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1. 发明申请

WO2004000895A1 LIQUID PHASE PROCESS FOR THE POLYMERIZATION OF ALPHA-OLEFINS 审中-公开
标题翻译：用于ALPHA-OLEFINS聚合的液相过程
公开(公告)号：WO2004000895A1
公开(公告)日：2003-12-31
申请号：PCT/EP2003/006348
申请日：2003-06-17
申请人： BASELL POLIOLEFINE ITALIA S.P.A , BIGIAVI, Daniele , MEI, Gabriele , ARICH DE FINETTI, Nicolò , PENZO, Giuseppe , VITALE, Gianni , COVEZZI, Massimo
发明人： BIGIAVI, Daniele , MEI, Gabriele , ARICH DE FINETTI, Nicolò , PENZO, Giuseppe , VITALE, Gianni , COVEZZI, Massimo
IPC分类号： C08F10/08
CPC分类号： C08F110/08 , Y10S526/903 , C08F2/001 , C08F2/06 , C08F2/42 , C08F2500/12 , C08F2/01 , C08F2/00
摘要： A liquid-phase process for polymerizing α-olefins of the formula CH 2 =CHR, where R is H or an alkyl radical C1-C6, to produce a polymer that is soluble in the reaction medium, comprising the steps of: a) continuously polymerizing in liquid phase the α- olefin in the presence of a catalyst system based on a transition metal compound; b) continuously withdrawing from step a) a solution of polymer in the liquid reaction medium; c) mixing in one or more mixing stages said solution of polymer in the reaction medium with an organic deactivator having: at least a hydroxy group, a boiling point higher than 150°C, and a ratio between the molecular weight (MW) and the number of hydroxy groups (OH) comprised between 20 and 100.
摘要翻译：用于聚合式CH 2 = CHR的α-烯烃的液相方法，其中R是H或烷基C1-C6，以产生可溶于反应介质的聚合物，包括以下步骤：a）连续聚合在基于过渡金属化合物的催化剂体系存在下在液相中的α-烯烃; b）连续地从步骤a）中取出聚合物在液体反应介质中的溶液; c）在一个或多个混合阶段将所述聚合物在反应介质中的溶液与有机失活剂混合，所述有机失活剂具有至少羟基，沸点高于150℃，分子量（MW）和羟基（OH）的数目在20和100之间。

2. 发明申请

WO2004048424A1 BUTENE-1 COPOLYMERS AND PROCESS FOR THEIR PREPARATION 审中-公开
标题翻译： BUTENE-1共聚物及其制备方法
公开(公告)号：WO2004048424A1
公开(公告)日：2004-06-10
申请号：PCT/EP2003/012233
申请日：2003-11-03
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni , BIGIAVI, Daniele , PELLICONI, Anteo , GARAGNANI, Enea , BAITA, Pietro
发明人： MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni , BIGIAVI, Daniele , PELLICONI, Anteo , GARAGNANI, Enea , BAITA, Pietro
IPC分类号： C08F210/08
CPC分类号： C08L23/04 , C08F10/00 , C08F210/08 , C08L23/14 , C08L23/22 , C08L2666/06 , C08F4/651 , C08F4/6543 , C08F4/6465 , C08F210/06 , C08F2500/15 , C08F2500/03 , C08F2500/17 , C08F2500/11 , C08F2500/20 , C08F210/16 , C08F2/001
摘要： The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived characterized by the following properties: d) Product of the reactivity ratios rl·r2≤2; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.
摘要翻译：本发明涉及含有至多40摩尔％乙烯和/或丙烯的丁烯-1共聚物，其特征在于以下性质：d）反应性比率r r.r2 <= 2的产物; e）全同立构五元组（mmmm）形式的丁烯-1单元含量> 98％; 和f）不存在4,1个丁烯单元的插入。

3. 发明申请

WO2005095472A1 MAGNESIUM CHLORIDE-BASED ADDUCTS AND CATALYST COMPONENTS OBTAINED THEREFROM 审中-公开
标题翻译：基于氯化镁的添加剂和由其获得的催化剂组分
公开(公告)号：WO2005095472A1
公开(公告)日：2005-10-13
申请号：PCT/EP2005/002371
申请日：2005-03-03
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , GULEVICH, Yuri , CAMURATI, Isabella , CRISTOFORI, Antonio , DALL'OCCO, Tiziano , MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni
发明人： GULEVICH, Yuri , CAMURATI, Isabella , CRISTOFORI, Antonio , DALL'OCCO, Tiziano , MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni
IPC分类号： C08F110/06
CPC分类号： C07F3/003 , C07F7/006 , C08F110/06 , C08F4/651 , C08F4/6543 , C08F2500/15 , C08F2500/12 , C08F2500/17
摘要： Lewis base adducts comprising MgCl n (OR) 2-n , and an aprotic Lewis base that are in molar ratios to each other defined by the formula: MgCl n (OR) 2-n LB p in which n is from 0.1 to 1.9, p is higher than 0.4, and R is a C1-C15 hydrocarbon group. The adducts of the present invention are particularly useful as precursors of Ziegler-Natta catalyst components for the polymerization of olefins.
摘要翻译：包含MgCln（OR）2-n和非质子路易斯碱的路易斯碱加成物，其彼此的摩尔比以下式定义：MgCln（OR）2-nLBp，其中n为0.1至1.9，p高于 0.4，R为C1-C15烃基。本发明的加合物特别可用作烯烃聚合的齐格勒 - 纳塔催化剂组分的前体。

4. 发明申请

WO2003022894A1 COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：WO2003022894A1
公开(公告)日：2003-03-20
申请号：PCT/EP2002/010049
申请日：2002-09-04
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , MORINI, Giampiero , BALBONTIN, Giulio , GULEVICH, Yuri, V. , VITALE, Gianni
发明人： MORINI, Giampiero , BALBONTIN, Giulio , GULEVICH, Yuri, V. , VITALE, Gianni
IPC分类号： C08F10/00
CPC分类号： C08F4/651 , C08F110/06 , C08F2500/15
摘要： The present invention relates to a solid catalyst component for the polymerization of olefins CH 2 =CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from maleates of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.
摘要翻译：本发明涉及用于烯烃CH 2 = CHR的聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和选自马来酸酯的电子给体。当用于烯烃聚合，特别是丙烯时，所述催化剂组分能够以高产率和高二甲苯不溶性表现的高全同立构指数得到聚合物。

5. 发明申请

WO2003076480A1 PROCESS FOR PREPARING A DIETHER-BASED CATALYST COMPONENT 审中-公开
标题翻译：制备基于二氧化碳的催化剂组分的方法
公开(公告)号：WO2003076480A1
公开(公告)日：2003-09-18
申请号：PCT/EP2003/002148
申请日：2003-02-28
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , VITALE, Gianni , CIMARELLI, Massimo , MORINI, Giampiero , CABRINI, Leo
发明人： VITALE, Gianni , CIMARELLI, Massimo , MORINI, Giampiero , CABRINI, Leo
IPC分类号： C08F10/00
CPC分类号： C08F4/651 , C08F110/06 , C08F2500/12
摘要： A process for preparing a diether-based catalyst component in which: a) a slurry is obtained by contacting a solid support comprising a magnesium halide or a precursor thereof, one or more 1,3-diethers and a liquid phase containing a titanium compound, and b) the obtained slurry is then subjected to a solid/liquid separation step in order to isolate a diether-based catalyst component; said separation step b) being characterized in that the ratio between the solid/liquid separation velocity and the final amount of separated solid must be higher than 0.5 liter/(min.Kg).
摘要翻译：一种制备二醚类催化剂组分的方法，其中：a）通过使包含卤化镁或其前体的固体载体，一种或多种1,3-二醚和含有钛化合物的液相，和b）然后对所获得的浆料进行固/液分离步骤以分离二醚类催化剂组分; 所述分离步骤b）的特征在于固/液分离速度与分离固体的最终量之间的比率必须高于0.5升/（分·克）。

6. 发明申请

WO2004055065A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2004055065A1
公开(公告)日：2004-07-01
申请号：PCT/EP2003/013807
申请日：2003-11-25
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , BRITA, Diego , COLLINA, Gianni , MORINI, Giampiero , VITALE, Gianni
发明人： BRITA, Diego , COLLINA, Gianni , MORINI, Giampiero , VITALE, Gianni
IPC分类号： C08F4/651
CPC分类号： C08F10/00 , C08F110/06 , C08F210/16 , Y02P20/52 , C08F2500/18 , C08F4/6565 , C08F4/651 , C08F4/6555 , C08F4/6494 , C08F4/6543 , C08F210/14 , C08F2500/12
摘要： A catalyst component for olefin (co)polymerization, and in particular for the preparation of LLDPE, comprising Mg, Ti, halogen and an electron donor compound (ED) belonging to ethers, esters, amines, ketones, or nitriles, characterized in that the molar ratio Mg/Ti is higher than 5, and the molar ratio ED/Ti is higher than 3.5. The said catalyst components display a homogeneous distribution of the comonomer in and among the copolymer chains.
摘要翻译：用于烯烃（共）聚合，特别是用于制备LLDPE的催化剂组分，其包含Mg，Ti，卤素和属于醚，酯，胺，酮或腈的电子给体化合物（ED），其特征在于，摩尔比Mg / Ti高于5，ED / Ti摩尔比高于3.5。所述催化剂组分显示共聚物链中和共聚物链中共聚单体的均匀分布。

7. 发明申请

WO2004106388A2 PROCESS FOR THE PREPARATION OF A CATALYST COMPONENT AND COMPONENTS THEREFROM OBTAINED 审中-公开
标题翻译：制备催化剂组分和获得的组分的方法
公开(公告)号：WO2004106388A2
公开(公告)日：2004-12-09
申请号：PCT/EP2004/005186
申请日：2004-05-07
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , MORINI, Giampiero , DALL'OCCO, Tiziano , PIEMONTESI, Fabrizio , SPOTO, Rosa , VINCENZI, Paolo , VITALE, Gianni
发明人： MORINI, Giampiero , DALL'OCCO, Tiziano , PIEMONTESI, Fabrizio , SPOTO, Rosa , VINCENZI, Paolo , VITALE, Gianni
IPC分类号： C08F4/651
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6367 , C08F4/651 , C08F210/08 , C08F2500/12 , C08F4/6555 , C08F4/6492 , C08F4/6545 , C08F4/6565
摘要： A process for preparing a catalyst component, comprising a Mg compound a Ti compound and an electron donor compound (ED) selected from alcohol, glycols, esters, ketones, amines, amides, nitriles, alkoxysilanes and aliphatic ethers as essential compounds, comprising two or more steps of reaction involving the use of at least one of said essential compounds as fresh reactant alone or in a mixture in which it constitutes the main component, said process being characterized by the fact that in the last of said one or more reaction steps the essential compound used as a fresh reactant is the ED compound.
摘要翻译：一种制备催化剂组分的方法，包括Mg化合物，Ti化合物和选自醇，二醇，酯，酮，胺，酰胺，腈，烷氧基硅烷和脂族醚作为必需化合物的电子给体化合物（ED），包括两个或更多的反应步骤涉及使用至少一种所述必需化合物作为新鲜反应物或其构成主要组分的混合物，所述方法的特征在于在所述一个或多个反应步骤的最后一个步骤中，用作新鲜反应物的必需化合物是ED化合物。

8. 发明申请

WO2004085495A1 MAGNESIUM DICHLORIDE-ALCOHOL ADDUCTS AND CATALYST COMPONENTS OBTAINED THEREFROM 审中-公开
标题翻译：二氯化碳 - 醇溶液和催化剂组分
公开(公告)号：WO2004085495A1
公开(公告)日：2004-10-07
申请号：PCT/EP2004/002519
申请日：2004-03-09
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , MORINI, Giampiero , BALBONTIN, Giulio , PIEMONTESI, Fabrizio , FUSTO, Maria , VITALE, Gianni , PRINI, Giansiro
发明人： MORINI, Giampiero , BALBONTIN, Giulio , PIEMONTESI, Fabrizio , FUSTO, Maria , VITALE, Gianni , PRINI, Giansiro
IPC分类号： C08F4/02
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F4/6543 , C08F4/651 , C08F2500/12 , C08F4/65
摘要： The present invention relates to MgCl 2 .(EtOH), m (ROH) n (H 2 0) p adduct in which R is a Cl-C15 hydrocarbon group different from ethyl, n and m are indexes, higher than 0, satisfying the equations (n+m) ≥.7 and 0.05 ≤n/(n+m) ≤0.95 and p is a number ranging from 0 to 0.7 with the proviso that when R is methyl and (n+m) is in the range of 0.7 to 1, the value of n/(n+m) ranges from 0.05 to 0.45. The catalyst components obtained from the adducts of the present invention are capable to give catalysts for the polymerization of olefins characterized by enhanced activity with respect to the catalysts prepared from the adducts of the prior art.
摘要翻译：本发明涉及MgCl 2（EtOH），m（ROH）n（H 2 O）p加合物，其中R是不同于乙基的C 1 -C 15烃基，n和m是指数，高于0，满足等式（n + m）> = 7和0.05 <= n /（n + m）<= 0.95，p为0至0.7的数，条件是当R为甲基且（n + m）为 0.7〜1，n /（n + m）的值为0.05〜0.45。从本发明的加合物得到的催化剂组分能够产生用于烯烃聚合的催化剂，其特征在于相对于由现有技术的加合物制备的催化剂具有增强的活性。

9. 发明申请

WO2004024785A1 COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：WO2004024785A1
公开(公告)日：2004-03-25
申请号：PCT/EP2003/008593
申请日：2003-08-01
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , MORINI, Giampiero , BALBONTIN, Giulio , VITALE, Gianni
发明人： MORINI, Giampiero , BALBONTIN, Giulio , VITALE, Gianni
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651 , C08F4/6543 , C08F2500/08
摘要： The present invention relates to a solid catalyst component for the polymerization of olefins CH 2 =CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from succinates, said catalyst component being obtainable by a process comprising the following steps: (a) dissolving a halide of magnesium in a solvent system comprising an organic epoxy compound or an organic phosphorus compound and optionally an inert diluent to form a solution; (b) mixing the obtained solution with a titanium compound to form a mixture; (c) precipitating a solid from the mixture obtained in step (b) in the presence of a succinate and/or an auxiliary precipitant; (d) if a succinate is not used in step (c), contacting the solid obtained in (c) with a succinate, and (e) treating the solid obtained in (c) or (d) with a titanium compound optionally in the presence of an inert diluent.
摘要翻译：本发明涉及用于烯烃CH 2 = CHR聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和选自琥珀酸盐的电子给体，所述催化剂组分可通过包括以下步骤的方法获得：（a）将镁的卤化物溶解在包含有机环氧化合物或有机磷化合物和任选的惰性稀释剂的溶剂体系中以形成溶液; （b）将所得溶液与钛化合物混合以形成混合物; （c）在琥珀酸盐和/或辅助沉淀剂存在下从步骤（b）中获得的混合物中沉淀出固体; （d）如果在步骤（c）中不使用琥珀酸酯，则将（c）中得到的固体与琥珀酸酯接触，和（e）用钛化合物处理在（c）或（d）中获得的固体，存在惰性稀释剂。

10. 发明申请

WO2003099883A1 BUTENE-1 (CO)POLYMERS AND PROCESS FOR THEIR PREPARATION 审中-公开
标题翻译： BUTENE-1（CO）聚合物及其制备方法
公开(公告)号：WO2003099883A1
公开(公告)日：2003-12-04
申请号：PCT/EP2003/003593
申请日：2003-04-07
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , VITALE, Gianni , MORINI, Giampiero , CECCHIN, Giuliano
发明人： VITALE, Gianni , MORINI, Giampiero , CECCHIN, Giuliano
IPC分类号： C08F10/08
CPC分类号： C08F10/08 , C08F110/08 , C08F210/08 , C08F4/6465 , C08F4/6545 , C08F4/651 , C08F2500/15 , C08F2500/11 , C08F210/16 , C08F210/06 , C08F210/14
摘要： The present invention relates to butene-1 homopolymers, or copolymers containing up to 20 % by weight of alpha olefins having from 2 to 10 carbon atoms other than butene-1, characterized by the following properties: (i) a Molecular Weight Distribution (MWD) in terms of Mw/Mn, measured by GPC analysis according to the method specified, of lower than 6; and (ii) a melt strength (measured according to the method specified below) higher than 2.8.
摘要翻译：本发明涉及丁烯-1均聚物或含有至多20重量％的除丁烯-1以外具有2至10个碳原子的α-烯烃的共聚物，其特征在于以下性质：（i）分子量分布（MWD）），以通过根据所述方法的GPC分析测量的Mw / Mn小于6; 和（ii）高于2.8的熔体强度（根据下面指定的方法测量）。

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