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1. 发明申请

WO2004050713A2 1-BUTEN COPOLYMERS AND PROCESS FOR PREPARING THEM 审中-公开
标题翻译： 1-BUTEN共聚物及其制备方法
公开(公告)号：WO2004050713A2
公开(公告)日：2004-06-17
申请号：PCT/EP0312944
申请日：2003-11-14
申请人： BASELL POLYOLEFINE GMBH , RESCONI LUIGI , PELLICONI ANTEO , GARAGNANI ENEA
发明人： RESCONI LUIGI , PELLICONI ANTEO , GARAGNANI ENEA
IPC分类号： C08F2/00 , C08F4/642 , C08F4/659 , C08F210/08 , C08F
CPC分类号： C08F210/08 , C08F4/65912 , C08F4/65927 , C08F210/16 , C08F2500/03 , C08F2500/15 , C08F2500/20
摘要： A process for preparing isotactic 1-butene copolymers containing up to 30% by mol of units derived from of one or more alpha olefins of formula CH2=CHZ, wherein Z is a C3C20 hydrocarbon group comprising contacting 1-butene and one or more of said alphaolefins under polymerization conditions in the presence of a catalyst system obtainable by contacting: (A) a metallocene compound of formula (I) (1) wherein: M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, are hydrogen atoms, halogen atoms, or an hydrocarbon group; L is a divalent bridging group; R and R are hydrocarbon groups; R and R are hydrogen atoms or hydrocarbon groups; T and T , equal to or different from each other are a moiety of formula (lI), (III) or (IV): wherein: the atom marked with the symbol * is bound the atom marked with the same symbol in formula (I); R , R , R , R and R , equal to or different from each other, are hydrogen or hydrocarbon groups; and (B) an alumoxane or a compound able to form an alkylmetallocene cation.
摘要翻译：一种制备全同立构1-丁烯共聚物的方法，该共聚物含有至多30摩尔％的衍生自一种或多种式CH 2 = CHZ的α-烯烃的单元，其中Z是C 3 C 20烃基，包括使1-丁烯和所述在（A）茂金属化合物（I）（1）的催化剂体系存在下，在聚合条件下，α-烯烃在其中：M是过渡金属的原子; p是0至3的整数; X相同或不同，为氢原子，卤素原子或烃基; L是二价桥基; R 1和R 3是烃基; R 2和R 4是氢原子或烃基; T 1和T 2彼此相同或不同的是式（I），（III）或（IV）的部分：其中：用符号*标记的原子与标记有式（I）中的相同符号; R 5，R 6，R 7，R 8和R 9彼此相同或不同，为氢或烃基; 和（B）铝氧烷或能够形成烷基茂金属阳离子的化合物。

2. 发明专利

DE60329523D1 未知
公开(公告)号：DE60329523D1
公开(公告)日：2009-11-12
申请号：DE60329523
申请日：2003-11-14
申请人： BASELL POLYOLEFINE GMBH
发明人： RESCONI LUIGI , PELLICONI ANTEO , GARAGNANI ENEA
IPC分类号： C08F210/08 , C08F2/00 , C08F4/642 , C08F4/659 , C08F4/6592
摘要： An isotactic 1-butene copolymer having a content up to 30% by mol of at least one alpha-olefin of formula CH2-CHZ derived units, wherein Z is a C3-C20 hydrocarbon group, having the following features: isotactic pentads (mmmm) >90%; and a percentage of soluble fraction in diethylether (% SD) and a molar content of said alpha olefins (% O) in the polymer chain meeting the following relation: % SD>2.8% O+8.

3. 发明专利

AT444315T 未知
公开(公告)号：AT444315T
公开(公告)日：2009-10-15
申请号：AT03812152
申请日：2003-11-14
申请人： BASELL POLYOLEFINE GMBH
发明人： RESCONI LUIGI , PELLICONI ANTEO , GARAGNANI ENEA
IPC分类号： C08F210/08 , C08F2/00 , C08F4/642 , C08F4/659 , C08F4/6592
摘要： A process for preparing isotactic 1-butene copolymers containing up to 30% by mol of units derived from of one or more alpha olefins of formula CH2=CHZ, wherein Z is a C3C20 hydrocarbon group comprising contacting 1-butene and one or more of said alphaolefins under polymerization conditions in the presence of a catalyst system obtainable by contacting: (A) a metallocene compound of formula (I) (1) wherein: M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, are hydrogen atoms, halogen atoms, or an hydrocarbon group; L is a divalent bridging group; R and R are hydrocarbon groups; R and R are hydrogen atoms or hydrocarbon groups; T and T , equal to or different from each other are a moiety of formula (lI), (III) or (IV): wherein: the atom marked with the symbol * is bound the atom marked with the same symbol in formula (I); R , R , R , R and R , equal to or different from each other, are hydrogen or hydrocarbon groups; and (B) an alumoxane or a compound able to form an alkylmetallocene cation.

4. 发明专利

BRPI0513109A 未知
公开(公告)号：BRPI0513109A
公开(公告)日：2008-04-29
申请号：BRPI0513109
申请日：2005-06-10
申请人： BASELL POLYOLEFINE GMBH
发明人： RESCONI LUIGI , PELLICONI ANTEO , SPATARO STEFANO , MOSCARDI GILBERTO
IPC分类号： C08L23/18 , C08F4/642 , C08F10/08 , C08F210/08 , C08L23/20
摘要： A 1-butene polymer composition comprising: a) from 5% by weight to 95% by weight of an atactic 1-butene-based polymer, having the following features: distribution of molecular weight Mw/Mn equal to or lower than 4; rr triads, measured by 13C-NMR comprised between 5% and 50%; no enthalpy of fusion detectable at a differential scanning calorimeter (DSC); intrinsic viscosity (IV) measured in tetrahydronaphtalene (THN) at 135° C. comprised between 0.85 dl/g and 5.0 dl/g; and infrared crystallinity lower than 0.5%; b) from 5% by weight to 95% by weight of an isotactic 1-butene-based polymer having the following features: isotactic pentads (mmmm) measured by 13C-NMR, higher than 80%; melting point higher than 80° C.; and intrinsic viscosity (IV) measured in tetrahydronaphtalene (THN) at 135° C. comprised between 0.1 dl/g and 5 dl/g.

5. 发明专利

DE602005005334D1 未知
公开(公告)号：DE602005005334D1
公开(公告)日：2008-04-24
申请号：DE602005005334
申请日：2005-06-10
申请人： BASELL POLYOLEFINE GMBH
发明人： RESCONI LUIGI , PELLICONI ANTEO , SPATARO STEFANO , MOSCARDI GILBERTO
IPC分类号： C08L23/18 , C08F4/642 , C08F10/08 , C08F210/08 , C08L23/20
摘要： A 1-butene polymer composition comprising: a) from 5% by weight to 95% by weight of an atactic 1-butene-based polymer, having the following features: distribution of molecular weight Mw/Mn equal to or lower than 4; rr triads, measured by 13C-NMR comprised between 5% and 50%; no enthalpy of fusion detectable at a differential scanning calorimeter (DSC); intrinsic viscosity (IV) measured in tetrahydronaphtalene (THN) at 135° C. comprised between 0.85 dl/g and 5.0 dl/g; and infrared crystallinity lower than 0.5%; b) from 5% by weight to 95% by weight of an isotactic 1-butene-based polymer having the following features: isotactic pentads (mmmm) measured by 13C-NMR, higher than 80%; melting point higher than 80° C.; and intrinsic viscosity (IV) measured in tetrahydronaphtalene (THN) at 135° C. comprised between 0.1 dl/g and 5 dl/g.

6. 发明专利

BRPI0413958A 未知
公开(公告)号：BRPI0413958A
公开(公告)日：2006-10-31
申请号：BRPI0413958
申请日：2004-08-06
申请人： BASELL POLYOLEFINE GMBH
发明人： PELLICONI ANTEO , TONTI MARIA SILVIA , RESCONI LUIGI
IPC分类号： C08F2/00 , C08F4/659 , C08F10/00 , C08F210/06 , C08F297/08 , C08L23/08 , C08L23/14 , C08F4/643
摘要： A multistage process comprising the following steps: a) polymerizing propylene with optionally one or more monomers selected from ethylene and alpha olefins of formula CH 2 -CHT 1 , wherein T 1 is a C 2 -C 20 alkyl radical in the presence of a catalysts system, supported on an inert carrier comprising: i) a transition metal compound containing a ligand having a cyclopentadienyl skeleton; and ii) an alumoxane or a compound capable of forming an alkyl metallocene cation; b) contacting, under polymerization conditions, in a gas phase, ethylene with one or more alpha olefins of formula CH 2 -CHT 1 , wherein T 1 is a C 2 -C 20 alkyl radical, and optionally a non-conjugated diene, in the presence of the polymer obtained in step a), in the presence of a weigh ratio hydrogen/hethylene higher than 1 ppm and optionally in the presence of an additional organo aluminum compound; wherein the amount of the polymer obtained in step a) ranges from 5% by weight and 90% by weight of the polymer obtained in the whole process and the amount of polymer obtained in step b) ranges from 10% by weight and 95% by weight of the polymer obtained in the whole process.

7. 发明专利

AU2005263670A1 1-butene polymers composition 未知
公开(公告)号：AU2005263670A1
公开(公告)日：2006-01-26
申请号：AU2005263670
申请日：2005-06-10
申请人： BASELL POLYOLEFINE GMBH
发明人： MOSCARDI GILBERTO , SPATARO STEFANO , RESCONI LUIGI , PELLICONI ANTEO
IPC分类号： C08L23/18 , C08F4/642 , C08F10/08 , C08F210/08 , C08L23/20
摘要： A 1-butene polymer composition comprising: a) from 5% by weight to 95% by weight of an atactic 1-butene-based polymer, having the following features: distribution of molecular weight Mw/Mn equal to or lower than 4; rr triads, measured by 13C-NMR comprised between 5% and 50%; no enthalpy of fusion detectable at a differential scanning calorimeter (DSC); intrinsic viscosity (IV) measured in tetrahydronaphtalene (THN) at 135° C. comprised between 0.85 dl/g and 5.0 dl/g; and infrared crystallinity lower than 0.5%; b) from 5% by weight to 95% by weight of an isotactic 1-butene-based polymer having the following features: isotactic pentads (mmmm) measured by 13C-NMR, higher than 80%; melting point higher than 80° C.; and intrinsic viscosity (IV) measured in tetrahydronaphtalene (THN) at 135° C. comprised between 0.1 dl/g and 5 dl/g.

8. 发明专利

DE602005005334T2 未知
公开(公告)号：DE602005005334T2
公开(公告)日：2009-03-26
申请号：DE602005005334
申请日：2005-06-10
申请人： BASELL POLYOLEFINE GMBH
发明人： RESCONI LUIGI , PELLICONI ANTEO , SPATARO STEFANO , MOSCARDI GILBERTO
IPC分类号： C08L23/18 , C08F4/642 , C08F10/08 , C08F210/08 , C08L23/20
摘要： A 1-butene polymer composition comprising: a) from 5% by weight to 95% by weight of an atactic 1-butene-based polymer, having the following features: distribution of molecular weight Mw/Mn equal to or lower than 4; rr triads, measured by 13C-NMR comprised between 5% and 50%; no enthalpy of fusion detectable at a differential scanning calorimeter (DSC); intrinsic viscosity (IV) measured in tetrahydronaphtalene (THN) at 135° C. comprised between 0.85 dl/g and 5.0 dl/g; and infrared crystallinity lower than 0.5%; b) from 5% by weight to 95% by weight of an isotactic 1-butene-based polymer having the following features: isotactic pentads (mmmm) measured by 13C-NMR, higher than 80%; melting point higher than 80° C.; and intrinsic viscosity (IV) measured in tetrahydronaphtalene (THN) at 135° C. comprised between 0.1 dl/g and 5 dl/g.

9. 发明专利

DE602004018516D1 未知
公开(公告)号：DE602004018516D1
公开(公告)日：2009-01-29
申请号：DE602004018516
申请日：2004-08-06
申请人： BASELL POLYOLEFINE GMBH
发明人： PELLICONI ANTEO , TONTI MARIA SILVIA , RESCONI LUIGI
IPC分类号： C08F297/08 , C08F2/00 , C08F4/643 , C08F4/659 , C08F10/00 , C08F210/06 , C08L23/08 , C08L23/14
摘要： A multistage process comprising the following steps: a) polymerizing propylene with optionally one or more monomers selected from ethylene and alpha olefins of formula CH 2 -CHT 1 , wherein T 1 is a C 2 -C 20 alkyl radical in the presence of a catalysts system, supported on an inert carrier comprising: i) a transition metal compound containing a ligand having a cyclopentadienyl skeleton; and ii) an alumoxane or a compound capable of forming an alkyl metallocene cation; b) contacting, under polymerization conditions, in a gas phase, ethylene with one or more alpha olefins of formula CH 2 -CHT 1 , wherein T 1 is a C 2 -C 20 alkyl radical, and optionally a non-conjugated diene, in the presence of the polymer obtained in step a), in the presence of a weigh ratio hydrogen/hethylene higher than 1 ppm and optionally in the presence of an additional organo aluminum compound; wherein the amount of the polymer obtained in step a) ranges from 5% by weight and 90% by weight of the polymer obtained in the whole process and the amount of polymer obtained in step b) ranges from 10% by weight and 95% by weight of the polymer obtained in the whole process.

10. 发明专利

AT417875T 未知
公开(公告)号：AT417875T
公开(公告)日：2009-01-15
申请号：AT04763927
申请日：2004-08-06
申请人： BASELL POLYOLEFINE GMBH
发明人： PELLICONI ANTEO , TONTI MARIA , RESCONI LUIGI
IPC分类号： C08F297/08 , C08F2/00 , C08F4/643 , C08F4/659 , C08F10/00 , C08F210/06 , C08L23/08 , C08L23/14
摘要： A multistage process comprising the following steps: a) polymerizing propylene with optionally one or more monomers selected from ethylene and alpha olefins of formula CH 2 -CHT 1 , wherein T 1 is a C 2 -C 20 alkyl radical in the presence of a catalysts system, supported on an inert carrier comprising: i) a transition metal compound containing a ligand having a cyclopentadienyl skeleton; and ii) an alumoxane or a compound capable of forming an alkyl metallocene cation; b) contacting, under polymerization conditions, in a gas phase, ethylene with one or more alpha olefins of formula CH 2 -CHT 1 , wherein T 1 is a C 2 -C 20 alkyl radical, and optionally a non-conjugated diene, in the presence of the polymer obtained in step a), in the presence of a weigh ratio hydrogen/hethylene higher than 1 ppm and optionally in the presence of an additional organo aluminum compound; wherein the amount of the polymer obtained in step a) ranges from 5% by weight and 90% by weight of the polymer obtained in the whole process and the amount of polymer obtained in step b) ranges from 10% by weight and 95% by weight of the polymer obtained in the whole process.

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