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1. 发明授权

US5459180A Polyol/epoxy adducts for use as emulsifier for liquid epoxy resins 失效
标题翻译：用作液体环氧树脂乳化剂的多元醇/环氧加合物
公开(公告)号：US5459180A
公开(公告)日：1995-10-17
申请号：US320964
申请日：1994-10-12
申请人： Armin Pfeil , Joerg-Peter Geisler , Claus Godau , Bernhard Stengel-Rutkowski , Matthias Meyer , Stefan Petri
发明人： Armin Pfeil , Joerg-Peter Geisler , Claus Godau , Bernhard Stengel-Rutkowski , Matthias Meyer , Stefan Petri
IPC分类号： C08G59/14 , B01F17/52 , C08G59/04 , C08J3/03 , C08L63/00 , C08L71/02
CPC分类号： C08G59/04 , C08L63/00
摘要： Polyol/epoxy adducts obtained by reaction of(A) an aliphatic polyol having an average molecular weight (Mw) of 200 to 2000 and(B) an epoxy compound having at least two epoxy groups per molecule and an epoxy equivalent weight of 100 to 2000,the equivalent ratio of the OH groups to the epoxy groups being 1:3.51 to 1:10, preferably 1:4 to 1:9, particularly preferably 1:45 to 1:8, and the epoxy equivalent weight of the adduct being between 150 g/eq and at least 800 g/eq, preferably between 250 g/eq and 1000 g/eq which adducts serve as nonionic emulsifiers in water-dilutable epoxy liquid resins.
摘要翻译：通过（A）平均分子量（Mw）为200〜2000的脂肪族多元醇与（B）每分子具有至少2个环氧基的环氧化合物和环氧当量为100〜2000反应而得到的多元醇/环氧加成物，OH基与环氧基的当量比为1:3.51至1:10，优选1:4至1:9，特别优选1:45至1:8，加合物的环氧当量重量介于 150g / eq和至少800g / eq，优选250g / eq和1000g / eq，该加合物在水可稀释环氧树脂液体树脂中用作非离子乳化剂。

2. 发明授权

US5539023A Curing agents for aqueous epoxy resin dispersions 失效
公开(公告)号：US5539023A
公开(公告)日：1996-07-23
申请号：US192868
申请日：1994-02-07
申请人： Dieter Dreischhoff , Joerg-Peter Geisler , Claus Godau , Michael Hoenel , Bernhard Stengel-Rutkowski
发明人： Dieter Dreischhoff , Joerg-Peter Geisler , Claus Godau , Michael Hoenel , Bernhard Stengel-Rutkowski
IPC分类号： C08G59/50 , C04B24/28 , C04B26/14 , C04B41/48 , C08G59/18 , C08G65/26 , C08L63/00 , C08L71/02 , C09D163/00 , D06M15/55 , C08K3/20 , C08L63/02
CPC分类号： D06M15/55 , C04B24/281 , C04B26/14 , C04B41/4853 , C08G59/184 , C08G65/26 , C08L71/02
摘要： Curing agents for aqueous epoxy resin dispersions obtained by reaction of an adduct (A) of at least one polyepoxide (A.sub.1) and at least one polyalkylene polyether polyol (A.sub.2), it being possible for the adduct (A) to be modified with a secondary amine (A.sub.3) if appropriate, withI. a reaction product of an amine (B) and an epoxide (C)orII. an amine (B) and subsequent reaction with an epoxide (C),the amount of amine (B) being chosen such that the H atoms on the nitrogen are present in a 2- to 10-fold excess, based on the epoxide groups in (A).

3. 发明授权

US5587409A Curing agents for aqueous epoxy resin dispersions 失效
标题翻译：水性环氧树脂分散体的固化剂
公开(公告)号：US5587409A
公开(公告)日：1996-12-24
申请号：US548204
申请日：1995-10-25
申请人： Dieter Dreischhoff , Joerg-Peter Geisler , Claus Godau , Michael Hoenel , Bernhard Stengel-Rutkowski
发明人： Dieter Dreischhoff , Joerg-Peter Geisler , Claus Godau , Michael Hoenel , Bernhard Stengel-Rutkowski
IPC分类号： C08G59/50 , C04B24/28 , C04B26/14 , C04B41/48 , C08G59/18 , C08G65/26 , C08L63/00 , C08L71/02 , C09D163/00 , D06M15/55 , C08K3/20 , C08L63/02
CPC分类号： D06M15/55 , C04B24/281 , C04B26/14 , C04B41/4853 , C08G59/184 , C08G65/26 , C08L71/02
摘要： Curing agents for aqueous epoxy resin dispersions obtained by reaction of an adduct (A) of at least one polyepoxide (A.sub.1) and at least one polyalkylene polyether polyol (A.sub.2), it being possible for the adduct (A) to be modified with a secondary amine (A.sub.3) if appropriate, withI. a reaction product of an amine (B) and an epoxide (C)orII. an amine (B) and subsequent reaction with an epoxide (C),the amount of amine (B) being chosen such that the H atoms on the nitrogen are present in a 2- to 10-fold excess, based on the epoxide groups in (A).
摘要翻译：通过至少一种聚环氧化物（A1）的加合物（A）与至少一种聚亚烷基聚醚多元醇（A2）的反应获得的水性环氧树脂分散体的固化剂，加成物（A）可以用二次胺（A3）（如果合适）与I.（胺）（B）和环氧化物（C）或II的反应产物。胺（B）和随后与环氧化物（C）的反应，胺（B）的量选择为使得氮上的H原子以2-10倍过量存在，基于环氧化物（一个）。

4. 发明授权

US5925694A Epoxy and epoxy-polyacrylate dispersions containing reactive diluent processes for their production and their use 失效
标题翻译：环氧和环氧 - 聚丙烯酸酯分散体含有反应性稀释剂，用于生产和使用
公开(公告)号：US5925694A
公开(公告)日：1999-07-20
申请号：US710985
申请日：1996-09-25
申请人： Bernhard Stengel-Rutkowski , Claus Godau , Armin Pfeil
发明人： Bernhard Stengel-Rutkowski , Claus Godau , Armin Pfeil
IPC分类号： C08L63/02 , C08F283/10 , C08G59/04 , C08G59/06 , C08G59/14 , C08G59/50 , C08J3/03 , C09D4/00 , C09D163/00 , C09D171/00 , C08K3/20
CPC分类号： C09D163/00 , C08G59/04 , C08G59/066 , C08G59/145 , C09D4/00 , Y10T428/31645
摘要： Aqueous, low-solvent coating compositions comprising a base resin dispersion comprising of an epoxy resin, prepared by condensation of one or more epoxide compounds having at least two epoxide groups per molecule and an aromatic polyol; a dispersant comprising a condensation product of an aliphatic polyol having a weight-average molar mass (M.sub.w) of from 200 to 20,000 g/mol and an epoxide compound having at least two epoxide groups per molecule, and low molar mass, liquid, epoxy-functional compounds as diluents, and also water; an aqueous curing agent for the modified epoxy resin (I), which is suitable for curing at room temperature or at elevated temperatures (forced drying), components (I) and (II) being employed in mass fractions such that the ratio of the number of reactive epoxide groups in (I) to the number of amine hydrogen atoms in (II) is between 1:0.75 and 1:2. The coating compositions exhibit an extended pot life. They can be used to produce coatings and in water-soluble adhesives.
摘要翻译：含水低溶剂涂料组合物，其包含由一种或多种每分子具有至少两个环氧基团的芳族化合物缩合制得的环氧树脂的基础树脂分散体和芳族多元醇; 包含重均摩尔质量（Mw）为200〜20,000g / mol的脂肪族多元醇与每分子具有至少两个环氧基的环氧化合物和低摩尔质量的液体，环氧 - 功能化合物作为稀释剂，以及水; 用于改性环氧树脂（I）的水性固化剂，其适用于在室温或高温下固化（强制干燥），组分（I）和（II）以质量份数使用，使得数量（I）中的反应性环氧基团与（II）中的胺氢原子数目在1:0.75至1:2之间。涂料组合物的适用期延长。它们可用于生产涂料和水溶性粘合剂。

5. 发明授权

US5708058A Aqueous coating composition based on low-solvent modified epoxy resin dispersions 失效
标题翻译：基于低溶剂改性环氧树脂分散体的水性涂料组合物
公开(公告)号：US5708058A
公开(公告)日：1998-01-13
申请号：US719647
申请日：1996-09-25
申请人： Armin Pfeil , Bernhard Stengel-Rutkowski , Claus Godau
发明人： Armin Pfeil , Bernhard Stengel-Rutkowski , Claus Godau
IPC分类号： C08G59/04 , C08G59/06 , C08G59/14 , C09D4/06 , C09D163/00 , C09J163/00 , C08K3/20
CPC分类号： C09D163/00 , C08G59/04 , C08G59/066 , C08G59/145 , C09D4/06 , Y10T428/31511
摘要： Aqueous low-solvent coating compositions comprising a modified epoxy resin dispersion comprising an epoxy resin which is prepared by condensation of one or more epoxide compounds having at least two epoxide groups per molecule with an aromatic polyol; a dispersant comprising a condensation product of an aliphatic polyol and an epoxide compound having at least two epoxide groups per molecule; a diluent consisting of ethylenically unsaturated otherwise inert or, if desired, functional monomers capable of free-radical polymerization or copolymerization, and water, and also an aqueous curing agent for the modified epoxy resin (I), which is suitable for curing at room temperature or at elevated temperatures (forced drying), components (I) and (II) being employed in proportions by mass such that the ratio of the number of epoxide groups which are capable of reaction to the number of amine hydrogen atoms is between 1:0.75 and 1:2. The coating compositions can be employed to produce matt coatings and in adhesives.
摘要翻译：包含改性环氧树脂分散体的水性低溶剂涂料组合物，其包含通过一种或多种每分子具有至少两个环氧基团的芳族化合物与芳族多元醇缩合制备的环氧树脂; 分散剂，其包含每分子具有至少两个环氧基团的脂族多元醇和环氧化合物的缩合产物; 由烯键式不饱和或惰性的（如果需要的话）能够进行自由基聚合或共聚的官能单体和水，以及适于在室温下固化的改性环氧树脂（I）的水性固化剂的稀释剂组成的稀释剂或在升高的温度下（强制干燥），组分（I）和（II）按质量比使用，使得能够与胺氢原子数反应的环氧化物基团的数量的比例为1:0.75 和1：2。涂料组合物可用于生产无光泽涂料和粘合剂。

6. 发明授权

US5319004A Hardener for epoxy resins comprising reaction products of polyamidoamines, secondary polyamines and epoxy-polyol adducts 失效
标题翻译：包括聚酰胺胺，仲胺和环氧多元醇加成物的反应产物的环氧树脂的固化剂
公开(公告)号：US5319004A
公开(公告)日：1994-06-07
申请号：US24195
申请日：1993-02-26
申请人： Manfred Marten , Bernhard Stengel-Rutkowski , Claus Godau
发明人： Manfred Marten , Bernhard Stengel-Rutkowski , Claus Godau
IPC分类号： C08G59/40 , C08G59/00 , C08G59/18 , C08L63/00 , C08L79/02
CPC分类号： C08L63/00 , C08G59/184 , C08L79/02
摘要： Hardeners for epoxy resins, comprising reaction products of(A) polyamidoamines that were obtained by polycondensation of (a) dicarboxylic acids containing oxyalkylene groups, or their derivatives, with (b) polyamines containing at least two amino groups capable of undergoing condensation with (a),(B) polyamines containing at least two secondary amino groups, and(C) adducts of (c) polyepoxy compounds and (d) polyalkylene polyether polyols.Epoxy resins that have been cured with these hardeners exhibit in particular a very good water resistance.
摘要翻译：环氧树脂硬化剂包括（A）聚酰胺胺的反应产物，其通过（a）含有氧化烯基的二羧酸或其衍生物与（b）含有至少两个能够与（a ），（B）含有至少两个仲氨基的多胺，（C）（c）聚环氧化合物和（d）聚亚烷基聚醚多元醇的加合物。用这些硬化剂固化的环氧树脂特别表现出非常好的耐水性。

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