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/12 , C08F2500/15 , C08F2500/20 , C08F2500/03 , C08F210/16
摘要： A process for polymerizing 1-butene comprising the step of contacting under polymerization conditions 1-butene and optionally from 0 to 20% by mol of an alpha olefin with a catalyst system obtainable by contacting a bridget metallocene compound of formula (I) wherein R 1 and R 2 are an hydrocarbon radical A is a carbon atom, a germanium atom or a silicon atom; m is 1, 2; M is a metal of group 4 of the Periodic Table of the Elements; X, is hydrogen, a halogen atom, or a group R, OR, OSO 2 CF 3 , OCOR, SR, NR 2 or PR 2 , wherein the substituents R are hydrocarbon radical; L is a moiety of formula (IIa) or (IIb) wherein T is an oxigen (O) or sulphur (S) atom or a CH 2 group; and R 3 and R 4 are hydrogen atoms or hydrocarbon radicals; one or more alumoxanes or compounds able to form an alkylmetallocene cation; and optionally an organo aluminium compound.
摘要翻译：一种聚合1-丁烯的方法，包括在聚合条件下使1-丁烯和任选的0至20摩尔％的α-烯烃与可通过使式（I）的桥连金属茂化合物（其中R 1， 1>和R 2是烃基A是碳原子，锗原子或硅原子; m为1,2; M是元素周期表第4族的金属; X是氢，卤素原子或基团R，OR，OSO 2 CF 3，OCOR，SR，NR 2或PR 2，其中取代基R是烃基; L是式（IIa）或（IIb）的部分，其中T是氧原子（O）或硫（S）原子或CH 2基团; R 3和R 4是氢原子或烃基; 一种或多种能够形成烷基茂金属阳离子的铝氧烷或化合物; 和任选的有机铝化合物。

6. 发明申请

WO2006134046A1 PROCESS FOR THE COPOLYMERIZATION OF PROPYLENE 审中-公开
标题翻译：丙烯共聚方法
公开(公告)号：WO2006134046A1
公开(公告)日：2006-12-21
申请号：PCT/EP2006/062964
申请日：2006-06-07
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , CIACCIA, Eleonora , FOCANTE, Francesca
发明人： RESCONI, Luigi , CIACCIA, Eleonora , FOCANTE, Francesca
IPC分类号： C08F210/06 , C08F4/6592
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65916 , C08F210/06 , C08F2/06 , C08F4/65927 , C08F210/16 , C08F2500/17
摘要： A solution polymerization process comprising contacting under polymerization conditions propylene and at least ethylene or an alpha olefin of formula CH 2 =CHT wherein T is a C 2 -C 20 alkyl radical, in the presence of a catalyst system obtainable by contacting: b) at least a metallocene compound of formula (I) b) alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally c) an organo aluminum compound; wherein the groups R 1 R 4 , L, M and W are described in the text.
摘要翻译：一种溶液聚合方法，包括在聚合条件下接触丙烯和至少乙烯或式CH 2 CH 2的α烯烃，其中T是C 2 -C 20 在通过使b）至少一种式（I）的茂金属化合物b）铝氧烷或能够形成烷基金属茂阳离子的化合物可以得到的催化剂体系的存在下，和任选地c）有机铝化合物; 其中基团R 1，R 4，L，M和W在文中描述。

7. 发明申请

WO2006008212A1 PROCESS FOR PRODUCING FRACTIONABLE 1-BUTENE POLYMERS 审中-公开
标题翻译：生产可分离的1-丁烯聚合物的方法
公开(公告)号：WO2006008212A1
公开(公告)日：2006-01-26
申请号：PCT/EP2005/052690
申请日：2005-06-10
申请人： BASELL POLYOLEFINE GMBH , TONTI, Maria, Silvia , RESCONI, Luigi
发明人： TONTI, Maria, Silvia , RESCONI, Luigi
IPC分类号： C08F10/08
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F110/08 , Y10S526/943 , C08F4/65904 , C08F2500/03 , C08F2500/17 , C08F2500/20 , C08F2/001
摘要： A process for producing a 1-butane polymer comprising the step of polymerizing 1-butene in the presence of a catalyst system obtainable by contacting: a) at least a metallocene compound of formula (Ia) in the meso or meso-like form, wherein M is an atom of a transition metal p is an integer from 0 to 3, X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group. L is a divalent C 1 -C 40 hydrocarbon radical R 1 and R 2 , equal to or different from each other, are C 1 -C 40 hydrocarbon radicals; T, equal to or different from each other, is a moiety of formula (IIa), (IIb) or (IIc), wherein R 3 and R 5 are a C 1 -C 40 hydrocarbon radical; R 4 and R 6 , equal to or different from each other, are hydrogen atoms or C 1 -C 40 hydrocarbon radicals and R 7 and R 8 , equal to or different from each other, arc hydrogen atoms or C 1 -C 40 hydrocarbon radicals; b) at least a metallocene compound of formula (Ib) in the racemic (rac) or racemic - like form; c) an alumoxane or a compound capable of forming an alkyl metallocenc cation.
摘要翻译：一种制备1-丁烷聚合物的方法，包括在催化剂体系存在下聚合1-丁烯的步骤，所述催化剂体系可以通过以下步骤获得：a）至少一种以中间或内消旋形式的式（Ia）金属茂化合物，其中 M为过渡金属的原子，p为0〜3的整数，X相同或不同，为氢原子，卤素原子或烃基。 L是二价C

8. 发明申请

WO2006008211A1 1-BUTENE POLYMERS COMPOSITION 审中-公开
标题翻译： 1-BOTENE聚合物组合物
公开(公告)号：WO2006008211A1
公开(公告)日：2006-01-26
申请号：PCT/EP2005/052688
申请日：2005-06-10
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , PELLICONI, Anteo , SPATARO, Stefano , MOSCARDI, Gilberto
发明人： RESCONI, Luigi , PELLICONI, Anteo , SPATARO, Stefano , MOSCARDI, Gilberto
IPC分类号： C08L23/18
CPC分类号： C08L23/18 , C08L23/20 , C08L2205/02 , Y10S526/943 , C08L2666/04
摘要： A 1-butene polymer composition comprising: a) from 5% by weight to 95% by weight of an atactic 1-butene-based polymer, having the following features: - distribution of molecular weight Mw/Mn equal to or lower than 4; - rr triads, measured by 13 C-NMR comprised between 5% and 50%; - no enthalpy of fusion detectable at a differential scanning calorimeter (DSC); - intrinsic viscosity (IV) measured in tetrahydronaphtalene (THN) at 135°C comprised between 0.85 dl/g and 5 dl/g; and - infrared crystallinity lower than 0.5%; b) from 5% by weight to 95% by weight of an isotactic 1-butene-based polymer having the following features: - isotactic pentads (mmmm) measured by 13 C-NMR, higher than 80%; melting point higher than 80°C; and - intrinsic viscosity (IV) measured in tetrahydronaphtalene (THN) at 135°C comprised between 0.1 dl/g and 5 dl/g.
摘要翻译： 1-丁烯聚合物组合物，其包含：a）5重量％至95重量％的无规立构1-丁烯基聚合物，具有以下特征： - 分子量Mw / Mn等于或低于4的分布; - 通过13 C-NMR测量的rr三单元组份在5％至50％之间; - 差示扫描量热仪（DSC）可检测不到融合焓; - 在135℃下在四氢萘（THN）中测得的特性粘度（Ⅳ）为0.85dl / g至5dl / g; 红外结晶度低于0.5％; b）5重量％至95重量％的具有以下特征的全同立构1-丁烯基聚合物： - 通过13 C-NMR测量的全同立构五单元组（mmmm），高于80％ ; 熔点高于80℃; 和在135℃下四氢萘（THN）中测得的特性粘度（Ⅳ）为0.1dl / g至5dl / g。

9. 发明申请

WO2005095468A3 CATALYST SYSTEM FOR THE POLYMERIZATION OF OLEFIN 审中-公开
公开(公告)号：WO2005095468A3
公开(公告)日：2005-10-13
申请号：PCT/EP2005/002479
申请日：2005-03-08
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , MOSCARDI, Gilberto , FAIT, Anna
发明人： RESCONI, Luigi , MOSCARDI, Gilberto , FAIT, Anna
IPC分类号： C08F110/08 , C08F4/602
摘要： A catalyst system solution obtainable by a process comprising the following steps: a) contacting a solution of methylalumoxane in an aromatic solvent (solvent a) with a solution of one or more organ-aluminium in a solvent (solvent b), or a solution of one or more alumoxanes different from methylalumoxane in a solvent (solvent b); (b) when solvent b) is an aromatic solvent or if solvent b) has a boiling point lower than solvent a) add to the solution formed in step a) an alifatic solvent (solvent c) having a boiling point higher than solvent a) and solvent b); or (c) solubilizing a metallocene compound in the solution obtained in step a) or in step b); and (d) substantially removing solvent a) or solvent a) and solvent b) from the solution.

10. 发明申请

WO2005063828A1 METALLOCENE COMPOUNDS 审中-公开
标题翻译：金属化合物
公开(公告)号：WO2005063828A1
公开(公告)日：2005-07-14
申请号：PCT/EP2004/012984
申请日：2004-11-16
申请人： BASELL POLYOLEFINE GMBH , NIFANT'EV, Ilya, E. , IVCHENKO, Pavel, V. , TAJDAKOV, Ilya, V. , RESCONI, Luigi
发明人： NIFANT'EV, Ilya, E. , IVCHENKO, Pavel, V. , TAJDAKOV, Ilya, V. , RESCONI, Luigi
IPC分类号： C08F10/00
CPC分类号： C07D495/04 , C07F17/00 , C08F4/65912 , C08F10/00 , C08F110/02 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/17
摘要： A metallocene compound of formula (I) wherein: M is an atom of a transition metal; X, same or different, is a hydrogen atom, a halogen atom, or a R, OR, OSO 2 CF 3 , OCOR, SR, NR 2 or PR 2 group, wherein R is C 1 -C 40 hydrocarbon group; L is a divalent bridging group; R 1 , is a C 1 -C 40 hydrocarbon group; R 3 is a C 1 -C 40 hydrocarbon group; R 2 , R 4 , R 5 , R 6 , R 7 and R 8 , equal to or different from each other, are hydrogen atoms or C 1 -C 40 hydrocarbon groups.
摘要翻译：式（I）的茂金属化合物，其中：M是过渡金属的原子; X相同或不同，为氢原子，卤素原子或R，OR，OSO 2 CF 3，OCOR，SR，NR 2或PR 2基团，其中R为C 1 -C 40烃基; L是二价桥基; R 1是C 1 -C 40烃基; R 3是C 1 -C 40烃基; R 2，R 4，R 5，R 6，R 7和R 8彼此相同或不同，是氢原子或C 1 -C 40烃基。

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