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1. 发明申请

WO2003018646A1 VERFAHREN ZUR HOCHDRUCKPOLYMERISATION VON ETHYLEN 审中-公开
标题翻译：方法高压低密度聚乙烯
公开(公告)号：WO2003018646A1
公开(公告)日：2003-03-06
申请号：PCT/EP2002/009033
申请日：2002-08-13
申请人： BASELL POLYOLEFINE GMBH , DECKERS, Andreas , MÄHLING, Frank-Olaf , GROOS, Georg , KÖHLER, Gernot , WEBER, Wilhelm
发明人： DECKERS, Andreas , MÄHLING, Frank-Olaf , GROOS, Georg , KÖHLER, Gernot , WEBER, Wilhelm
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C08F110/02 , C08F2/00 , C08F2/002 , C08F2/001 , C08F2500/12
摘要： Verfahren zur Polymerisation von Ethylen und optional weiteren Monomeren in einem Hochdruckreaktor bei Drücken zwischen 1000 und 4000 bar und Temperaturen zwischen 120 und 350°C, wobei intermittierend Wasserstoff in den Reaktor einbracht wird.
摘要翻译：一种用于乙烯和任选的其它单体的在高压反应器中的压力下在1000和4000巴和温度之间120和350℃，其中氢是间歇einbracht在反应器之间的聚合过程。

2. 发明申请

WO2005049664A1 CONTINUOUS PREPARATION OF ETHYLENE HOMOPOLYMERS OR COPOLYMERS 审中-公开
标题翻译：连续制备乙烯共聚物或共聚物
公开(公告)号：WO2005049664A1
公开(公告)日：2005-06-02
申请号：PCT/EP2004/012108
申请日：2004-10-27
申请人： BASELL POLYOLEFINE GMBH , GONIOUKH, Andrei , KÖHLER, Gernot , TEUBER, Theo , DRÖGE, Thomas
发明人： GONIOUKH, Andrei , KÖHLER, Gernot , TEUBER, Theo , DRÖGE, Thomas
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F2/06 , C08F4/32 , C08F2/00 , C08F4/34 , C08F2/38 , C08F2500/12
摘要： The invention relates to a process for the continuous preparation of ethylene homopolymers or copolymers in the presence of free-radical polymerization initiators and, if desired, molecular weight regulators at from 120°C to 350°C and pressures in the range from 100 to 4000 bar, in which the polymer is separated from unpolymerized ethylene in a high-pressure stage at a pressure of from 100 to 500 bar and at least one low-pressure stage at a pressure of from 1 to 100 bar and the ethylene separated off in the high-pressure stage is separated from remaining monomeric, oligomeric and/or polymeric constituents and recirculated to the inlet of the tube reactor in a high-pressure circuit and the ethylene separated off in the low-pressure stage is separated from remaining monomeric, oligomeric and/or polymeric constituents and recirculated to the inlet of the tube reactor in a low-pressure circuit. The initiator is used as a solution in an isoparaffinic solvent having a boiling point of not more than 160°C and the solvent is separated from the other monomeric, oligomeric and/or polymeric constituents in the low-pressure circuit. The solvent is then, if appropriate after being admixed with fresh solvent, reused for dissolving initiator.
摘要翻译：本发明涉及一种在自由基聚合引发剂存在下连续制备乙烯均聚物或共聚物的方法，如果需要，本发明涉及120℃至350℃的分子量调节剂和100至4000的压力棒，其中聚合物在高压阶段在100至500巴的压力和至少一个低压级在1至100巴的压力下从未聚合的乙烯分离，并且乙烯在将高压级与剩余的单体，低聚物和/或聚合物组分分离，并在高压回路中再循环到管式反应器的入口，并将在低压级分离的乙烯与剩余的单体，低聚物和 /或聚合物组分，并在低压回路中再循环到管式反应器的入口。引发剂用作沸点不超过160℃的异链烷烃溶剂中的溶液，并且溶剂与低压回路中的其它单体，低聚物和/或聚合物组分分离。如果在与新鲜溶剂混合后适当，溶剂再次用于溶解引发剂。

3. 发明授权

EP1287045B1 VERFAHREN ZUR HOCHDRUCKPOLYMERISATION VON ETHYLEN IN GEGENWART VON ÜBERKRITISCHEM WASSER 有权
标题翻译：在GEGENWART VONÜBERKRITISCHEMWASSER VERFAHREN ZUR HOCHDRUCKPOLYMERISATION VON ETHYLEN
公开(公告)号：EP1287045B1
公开(公告)日：2003-12-10
申请号：EP01964950.8
申请日：2001-05-25
申请人： Basell Polyolefine GmbH
发明人： HÄFFNER, Eckhard , LITTMANN, Dieter , MÄHLING, Frank-Olaf , KÖHLER, Gernot
IPC分类号： C08F210/02 , C08F2/00
CPC分类号： C08F210/02 , Y02P20/544 , C08F2/00 , C08F2/005
摘要： In a process for polymerizing ethylene and, if desired, further monomers in a high-pressure reactor at from 140 to 320° C. and pressures of from 1000 to 4000 bar, but in any case under pressure and temperature conditions under which water displays supercritical behavior, water is introduced continuously or intermittently into the reactor.
摘要翻译：在使乙烯和如果需要的话其它单体在高压反应器中在140-320℃和1000-4000巴的压力下聚合的方法中，但是在任何情况下在压力和温度条件下水显示超临界行为，水被连续或间歇地引入反应器。

4. 发明授权

EP1419186B1 VERFAHREN ZUR HOCHDRUCKPOLYMERISATION VON ETHYLEN 有权
标题翻译：方法高压低密度聚乙烯
公开(公告)号：EP1419186B1
公开(公告)日：2005-02-16
申请号：EP02796223.2
申请日：2002-08-13
申请人： Basell Polyolefine GmbH
发明人： DECKERS, Andreas , MÄHLING, Frank-Olaf , GROOS, Georg , KÖHLER, Gernot , WEBER, Wilhelm
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C08F110/02 , C08F2/00 , C08F2/002 , C08F2/001 , C08F2500/12
摘要： The invention relates to a method for polymerizing ethylene and, optionally, other monomers in a high-pressure reactor at pressures between 1000 and 4000 bars and temperatures between 120 and 350 °C, whereby hydrogen is intermittently introduced into said reactor.

5. 发明公开

EP1287045A2 VERFAHREN ZUR HOCHDRUCKPOLYMERISATION VON ETHYLEN IN GEGENWART VON ÜBERKRITISCHEM WASSER 有权
标题翻译：方法高压乙烯超临界水的存在下
公开(公告)号：EP1287045A2
公开(公告)日：2003-03-05
申请号：EP01964950.8
申请日：2001-05-25
申请人： Basell Polyolefine GmbH
发明人： HÄFFNER, Eckhard , LITTMANN, Dieter , MÄHLING, Frank-Olaf , KÖHLER, Gernot
IPC分类号： C08F210/02 , C08F2/00
CPC分类号： C08F210/02 , Y02P20/544 , C08F2/00 , C08F2/005
摘要： In a process for polymerizing ethylene and, if desired, further monomers in a high-pressure reactor at from 140 to 320° C. and pressures of from 1000 to 4000 bar, but in any case under pressure and temperature conditions under which water displays supercritical behavior, water is introduced continuously or intermittently into the reactor.

6. 发明授权

EP1351999B1 Verwendung von geruchlosen Ethylenhomopolymeren 有权
标题翻译：使用无味乙烯均聚物
公开(公告)号：EP1351999B1
公开(公告)日：2012-02-22
申请号：EP01272001.7
申请日：2001-12-12
申请人： Basell Polyolefine GmbH
发明人： MÄHLING, Frank-Olaf , DECKERS, Andreas , KÖHLER, Gernot , SCHMITZ, Axel , WITTKOWSKI, Lars , HOPPACH, Michael
IPC分类号： C08F10/02 , C08F4/28 , C08F2/38
CPC分类号： C08F210/02 , C08F110/02 , Y10T428/1352 , Y10T428/139 , C08F2/001 , C08F4/28 , C08F2/38 , C08F2500/12
摘要： The invention relates to a method for producing ethylene homopolymers and copolymers in a tubular reactor having at least two polymerisation zones, at temperatures of between 150 °C and 350 °C and pressures of between 500 and 5000 bar, using oxygen as an initiator. Said method is characterised in that at least one aliphatic ketone of general formula (I) is used as a molar mass regulator. The variable R1 in formula (I) represents a C¿1?-C6 alkyl or a C3-C12-cycloalkyl. The invention also relates to ethylene homopolymers and copolymers that can be obtained using the inventive method and the use of the same for producing injection-moulded products in the fields of cosmetics, medicine and food.

7. 发明授权

EP1263812B1 VERFAHREN ZUR HERSTELLUNG VON POLYETHYLEN 无效
标题翻译：用于生产聚乙烯
公开(公告)号：EP1263812B1
公开(公告)日：2004-07-14
申请号：EP01929431.3
申请日：2001-03-13
申请人： Basell Polyolefine GmbH
发明人： GONIOUKH, Andrei , WITTKOWSKI, Lars , DRÖGE, Thomas , FISCHER, Ernst , KLIMESCH, Roger , ROSENDORFER, Philipp , KÖHLER, Gernot , LITTMANN, Dieter
IPC分类号： C08F10/02 , C08F4/38 , C08F2/00 , C08J5/18
CPC分类号： C08F10/02 , C08F110/02 , C08F4/38 , C08F4/36 , C08F2/00 , C08F2500/12 , C08F2500/26
摘要： The invention relates to a method for the production of ethylene homopolymers and copolymers in a tubular reactor at temperatures of from 160 °C to 350 °C and pressures in the range from 500 to 50000 bar, optionally with the use of molecular mass regulators. The invention is characterised in that a peroxide mixture is used as polymerisation initiator, which contains 1 to 95 mol % of at least one cyclic peroxide of formula (I), based upon the total amount of the peroxide mixture, where the group R is either the same or different and may be chosen from alkyl or aryl groups.

8. 发明公开

EP1419186A1 VERFAHREN ZUR HOCHDRUCKPOLYMERISATION VON ETHYLEN 有权
标题翻译：方法高压低密度聚乙烯
公开(公告)号：EP1419186A1
公开(公告)日：2004-05-19
申请号：EP02796223.2
申请日：2002-08-13
申请人： Basell Polyolefine GmbH
发明人： DECKERS, Andreas , MÄHLING, Frank-Olaf , GROOS, Georg , KÖHLER, Gernot , WEBER, Wilhelm
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C08F110/02 , C08F2/00 , C08F2/002 , C08F2/001 , C08F2500/12
摘要： The invention relates to a method for polymerizing ethylene and, optionally, other monomers in a high-pressure reactor at pressures between 1000 and 4000 bars and temperatures between 120 and 350 °C, whereby hydrogen is intermittently introduced into said reactor.

9. 发明公开

EP1351999A2 GERUCHLOSE ETHYLENHOMO- UND COPOLYMERE MIT GUTEN MECHANISCHEN EIGENSCHAFTEN 有权
标题翻译：使用无味乙烯均聚物
公开(公告)号：EP1351999A2
公开(公告)日：2003-10-15
申请号：EP01272001.7
申请日：2001-12-12
申请人： Basell Polyolefine GmbH
发明人： MÄHLING, Frank-Olaf , DECKERS, Andreas , KÖHLER, Gernot , SCHMITZ, Axel , WITTKOWSKI, Lars , HOPPACH, Michael
IPC分类号： C08F10/02 , C08F4/28 , C08F2/38
CPC分类号： C08F210/02 , C08F110/02 , Y10T428/1352 , Y10T428/139 , C08F2/001 , C08F4/28 , C08F2/38 , C08F2500/12
摘要： The invention relates to a method for producing ethylene homopolymers and copolymers in a tubular reactor having at least two polymerisation zones, at temperatures of between 150 °C and 350 °C and pressures of between 500 and 5000 bar, using oxygen as an initiator. Said method is characterised in that at least one aliphatic ketone of general formula (I) is used as a molar mass regulator. The variable R1 in formula (I) represents a C¿1?-C6 alkyl or a C3-C12-cycloalkyl. The invention also relates to ethylene homopolymers and copolymers that can be obtained using the inventive method and the use of the same for producing injection-moulded products in the fields of cosmetics, medicine and food.

10. 发明授权

EP1287045B2 VERFAHREN ZUR HOCHDRUCKPOLYMERISATION VON ETHYLEN IN GEGENWART VON ÜBERKRITISCHEM WASSER 有权
标题翻译：方法高压乙烯超临界水的存在下
公开(公告)号：EP1287045B2
公开(公告)日：2010-01-27
申请号：EP01964950.8
申请日：2001-05-25
申请人： Basell Polyolefine GmbH
发明人： HÄFFNER, Eckhard , LITTMANN, Dieter , MÄHLING, Frank-Olaf , KÖHLER, Gernot
IPC分类号： C08F210/02 , C08F2/00 , C08F220/00
CPC分类号： C08F210/02 , Y02P20/544 , C08F2/00 , C08F2/005
摘要： In a process for polymerizing ethylene and, if desired, further monomers in a high-pressure reactor at from 140 to 320° C. and pressures of from 1000 to 4000 bar, but in any case under pressure and temperature conditions under which water displays supercritical behavior, water is introduced continuously or intermittently into the reactor.

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