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    • 7. 发明授权
    • Golf ball
    • 高尔夫球
    • US07534835B2
    • 2009-05-19
    • US11336790
    • 2006-01-23
    • Jun ShindoAtsushi Nanba
    • Jun ShindoAtsushi Nanba
    • A63B37/06A63B37/00C08L9/00
    • A63B37/0003A63B37/0054A63B2209/00C08F8/44
    • A golf ball is composed at least in part of a material molded under heat from a rubber composition which includes: (a) a base rubber composed primarily of a mixture of at least 60 wt % of a polybutadiene having a stress relaxation time (T80), defined as the length of time it takes from the moment when rotor rotation is stopped immediately after measurement of the ML1+4 (100° C.) value (the Mooney viscosity measured at 100° C. in accordance with ASTM D-1646-96) for the ML1+4 value to decrease 80%, of less than 4 seconds with up to 40 wt % of a polybutadiene having a stress relaxation time (T80) of at least 4 seconds; (b) an unsaturated carboxylic acid and/or a metal salt thereof; and (c) an organic peroxide. The golf ball has an excellent manufacturability and rebound.
    • 高尔夫球至少部分由在橡胶组合物的加热下成型的材料组成,该橡胶组合物包括:(a)主要由至少60重量%的具有应力松弛时间(T80)的聚丁二烯的混合物组成的基础橡胶, ,定义为在ML1 + 4(100℃)值测量之后立即停止转子转动时的时间长度(根据ASTM D-1646-)测定的100℃下的门尼粘度, 96)对于ML1 + 4值降低80%,小于4秒,高达40重量%的具有应力松弛时间(T80)的聚丁二烯至少为4秒; (b)不饱和羧酸和/或其金属盐; 和(c)有机过氧化物。 高尔夫球具有很好的可制造性和反弹性。
    • 10. 发明授权
    • Molded rubber material for golf ball, method of producing the material, and golf ball
    • 用于高尔夫球的模制橡胶材料,该材料的生产方法和高尔夫球
    • US07530905B2
    • 2009-05-12
    • US11360428
    • 2006-02-24
    • Jun ShindoAtsushi Nanba
    • Jun ShindoAtsushi Nanba
    • A63B37/00
    • C08J3/226A63B37/0051A63B37/0062A63B45/00C08J2309/00C08J2409/00
    • The invention provides a molded rubber material for a golf ball which is obtained by molding and vulcanizing a rubber composition that includes a portion of a master batch prepared by mixing together a synthetic rubber, an unsaturated carboxylic acid metal salt and a higher fatty acid or metal salt thereof, and includes also a diene rubber and an organic peroxide, wherein the master batch is prepared at a maximum temperature attained during preparation of above 110° C. Also disclosed are a method of producing such a molded rubber material, and a golf ball in which such a molded rubber material is used as a component of the ball. Use of the molded rubber material as a golf ball core enables a good core hardness under load and a good core resilience to be achieved.
    • 本发明提供了一种用于高尔夫球的模制橡胶材料,其通过模制和硫化橡胶组合物获得,所述橡胶组合物包括通过将合成橡胶,不饱和羧酸金属盐和高级脂肪酸或金属 并且还包括二烯橡胶和有机过氧化物,其中母料在制备高于110℃时达到的最高温度下制备。还公开了制备这种模制橡胶材料的方法,以及高尔夫球 其中使用这种模制橡胶材料作为球的组分。 使用模制橡胶材料作为高尔夫球芯能够实现在负载下的良好的芯硬度和良好的芯回弹性。