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1. 发明申请

US20120253072A1 PROCESS FOR THE PREPARATION OF AROMATIC FORMAMIDES 失效
标题翻译：制备芳香霉素的方法
公开(公告)号：US20120253072A1
公开(公告)日：2012-10-04
申请号：US13513752
申请日：2010-12-01
申请人： Axel Franzke , Torsten Mattke , Julia Leschinski , Radwan Abdallah , Michael Bock , Robert Baumann , Eckhard Stroefer
发明人： Axel Franzke , Torsten Mattke , Julia Leschinski , Radwan Abdallah , Michael Bock , Robert Baumann , Eckhard Stroefer
IPC分类号： C07C231/02
CPC分类号： C07C231/02 , C07C233/03 , C07C233/43
摘要： The invention relates to a process for the preparation of formamides by reacting aromatic amines with a formic acid ester in the presence of a catalyst, wherein the catalyst is a phosphorus-containing acid or a Lewis-acidic metal salt.
摘要翻译：本发明涉及一种在催化剂存在下使芳族胺与甲酸酯反应制备甲酰胺的方法，其中催化剂是含磷酸或路易斯酸性金属盐。

2. 发明授权

US08680333B2 Process for the preparation of aromatic formamides 失效
标题翻译：制备芳族甲酰胺的方法
公开(公告)号：US08680333B2
公开(公告)日：2014-03-25
申请号：US13513752
申请日：2010-12-01
申请人： Axel Franzke , Torsten Mattke , Julia Leschinski , Radwan Abdallah , Michael Bock , Robert Baumann , Eckhard Stroefer
发明人： Axel Franzke , Torsten Mattke , Julia Leschinski , Radwan Abdallah , Michael Bock , Robert Baumann , Eckhard Stroefer
IPC分类号： C07C231/02 , C07C233/03
CPC分类号： C07C231/02 , C07C233/03 , C07C233/43
摘要： The invention relates to a process for the preparation of formamides by reacting aromatic amines with a formic acid ester in the presence of a catalyst, wherein the catalyst is a phosphorus-containing acid or a Lewis-acidic metal salt.
摘要翻译：本发明涉及一种在催化剂存在下使芳族胺与甲酸酯反应制备甲酰胺的方法，其中催化剂是含磷酸或路易斯酸性金属盐。

3. 发明申请

US20120253063A1 PROCESS FOR PREPARING ISOCYANATES 有权
标题翻译：制备异氰酸酯的方法
公开(公告)号：US20120253063A1
公开(公告)日：2012-10-04
申请号：US13513595
申请日：2010-12-03
申请人： Torsten Mattke , Eckhard Stroefer , Julia Leschinski , Radwan Abdallah , Axel Franzke , Michael Bock
发明人： Torsten Mattke , Eckhard Stroefer , Julia Leschinski , Radwan Abdallah , Axel Franzke , Michael Bock
IPC分类号： C07C263/00
CPC分类号： C07C263/04 , C07C265/12 , C07C265/14
摘要： Process for preparing aromatic isocyanates by reacting the corresponding formamides with an oxygen-comprising gas over noble metal catalysts at temperatures of from 300 to 600° C. and a contact time of from 1 to 1000 ms, wherein: a. the formamide is vaporized before entering the reaction zone, b. the reaction mixture obtained is quenched with an alcohol-comprising quenching liquid and c. the urethane formed is dissociated into isocyanate and alcohol.
摘要翻译：通过使贵金属催化剂上的相应的甲酰胺与含氧气体在300-600℃的温度和1至1000ms的接触时间下反应来制备芳族异氰酸酯的方法，其中：a。甲酰胺在进入反应区之前蒸发，b。得到的反应混合物用含醇的淬火液骤冷，c。所形成的聚氨酯被分解成异氰酸酯和醇。

4. 发明授权

US08835673B2 Process for preparing isocyanates 有权
标题翻译：异氰酸酯的制备方法
公开(公告)号：US08835673B2
公开(公告)日：2014-09-16
申请号：US13513595
申请日：2010-12-03
申请人： Torsten Mattke , Eckhard Stroefer , Julia Leschinski , Radwan Abdallah , Axel Franzke , Michael Bock
发明人： Torsten Mattke , Eckhard Stroefer , Julia Leschinski , Radwan Abdallah , Axel Franzke , Michael Bock
IPC分类号： C07C263/04
CPC分类号： C07C263/04 , C07C265/12 , C07C265/14
摘要： Process for preparing aromatic isocyanates by reacting the corresponding formamides with an oxygen-comprising gas over noble metal catalysts at temperatures of from 300 to 600° C. and a contact time of from 1 to 1000 ms, wherein: a. the formamide is vaporized before entering the reaction zone, b. the reaction mixture obtained is quenched with an alcohol-comprising quenching liquid and c. the urethane formed is dissociated into isocyanate and alcohol.
摘要翻译：通过使贵金属催化剂上的相应的甲酰胺与含氧气体在300-600℃的温度和1至1000ms的接触时间下反应来制备芳族异氰酸酯的方法，其中：a。甲酰胺在进入反应区之前蒸发，b。得到的反应混合物用含醇的淬火液骤冷，c。所形成的聚氨酯被分解成异氰酸酯和醇。

5. 发明申请

US20120245377A1 PROCESS FOR PREPARING ISOCYANATES BY THERMALLY CLEAVING CARBAMATES 有权
标题翻译：通过热清除碳酸钙制备异氰酸酯的方法
公开(公告)号：US20120245377A1
公开(公告)日：2012-09-27
申请号：US13513460
申请日：2010-11-30
申请人： Michael Bock , Eckhard Stroefer , Robert Baumann , Axel Franzke , Joachim Pfeffinger
发明人： Michael Bock , Eckhard Stroefer , Robert Baumann , Axel Franzke , Joachim Pfeffinger
IPC分类号： C07C263/04
CPC分类号： C07C263/04 , C07C265/14
摘要： A process is proposed for preparing isocyanates by thermally cleaving carbamates to obtain a carbamate cleavage gas comprising the corresponding isocyanate and the corresponding alcohol, which comprises quenching the carbamate cleavage gas in the presence of an ether which functions as an inhibitor for the reverse reaction of the isocyanate with the alcohol.
摘要翻译：提出了通过热裂解氨基甲酸酯制备异氰酸酯以获得包含相应的异氰酸酯和相应的醇的氨基甲酸酯裂解气体的方法，该方法包括在醚的存在下猝灭氨基甲酸酯裂解气体，该醚用作反应的反应的抑制剂异氰酸酯与醇。

6. 发明授权

US08822718B2 Process for preparing isocyanates by thermally cleaving carbamates 有权
标题翻译：通过热裂解氨基甲酸酯制备异氰酸酯的方法
公开(公告)号：US08822718B2
公开(公告)日：2014-09-02
申请号：US13513460
申请日：2010-11-30
申请人： Michael Bock , Eckhard Stroefer , Robert Baumann , Axel Franzke , Joachim Pfeffinger
发明人： Michael Bock , Eckhard Stroefer , Robert Baumann , Axel Franzke , Joachim Pfeffinger
IPC分类号： C07C263/04
CPC分类号： C07C263/04 , C07C265/14
摘要： A process is proposed for preparing isocyanates by thermally cleaving carbamates to obtain a carbamate cleavage gas comprising the corresponding isocyanate and the corresponding alcohol, which comprises quenching the carbamate cleavage gas in the presence of an ether which functions as an inhibitor for the reverse reaction of the isocyanate with the alcohol.
摘要翻译：提出了通过热裂解氨基甲酸酯制备异氰酸酯以获得包含相应的异氰酸酯和相应的醇的氨基甲酸酯裂解气体的方法，该方法包括在醚的存在下猝灭氨基甲酸酯裂解气体，该醚用作反应的反应的抑制剂异氰酸酯与醇。

7. 发明授权

US09000213B2 Process for coproducing di- and/or polyisocyanates and glycols 有权
标题翻译：共聚产生二 - 和/或多异氰酸酯和二醇的方法
公开(公告)号：US09000213B2
公开(公告)日：2015-04-07
申请号：US13502763
申请日：2010-10-27
申请人： Michael Bock , Robert Baumann , Axel Franzke , Eckhard Stroefer , Gerhard Theis
发明人： Michael Bock , Robert Baumann , Axel Franzke , Eckhard Stroefer , Gerhard Theis
IPC分类号： C07C263/04 , C07C29/12 , C07C29/128 , C07C68/06
CPC分类号： C07C263/04 , C07C29/12 , C07C29/128 , C07C68/065 , C07C2601/14 , C07C69/96 , C07C265/12 , C07C265/14 , C07C31/202
摘要： A process for coproducing di- and/or polyisocyanates and glycols, comprising process stages A, B, C and E for preparing glycols and process stages A, C, D, E, F and G for preparing di- and/or polyisocyanates,which comprises accomplishing the material coupling via the separation of the reaction mixture obtained in process stage A into process stages B and C, by in process stage A, reacting an aqueous alkylene oxide with carbon dioxide to give a reaction mixture comprising alkylene carbonate, hydrolyzing a portion of the alkylene carbonate-comprising reaction mixture obtained in process stage A to glycol in process stage B, dewatering the remaining alkylene carbonate-comprising stream of the reaction mixture from process stage A in process stage C, in process stage D, synthesizing amine by hydrogenating an aromatic nitro compound or a nitrile, in process stage E, transesterifying the dewatered alkylene carbonate-comprising mixture from process stage C with a monohydroxy alcohol to give the corresponding dialkyl carbonate, obtaining glycol as a coproduct, in process stage F, reacting the dialkyl carbonate-comprising reaction mixture obtained in process stage E with the amine obtained in process stage D to a mixture comprising the corresponding mono-, di- and/or polycarbamate, which in process stage G is cleaved to obtain the corresponding di- and/or polyisocyanate.
摘要翻译：用于共混生产二 - 和/或多异氰酸酯和二醇的方法，包括制备二元醇和工艺阶段A，C，D，E，F和G的制备二 - 和/或多异氰酸酯的工艺阶段A，B，C和E，包括通过在工艺阶段A中将经处理阶段A获得的反应混合物分离成工艺阶段B和C来实现材料偶联，使环氧烷水溶液与二氧化碳反应，得到包含碳酸亚烷基酯的反应混合物，水解部分在工艺阶段B中获得的含碳酸亚烷基酯的反应混合物在工艺阶段B中与二醇的混合物，在工艺阶段D中将来自反应混合物的剩余的含有碳酸亚烃的物流从工艺阶段C脱水，通过氢化合成胺芳香族硝基化合物或腈，在工艺阶段E中，将来自工艺阶段C的脱水的含碳酸亚烷基酯混合物与单羟基醇酯交换，得到相应的碳酸二烷基酯，在工艺阶段F中获得二醇作为副产物，将在工艺阶段E中获得的含碳酸二烷基酯的反应混合物与在工艺阶段D中获得的胺反应到包含相应的单 - ，二 - 和/ 或聚氨酯，其在工艺阶段G被切割以获得相应的二 - 和/或多异氰酸酯。

8. 发明授权

US08680323B2 Process for preparing isocyanates by thermal dissociation of carbamates 失效
标题翻译：通过氨基甲酸酯的热解制备异氰酸酯的方法
公开(公告)号：US08680323B2
公开(公告)日：2014-03-25
申请号：US13008457
申请日：2011-01-18
申请人： Michael Bock , Axel Franzke , Robert Baumann , Eckhard Stroefer
发明人： Michael Bock , Axel Franzke , Robert Baumann , Eckhard Stroefer
IPC分类号： C07C263/04
CPC分类号： C07C263/04 , C07C265/14
摘要： The invention relates to a process for preparing isocyanates by thermal dissociation of carbamates and separation by distillation of the reaction mixture from the carbamate dissociation, comprising the corresponding isocyanate and the corresponding alcohol, by distillation in a column (K) having an enrichment section (V) and a stripping section (A), where the carbamate (1) is introduced between the enrichment section (V) and the stripping section (A) and the isocyanate is taken off as a constituent of the bottom stream (2) and the alcohol is taken off as a constituent of the overhead stream (3) from the column (K), in the presence of an inert solvent, wherein an intermediate boiler having a boiling point between the boiling point of the isocyanate and the boiling point of the alcohol under the operating conditions of the carbamate dissociation is used as inert solvent and is fed as external runback (4) in liquid form in a purity of >95% by weight, based on the total weight of the external runback (4), in the upper region of the enrichment section (V) and as gaseous, superheated stream (5) into the lower region of stripping section (A) at one or more points.
摘要翻译：本发明涉及一种通过氨基甲酸酯的热解解制备异氰酸酯的方法，并且通过在具有富集部分（V）的塔（K）中蒸馏，将反应混合物从氨基甲酸酯解离（包括相应的异氰酸酯和相应的醇）中蒸馏分离）和汽提段（A），其中将氨基甲酸酯（1）引入富集部分（V）和汽提部分（A）之间，异氰酸酯作为底部流（2）的组分和醇在惰性溶剂的存在下从柱（K）中作为塔顶馏出物（3）的组分脱去，其中沸点介于异氰酸酯的沸点和醇的沸点之间的中间锅炉在氨基甲酸酯解离的操作条件下，将其作为惰性溶剂使用，并作为外部回流（4）以> 95％重量的液体形式供给，基于外加剂的总重量（4），在富集部分（V）的上部区域和作为气体的过热流（5）在一个或多个点处进入汽提段（A）的下部区域。

9. 发明申请

US20120209024A1 PROCESS FOR COPRODUCING DI- AND/OR POLYISOCYANATES AND GLYCOLS 有权
标题翻译：用于制备二 - 和/或多烯酸酯和甘油的方法
公开(公告)号：US20120209024A1
公开(公告)日：2012-08-16
申请号：US13502763
申请日：2010-10-27
申请人： Michael Bock , Robert Baumann , Axel Franzke , Eckhard Stroefer , Gerhard Theis
发明人： Michael Bock , Robert Baumann , Axel Franzke , Eckhard Stroefer , Gerhard Theis
IPC分类号： C07C263/04
CPC分类号： C07C263/04 , C07C29/12 , C07C29/128 , C07C68/065 , C07C2601/14 , C07C69/96 , C07C265/12 , C07C265/14 , C07C31/202
摘要： A process for coproducing di- and/or polyisocyanates and glycols, comprising process stages A, B, C and E for preparing glycols and process stages A, C, D, E, F and G for preparing di- and/or polyisocyanates,which comprises accomplishing the material coupling via the separation of the reaction mixture obtained in process stage A into process stages B and C, by in process stage A, reacting an aqueous alkylene oxide with carbon dioxide to give a reaction mixture comprising alkylene carbonate, hydrolyzing a portion of the alkylene carbonate-comprising reaction mixture obtained in process stage A to glycol in process stage B, dewatering the remaining alkylene carbonate-comprising stream of the reaction mixture from process stage A in process stage C, in process stage D, synthesizing amine by hydrogenating an aromatic nitro compound or a nitrile, in process stage E, transesterifying the dewatered alkylene carbonate-comprising mixture from process stage C with a monohydroxy alcohol to give the corresponding dialkyl carbonate, obtaining glycol as a coproduct, in process stage F, reacting the dialkyl carbonate-comprising reaction mixture obtained in process stage E with the amine obtained in process stage D to a mixture comprising the corresponding mono-, di- and/or polycarbamate, which in process stage G is cleaved to obtain the corresponding di- and/or polyisocyanate.
摘要翻译：共聚产生二 - 和/或多异氰酸酯和二醇的方法，包括用于制备二元醇和工艺步骤A，C，D，E，F和G的制备二 - 和/或多异氰酸酯的方法阶段A，B，C和E，包括通过在工艺阶段A中将经处理阶段A获得的反应混合物分离成工艺阶段B和C来实现材料偶联，使环氧烷水溶液与二氧化碳反应，得到包含碳酸亚烷基酯的反应混合物，水解部分在工艺阶段B中获得的含碳酸亚烷基酯的反应混合物在工艺阶段B中与二醇的混合物，在工艺阶段D中将来自反应混合物的剩余的含有碳酸亚烃的物流从工艺阶段C脱水，通过氢化合成胺芳香族硝基化合物或腈，在工艺阶段E中，将来自工艺阶段C的脱水的含碳酸亚烷基酯混合物与单羟基醇酯交换，得到相应的碳酸二烷基酯，在工艺阶段F中获得二醇作为副产物，将在工艺阶段E中获得的含碳酸二烷基酯的反应混合物与在工艺阶段D中获得的胺反应到包含相应的单 - ，二 - 和/ 或聚氨酯，其在工艺阶段G被切割以获得相应的二 - 和/或多异氰酸酯。

10. 发明申请

US20130144080A1 PROCESS FOR OBTAINING A DIALKYL CARBONATE AND AN ALKYLENE GLYCOL 审中-公开
标题翻译：获得碳酸二乙酯和烷基甘氨酸的方法
公开(公告)号：US20130144080A1
公开(公告)日：2013-06-06
申请号：US13693281
申请日：2012-12-04
申请人： Andrea SCHMIDT , Michael Bock , Roderich Roettger , Robert Baumann , Axel Franzke
发明人： Andrea SCHMIDT , Michael Bock , Roderich Roettger , Robert Baumann , Axel Franzke
IPC分类号： C07C68/08 , C07C29/82
CPC分类号： C07C68/08 , C07C29/82 , Y02P20/127 , Y02P20/582 , C07C69/96 , C07C31/202
摘要： The invention relates to a process for obtaining a dialkyl carbonate and an alkylene glycol from a stream comprising dialkyl carbonate, alkylene carbonate, alkylene glycol and alcohol, comprising the following steps: (a) distillatively removing a stream (5) comprising dialkyl carbonate and alkylene glycol as a heteroazeotrope from the stream comprising dialkyl carbonate, alkylene carbonate, alkylene glycol and alcohol in a first distillation stage (1), (b) separating the stream (5) comprising dialkyl carbonate and alkylene glycol as a heteroazeotrope into a first crude product stream (27) comprising essentially di-alkyl carbonate and a second crude product stream (29) comprising essentially alkylene glycol in an apparatus for phase separation (25).
摘要翻译：本发明涉及从包含碳酸二烷基酯，亚烷基碳酸酯，亚烷基二醇和醇的物流中获得碳酸二烷基酯和亚烷基二醇的方法，包括以下步骤：（a）蒸馏除去包含碳酸二烷基酯和亚烷基在第一蒸馏阶段（1）中，将包含碳酸二烷基酯，亚烷基碳酸酯，亚烷基二醇和醇的物流作为杂化物二醇，（b）将包含碳酸二烷基酯和亚烷基二醇的物流（5）分离成第一粗产物包含基本上二烷基碳酸酯的流（27）和在用于相分离的装置（25）中基本上包含亚烷基二醇的第二粗产物流（29）。

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