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1. 发明授权

US4329513A Method for dehydration of unsaturated aldehyde-containing gas 失效
标题翻译：含不饱和醛的气体脱水方法
公开(公告)号：US4329513A
公开(公告)日：1982-05-11
申请号：US213703
申请日：1980-12-05
申请人： Atsushi Aoshima , Ryoichi Mitsui , Toshiaki Kaneko
发明人： Atsushi Aoshima , Ryoichi Mitsui , Toshiaki Kaneko
IPC分类号： C07C47/22 , B01D53/26 , C07C45/00 , C07C45/35 , C07C45/37 , C07C45/78 , C07C45/81 , C07C67/00 , C07C45/58 , C07C47/20
CPC分类号： C07C45/81 , C07C45/35 , C07C45/37 , C07C45/783
摘要： Methanol is allowed to flow downwardly and contacted countercurrently with an unsaturated aldehyde-containing gas obtained from gas phase catalytic oxidation of the starting gas containing at least one gas selected from the group consisting of propylene, isobutylene and t-butanol, said methanol being supplied in such an amount that substantially the whole thereof can be gasified in the treatment. According to this method, the water content in said unsaturated aldehyde-containing gas can be rendered smaller than that in the azeotropic mixture of the unsaturated aldehyde and water, and also there takes place no polymerization of the unsaturated aldehyde.
摘要翻译：允许甲醇向下流动并与含有至少一种选自丙烯，异丁烯和叔丁醇的气体的起始气体的气相催化氧化得到的不饱和含醛气体逆流接触，所述甲醇供应于在处理中基本上全部可以气化的量。根据该方法，可以使不饱和醛的气体中的含水量比不饱和醛和水的共沸混合物中的含水量少，也不发生不饱和醛的聚合。

2. 发明授权

US4236034A Process for producing tert-butanol from mixed butylenes 失效
标题翻译：从混合丁烯生产叔丁醇的方法
公开(公告)号：US4236034A
公开(公告)日：1980-11-25
申请号：US46315
申请日：1979-06-07
申请人： Atsushi Aoshima , Toshiaki Murobushi , Ryoichi Mitsui , Nobuhiro Tamura
发明人： Atsushi Aoshima , Toshiaki Murobushi , Ryoichi Mitsui , Nobuhiro Tamura
IPC分类号： C07C29/04
CPC分类号： C07C29/04
摘要： A process for producing tert-butanol by selective hydration of isobutylene in a hydrocarbon mixture comprising isobutylene and n-butene where an aqueous solution is used which contains a heteropolyacid, characterized in that the hydration reaction of isobutylene is carried out at a temperature of less than 100.degree. C.
摘要翻译：一种通过在包含异丁烯和正丁烯的烃混合物中选择性水合异丁烯来生产叔丁醇的方法，其中使用含有杂多酸的水溶液，其特征在于异丁烯的水合反应在小于 100℃

3. 发明授权

US4446328A Process for producing methacrolein 失效
标题翻译：生产异丁烯醛的方法
公开(公告)号：US4446328A
公开(公告)日：1984-05-01
申请号：US263667
申请日：1981-05-14
申请人： Atsushi Aoshima , Ryoichi Mitsui
发明人： Atsushi Aoshima , Ryoichi Mitsui
IPC分类号： B01J23/88 , C07C45/35 , C07C45/37 , C07C51/23 , C07C45/32
CPC分类号： B01J23/8871 , B01J23/8874 , B01J23/8875 , C07C45/35 , C07C45/37 , C07C51/23 , B01J2523/00
摘要： A process for producing methacrolein by oxidizing isobutylene or tertiary butanol with molecular oxygen, characterized by contacting a gaseous mixture of isobutylene or tertiary butanol, air or oxygen and optionally steam and an inert gas with a catalyst having the general composition:Mo.sub.12 Fe.sub.a Ni.sub.b Te.sub.c X.sub.d Z.sub.f Y.sub.g O.sub.hwherein a, b, c, d, f and g represent the numbers of atoms of the respective elements per 12 molybdenum atoms; X is Tl, Rb or Cs; Z is In or Ti; Y represents at least one element selected from the group consisting of Cu, Nd, Sm and Pb; a is a value of 0.2-6; b is a value of 0.2-6; a+b is a value of 1-10; c is a value of 0.1-4; d is a value of 0.1-3; f is a value of 0.1-3; g is a value of 0-5; and h is the number of oxygen atoms for satisfying the valencies of the existing elements. The use of this catalyst enables the selectivity for methacrolein to be improved to 90 or more and the yield based on the starting material to be increased to 89-91%. In addition, the high activity of said catalyst and high selectivity are stably maintained for a long period of time.
摘要翻译：通过用分子氧氧化异丁烯或叔丁醇来生产异丁烯醛的方法，其特征在于使异丁烯或叔丁醇，空气或氧气的气体混合物和任选的蒸汽和惰性气体与具有一般组成的催化剂接触：其中a，b ，c，d，f和g表示每12个钼原子的各元素的原子数; X是Tl，Rb或Cs; Z是In或Ti; Y表示选自Cu，Nd，Sm和Pb中的至少一种元素; a是0.2-6的值; b为0.2-6的值; a + b为1-10; c为0.1-4的值; d为0.1-3的值; f为0.1-3的值; g是0-5的值; 并且h是满足现有元素的价态的氧原子数。使用该催化剂使甲基丙烯醛的选择性提高到90以上，原料的收率提高到89〜91％。此外，所述催化剂的高活性和高选择性长时间稳定地保持。

4. 发明授权

US4354044A Method for preparing methacrolein 失效
标题翻译：甲基丙烯醛的制备方法
公开(公告)号：US4354044A
公开(公告)日：1982-10-12
申请号：US265136
申请日：1981-05-20
申请人： Atsushi Aoshima , Ryoichi Mitsui , Hitoshi Nihei
发明人： Atsushi Aoshima , Ryoichi Mitsui , Hitoshi Nihei
IPC分类号： C07C47/22 , B01J23/00 , B01J23/88 , C07C45/00 , C07C45/35 , C07C45/37 , C07C45/38 , C07C51/23 , C07C67/00 , C07C45/32 , C07C45/29
CPC分类号： B01J23/8871 , B01J23/8874 , B01J23/8875 , C07C45/35 , C07C45/37 , C07C51/23 , B01J2523/00
摘要： A method for preparing methacrolein by oxidizing isobutylene or tertiary butanol with molecular oxygen, characterized by contacting a gaseous mixture of isobutylene or tertiary butanol, air or oxygen and optionally steam and an inert gas with a catalyst having the general combination:Mo.sub.12 Fe.sub.a Ni.sub.b Te.sub.c Tl.sub.d Pb.sub.f X.sub.g O.sub.hwherein a, b, c, d, f and g represent the numbers of atoms of the respective elements per 12 molybdenum atoms; X is at least one element selected from the group consisting of Cu, Nd and Sm; a is a value of 0.2-6; b is a value of 0.2-6; a+b is a value of 1-10; c is a value of 0.1-4; d is a value of 0.1-3; f is a value of 0.1-5; g is a value of 0.1-5; and h is the number of oxygen atoms for satisfying the valencies of the existing elements. The use of this catalyst enables the selectivity for methacrolein to be improved to 90-94% and the yield based on the starting material to be increased to 89-91%. In addition, the activity of said catalyst is stably maintained for a long period of time.
摘要翻译：通过用分子氧氧化异丁烯或叔丁醇来制备甲基丙烯醛的方法，其特征在于将异丁烯或叔丁醇，空气或氧气的气体混合物和任选的蒸汽和惰性气体与具有以下通用组合的催化剂接触：其中a，b ，c，d，f和g表示每12个钼原子的各元素的原子数; X是选自Cu，Nd和Sm中的至少一种元素; a是0.2-6的值; b为0.2-6的值; a + b为1-10; c为0.1-4的值; d为0.1-3的值; f为0.1-5的值; g值为0.1-5; 并且h是满足现有元素的价态的氧原子数。使用该催化剂使得甲基丙烯醛的选择性提高到90-94％，并且基于原料的产率将提高到89-91％。此外，所述催化剂的活性稳定地保持长时间。

5. 发明授权

US4258217A Process for producing methacrolein 失效
标题翻译：生产异丁烯醛的方法
公开(公告)号：US4258217A
公开(公告)日：1981-03-24
申请号：US83878
申请日：1979-10-11
申请人： Atsushi Aoshima , Ryoichi Mitsui , Tatsuo Yamaguchi
发明人： Atsushi Aoshima , Ryoichi Mitsui , Tatsuo Yamaguchi
IPC分类号： B01J23/887 , C07C45/37 , C07C45/30 , C07C45/39
CPC分类号： B01J23/8876 , C07C45/37 , B01J2523/00
摘要： A process for producing methacrolein by oxidation of isobutylene or tert-butanol with molecular oxygen in the presence of a catalyst having the following composition:ti Mo.sub.12 Bi.sub.a Fe.sub.b Ni.sub.c Pb.sub.d X.sub.f O.sub.g orMo.sub.12 Bi.sub.a Fe.sub.b Ni.sub.c Pb.sub.d Sm.sub.e X.sub.f O.sub.gwherein X represents at least one element selected from the group consisting of Rb, Cs and Tl; and when X represents at least two of the elements f is the sum of the elements; a is a value of 0.1 to 10; b is a value of 0.05 to 2; c is a value of 0.05 to 2; d is a value of 0.05 to 5; e is a value of 0.05 to 5; f is a value of 0.01 to 2; and g is the number of oxygen atoms satisfying the valencies of the elements. Said catalyst enables methacrolein to be produced in high yield and can prevent the formation of methacrylic acid.
摘要翻译：在具有以下组成的催化剂存在下，通过用分子氧氧化异丁烯或叔丁醇来制备异丁烯醛的方法：其中X表示选自Rb，Cs和T1中的至少一种元素;其中X表示选自Rb，Cs和Tl中的至少一种元素。并且当X表示元素中的至少两个元素时，元素的总和; a为0.1〜10的值; b为0.05〜2的值; c为0.05〜2的值; d为0.05〜5的值; e为0.05〜5的值; f为0.01〜2的值; g是满足元素价态的氧原子数。所述催化剂能够以高产率生产异丁烯醛，并且可以防止形成甲基丙烯酸。

6. 发明授权

US4249019A Process for producing carboxylic esters 失效
标题翻译：羧酸酯的制备方法
公开(公告)号：US4249019A
公开(公告)日：1981-02-03
申请号：US960324
申请日：1978-11-13
申请人： Nobuhiro Tamura , Yohei Fukuoka , Setsuo Yamamatsu , Yoshio Suzuki , Ryoichi Mitsui , Tadayuki Ibuki
发明人： Nobuhiro Tamura , Yohei Fukuoka , Setsuo Yamamatsu , Yoshio Suzuki , Ryoichi Mitsui , Tadayuki Ibuki
IPC分类号： B01J23/58 , C07C67/39 , C07C69/14 , C07C69/54 , C07C69/78
CPC分类号： B01J23/58 , C07C67/39
摘要： A carboxylic ester is produced in one step in a high yield and with a high selectivity by reacting an aldehyde with an alcohol in the presence of oxygen by using a catalyst comprising (I) palladium, (II) at least one compound selected from the group consisting of lead compounds, thallium compounds and mercury compounds and (III) at least one compound selected from the group consisting of alkali metal compounds and alkaline earth metal compounds.
摘要翻译：通过使用包含（I）钯，（II）至少一种选自下组的化合物的催化剂，在氧气存在下通过使醛与醇反应而以高产率和高选择性制备羧酸酯，由铅化合物，铊化合物和汞化合物组成，和（III）选自碱金属化合物和碱土金属化合物中的至少一种化合物。

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