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    • 1. 发明授权
    • Oil based well fluids with high solids content
    • 油基井液,固体含量高
    • US06770602B2
    • 2004-08-03
    • US10062854
    • 2002-01-31
    • Arvind D. PatelReginald BellBurhan HoxhaJim Friedheim
    • Arvind D. PatelReginald BellBurhan HoxhaJim Friedheim
    • C09K706
    • C09K8/36C09K2208/18
    • A fluid having utility in subterranean wells is formulated to include: an oleaginous fluid; and a solids tolerance agent having the formula: in which R is a C6 to C20 aliphatic group and R′ is a C2 to C6 aliphatic group and x has a value from about 1 to about 10. Preferably R′ is selected from ethyl and isopropyl and R is an unsaturated aliphatic group. The fluid is formulated such that the oleaginous fluid is from about 30% to about 99% by volume of said fluid. In one illustrative embodiment, the oleaginous fluid is composed from about 5% to about 100% by volume of the oleaginous fluid of a material selected from a group consisting of diesel oil, mineral oil, synthetic oil, esters, ethers, acetals, di-alkylcarbonates, olefins, and combinations of these and similar fluids. A non-oleaginous fluid may also be included in the formulation that is from about 1% to about 70% by volume of said fluid. The non-oleaginous fluid is preferably selected from sea water, a brine containing organic or inorganic dissolved salts, a liquid containing water-miscible organic compounds, and combinations thereof. Also included in the fluid formulation may be weighting agents, fluids loss agents, viscosity agents and other similar agents utilized in the formulation of oil-based and invert emulsion drilling fluids.
    • 在地下井中具有效用的流体被配制成包括:含油流体; 和具有下式的固体耐受剂:其中R是C6至C20脂族基团,R'是C2至C6脂族基团,x具有约1至约10的值。优选地,R'选自乙基和异丙基 并且R是不饱和脂族基团。 流体被配制成使得含油流体占所述流体的约30体积%至约99体积%。 在一个说明性实施方案中,含油流体由选自柴油,矿物油,合成油,酯,醚,缩醛,二缩水甘油醚的材料的约5体积%至约100体积%的油质流体组成, 烷基碳酸酯,烯烃,以及这些和类似流体的组合。 制剂中也可以包含约1%至约70%体积的所述流体的非含油液体。 非油质流体优选选自海水,含有机或无机溶解盐的盐水,含有水混溶性有机化合物的液体及其组合。 还包括在流体配方中可以是增稠剂,流体损失剂,粘度剂和用于油基和反相乳液钻井液配方中的其它类似物质。
    • 2. 发明授权
    • Biodegradable surfactant for invert emulsion drilling fluid
    • 用于反相乳液钻井液的可生物降解的表面活性剂
    • US06828279B2
    • 2004-12-07
    • US09927619
    • 2001-08-10
    • Arvind D. PatelBurnhan HoxhaReginald Bell
    • Arvind D. PatelBurnhan HoxhaReginald Bell
    • C09K706
    • C09K8/36
    • An invert emulsion drilling fluid includes an oleaginous continuous phase; a non-oleaginous discontinuous phase; a biodegradable surfactant including a di-fatty acid ester of triglycerol; and a weighting agent. It is preferred that the fatty acid have the formula RCO2H in which R is an alkyl or alkenyl having 10 to 20 carbon atoms. The oleaginous fluid is selected from diesel oil, mineral oil, synthetic oil, ester oils, glycerides of fatty acids, aliphatic esters, aliphatic ethers, aliphatic acetals, or other such hydrocarbons and combinations of these and similar compounds. The non-oleaginous phase is selected from fresh water, sea water, brine, aqueous solutions containing water soluble organic salts, water soluble alcohols or water soluble glycols or combinations of these and similar compounds. The weighting agent is any suitable weighting agent and is preferably selected from water insoluble weighting agents such as barite, calcite, mullite, gallena, manganese oxides, iron oxides, or combinations of these or water soluble weighting agents such as water soluble salts of zinc, iron, barium, calcium or combinations of these and similar compounds.
    • 反相乳液钻井液包括油性连续相; 非油质不连续相; 包含三甘油二脂肪酸酯的生物可降解表面活性剂; 和加重剂。 优选脂肪酸具有式RCO 2 H,其中R是具有10至20个碳原子的烷基或链烯基。 含油流体选自柴油,矿物油,合成油,酯油,脂肪酸甘油酯,脂肪族酯,脂族醚,脂肪族缩醛或其它这些烃,以及这些和类似化合物的组合。 非油质相选自淡水,海水,盐水,含有水溶性有机盐的水溶液,水溶性醇或水溶性二醇或这些和类似化合物的组合。 加重剂是任何合适的加重剂,优选选自水不溶性加重剂,例如重晶石,方解石,莫来石,gallena,氧化锰,铁氧化物或这些的组合或水溶性增重剂,例如锌, 铁,钡,钙或这些和类似化合物的组合。