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1. 发明授权

US08597829B2 Nonaqueous electrolyte secondary battery with rolled electrode assembly 有权
标题翻译：具有卷绕电极组件的非水电解质二次电池
公开(公告)号：US08597829B2
公开(公告)日：2013-12-03
申请号：US12702346
申请日：2010-02-09
申请人： Atsushi Kaiduka , Masanori Ogi , Yukihiro Oki , Masato Iwanaga
发明人： Atsushi Kaiduka , Masanori Ogi , Yukihiro Oki , Masato Iwanaga
IPC分类号： H01M2/02 , H01M6/10
CPC分类号： H01M10/0431 , H01M2/022 , H01M2/1673 , H01M2/168 , Y10T29/49108 , Y10T29/49114
摘要： The nonaqueous electrolyte secondary battery includes a rolled electrode assembly 14E formed by rolling a positive electrode plate 11 and a negative electrode plate 12 with a separator 13 interposed therebetween, the separator 13 is fixed on the outermost periphery of the rolled electrode assembly 14E with an adhesive tape for fixing a roll end 30e, an exposed portion of a negative electrode substrate 12c without an active material mixture layer 12b is placed on an outermost periphery side of the negative electrode plate 12, a negative electrode tab 12a is connected to the negative electrode substrate 12c on an outermost periphery side, and the adhesive tape 30e is not overlapped with a roll end 11d of the positive electrode plate 11 and a roll end 12d of the negative electrode substrate 12c. Thus the battery is seldom broken even when charging and discharging are repeatedly provided at high voltage.
摘要翻译：非水电解质二次电池包括通过将隔板13插入其间的正极板11和负极板12进行轧制而形成的卷绕电极组件14E，隔板13用粘合剂固定在卷绕电极组件14E的最外周上用于固定辊端30e的带，没有活性物质混合层12b的负电极基板12c的露出部分放置在负极板12的最外周侧，负电极接线片12a连接到负电极基板 12c，并且粘合带30e不与正极板11的辊端部11d和负极基板12c的辊端部12d重叠。因此，即使在高电压下重复提供充电和放电时，电池也很少损坏。

2. 发明申请

US20100233525A1 NONAQUEOUS ELECTROLYTE SECONDARY BATTERY 有权
标题翻译：非电解电解质二次电池
公开(公告)号：US20100233525A1
公开(公告)日：2010-09-16
申请号：US12702346
申请日：2010-02-09
申请人： Atsushi Kaiduka , Masanori Ogi , Yukihiro Oki , Masato Iwanaga
发明人： Atsushi Kaiduka , Masanori Ogi , Yukihiro Oki , Masato Iwanaga
IPC分类号： H01M2/02
CPC分类号： H01M10/0431 , H01M2/022 , H01M2/1673 , H01M2/168 , Y10T29/49108 , Y10T29/49114
摘要： The nonaqueous electrolyte secondary battery includes a rolled electrode assembly 14E formed by rolling a positive electrode plate 11 and a negative electrode plate 12 with a separator 13 interposed therebetween, the separator 13 is fixed on the outermost periphery of the rolled electrode assembly 14E with an adhesive tape for fixing a roll end 30e, an exposed portion of a negative electrode substrate 12c without an active material mixture layer 12b is placed on an outermost periphery side of the negative electrode plate 12, a negative electrode tab 12a is connected to the negative electrode substrate 12c on an outermost periphery side, and the adhesive tape 30e is not overlapped with a roll end 11d of the positive electrode plate 11 and a roll end 12d of the negative electrode substrate 12c. Thus the battery is seldom broken even when charging and discharging are repeatedly provided at high voltage.
摘要翻译：非水电解质二次电池包括通过将隔板13插入其间的正极板11和负极板12进行轧制而形成的卷绕电极组件14E，隔板13用粘合剂固定在卷绕电极组件14E的最外周上用于固定辊端30e的带，没有活性物质混合层12b的负电极基板12c的露出部分放置在负极板12的最外周侧，负电极接线片12a连接到负电极基板 12c，并且粘合带30e不与正极板11的辊端部11d和负极基板12c的辊端部12d重叠。因此，即使在高电压下重复提供充电和放电时，电池也很少损坏。

3. 发明申请

US20080241694A1 NON-AQUEOUS ELECTROLYTE SECONDARY CELL 失效
标题翻译：非水溶性电解质二次电池
公开(公告)号：US20080241694A1
公开(公告)日：2008-10-02
申请号：US12059196
申请日：2008-03-31
申请人： Atsushi Kaiduka , Masato Iwanaga , Yukihiro Oki
发明人： Atsushi Kaiduka , Masato Iwanaga , Yukihiro Oki
IPC分类号： H01M4/52
CPC分类号： H01M4/485 , H01M2/1653 , H01M4/525 , H01M4/5825 , H01M10/052 , H01M2010/4292
摘要： A non-aqueous electrolyte secondary cell superior in resistance against continuous charging at high potential is provided. The non-aqueous electrolyte secondary cell includes: a positive electrode having lithium phosphate and a positive electrode active material comprising lithium cobalt oxide containing at least one selected from Mg, Al, Ti, and Zr; and a separator having pores having an average diameter of 0.05 to 0.2 μm.
摘要翻译：提供了在高电位下耐连续充电性优异的非水电解质二次电池。非水电解质二次电池包括：具有磷酸锂的正极和包含选自Mg，Al，Ti和Zr中的至少一种的含有钴酸锂的正极活性物质; 以及具有平均直径为0.05〜0.2μm的孔的隔膜。

4. 发明授权

US08021786B2 Non-aqueous electrolyte secondary cell 失效
标题翻译：非水电解质二次电池
公开(公告)号：US08021786B2
公开(公告)日：2011-09-20
申请号：US12059196
申请日：2008-03-31
申请人： Atsushi Kaiduka , Masato Iwanaga , Yukihiro Oki
发明人： Atsushi Kaiduka , Masato Iwanaga , Yukihiro Oki
IPC分类号： H01M4/48
CPC分类号： H01M4/485 , H01M2/1653 , H01M4/525 , H01M4/5825 , H01M10/052 , H01M2010/4292
摘要： A non-aqueous electrolyte secondary cell superior in resistance against continuous charging at high potential is provided. The non-aqueous electrolyte secondary cell includes: a positive electrode having lithium phosphate and a positive electrode active material comprising lithium cobalt oxide containing at least one selected from Mg, Al, Ti, and Zr; and a separator having pores having an average diameter of 0.05 to 0.2 μm.
摘要翻译：提供了在高电位下耐连续充电性优异的非水电解质二次电池。非水电解质二次电池包括：具有磷酸锂的正极和包含选自Mg，Al，Ti和Zr中的至少一种的含有钴酸锂的正极活性物质; 以及具有平均直径为0.05〜0.2μm的孔的隔膜。

5. 发明授权

US08026000B2 Nonaqueous electrolyte secondary battery, nonaqueous electrolyte, and charging method therefor 有权
标题翻译：非水电解质二次电池，非水电解质及其充电方法
公开(公告)号：US08026000B2
公开(公告)日：2011-09-27
申请号：US11656486
申请日：2007-01-23
申请人： Masato Iwanaga , Yukihiro Oki , Koji Abe , Kazuhiro Miyoshi
发明人： Masato Iwanaga , Yukihiro Oki , Koji Abe , Kazuhiro Miyoshi
IPC分类号： H01M6/04
CPC分类号： H01M10/0567 , H01M4/131 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/0569 , H01M2300/004
摘要： A nonaqueous electrolyte secondary battery of the invention has a positive electrode having a positive electrode active material, a negative electrode, and a nonaqueous electrolyte having electrolyte salt in a nonaqueous solvent. The electric potential of the positive electrode active material is 4.4 to 4.6 V relative to lithium, and the nonaqueous electrolyte contains a compound expressed by structural formula (I) below. The quantity of compound added is preferably 0.1% to 2% by mass. Also, the positive electrode active material preferably comprises a mixture of a lithium-cobalt composite oxide which is LiCoO2 containing at least both zirconium and magnesium and a lithium-manganese-nickel composite oxide that has a layer structure and contains at least both manganese and nickel. Thanks to such structure, a nonaqueous electrolyte secondary battery can be provided that is charged to charging termination potential of 4.4 to 4.6 V relative to lithium and that has enhanced overcharging safety.[Chemical Formula 1]
摘要翻译：本发明的非水电解质二次电池具有正极，具有正极活性物质，负极和非水电解质，在非水溶剂中具有电解质盐。正极活性物质的电位相对于锂为4.4〜4.6V，非水电解质含有下述结构式（I）表示的化合物。化合物的添加量优选为0.1质量％〜2质量％。此外，正极活性物质优选包含锂 - 钴复合氧化物的混合物，其为至少含有锆和镁的两种LiCoO 2和具有层结构并且至少包含锰和镍两者的锂锰镍复合氧化物的混合物。由于这样的结构，可以提供非水电解质二次电池，其相对于锂充电至4.4至4.6V的充电终止电位，并且具有增强的过充电安全性。 [化学式1]

6. 发明申请

US20070172730A1 Nonaqueous electrolyte secondary battery, nonaqueous electrolyte, and charging method therefor 有权
标题翻译：非水电解质二次电池，非水电解质及其充电方法
公开(公告)号：US20070172730A1
公开(公告)日：2007-07-26
申请号：US11656486
申请日：2007-01-23
申请人： Masato Iwanaga , Yukihiro Oki , Koji Abe , Kazuhiro Miyoshi
发明人： Masato Iwanaga , Yukihiro Oki , Koji Abe , Kazuhiro Miyoshi
IPC分类号： H01M10/40 , H01M4/50 , H01M4/52
CPC分类号： H01M10/0567 , H01M4/131 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/0569 , H01M2300/004
摘要： A nonaqueous electrolyte secondary battery of the invention has a positive electrode having a positive electrode active material, a negative electrode, and a nonaqueous electrolyte having electrolyte salt in a nonaqueous solvent. The electric potential of the positive electrode active material is 4.4 to 4.6 V relative to lithium, and the nonaqueous electrolyte contains a compound expressed by structural formula (I) below. The quantity of compound added is preferably 0.1% to 2% by mass. Also, the positive electrode active material preferably comprises a mixture of a lithium-cobalt composite oxide which is LiCoO2 containing at least both zirconium and magnesium and a lithium-manganese-nickel composite oxide that has a layer structure and contains at least both manganese and nickel. Thanks to such structure, a nonaqueous electrolyte secondary battery can be provided that is charged to charging termination potential of 4.4 to 4.6 V relative to lithium and that has enhanced overcharging safety.[Chemical Formula 1]
摘要翻译：本发明的非水电解质二次电池具有正极，具有正极活性物质，负极和非水电解质，在非水溶剂中具有电解质盐。正极活性物质的电位相对于锂为4.4〜4.6V，非水电解质含有下述结构式（I）表示的化合物。化合物的添加量优选为0.1质量％〜2质量％。此外，正极活性物质优选含有至少含有锆和镁两者的LiCoO 2 2的锂 - 钴复合氧化物和具有层结构的锂 - 锰 - 镍复合氧化物的混合物并且至少含有锰和镍。由于这样的结构，可以提供非水电解质二次电池，其相对于锂充电至4.4至4.6V的充电终止电位，并且具有增强的过充电安全性。 [化学式1]

7. 发明申请

US20120231344A1 NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 审中-公开
标题翻译：非水电解质二次电池
公开(公告)号：US20120231344A1
公开(公告)日：2012-09-13
申请号：US13512431
申请日：2010-11-29
申请人： Koji Okushi , Yukihiro Oki , Masato Iwanaga
发明人： Koji Okushi , Yukihiro Oki , Masato Iwanaga
IPC分类号： H01M4/13 , H01M4/583 , H01M4/48
CPC分类号： H01M2/18 , H01M4/13 , H01M4/366 , H01M10/052 , Y02T10/7011
摘要： The present invention provides a nonaqueous electrolyte secondary battery that can be charged at high voltage and suppress capacity deterioration after charged storage in a high temperature environment.A nonaqueous electrolyte secondary battery 10 includes a positive electrode sheet 11, a negative electrode sheet 12, a nonaqueous electrolyte, and a separator 13, and the positive electrode active material has a potential of 4.35 to 4.60 V based on lithium. The positive electrode sheet 11 has a surface provided with an inorganic particle layer. The separator 13 has an average pore size of 0.15 μm or more and 0.3 μm or less. It is preferable that the inorganic particle layer provided to the surface of the positive electrode sheet 11 contain titanium oxide or aluminum oxide.
摘要翻译：本发明提供一种可在高电压下充电并抑制在高温环境下充电保存后的容量劣化的非水电解质二次电池。非水电解质二次电池10包括正极片11，负极片12，非水电解质和隔膜13，正极活性物质的电位为锂的4.35〜4.60V。正极片11具有设置无机粒子层的面。隔板13的平均孔径为0.15μm以上且0.3μm以下。设置在正极片11的表面的无机粒子层优选含有氧化钛或氧化铝。

8. 发明授权

US08021787B2 High-voltage charge type nonaqueous electrolyte secondary cell 有权
标题翻译：高压充电型非水电解质二次电池
公开(公告)号：US08021787B2
公开(公告)日：2011-09-20
申请号：US12302713
申请日：2007-05-30
申请人： Masato Iwanaga , Kentaro Takahashi , Yukihiro Oki , Yoshihiko Ikeda , Akira Kinoshita , Nobumichi Nishida
发明人： Masato Iwanaga , Kentaro Takahashi , Yukihiro Oki , Yoshihiko Ikeda , Akira Kinoshita , Nobumichi Nishida
IPC分类号： H01M4/58
CPC分类号： H01M10/052 , H01M4/131 , H01M4/136 , H01M4/485 , H01M4/525 , H01M4/5825 , H01M10/0567 , H01M2004/021 , H01M2010/4292
摘要： The preservation performance of a nonaqueous electrolyte secondary cell charged to high potential is improved while the initial capacity and the cycle property of the cell are also improved. The nonaqueous electrolyte secondary cell includes: a positive electrode having lithium phosphate and a positive electrode active material containing lithium cobalt compound oxide and lithium manganese nickel compound oxide having a layer structure, the lithium cobalt compound oxide having at least zirconium and magnesium added in LiCoO2; a negative electrode having a negative electrode active material; and a nonaqueous electrolyte having a nonaqueous solvent and an electrolytic salt. The potential of the positive electrode is more than 4.3 V and 5.1 V or less based on lithium. The nonaqueous electrolyte contains vinylene carbonate as the nonaqueous solvent and, as the electrolytic salt, at least one of lithium bis(pentafluoroethane sulfonyl)imide and lithium bis(trifluoromethane sulfonyl)imide at 0.1 M or more and 0.5 M or less. The nonaqueous electrolyte contains 1,3-dioxane.
摘要翻译：提高了充电至高电位的非水电解质二次电池的保存性能，同时电池的初始容量和循环特性也得到改善。非水电解质二次电池包括：具有磷酸锂的正极和含有钴酸钴复合氧化物的正极活性物质和具有层结构的锂锰镍复合氧化物，所述锂钴复合氧化物在LiCoO 2中加入至少锆和镁; 具有负极活性物质的负极; 和具有非水溶剂和电解质盐的非水电解质。基于锂，正极的电位大于4.3V且为5.1V以下。非水电解质含有碳酸亚乙烯酯作为非水溶剂，作为电解质盐，为0.1M以上且0.5M以下的双（五氟乙烷磺酰基）亚胺锂和双（三氟甲磺酰基）亚胺锂中的至少一种。非水电解质含有1,3-二恶烷。

9. 发明申请

US20090181311A1 HIGH-VOLTAGE CHARGE TYPE NONAQUEOUS ELECTROLYTE SECONDARY CELL 有权
标题翻译：高电压充电型非电解电解质二次电池
公开(公告)号：US20090181311A1
公开(公告)日：2009-07-16
申请号：US12302713
申请日：2007-05-30
申请人： Masato Iwanaga , Kentaro Takahashi , Yukihiro Oki , Yoshihiko Ikeda , Akira Kinoshita , Nobumichi Nishida
发明人： Masato Iwanaga , Kentaro Takahashi , Yukihiro Oki , Yoshihiko Ikeda , Akira Kinoshita , Nobumichi Nishida
IPC分类号： H01M6/16
CPC分类号： H01M10/052 , H01M4/131 , H01M4/136 , H01M4/485 , H01M4/525 , H01M4/5825 , H01M10/0567 , H01M2004/021 , H01M2010/4292
摘要： The preservation performance of a nonaqueous electrolyte secondary cell charged to high potential is improved while the initial capacity and the cycle property of the cell are also improved. The nonaqueous electrolyte secondary cell includes: a positive electrode having lithium phosphate and a positive electrode active material containing lithium cobalt compound oxide and lithium manganese nickel compound oxide having a layer structure, the lithium cobalt compound oxide having at least zirconium and magnesium added in LiCoO2; a negative electrode having a negative electrode active material; and a nonaqueous electrolyte having a nonaqueous solvent and an electrolytic salt. The potential of the positive electrode is more than 4.3 V and 5.1 V or less based on lithium. The nonaqueous electrolyte contains vinylene carbonate as the nonaqueous solvent and, as the electrolytic salt, at least one of lithium bis(pentafluoroethane sulfonyl)imide and lithium bis(trifluoromethane sulfonyl)imide at 0.1 M or more and 0.5 M or less. The nonaqueous electrolyte contains 1,3-dioxane.
摘要翻译：提高了充电至高电位的非水电解质二次电池的保存性能，同时电池的初始容量和循环特性也得到改善。非水电解质二次电池包括具有磷酸锂的正极和含有钴钴复合氧化物的正极活性物质和具有层结构的锂锰镍复合氧化物，所述锂钴复合氧化物在LiCoO 2中加入至少锆和镁; 具有负极活性物质的负极; 和具有非水溶剂和电解质盐的非水电解质。基于锂，正极的电位大于4.3V且为5.1V以下。非水电解质含有碳酸亚乙烯酯作为非水溶剂，作为电解质盐，为0.1M以上且0.5M以下的双（五氟乙烷磺酰基）亚胺锂和双（三氟甲磺酰基）亚胺锂中的至少一种。非水电解质含有1,3-二恶烷。

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