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1. 发明申请

WO2011012500A1 POLYOLEFINIC COMPOSITIONS 审中-公开
标题翻译：聚合物组合物
公开(公告)号：WO2011012500A1
公开(公告)日：2011-02-03
申请号：PCT/EP2010/060483
申请日：2010-07-20
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , MASSARI, Paola , CIARAFONI, Marco , BIONDINI, Gisella , PANTALEONI, Roberto
发明人： MASSARI, Paola , CIARAFONI, Marco , BIONDINI, Gisella , PANTALEONI, Roberto
IPC分类号： C08L23/12 , C08F297/08 , C08J5/18
CPC分类号： C08L23/12 , C08F297/083 , C08L23/06 , C08L23/16 , C08L2205/03 , C08L2666/02
摘要： A polymer composition comprising (per cent by weight): a) 70-84% of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13 C-MNR on the fraction insoluble in xylene at 25° C, higher than 97.5 molar %; b) 8 -15% of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 25 to 50 wt% and being partially soluble in xylene at ambient temperature; the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2.5 to 3.5 dl/g; and c) 8-15% of ethylene homopolymer having an intrinsic viscosity value ranging from 1.5 to 4 dl/g; said composition having a value of melt flow rate ranging from 55 to 90 g/10 min, and the amount of hexane extractables lower than 3.5 wt%,.
摘要翻译：包含（重量百分比）的聚合物组合物：a）70-84％的具有全同立构五单元组的结晶丙烯聚合物（mmmm），通过13C-MNR测量在25℃下不溶于二甲苯的级分，高于 97.5摩尔％ b）8-15％的乙烯和丙烯的弹性体共聚物，所述共聚物具有一定量的衍生自乙烯的重复单元，范围为25至50重量％，并且在环境温度下部分可溶于二甲苯; 在环境温度下可溶于二甲苯的聚合物级分的特性粘度值为2.5至3.5dl / g; 和c）8-15％的特性粘度值为1.5-4dl / g的乙烯均聚物; 所述组合物的熔体流动速率范围为55至90g / 10min，并且己烷可提取物的量低于3.5wt％。

2. 发明申请

WO2010108866A9 POLYOLEFIN MASTERBATCH AND COMPOSITION SUITABLE FOR INJECTION MOLDING 审中-公开
公开(公告)号：WO2010108866A9
公开(公告)日：2010-09-30
申请号：PCT/EP2010/053621
申请日：2010-03-19
申请人： BASELL POLIOLEFINE ITALIA S.r.l. , CIARAFONI, Marco , MASSARI, Paola , BIONDINI, Gisella , PANTALEONI, Roberto , WILLEMS, Sander
发明人： CIARAFONI, Marco , MASSARI, Paola , BIONDINI, Gisella , PANTALEONI, Roberto , WILLEMS, Sander
IPC分类号： C08L23/10 , C08L23/12
摘要： A masterbatch composition comprising: 70-90 %wt of a component (A) being a propylene homopolymer or copolymer of propylene with ethylene or C 4 -C 10 alpha olefins, having a MFR A according to ISO 1133 (230°C/2.16 Kg) ranging from 15 to 70 g/10 min; and 10-30 %wt of a component B) being a propylene-ethylene copolymer comprising 25-45 %wt of ethylene derived units and having a value of the intrinsic viscosity [η] of the fraction soluble in xylene at room temperature ranging from 5 to 9 dl/g, said masterbatch composition having a total MFR higher than 4 g/10 min, and a value of the fiexural modulus measured according to ISO method 178 ranging from 950 to 2000 MPa.

3. 发明申请

WO2011012491A1 POLYOLEFINIC COMPOSITIONS 审中-公开
标题翻译：聚合物组合物
公开(公告)号：WO2011012491A1
公开(公告)日：2011-02-03
申请号：PCT/EP2010/060461
申请日：2010-07-20
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , CIARAFONI, Marco , MASSARI, Paola , BIONDINI, Gisella , PANTALEONI, Roberto
发明人： CIARAFONI, Marco , MASSARI, Paola , BIONDINI, Gisella , PANTALEONI, Roberto
IPC分类号： C08L23/12 , C08F297/08 , C08J5/18
CPC分类号： C08J5/18 , C08F297/083 , C08J2323/12 , C08L23/06 , C08L23/12 , C08L23/16 , C08L2205/03 , C08L2666/02
摘要： A polymer composition comprising (per cent by weight): a) 57%-74%, of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13 C-MNR on the fraction insoluble in xylene at 25° C, higher than 97.5 molar % and a polydispersity index ranging from 5 to 10; b) 8 to 15%, of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 50%, and being partially soluble in xylene at ambient temperature; the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2.5 to 3.5 dl/g; and c) 18-28%, of ethylene homopolymer having an intrinsic viscosity value ranging from 1.5 to 4 dl/g; said composition having a value of melt flow rate ranging from 35 to 60 g/10 min, and the amount of hexane extractables lower than 4.0 wt%.
摘要翻译：包含（重量％）的聚合物组合物：a）57％-74％的具有全同立构五单元组的结晶丙烯聚合物（mmmm），通过13C-MNR测量在25℃下不溶于二甲苯的级分，高于97.5摩尔％，多分散指数为5〜10; b）8至15％的乙烯和丙烯的弹性体共聚物，所述共聚物具有一定量的衍生自乙烯的重复单元，范围为30至50％，并且在环境温度下部分溶于二甲苯; 在环境温度下可溶于二甲苯的聚合物级分的特性粘度值为2.5至3.5dl / g; 和c）18-28％的特性粘度值为1.5-4dl / g的乙烯均聚物; 所述组合物的熔体流动速率范围为35至60g / 10min，并且己烷可提取物的量低于4.0wt％。

4. 发明申请

WO2012120069A1 POLYOLEFIN-BASED CONTAINERS 审中-公开
标题翻译：基于聚烯烃的容器
公开(公告)号：WO2012120069A1
公开(公告)日：2012-09-13
申请号：PCT/EP2012/053967
申请日：2012-03-08
申请人： BASELL POLIOLEFINE ITALIA S.r.l. , FREDERICK, Thomas, A. , CAVALIERI, Claudio , SMITH, Jeanine, A. , JOBIN, Gilles , BRASEL, Timothy, C. , PANTALEONI, Roberto , CIARAFONI, Marco , MASSARI, Paola
发明人： FREDERICK, Thomas, A. , CAVALIERI, Claudio , SMITH, Jeanine, A. , JOBIN, Gilles , BRASEL, Timothy, C. , PANTALEONI, Roberto , CIARAFONI, Marco , MASSARI, Paola
IPC分类号： C08L23/12 , B29C45/00 , B65D1/02
CPC分类号： B65D1/0207 , B29C45/0001 , C08L23/12 , C08L23/14 , Y10T428/1352
摘要： A container comprising a polyolefin composition comprising: A) from 59 wt% to 84 wt%, of a propylene homopolymer having isotactic pentads (mmmm) measured with by 13 C-NMR higher than 96%, B) from 16 wt% to 41 wt%, of a copolymer of propylene and ethylene with from 30wt% to 44wt%, of ethylene derived units; the sum A) + B) being 100; the composition having an MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230°C and 2.16 kg load) comprised from 72 to 100 g/10 min.
摘要翻译：一种包含聚烯烃组合物的容器，其包含：A）59重量％至84重量％的具有通过13 C-NMR测量的全同立构五单元组（mmmm）的丙烯均聚物高于96％，B）16重量％至41重量％的丙烯和乙烯与30重量％至44重量％的乙烯衍生单元的共聚物; 总和A）+ B）为100; 组合物的MFR L（根据ISO 1133的熔体流动速率，条件L，即230℃和2.16kg负荷）由72至100g / 10分钟组成。

5. 发明申请

WO2012098086A1 POLYOLEFIN COMPOSITION 审中-公开
标题翻译：聚烯烃组合物
公开(公告)号：WO2012098086A1
公开(公告)日：2012-07-26
申请号：PCT/EP2012/050589
申请日：2012-01-17
申请人： BASELL POLIOLEFINE ITALIA S.r.l. , CIARAFONI, Marco , DESTRO, Mara , MASSARI, Paola , PANTALEONI, Roberto
发明人： CIARAFONI, Marco , DESTRO, Mara , MASSARI, Paola , PANTALEONI, Roberto
IPC分类号： C08L23/10
CPC分类号： C08L23/12 , C08L23/06 , C08L23/0815 , C08L23/10 , C08L2207/02 , C08L2314/02 , H01M2/1022 , H01M2/1072 , C08L2666/02
摘要： A polyolefin composition comprising: a) from 66 wt% to 76 wt% of a propylene polymer having the fraction insoluble in xylene at 25°C, higher than 97 wt%, a polydispersity index lower than 4.5, and a melt flow rate (MFR) determined according to ISO method 1133 (230° C and 2.16 kg)comprised between 6.0 g/10 min and 10.0 g/10 min, b) from 12 wt% to 20 wt% of acopolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 40 wt% to 53 wt%,the polymer fraction soluble in xylene at 25°C having an intrinsic viscosity value ranging from 2 to 4 dl/g; c) from 12% to 20%% of ethylene homopolymer; the sum of the amount of a) +b) +c) being100; said composition having a value of melt flowrate (MFR) determined according to ISO method 1133 (230° C and 2.16 kg)ranging from 3.6 to 8.0 g/10 min.
摘要翻译：一种聚烯烃组合物，其包含：a）66重量％至76重量％的丙烯聚合物，其具有在25℃下不溶于二甲苯的馏分，高于97重量％，多分散指数低于4.5，熔体流动速率（MFR ）根据ISO方法1133（230℃和2.16kg）测定，包括6.0g / 10min至10.0g / 10min，b）12wt％至20wt％的乙烯和丙烯共聚物，该共聚物具有来自乙烯的重复单元的量为40重量％至53重量％，在25℃下可溶于二甲苯的聚合物部分的特性粘度值为2至4dl / g; c）12％-20％的乙烯均聚物; a）+ b）+ c）的数量之和为100; 所述组合物具有根据ISO方法1133（230℃和2.16kg）测定的熔体流动速率（MFR）为3.6至8.0g / 10min。

6. 发明申请

WO2010149705A1 POLYOLEFIN COMPOSITIONS 审中-公开
标题翻译：聚烯烃组合物
公开(公告)号：WO2010149705A1
公开(公告)日：2010-12-29
申请号：PCT/EP2010/058916
申请日：2010-06-23
申请人： Basell Poliolefine Italia S.r.l. , GALVAN, Monica , CIARAFONI, Marco , PANTALEONI, Roberto , FERRARO, Angelo
发明人： GALVAN, Monica , CIARAFONI, Marco , PANTALEONI, Roberto , FERRARO, Angelo
IPC分类号： C08L23/10 , B29C45/00 , C08J5/18
CPC分类号： C08J5/18 , C08J2323/10 , C08L23/0807 , C08L23/0815 , C08L23/10 , C08L2666/06
摘要： Polyolefin compositions particularly suitable for cast film, exhibiting heat sealability, retortability, low haze and stiffness, comprising: 1) 75-85% of a propylene homopolymer or copolymer of propylene with ethylene and/or one or more C 4 -C 10 α-olefin(s), the homopolymer or copolymer having melting temperature equal to or higher than 150°C, 2) 15-25% of a copolymer of ethylene with one or more C 4 -C 10 α-olefin(s) containing from 20 to 30% of said C 4 -C 10 α-olefin(s); said composition having MFR (at 230°C, 2.16 kg) of from 5-10 g/10 min, the total content of ethylene of from 10 to 20 %, the total content of C 4 -C 10 α-olefin(s) of from 2 to 8 %, the ratio XStot/XSm of the total fraction soluble in Xylene at room temperature to the fraction soluble in Xylene at room temperature of the matrix component (1) of from 5 to 15, and the value of the intrinsic viscosity of the total fraction soluble in Xylene at room temperature (XSIVtot) of 1.5 dl/g or less.
摘要翻译：特别适用于流延膜的聚烯烃组合物，具有热封性，蒸馏性，低雾度和刚度，包括：1）75-85％的丙烯均聚物或丙烯与乙烯和/或一种或多种C 4 -C 10α-烯烃的共聚物 s），熔融温度等于或高于150℃的均聚物或共聚物，2）乙烯与一种或多种C 20 -C 30α-烯烃的共聚物的15-25％所述C 4 -C 10α-烯烃; 所述组合物的MFR（在230℃，2.16kg）为5-10g / 10min，乙烯的总含量为10至20％，C 4 -C 10α-烯烃的总含量为 2〜8％，室温下可溶于二甲苯的总馏分的比例XStot / XSm与基体成分（1）的室温下可溶于二甲苯的馏分的比例为5〜15，特性粘度的值在室温下可溶于二甲苯的总馏分（XSIVtot）为1.5dl / g以下。

7. 发明申请

WO2010146074A1 PROCESS FOR THE PREPARATION OF IMPACT RESISTANT PROPYLENE POLYMER COMPOSITIONS 审中-公开
标题翻译：制备抗冲击丙烯聚合物组合物的方法
公开(公告)号：WO2010146074A1
公开(公告)日：2010-12-23
申请号：PCT/EP2010/058437
申请日：2010-06-16
申请人： BASELL POLIOLEFINE ITALIA S.r.l. , COLLINA, Gianni , CIARAFONI, Marco , FUSCO, Ofelia , GADDI, Benedetta , GALVAN, Monica , MORINI, Giampiero , PANTALEONI, Roberto , VERROCCHIO, Francesca
发明人： COLLINA, Gianni , CIARAFONI, Marco , FUSCO, Ofelia , GADDI, Benedetta , GALVAN, Monica , MORINI, Giampiero , PANTALEONI, Roberto , VERROCCHIO, Francesca
IPC分类号： C08F10/06
CPC分类号： C08F10/06 , C08F110/06 , C08F4/6492 , C08F4/651 , C08F2/001 , C08F210/06 , C08F210/16 , C08F2500/12 , C08F2500/17 , C08F4/6494
摘要： A process for the preparation of propylene polymer compositions carried out in the presence of a catalyst system comprising (a) a solid catalyst component having average particle size ranging from 15 to 80 μm comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and optionally (c) an external electron donor compound, and comprising the following steps: (i) contacting the catalyst components (a), (b) and optionally (c); (ii) pre -polymerizing up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); (iii)polymerizing propylene producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25°C and (iv)in a successive step, carried out in gas-phase, polymerizing mixtures of ethylene with α-olefϊns CH 2 =CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce the said ethylene copolymer.
摘要翻译：一种制备丙烯聚合物组合物的方法，所述组合物在催化剂体系存在下进行，所述催化剂体系包含（a）平均粒度为15-80μm的固体催化剂组分，其包含卤化镁，至少具有Ti- 卤素键和至少两种电子给体化合物，其中一种以相对于供体总量为50-90％摩尔量存在，选自琥珀酸盐，另一种选自1,3-二醚，（b）烷基铝和任选的（c）外电子给体化合物，并包括以下步骤：（i）使催化剂组分（a），（b）和任选的（c）接触; （ii）预聚合至每克固体催化剂组分（a）约0.1至约1000g的聚合物的形成量; （iii）聚合产生丙烯（共）聚合物的丙烯，其在25℃下为不溶于二甲苯的至少85重量％，和（iv）在连续步骤中，在气相中进行乙烯与乙烯的聚合混合物烯基-CH 2 = CHR，其中R是具有1-10个碳原子的烃基，以制备所述乙烯共聚物。

8. 发明申请

WO2011061134A1 PROCESS FOR THE PREPARATION OF IMPACT RESISTANT PROPYLENE POLYMER COMPOSITIONS 审中-公开
标题翻译：制备抗冲击丙烯聚合物组合物的方法
公开(公告)号：WO2011061134A1
公开(公告)日：2011-05-26
申请号：PCT/EP2010/067434
申请日：2010-11-15
申请人： Basell Poliolefine Italia S.r.l. , COLLINA, Gianni , CIARAFONI, Marco , FUSCO, Ofelia , GADDI, Benedetta , GALVAN, Monica , MORINI, Giampiero , PANTALEONI, Roberto , PATER, Joachim T.M. , PIEMONTESI, Fabrizio , VERROCCHIO, Francesca
发明人： COLLINA, Gianni , CIARAFONI, Marco , FUSCO, Ofelia , GADDI, Benedetta , GALVAN, Monica , MORINI, Giampiero , PANTALEONI, Roberto , PATER, Joachim T.M. , PIEMONTESI, Fabrizio , VERROCCHIO, Francesca
IPC分类号： C08F10/06
CPC分类号： C08F10/06 , C08F110/06 , C08F210/06 , C08F210/16 , C08F2/001 , C08F4/6494 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F2500/05
摘要： A process for the preparation of propylene polymer compositions comprising from 50 to 90% by weight of a propylene polymer fraction insoluble in xylene at 25°C, and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25°C, said process being carried out in the presence of a specific catalyst system, is also characterized by the following step: (i) contacting the catalyst components (a), (b) and optionally (c) for a period of time ranging from 0.1 to 120 minutes, at a temperature ranging from 0 to 90°C; (ii) polymerizing propylene in the optional presence of ethylene and/or C 4 -C 10 alpha olefins producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25°C and (iii) in a successive step, carried out in gas-phase, in the presence of the product coming from (ii), polymerizing mixtures of ethylene with α-olefins CH 2 =CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce an ethylene copolymer. An increased reactivity in the last step is observed.
摘要翻译：一种制备丙烯聚合物组合物的方法，其包含50至90重量％的在25℃下不溶于二甲苯的丙烯聚合物级分和10至50重量％在25℃下可溶于二甲苯的乙烯共聚物部分所述方法在特定催化剂体系的存在下进行，其特征还在于以下步骤：（i）使催化剂组分（a），（b）和任选地（c）接触一段时间为0.1 至120分钟，温度范围为0至90℃; （ii）在乙烯和/或C 4 -C 10α-烯烃的任选存在下聚合丙烯，产生丙烯（共）聚合物，其在25℃下为不溶于二甲苯的至少85重量％，和（iii）在连续步骤在（ii）产物存在下进行，在乙烯与α-烯烃CH2 = CHR的混合物中聚合，其中R是具有1-10个碳原子的烃基，以产生乙烯共聚物。观察到在最后步骤中增加的反应性。

9. 发明申请

WO2011036021A1 PROPYLENE POLYMER COMPOSITIONS 审中-公开
标题翻译：丙烯聚合物组合物
公开(公告)号：WO2011036021A1
公开(公告)日：2011-03-31
申请号：PCT/EP2010/062486
申请日：2010-08-26
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , GALVAN, Monica , CIARAFONI, Marco , COLLINA, Gianni , FUSCO, Ofelia , PANTALEONI, Roberto , MAZZUCCO, Antonio
发明人： GALVAN, Monica , CIARAFONI, Marco , COLLINA, Gianni , FUSCO, Ofelia , PANTALEONI, Roberto , MAZZUCCO, Antonio
IPC分类号： C08L23/12 , C08F297/08
CPC分类号： C08F297/083 , C08F110/06 , C08F210/06 , C08L23/12 , C08L23/16 , C08L2205/02 , C08L2207/02 , C08L2308/00 , C08L2314/02 , C08L2666/06 , C08F2500/04 , C08F2500/12 , C08F210/16 , C08F2500/17
摘要： A propylene polymer composition comprising (percent by weight): A) 74%-84% of a propylene homopolymer having a Polydispersity Index (P.I.) value of from 4.6 to 10, a fraction insoluble in xylene at 25 °C, higher than 90 %, and a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230°C and 2.16 kg load) from 110 to 200 g/10 min; B) 16%-26%, of a copolymer of propylene with from 39% to 48%, of ethylene derived units; the composition having an intrinsic viscosity of the fraction soluble in xylene at 25 °C comprised between 2.7 and 4.0 dl/g; and a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230°C and 2.16 kg load) from 30 to 80 g/10 min.
摘要翻译：包含（重量％）的丙烯聚合物组合物：A）74％-84％的多分散指数（PI）值为4.6至10的丙烯均聚物，25℃下不溶于二甲苯的级分，高于90％，和MFR L（根据ISO 1133的熔体流动速率，条件L，即230℃和2.16kg负荷）为110至200g / 10min; B）16％-26％的丙烯与39％至48％的乙烯衍生单元的共聚物; 所述组合物的特性粘度在25℃下可溶于二甲苯的馏分的特性粘度为2.7至4.0dl / g; 和MFR L（根据ISO 1133的熔体流动速率，条件L，即230℃和2.16kg负荷）为30至80g / 10min。

10. 发明申请

WO2011076611A1 POLYOLEFINIC COMPOSITIONS FOR INJECTION-MOULDED DRAINAGE SYSTEMS 审中-公开
标题翻译：用于注射成型的排水系统的聚合物组合物
公开(公告)号：WO2011076611A1
公开(公告)日：2011-06-30
申请号：PCT/EP2010/069582
申请日：2010-12-14
申请人： CAVALIERI, Claudio , GALVAN, Monica , PANTALEONI, Roberto , BECCARINI, Enrico , TISI, Francesca , ROTHHÖFT, Werner , BASELL POLIOLEFINE ITALIA S.R.L.
发明人： CAVALIERI, Claudio , GALVAN, Monica , PANTALEONI, Roberto , BECCARINI, Enrico , TISI, Francesca , ROTHHÖFT, Werner
IPC分类号： C08L23/10 , C08L23/14
CPC分类号： C08L23/10 , C08L23/0815 , C08L23/14 , C08L23/16 , C08L2203/18 , C08L2205/03 , C08L2666/02 , C08L2666/06 , C08F210/06 , C08F2/001 , C08F4/651 , C08F4/6492
摘要： A polypropylene composition for injection-moulded drainage systems comprising 78-84 wt% of a crystalline propylene polymer, 8 to less than 13 wt% of an elastomeric copolymer and 8 to less than 13 wt% of polyethylene. The said composition exhibits a flexural modulus value higher than 1400 MPa, a melt flow rate (MFR), determined according to ISO method 1133 (230° C and 2.16 kg), of from 1.5 to 5.0 g/10 min, and a value of Izod impact resistance at 0° C of more than 6 kJ/m2 according to ISO method 180/1 A.
摘要翻译：一种用于注射成型的排水系统的聚丙烯组合物，其包含78-84重量％的结晶丙烯聚合物，8至小于13重量％的弹性体共聚物和8至小于13重量％的聚乙烯。所述组合物显示高于1400MPa的挠曲模量值，根据ISO方法1133（230℃和2.16kg）测定的熔体流动速率（MFR）为1.5至5.0g / 10min，值为根据ISO方法180/1 A，0℃下的悬臂梁式冲击强度大于6kJ / m 2。

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