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1. 发明申请

WO2008135254A3 CATALYST SYSTEM FOR OLEFIN POLYMERIZATION, PROCESS FOR PRODUCING IT AND A PROCESS FOR THE POLYMERIZATION OF ALPHA-OLEFINS USING THE CATALYST SYSTEM 审中-公开
标题翻译：用于烯烃聚合的催化剂体系，其生产方法和使用催化剂体系合成α-烯烃的方法
公开(公告)号：WO2008135254A3
公开(公告)日：2009-07-02
申请号：PCT/EP2008003579
申请日：2008-05-05
申请人： BASELL POLYOLEFINE GMBH , KRISTEN MARC OLIVER , MUELHAUPT ROLF , SCHEUERMANN GIL , KUREK ALEXANDER
发明人： KRISTEN MARC OLIVER , MUELHAUPT ROLF , SCHEUERMANN GIL , KUREK ALEXANDER
IPC分类号： C08F10/00 , C08F4/69 , C08F4/70
CPC分类号： C08F10/00 , C08F110/02 , C08F4/7006 , C08F4/69034 , C08F4/025 , C08F2500/20 , C08F2500/04 , C08F4/69224
摘要： The invention relates to a catalyst system comprising a support in which transition metal cations or uncharged transition metal aroms are distributed. The system further comprises one or more separately added ligands which are capable of forming a coordinate or covalent bond with the transition metals. The catalyst system is produced by replacing metal ions present in a support by transition metal ions. The transition metal ions can optionally be reduced. One or more ligands which are capable of forming a coordinate or covalent bond with the transition metal or metals are subsequently added. The catalyst is used for the polymerization of olefins.
摘要翻译：本发明涉及包含其中分布有过渡金属阳离子或不带电的过渡金属香料的载体的催化剂体系。该体系还包含一个或多个单独添加的能够与过渡金属形成配位或共价键的配体。通过用过渡金属离子代替载体中存在的金属离子来制备催化剂体系。可以任选地还原过渡金属离子。随后加入能够与过渡金属或金属形成配位或共价键的一个或多个配位体。该催化剂用于烯烃的聚合。

2. 发明申请

WO02083749A3 METHOD FOR TRANSITION METAL-CATALYZED PRODUCTION OF AQUEOUS DISPERSIONS CONTAINING POLYOLEFINS OR VINYL AROMATIC POLYMERS 审中-公开
标题翻译：用于生产过渡水性分散体含聚烯烃或乙烯基芳族聚合物
公开(公告)号：WO02083749A3
公开(公告)日：2003-09-25
申请号：PCT/EP0203831
申请日：2002-04-06
申请人： BASF AG , KRISTEN MARC OLIVER , MANDERS LAMBERTUS , CHOWDHRY MUBARIK MAHMOOD , SCHMID MARKUS
发明人： KRISTEN MARC OLIVER , MANDERS LAMBERTUS , CHOWDHRY MUBARIK MAHMOOD , SCHMID MARKUS
IPC分类号： C08F2/16 , C08F2/24 , C08F4/60 , C08F4/69 , C08F4/70 , C08F4/78 , C08F4/80 , C08F10/02 , C08F110/02 , C08F10/00
CPC分类号： C08F10/02 , C08F110/02 , C08F2/16 , C08F2/24 , C08F2500/10 , C08F2500/20 , C08F2500/03
摘要： The invention relates to a method for transition metal-catalyzed production of aqueous dispersions containing (co)polyolefins or vinyl aromatic (co)polymers by reacting (co)monomers in the presence of a cationic complex of a late transition metal and optionally an ionic compound with a Brönsted acid as cation, a strong neutral Lewis acid or an ionic compound with Lewis acid cations as cocatalyst in an aqueous reaction medium.
摘要翻译：一种用于容纳（共）聚烯烃或乙烯基芳族（共）聚合物通过在后过渡金属的阳离子络合物和具有布朗斯台德酸作为阳离子的，不带电的强路易斯任选的离子性化合物的存在下（共）单体的反应水分散体的过渡金属催化的制备方法酸或含路易斯酸阳离子作为助催化剂在水性反应介质中的离子化合物。

3. 发明申请

WO0177186A3 METHOD FOR THE PRODUCTION OF A SUPPORTED CATALYST FOR THE POLYMERISATION OF OLEFINS 审中-公开
标题翻译：用于生产负载型催化剂聚合烯烃
公开(公告)号：WO0177186A3
公开(公告)日：2002-04-11
申请号：PCT/EP0103779
申请日：2001-04-03
申请人： BASF AG , KRISTEN MARC OLIVER , HAUCK GERHARD
发明人： KRISTEN MARC OLIVER , HAUCK GERHARD
IPC分类号： C08F4/00 , C08F4/42 , C08F4/659 , C08F4/6592 , C08F4/70 , C08F10/02 , C08F110/02 , C08F210/16 , C08F10/00
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/61904 , C08F2500/17 , C08F210/14 , C08F4/7042
摘要： A method for the production of a supported catalyst for the polymerisation of olefins is characterised in that one or several compounds of general formula (Ia or b), together with a molecularly defined activator of general formula (IIa to c); [(L-H)] [M')Q Q Q Q ]- IIa [(Car3)] [(M') Q Q Q Q ]- IIb [(M')Q Q Q ] IIc are deposited on a porous support, containing 2 10 wt. % water.
摘要翻译：一种制备负载型催化剂用于烯烃的聚合，其特征在于在通式（I a或b），其中式II a到c [（LH）] <一个分子定义的活化剂一起的该一种或多种化合物+过程 > [M '）问<1> Q <2> Q <3> Q <4>] - IIA [（的Car3）] <+> [（M'）问<1> Q <2> Q <3> Q <4>] - IIB [（M“）问<1> Q <2> Q <3>] IIC沉积在含有2至10重量％的水的多孔载体材料。

4. 发明申请

WO02064645A3 COMPLEX COMPOUNDS AND THEIR USE IN OLEFIN POLYMERIZATION 审中-公开
标题翻译：复杂的化合物和它们在烯烃聚合
公开(公告)号：WO02064645A3
公开(公告)日：2002-12-27
申请号：PCT/EP0201264
申请日：2002-02-07
申请人： BASF AG , KRISTEN MARC OLIVER , BILDSTEIN BENNO , KRAJETE ALEXANDER
发明人： KRISTEN MARC OLIVER , BILDSTEIN BENNO , KRAJETE ALEXANDER
IPC分类号： C07C251/24 , C07F15/04 , C08F4/60 , C08F4/642 , C08F4/80 , C08F10/00
CPC分类号： C07F15/04 , C08F10/00 , C08F2410/03 , C08F4/7022 , C08F4/7004 , C08F4/7021
摘要： The invention relates to complex compounds of general formula (Ia)(Ib)(Ic)(Id), wherein M is an element of groups 6 to 10 of the periodic table of the elements, preferably Ni. The invention also relates to a method for the production and of said compounds and to their use in the polymerization and copolymerization of olefins, for example in suspension polymerization methods, gaseous phase polymerization methods, mass polymerization methods or emulsion polymerization methods.
摘要翻译：式（Ia）（Ib）的（IC）（Id）的本发明涉及通式（Ia）（Ib）的（IC）（同上）其中M是第6族的元素（elements）的周期表第10的元素，优选为Ni的配位化合物，此外，本发明涉及它们的制备方法以及它们在悬浮聚合中Gasphasenpolymersiationsverfahren，Massepolymersationsverfahren或乳液聚合方法用于烯烃聚合和共聚的使用，例如一个过程。

5. 发明申请

WO0177187A3 METHOD FOR THE PRODUCTION OF A CATALYST SYSTEM FOR THE POLYMERISATION OF OLEFINS 审中-公开
标题翻译：用于生产催化剂体系的烯烃聚合
公开(公告)号：WO0177187A3
公开(公告)日：2002-03-28
申请号：PCT/EP0103829
申请日：2001-04-04
申请人： BASF AG , KRISTEN MARC OLIVER , HAUCK GERHARD
发明人： KRISTEN MARC OLIVER , HAUCK GERHARD
IPC分类号： C08F4/606 , C08F4/00 , C08F4/42 , C08F4/60 , C08F4/70 , C08F10/00 , C08F110/02
CPC分类号： C08F110/02 , C08F10/00 , C08F2500/17 , C08F4/7042
摘要： A method for the production of a catalyst system for the polymerisation of olefins is characterised in that one or several compounds of general formula (Ia) or (Ib) are deposited, then a molecularly defined activator of general formula (IIa to c) [(L H)] [(M')Q Q Q Q ]- (II a) [(CAr3)] [(M')Q Q Q Q ]- (II b) [(M')Q Q Q ] (II c) is added and finally an alkylating agent, selected from LiR R or A1R R R , is added.
摘要翻译：一种用于制备催化剂体系用于烯烃聚合，其特征在于，一个或多个一般式（Ia）（Ib）的化合物或方法最初引入，随后将式II a到c [（LH）]的分子定义的活化剂< +> [（M '）问<1> Q <2> Q <3> Q <4>] - （II A）[（的Car3）] <+> [（M'）问<1> Q <2> Q <3> Q <4>] - （b II）[（M“）问<1> Q <2> Q <3>]（II C）加入，最后从LIR <11>中选择的烷基化剂， Mg11R <12>或A1R <12> - [R <13> - [R <14>，增加了。

6. 发明申请

WO03006528A8 METHOD FOR PRODUCING AQUEOUS COPOLYMER DISPERSIONS OF COPOLYMERS CONSISTING OF CARBON MONOXIDE AND OLEFINICALLY UNSATURATED COMPOUNDS 审中-公开
标题翻译： METHOD FOR PRODUCING一氧化碳的含水共聚物分散液共聚物和烯属不饱和化合物
公开(公告)号：WO03006528A8
公开(公告)日：2004-04-08
申请号：PCT/EP0207409
申请日：2002-07-04
申请人： BASF AG , SCHMID MARKUS , CHOWDHRY MUBARIK MAHMOOD , KRISTEN MARC OLIVER , MECKING STEFAN , HELD ANKE , LINDNER EKKEHARD , SUNJUK MAHMOUD , WEGNER PETER
发明人： SCHMID MARKUS , CHOWDHRY MUBARIK MAHMOOD , KRISTEN MARC OLIVER , MECKING STEFAN , HELD ANKE , LINDNER EKKEHARD , SUNJUK MAHMOUD , WEGNER PETER
IPC分类号： C09K3/10 , B01J31/18 , B01J31/24 , C08G67/02 , C09D173/00 , C09J173/00
CPC分类号： B01J31/1815 , B01J31/18 , B01J31/24 , B01J2531/10 , B01J2531/20 , B01J2531/80 , B01J2531/824 , C08G67/02
摘要： The invention relates to a method for producing aqueous copolymer dispersions of copolymers consisting of carbon monoxide and olefinically unsaturated compounds, by means of copolymerisation of carbon monoxide and olefinically unsaturated compounds in an aqueous medium in the presence of metallic complexes.
摘要翻译：一种用于在金属配合物存在下，在水性介质中的一氧化碳和烯属不饱和化合物的共聚制备一氧化碳的共聚物，以及烯属不饱和化合物的水性共聚物分散体的过程。

7. 发明申请

WO02064638A2 METHOD FOR THE EMULSION POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：方法烯烃乳液聚合
公开(公告)号：WO02064638A2
公开(公告)日：2002-08-22
申请号：PCT/EP0201467
申请日：2002-02-13
申请人： BASF AG , KRISTEN MARC OLIVER , CHOWDHRY MUBARIK MAHMOOD
发明人： KRISTEN MARC OLIVER , CHOWDHRY MUBARIK MAHMOOD
IPC分类号： C08F2/22 , C08F4/26 , C08F4/80 , C08F10/00 , C08F110/02
CPC分类号： C08F10/00 , C08F110/02 , C08F2/24 , C08F4/80
摘要： The invention relates to a method for the emulsion polymerization of one or more olefins by reacting a ligand according to the general formulae (Ia) to (Ic) or a mixture of at least two of the ligands (Ia) to (Ic), wherein M is a metal of the first group of the periodic table of elements or hydrogen, with a metal compound of the general formula (M(L )2 or M(L )2(L )z, wherein M is a transition metal of the 7 to 10 group of the periodic table of elements and preferably nickel, and immediately using the reaction product for the polymerization or copolymerization of olefins in water or in a solvent mixture that contains at least 50 % by volume of water, optionally in the presence of an activator and an emulsifier. The aqueous dispersions of polyolefins such as polyethylene and ethylene copolymerizates obtained according to the inventive method are suitable for applications in the paper industry such as paper coating or surface sizing, paint coatings, raw materials for adhesives, molded foams such as mattresses, textile or leather applications, carpet backings or pharmaceutical applications.
摘要翻译：由通式的配位体反应的乳液聚合过程I A至I C，或至少两个的配位体的混合物我一个至I C，其中M <1>是元素或氢的周期表第1族的金属，具有（<2> L）2或通式M（L <2>）2（L <1>）Z，其中M是组7的的元素并且优选地，镍的周期表第10的过渡金属的M个金属化合物，和立即使用用于烯烃在水中的聚合或共聚或至少含有50体积％的水，任选地在活化剂和乳化剂的存在下于溶剂混合物中的反应产物。根据本发明的聚烯烃如聚乙烯和乙烯共聚物的水性分散体适合用于造纸的应用，如纸张涂层或表面施胶，涂清漆，粘合剂原材料，模塑泡沫，如床垫，纺织品和皮革应用，地毯背衬或药物应用的方法获得。

8. 发明专利

AT459606T 未知
公开(公告)号：AT459606T
公开(公告)日：2010-03-15
申请号：AT03779830
申请日：2003-11-03
申请人： BASELL POLYOLEFINE GMBH
发明人： PREISHUBER-PFLUEGL PETER , OKUDA JUN , REIMER VALENTINE , KRISTEN MARC OLIVER
IPC分类号： C07D277/82 , B01J31/00 , B01J31/14 , B01J31/18 , B01J31/22 , C07D277/42 , C07F7/00 , C08F4/62 , C08F4/64 , C08F4/659 , C08F10/00 , C08F110/02
摘要： Compounds with a 5-membered unsaturated heterocycle attached by an optionally substituted aminomethyl or phosphinomethyl group to a benzene ring substituted in the o-position with a hydroxy, thiol, amino, alkoxy or alkylthio group. Compounds of formulae (Ia) or (Ib) are new. E1 = O, S, Se, Te, NR, CR2 or PR; E2, E3 = CR, N or P; E4 = N or P; E5 = OH, SH, NHR, OR, SR or NRR; E6 = NH, PH, NR or PR, and at least one of the groups E5 or E6 contains a hydrogen atom; R5, R6 = H, alkyl (linear, branched or cyclic) or aryl; R1-R4 = H, alkyl, aryl, halogen or nitro; R, R = H or alkyl; E2, E3 = O, S, Se, Te, NR, CR2 or PR Independent claims are included for: (1) a method for the production of (Ia) and (Ib) by reacting an aromatic aldehyde with a 5-membered heterocyclic compound substituted with the group -E6H2, followed by reduction of the -CH=E6- group; (2) metal complexes of formula LxMRYz (V); (3) a method for the production of (V) by deprotonation of (Ia) or (Ib) with a base followed by reaction with a metal compound, or by direct reaction of (Ia) or (Ib) with a metal compound; (4) catalytically-active compositions (CAC) comprising: (A) a complex (V) as above; and (B) a component selected from (B1) an organometallic compound, (B2) an organoaluminum-oxy compound and/or (B3) a compound which reacts with complex (A) to form an ion pair; (5) a method for the production of CAC by contacting (A) with (B); and optionally a support material; (6) a method for the (co)polymerization of olefins in presence of CAC as above polymers and copolymers obtained by this method. L = mono- (a) or di-anionic ligand (b) derived from (Ia) or (Ib); E5 = O-, S- or RN- (preferably O-) with E6 = N- or P- (preferably N-) if L is (b), or O-, S- or RN- (preferably O-) with E6 = NR or PR, or OR, SR or NRR' with E6 = N- or P- (preferably N-) if L is (a); M = Ti, Zr, Hf, V, Nb, Ta, Cr, Mo or W (preferably Ti, Zr or Hf) if L is (b), or the above metals plus Ni, Pd, Co, Fe, Cu, Ru or Rh (preferably Ti, Zr, Hf, Ni or Pd) if L is (a); R = H, hydrocarbyl (preferably alkyl as above), NR2, OR, halogen or acetylacetonate, preferably halogen or OR; R = H or alkyl; Y = Lewis acid; x = 1 or 2, preferably 1 if L is (b), or 1, 2 or 3 if L is (a); y = 1-4, preferably 2 if L is (b), or 1-4 if L is (a); z = 0-2, preferably 0; R and Y may form a common group, with 2x + y and x + y being the valency of M when L is (b) and (a) respectively.

9. 发明专利

AU2003273886A1 SELECTION OF POLYMERIZATION CATALYSTS AND APPARATUS FOR CARRYING THIS OUT 未知
公开(公告)号：AU2003273886A1
公开(公告)日：2004-04-08
申请号：AU2003273886
申请日：2003-09-16
申请人： BASELL POLYOLEFINE GMBH
发明人： LILGE DIETER , RHODE WOLFGANG , KRISTEN MARC OLIVER
IPC分类号： C08F2/01 , B01J8/18 , B01J19/00 , C08F4/24 , C08F4/69 , C08F10/00 , C40B30/08 , C40B40/14 , C40B40/18 , C40B60/14 , C07B61/00
摘要： In a method of selecting polymerization catalysts, in particular Phillips catalysts for the polymerization of olefins, from a multiplicity of catalysts on the basis of their catalytic properties, a multiplicity of catalyst precursors or catalyst supports are converted in parallel into polymerization catalysts in a pretreatment step in an array of reactors, where the pretreatment comprises at least one thermal treatment step at from 250 to 1200° C. Furthermore, at least one starting material is converted with the aid of the respective polymerization catalysts under prescribed polymerization conditions into at least one polymer product in a polymerization step and, finally, analysis of the polymer product or products is carried out to determine its composition and/or chosen properties. This makes it possible to carry out a thermal pretreatment of polymerization catalysts quickly under defined conditions which can be varied.

10. 发明专利

DE10243239A1 Selection of polymerization catalyst for polymerization of olefins, involves pre-treating catalyst precursors at preset temperature to form polymerization catalyst using which starting material(s) are converted into to polymer 未知
公开(公告)号：DE10243239A1
公开(公告)日：2004-03-25
申请号：DE10243239
申请日：2002-09-17
申请人： BASELL POLYOLEFINE GMBH
发明人： ROHDE WOLFGANG , KRISTEN MARC OLIVER , LILGE DIETER
IPC分类号： B01J8/18 , B01J19/00 , C08F10/00 , C40B30/08 , C40B40/14 , C40B40/18 , C40B60/14 , C08F2/34 , B01J8/24 , C08F4/24
摘要： Several catalyst precursors or catalyst supports are converted into polymerization catalysts in an array of reactors by pre-treatment process which involves thermal treatment at 250-1200 degrees Celsius. At least one starting material is converted using the catalyst into at least one polymer product. The polymer product(s) is analyzed to determine its composition and/or chosen properties. Several catalyst precursors or catalyst supports are converted in parallel into polymerization catalysts in an array of reactors by pre-treatment process. The pre-treatment involves at least one thermal treatment at 250-1200 degrees Celsius. At least one starting material is converted with the aid of the respective polymerization catalyst under preset conditions into at least one polymer product. The polymer product(s) is analyzed to determine its composition and/or chosen properties. An Independent claim is included for array of parallel reactors.

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