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1. 发明申请

WO2007003528A3 METALLOCENE COMPOUNDS 审中-公开
标题翻译：金属化合物
公开(公告)号：WO2007003528A3
公开(公告)日：2007-03-22
申请号：PCT/EP2006063577
申请日：2006-06-27
申请人： BASELL POLYOLEFINE GMBH , ELDER MICHAEL J , JONES ROBERT L , RESCONI LUIGI
发明人： ELDER MICHAEL J , JONES ROBERT L , RESCONI LUIGI
IPC分类号： C07F17/00
CPC分类号： C07F17/00 , C08F4/65912 , C08F110/08 , C08F2420/06 , C08F2500/17 , C08F4/65927
摘要： A metallocene compound of formula (I) wherein M is zirconium titanium or hafiiium; X is hydrogen, halogen or an hydrocarbon group; R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , and R 11 , R 12 and R 13 are hydrogen atoms, or C 1 -C 40 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; R 1 and R 2 , equal to or different from each other, are linear or branched, C 1 -C 20 -alkyl radicals, and R 3 is a C 1 -C 40 hydrocarbon radical optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements.
摘要翻译：式（I）的茂金属化合物，其中M为锆钛或铪; X是氢，卤素或烃基; R 4，R 5，R 6，R 7，R 8， R 9，R 10和R 11，R 12和R 13，是任选地含有元素周期表第13-17族的杂原子的氢原子或C 1 -C 40烃基; R 1，R 2和R 2彼此相同或不同，为直链或支链C 1 -C 20 - R 3 - 烷基，R 3是任选地含有属于第13〜13族的杂原子的C 1 -C 40烃基元素周期表。

2. 发明申请

WO2004078804A2 CATALYST SYSTEM FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：WO2004078804A2
公开(公告)日：2004-09-16
申请号：PCT/EP2004001847
申请日：2004-02-24
申请人： BASELL POLYOLEFINE GMBH , BUSICO VINCENZO , GUARDASOLE MAURO , CIPULLO ROBERTA , RESCONI LUIGI , MORINI GIAMPIERO
发明人： BUSICO VINCENZO , GUARDASOLE MAURO , CIPULLO ROBERTA , RESCONI LUIGI , MORINI GIAMPIERO
IPC分类号： C07F5/02 , C07F7/18 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16
CPC分类号： C08F10/00 , C07F5/027 , C07F7/1836 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/70 , C08F4/65908 , C08F2500/03 , C08F2500/20 , C08F210/08
摘要： A heterogeneous catalyst component obtainable by contacting: (a) a solid Lewis acid of formula MR a wherein M is a metal of group 1-12 of the Periodic Table of the Elements; R is a fluorine, chlorine, bromine or iodine atom; and a is equal to the valence of the metal M; and (b) at least one ionic compound of formula (I) [((T)pR )nM (R )m] [D] (I) wherein: M is an element belonging to group 13 of the Periodic Table of the Elements; R , equal to or different from each other, are halogen atoms, halogenated C6-C20 aryl and halogenated C7-C20 alkylaryl groups; two R groups, can also form with the element M one condensed ring; R , equal to or different from each other, are hydrocarbon groups; T is a Lewis base in its neutral form; n ranges from 1 to 4; m ranges from 0 to 3; and m+n= 4; p ranges from 1 to 10; and [D] is a monovalent cation.
摘要翻译：通过使以下物质接触获得的非均相催化剂组分：（a）式MR的固体路易斯酸其中M是元素周期表第1-12族的金属; R 1是氟，氯，溴或碘原子; a等于金属M的化合价; （I）的至少一种离子化合物[（（T）pR 2）nM（R 3）m] - [D] +（I）其中： M是属于元素周期表第13族的元素; R 3彼此相同或不同，为卤素原子，卤代C 6 -C 20芳基和卤代C 7 -C 20烷基芳基; 两个R 1基团，也可以与元素M形成一个稠环; R 2彼此相同或不同，为烃基; T是其中性形式的路易斯碱; n范围从1到4; m范围从0到3; 和m + n = 4; p范围从1到10; 和[D] +是一价阳离子。

3. 发明申请

WO2004050713A2 1-BUTEN COPOLYMERS AND PROCESS FOR PREPARING THEM 审中-公开
标题翻译： 1-BUTEN共聚物及其制备方法
公开(公告)号：WO2004050713A2
公开(公告)日：2004-06-17
申请号：PCT/EP0312944
申请日：2003-11-14
申请人： BASELL POLYOLEFINE GMBH , RESCONI LUIGI , PELLICONI ANTEO , GARAGNANI ENEA
发明人： RESCONI LUIGI , PELLICONI ANTEO , GARAGNANI ENEA
IPC分类号： C08F2/00 , C08F4/642 , C08F4/659 , C08F210/08 , C08F
CPC分类号： C08F210/08 , C08F4/65912 , C08F4/65927 , C08F210/16 , C08F2500/03 , C08F2500/15 , C08F2500/20
摘要： A process for preparing isotactic 1-butene copolymers containing up to 30% by mol of units derived from of one or more alpha olefins of formula CH2=CHZ, wherein Z is a C3C20 hydrocarbon group comprising contacting 1-butene and one or more of said alphaolefins under polymerization conditions in the presence of a catalyst system obtainable by contacting: (A) a metallocene compound of formula (I) (1) wherein: M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, are hydrogen atoms, halogen atoms, or an hydrocarbon group; L is a divalent bridging group; R and R are hydrocarbon groups; R and R are hydrogen atoms or hydrocarbon groups; T and T , equal to or different from each other are a moiety of formula (lI), (III) or (IV): wherein: the atom marked with the symbol * is bound the atom marked with the same symbol in formula (I); R , R , R , R and R , equal to or different from each other, are hydrogen or hydrocarbon groups; and (B) an alumoxane or a compound able to form an alkylmetallocene cation.
摘要翻译：一种制备全同立构1-丁烯共聚物的方法，该共聚物含有至多30摩尔％的衍生自一种或多种式CH 2 = CHZ的α-烯烃的单元，其中Z是C 3 C 20烃基，包括使1-丁烯和所述在（A）茂金属化合物（I）（1）的催化剂体系存在下，在聚合条件下，α-烯烃在其中：M是过渡金属的原子; p是0至3的整数; X相同或不同，为氢原子，卤素原子或烃基; L是二价桥基; R 1和R 3是烃基; R 2和R 4是氢原子或烃基; T 1和T 2彼此相同或不同的是式（I），（III）或（IV）的部分：其中：用符号*标记的原子与标记有式（I）中的相同符号; R 5，R 6，R 7，R 8和R 9彼此相同或不同，为氢或烃基; 和（B）铝氧烷或能够形成烷基茂金属阳离子的化合物。

4. 发明申请

WO02083699A3 PROCESS FOR THE PRODUCTION OF MONOHALIDE OR DIHALIDE METALLOCENE COMPOUNDS 审中-公开
标题翻译：用于生产单盐或二卤化物金属化合物的方法
公开(公告)号：WO02083699A3
公开(公告)日：2003-05-15
申请号：PCT/EP0203697
申请日：2002-04-03
申请人： BASELL POLYOLEFINE GMBH , RESCONI LUIGI , BALBONI DAVIDE
发明人： RESCONI LUIGI , BALBONI DAVIDE
IPC分类号： C07F7/00 , C07F7/28 , C07F17/00 , C08F4/64 , C08F4/6592 , C08F10/00
CPC分类号： C07F17/00 , Y10S526/943
摘要： A process for preparing dihalide or monohalide metallocene compounds comprising contacting a compound of formula (II) (Cp)(ZR m)n(A)rML'y (II) wherein Cp is a cyclopentadienyl radical; (ZR m)n is a divalent bridging group between Cp and A; A is a cyclopentadienyl radical or O, S, NR , PR wherein R is an hydrocarbon radical, M is zirconium, titanium or hafnium, L' is an hydrocarbon radical, r ranges from 0 to 2 and y is equal to 4; with an halogenating agent selected from the group consisting of: T Lw wherein T is a metal of groups 3-13 of the periodic table; L is halogen and w is equal to the oxidation state of the metal T ; T Lw wherein T is a nonmetal element of groups 13-16 of the periodic table (new IUPAC version); and w is equal to the oxidation state of the element T ; O=T Lw where T is a selected from the group consisting of C, P and S; O is an oxygen atom bonded to T trough a double bond; and w is equal to the oxidation state of the element T minus 2; R C(O)L, wherein R is an hydrocarbon radical; L2 and HL.
摘要翻译：一种制备二卤化物或一卤化物茂金属化合物的方法，包括使式（II）（Cp）（ZR 1 m）n（A）rML'y（II）的化合物其中Cp是环戊二烯基; （ZR 1 m）n是Cp和A之间的二价桥连基团; A是环戊二烯基或O，S，NR 2，PR 2，其中R 2是烃基，M是锆，钛或铪，L'是烃基，r的范围是0-2 y等于4; 与选自以下的卤化剂：T 1 Lw 1其中T 1是周期表的3-13族的金属; L是卤素，W 1等于金属T 1的氧化态; T 2 Lw 2其中T 2是周期表第13-16族的非金属元素（新的IUPAC版本）; w 2等于元素T 2的氧化态; O = T 3 Lw 3其中T 3选自C，P和S; O是通过双键键合到T 3的氧原子; 并且w 3等于元素T 3的氧化状态减去2; R 6 C（O）L，其中R 6是烃基; L2和HL。

5. 发明申请

WO2004005360A3 CATALYST SYSTEM FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：WO2004005360A3
公开(公告)日：2005-11-10
申请号：PCT/EP0307485
申请日：2003-07-09
申请人： BASELL POLYOLEFINE GMBH , RESCONI LUIGI , FOCANTE FRANCESCA , CAMURATI ISABELLA , GUIDOTTI SIMONA
发明人： RESCONI LUIGI , FOCANTE FRANCESCA , CAMURATI ISABELLA , GUIDOTTI SIMONA
IPC分类号： C07F5/02 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F4/645
CPC分类号： C07F5/027 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F110/02 , C08F4/65908
摘要： An organometallic compound obtainable by contacting: a compound having the following formula (I), wherein: R is a hydrocarbon radical; R , R and R , are hydrogen atoms, halogen atoms, or hydrocarbon radicals; with a Lewis acid of formula (II) MtR 3 (II) wherein Mt is a metal belonging to Group 13 of the Periodic Table of the Elements; R are selected from the group consisting of halogen atoms, halogenated C6-C20 aryl and halogenated C7-C20 alkylaryl groups.
摘要翻译：通过使具有下式（I）的化合物接触而获得的有机金属化合物，其中：R a是烃基; R b，R o和R d分别是氢原子，卤素原子或烃基; 与式（II）的路易斯酸MtR 1（II）其中Mt是属于元素周期表第13族的金属; R 1选自卤素原子，卤代C 6 -C 20芳基和卤代C 7 -C 20烷基芳基。

6. 发明申请

WO2005095468A2 CATALYST SYSTEM FOR THE POLYMERIZATION OF OLEFIN 审中-公开
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：WO2005095468A2
公开(公告)日：2005-10-13
申请号：PCT/EP2005002479
申请日：2005-03-08
申请人： BASELL POLYOLEFINE GMBH , RESCONI LUIGI , MOSCARDI GILBERTO , FAIT ANNA
发明人： RESCONI LUIGI , MOSCARDI GILBERTO , FAIT ANNA
IPC分类号： C08F4/6592 , C08F10/00 , C08F110/08
CPC分类号： C08F110/08 , C08F4/65927 , C08F10/00 , Y10S526/943 , C08F4/65912 , C08F2500/17 , C08F2500/03
摘要： A catalyst system solution obtainable by a process comprising the following steps: a) contacting a solution of methylalumoxane in an aromatic solvent (solvent a) with a solution of one or more organ-aluminium in a solvent (solvent b), or a solution of one or more alumoxanes different from methylalumoxane in a solvent (solvent b); (b) when solvent b) is an aromatic solvent or if solvent b) has a boiling point lower than solvent a) add to the solution formed in step a) an alifatic solvent (solvent c) having a boiling point higher than solvent a) and solvent b); or (c) solubilizing a metallocene compound in the solution obtained in step a) or in step b); and (d) substantially removing solvent a) or solvent a) and solvent b) from the solution.
摘要翻译：一种可通过包括以下步骤的方法获得的催化剂体系溶液：a）将甲基铝氧烷在芳族溶剂（溶剂a）中的溶液与一种或多种器官铝在溶剂（溶剂b）中的溶液或一种或多种在溶剂（溶剂b）中与甲基铝氧烷不同的铝氧烷; （b）当溶剂b）是芳族溶剂或溶剂b）的沸点低于溶剂a）加入在步骤a）中形成的溶液中沸点高于溶剂的溶剂（溶剂c）a）和溶剂b）; 或（c）将茂金属化合物溶解在步骤a）或步骤b）中获得的溶液中; 和（d）从溶液中基本上除去溶剂a）或溶剂a）和溶剂b）。

7. 发明申请

WO2004099269A2 PROCESS FOR POLYMERIZING 1-BUTENE 审中-公开
标题翻译：聚合1-BOTENE的方法
公开(公告)号：WO2004099269A2
公开(公告)日：2004-11-18
申请号：PCT/EP2004005078
申请日：2004-05-07
申请人： BASELL POLYOLEFINE GMBH , RESCONI LUIGI
发明人： RESCONI LUIGI
IPC分类号： C07F17/00 , C08F4/642 , C08F4/659 , C08F10/08 , C08F110/08 , C08F210/08
CPC分类号： C07F17/00 , C08F4/65912 , C08F10/08 , C08F110/08 , C08F210/08 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/15 , C08F2500/03 , C08F210/16
摘要： A process for polymerizing 1-butene, optionally with up to 3 0% by mol of ethylene, propylene or an alpha olefin of formula CH2=CHT wherein T is a C3-Clo alkyl group, in the presence of a catalyst system obtainable by contacting a metallocene compound of formula (I) Wherein M is an atom of a transition metal; X, is a hydrogen atom, a halogen atoms or a hydrocarbon group; R , R , R , R , R , R and R are hydrogen atoms or hydrocarbon groups; with the proviso that at least one of R or R is a C1-C20 alkyl group; R and R are C1-C20 alkyl groups; and an alumoxane and/or a compound capable of forming an alkyl metallocene cation.
摘要翻译：聚合1-丁烯的方法，任选地含有至多3.0摩尔％的乙烯，丙烯或式CH 2 = CHT的α-烯烃，其中T是C 3-8烷基，在催化剂体系存在下，可通过接触式（I）的茂金属化合物，其中M是过渡金属的原子; X是氢原子，卤素原子或烃基; R 1，R 2，R 5，R 6，R 7，R 8和R 9是氢原子或烃基; 条件是R 6或R 7中的至少一个是C 1 -C 20烷基; R 3和R 4是C 1 -C 20烷基; 和铝氧烷和/或能够形成烷基茂金属阳离子的化合物。

8. 发明申请

WO2004033510A3 PROCESS FOR THE COPOLYMERIZATION OF ETHYLENE 审中-公开
标题翻译：乙烯共聚工艺
公开(公告)号：WO2004033510A3
公开(公告)日：2004-08-12
申请号：PCT/EP0310107
申请日：2003-09-10
申请人： BASELL POLYOLEFINE GMBH , RESCONI LUIGI , MASCELLANI NICOLETTA
发明人： RESCONI LUIGI , MASCELLANI NICOLETTA
IPC分类号： C08F4/642 , C08F4/659 , C08F210/16
CPC分类号： C08F210/16 , C08F4/65912 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F210/14 , C08F2500/17 , C08F2500/03
摘要： A process for producing a copolymer of ethylene containing from 0.1 to 99 % by mol of one or more derived units of alpha-olefins of formula CH2=CHA, wherein A is a C2-C20 alkyl radical, comprising contacting, under polymerization conditions, ethylene and one or more alpha-olefins in the presence of a catalyst system obtainable by contacting: a) a metallocene compound of formula (I): wherein M is zirconium, titanium or hafnium; X, same or different, is a hydrogen atom, a halogen atom, or an hydrocarbon group; R , is a hydrocarbon group; R R , R , R5 and R , are hydrogen atoms or hydrocarbon groups; Q is a radical of formula (II), being bonded to the indenyl at the position marked by the symbol *; (II) wherein: T , T , T , T and T , are carbon atoms (C) or nitrogen atoms (N); m , m , m , m and m are 0 or 1; R , R , R , R and R are hydrogen atoms or hydrocarbon groups; and b) an alumoxane or a compound capable of forming an alkyl metallocene cation.
摘要翻译：一种制备乙烯共聚物的方法，该共聚物含有0.1-99％（摩尔）的一种或多种式CH2 = CHA（其中A是C2-C20烷基）的α-烯烃的衍生单元，该方法包括在聚合条件下使乙烯和一种或多种α-烯烃在催化剂体系存在下可通过以下方式获得：a）式（I）的茂金属化合物：其中M是锆，钛或铪; X相同或不同，是氢原子，卤素原子或烃基; R 1是烃基; R 2，R 3，R 4，R 5和R 6是氢原子或烃基; Q是式（II）的基团，其在由符号*标记的位置处与茚基键合; （II）其中：T 1，T 2，T 3，T 4和T 5是碳原子（C）或氮原子（N）; m 1，m 2，m 3，m 4和m 5为0或1; R 7，R 8，R 9，R 10和R 11是氢原子或烃基; 和b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

9. 发明专利

JP2011168784A Method for polymerizing 1-butene 有权
标题翻译：聚合1-BOTENE的方法
公开(公告)号：JP2011168784A
公开(公告)日：2011-09-01
申请号：JP2011053949
申请日：2011-03-11
申请人： Basell Polyolefine Gmbh , バーゼル・ポリオレフィン・ゲーエムベーハー
发明人： RESCONI LUIGI
IPC分类号： C08F4/6592 , C07F7/00 , C07F7/08 , C07F17/00 , C08F4/642 , C08F4/659 , C08F10/08 , C08F110/08 , C08F210/08
CPC分类号： C07F17/00 , C08F4/65912 , C08F10/08 , C08F110/08 , C08F210/08 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/15 , C08F2500/03 , C08F210/16
摘要： PROBLEM TO BE SOLVED: To provide a metallocene compound capable of further increasing the molecular weight of 1-butene polymers and simultaneously obtaining at a high yield.
SOLUTION: There is provided a process for producing 1-butene polymers, comprising (co)polymerization of 1-butene in the presence of a metallocene compound of formula (I). In the formula, each symbol has a specific definition.
COPYRIGHT: (C)2011,JPO&INPIT

10. 发明申请

WO2011135004A3 SOLID PARTICULATE CATALYSTS COMPRISING BRIDGED METALLOCENES 审中-公开
标题翻译：包含桥接金属的固体颗粒催化剂
公开(公告)号：WO2011135004A3
公开(公告)日：2012-10-04
申请号：PCT/EP2011056672
申请日：2011-04-27
申请人： BOREALIS AG , RESCONI LUIGI , CASTRO PASCAL , HUHTANEN LAURI
发明人： RESCONI LUIGI , CASTRO PASCAL , HUHTANEN LAURI
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F4/65927 , C08F4/65912 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F2500/12 , C08F2500/15 , C08F2500/17
摘要： A solid, particulate catalyst comprising: (i) a complex of Formula (I), wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R'2C-, -R'2C-CR'2-, -R'2Si-, -R'2Si-SiR'2-, -R'2Ge-, wherein each R' is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 independently is a linear or branched C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms from groups 14-16; T1 and T4, which can be the same or different, are an OR2, a SR2, CH(R18)2, CH2R18, aryl or heteroaryl group; each R2, which can be the same or different, is a C1-C20 hydrocarbyl radical; each R18, which can be the same or different, is a C1-C20 hydrocarbyl radical or two R18 groups together with the carbon atom to which they are attached may form a cyclic C4-C20 hydrocarbyl group; T2 and T3, which may be the same or different, are a C(R18 )3 group; W1 and W2, which may be the same or different, are a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R5 group; each R5, which can be the same or different, is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W1 or W2, optionally substituted by one or two groups R5; and (ii) a cocatalyst.
摘要翻译：一种固体颗粒催化剂，其包含：（i）式（I）的络合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烷基，三（C 1 -C 20 - 烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1独立地是任选地含有一个或多个第14-16族的杂原子的直链或支链C 1 -C 20烃基; T1和T4可以相同或不同，是OR2，SR2，CH（R18）2，CH2R18，芳基或杂芳基; 每个R 2可以相同或不同，是C 1 -C 20烃基; 每个R 18可以相同或不同，是C1-C20烃基或两个R18基团与它们所连接的碳原子一起形成环状C 4 -C 20烃基; T2和T3可以相同或不同，是C（R18）3基团; W1和W2可以相同或不同，是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R 5基团取代; 每个R 5可以相同或不同，是任选地含有一个或多个属于第14-16族的杂原子的C1-C20烃基; 并且任选地两个相邻的R5基团可以形成另外的稠合成W1或W2的单环或多环，任选地被一个或两个基团R 5取代; 和（ii）助催化剂。

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