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    • 6. 发明申请
    • PERMEABLE POLYMER FILM
    • 透明聚合物薄膜
    • WO2012076633A1
    • 2012-06-14
    • PCT/EP2011/072144
    • 2011-12-08
    • BASELL POLIOLEFINE ITALIA S.R.L.GRAZZI, MicheleFELISATI, AndreaPELLEGATTI, Giampaolo
    • GRAZZI, MicheleFELISATI, AndreaPELLEGATTI, Giampaolo
    • B32B27/32C08L23/14
    • B65D81/28B32B27/08B32B27/32B32B2270/00B32B2307/30B32B2307/732C08L23/142C08L2203/16Y10T428/31917C08L23/16
    • Films especially suitable for the packaging of fresh foodstuff, like salad and vegetables, due to their valuable balance of high permeability to oxygen and optimal permeability to water vapour, comprising at least one layer A) and at least one layer B), wherein the layer A) comprises a copolymer of propylene with hexene-1 containing from 3 to 9% by weight of recurring units derived from hexene-1, said copolymer having a melting temperature from 125°C to 143°C, and the layer B) comprises a polyolefin composition containing (all percentages being by weight): a) 10-40% of one or more propylene homopolymers or copolymers containing over 85% of propylene and having a fraction insoluble in xylene at room temperature greater than 80%; and b) 60-90 of one or more copolymers of ethylene with α-olefin(s), containing ethylene in a quantity from 20 to 80%, and having solubility in xylene at room temperature greater than 70%.
    • 由于其对氧的高渗透性和对水蒸气的最佳渗透性的有价​​值的平衡,包括至少一层A)和至少一层B),特别适用于新鲜食品(如沙拉和蔬菜)的包装的薄膜,其中层 A)包含丙烯与己烯-1的共聚物,其含有3至9重量%的衍生自己烯-1的重复单元,所述共聚物的熔融温度为125℃至143℃,并且B层包括 含有(所有百分比均为重量百分比)的聚烯烃组合物:a)10-40%的一种或多种丙烯均聚物或共聚物,其含有超过85%的丙烯并且在室温下不溶于二甲苯的级分大于80%; 和b)60-90的乙烯与α-烯烃的一种或多种共聚物,其含有量为20至80%的乙烯,并且在室温下在二甲苯中的溶解度大于70%。
    • 9. 发明申请
    • POLYMER COMPOSITION
    • 聚合物组合物
    • WO2010081753A1
    • 2010-07-22
    • PCT/EP2010/050015
    • 2010-01-04
    • BASELL POLIOLEFINE ITALIA S.R.L.PELLEGATTI, GiampaoloMICHELETTI, DavideMIHAN, ShahramFANTINELL, FabianaMANNEBACH, Gerd
    • PELLEGATTI, GiampaoloMICHELETTI, DavideMIHAN, ShahramFANTINELL, FabianaMANNEBACH, Gerd
    • C08L23/08C08L23/10
    • C08L23/08C08F110/06C08F210/16C08F297/08C08L23/0815C08L23/10C08L2666/02C08L2666/06C08F2500/15C08F2500/21C08F2500/12C08F210/08C08F2500/04C08F2500/17
    • A polypropylene composition comprising: A) from 30% to 90% by weight of a propylene polymer composition comprising: a1) from 20% to 90% of a propylene homopolymer, or a copoloymer of propylene containing 3% or less of derived units of ethylene or C 4 -C 10 α-olefin(s) or of combinations thereof, said homopolymer or copolymer having a content of isotactic pentads (mmmm), measured by 13 C NMR on the fraction insoluble in xylene at 25 °C, higher than 96; a2) from 10% to 80%, of a copolymer of ethylene containing from 40% to 70% of derived units of propylene or C 4 -C 10 α-olefin(s) or of combinations thereof; B) from 10% to 70% by weight of a multimodal ethylene copolymer wherein the comonomer is selected from the derived units of alpha olefins of formula CH 2 =CHT wherein T is a C 3 -C 10 alkyl group; having the following properties: i) density (with ISO 1183) comprised in the range from 0.850 to 0.935 g/cm 3 ; ii) total comonomer content ranging from 6% to 30% by weight; iii) content of 1-butene derived units ranging from 0 to 2% by weight; iv) Mw/Mn comprised from 4 to 20; v) intrinsic viscosity (decalin at 135°C as determined according to EN IS0 1628-312003) comprised between 1.0 and 4.0 dL/g, and C) from 0 to 50 % by weight; preferably from 0 to 20% of a filler.
    • 一种聚丙烯组合物,其包含:A)30重量%至90重量%的丙烯聚合物组合物,其包含:a1)20重量%至90重量%的丙烯均聚物,或含有3%或更少的衍生的乙烯单元的丙烯共聚物 或C 4 -C 10α-烯烃或其组合,所述均聚物或共聚物的含量为全同立构五单元组(mmmm),通过13 C NMR测量在25℃下不溶于二甲苯的级分,高于96; a2)10%至80%的含有40%至70%的衍生单元的丙烯或C 4 -C 10α-烯烃的乙烯的共聚物或其组合; B)10重量%至70重量%的多峰乙烯共聚物,其中共聚单体选自式CH 2 = CHT的α-烯烃的衍生单元,其中T是C 3 -C 10烷基; 具有以下特性:i)密度(ISO 1183),范围为0.850-0.935g / cm3; ii)总共聚单体含量为6重量%至30重量%; iii)1-丁烯衍生单元的含量为0-2重量%; iv)Mw / Mn为4〜20; v)特性粘度(根据EN IS 1628-312003确定的135℃下的萘烷)为1.0-4.0dL / g,C)为0至50重量% 优选0至20%的填料。