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1. 发明申请

US20100317811A1 PROCESS FOR THE GAS-PHASE POLYMERIZATION OF OLEFINS 有权
标题翻译：油相的气相聚合方法
公开(公告)号：US20100317811A1
公开(公告)日：2010-12-16
申请号：US12735090
申请日：2008-12-17
申请人： Antonio Mazzucco , Riccardo Rinaldi , Silvia Soffritti , Enrico Balestra , Giuseppe Penzo , Gabriele Mei
发明人： Antonio Mazzucco , Riccardo Rinaldi , Silvia Soffritti , Enrico Balestra , Giuseppe Penzo , Gabriele Mei
IPC分类号： C08F2/01
CPC分类号： B01J19/2435 , B01J2219/00164 , B01J2219/00166 , B01J2219/00173 , C08F10/00 , C08F110/06 , C08F210/06 , C08F2/34 , C08F2/001 , C08F2500/05 , C08F210/16
摘要： A process for the gas-phase polymerization of α-olefins carried out in two interconnected polymerization zones, wherein the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said riser and enter the second of said polymerization zones (downcomer) through which they flow downward in a densified form, the process being characterized in that: (a) the gas mixture present in the riser is totally or partially prevented from entering the downcomer by introducing into the upper part of said downcomer a liquid stream LB having a composition different from the gaseous mixture present in the riser; (b) the ratio R between the flow rate Fp of polymer circulated between said downcomer and said riser and the flow rate LB of said liquid being adjusted in a range from 10 to 50.
摘要翻译：一种用于在两个相互连接的聚合区中进行的α-烯烃的气相聚合的方法，其中生长的聚合物颗粒在快速流化条件下流过第一个所述聚合区（提升管），离开所述提升管并进入所述聚合区（降液管），通过它们以致密化形式向下流动，该方法的特征在于：（a）通过引入所述降液管的上部，存在于提升管中的气体混合物被全部或部分地防止进入降液管具有与提升管中存在的气体混合物不同的组成的液体流LB; （b）在所述降液管和所述提升管之间循环的聚合物的流量Fp与所述液体的流量LB之间的比R调节在10至50的范围内。

2. 发明授权

US08198383B2 Process for the gas-phase polymerization of olefins 有权
标题翻译：烯烃气相聚合方法
公开(公告)号：US08198383B2
公开(公告)日：2012-06-12
申请号：US12735090
申请日：2008-12-17
申请人： Antonio Mazzucco , Riccardo Rinaldi , Silvia Soffritti , Enrico Balestra , Giuseppe Penzo , Gabriele Mei
发明人： Antonio Mazzucco , Riccardo Rinaldi , Silvia Soffritti , Enrico Balestra , Giuseppe Penzo , Gabriele Mei
IPC分类号： C08F2/00 , C08F210/00 , C08F110/02 , B01J19/18 , B01J8/18
CPC分类号： B01J19/2435 , B01J2219/00164 , B01J2219/00166 , B01J2219/00173 , C08F10/00 , C08F110/06 , C08F210/06 , C08F2/34 , C08F2/001 , C08F2500/05 , C08F210/16
摘要： A process for the gas-phase polymerization of α-olefins carried out in two interconnected polymerization zones, wherein the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said riser and enter the second of said polymerization zones (downcomer) through which they flow downward in a densified form, the process being characterized in that: (a) the gas mixture present in the riser is totally or partially prevented from entering the downcomer by introducing into the upper part of said downcomer a liquid stream LB having a composition different from the gaseous mixture present in the riser; (b) the ratio R between the flow rate Fp of polymer circulated between said downcomer and said riser and the flow rate LB of said liquid being adjusted in a range from 10 to 50.
摘要翻译：一种用于在两个相互连接的聚合区中进行的α-烯烃的气相聚合的方法，其中生长的聚合物颗粒在快速流化条件下流过第一个所述聚合区（提升管），离开所述提升管并进入所述聚合区（降液管），通过它们以致密化形式向下流动，该方法的特征在于：（a）通过引入所述降液管的上部，存在于提升管中的气体混合物被全部或部分地防止进入降液管具有与提升管中存在的气体混合物不同的组成的液体流LB; （b）在所述降液管和所述提升管之间循环的聚合物的流量Fp与所述液体的流量LB之间的比R调节在10至50的范围内。

3. 发明授权

US08148478B2 Process for the gas-phase polymerization of olefins 有权
标题翻译：烯烃气相聚合方法
公开(公告)号：US08148478B2
公开(公告)日：2012-04-03
申请号：US12990536
申请日：2009-05-15
申请人： Riccardo Rinaldi , Antonio Mazzucco , Enrico Balestra , Giuseppe Penzo , Maurizio Dorini , Gabriele Mei
发明人： Riccardo Rinaldi , Antonio Mazzucco , Enrico Balestra , Giuseppe Penzo , Maurizio Dorini , Gabriele Mei
IPC分类号： C08F2/34 , C08L23/20
CPC分类号： B01J19/2435 , B01J19/2465 , B01J2219/00087 , C08F10/00 , C08F110/02 , C08F110/06 , Y10S526/901 , C08F2/34 , C08F2/001 , C08F2/01 , C08F2500/05 , C08F2500/15
摘要： A process for the polymerization of olefins carried out in a gas-phase reactor having interconnected polymerization zones, where the growing polymer particles flow upward through a first polymerization zone (riser) under fast fluidization or transport conditions, leave said riser and enter a second polymerization zone (downcomer) through which they flow downward under the action of gravity, leave said downcomer and are reintroduced into the riser, a gas recycle stream being withdrawn from said first polymerization zone, subjected to cooling below its dew point and then returned to said first polymerization zone, the process being characterized in that said gas recycle stream is cooled at a temperature Tc ranging from 0.05° C. to 3° C. below its dew point.
摘要翻译：在具有互连聚合区的气相反应器中进行的烯烃聚合方法，其中生长的聚合物颗粒在快速流化或输送条件下向上流过第一聚合区（提升管），离开所述提升管并进入第二聚合（降液管），通过它们在重力作用下向下流动，离开所述降液管并重新引入提升管，从所述第一聚合区域排出的气体循环物流经过其露点以下的冷却，然后返回到所述第一聚合区，其特征在于，所述气体循环物流在低于其露点的范围为0.05℃至3℃的温度Tc下冷却。

4. 发明申请

US20110054127A1 PROCESS FOR THE GAS-PHASE POLYMERIZATION OF OLEFINS 有权
标题翻译：油相的气相聚合方法
公开(公告)号：US20110054127A1
公开(公告)日：2011-03-03
申请号：US12990536
申请日：2009-05-15
申请人： Riccardo Rinaldi , Antonio Mazzucco , Enrico Balestra , Giuseppe Penzo , Maurizio Dorini , Gabriele Mei
发明人： Riccardo Rinaldi , Antonio Mazzucco , Enrico Balestra , Giuseppe Penzo , Maurizio Dorini , Gabriele Mei
IPC分类号： C08F2/01
CPC分类号： B01J19/2435 , B01J19/2465 , B01J2219/00087 , C08F10/00 , C08F110/02 , C08F110/06 , Y10S526/901 , C08F2/34 , C08F2/001 , C08F2/01 , C08F2500/05 , C08F2500/15
摘要： A process for the polymerisation of olefins carried out in a gas-phase reactor having interconnected polymerization zones, where the growing polymer particles flow upward through a first polymerization zone (riser) under fast fluidization or transport conditions, leave said riser and enter a second polymerization zone (downcomer) through which they flow downward under the action of gravity, leave said downcomer and are reintroduced into the riser, a gas recycle stream being withdrawn from said first polymerisation zone, subjected to cooling below its dew point and then returned to said first polymerisation zone, the process being characterised in that said gas recycle stream is cooled at a temperature Tc ranging from 0.05° C. to 3° C. below its dew point.
摘要翻译：在具有相互连接的聚合区的气相反应器中进行烯烃聚合的方法，其中生长的聚合物颗粒在快速流化或输送条件下向上流过第一聚合区（提升管），离开所述提升管并进入第二聚合（下降管），通过它们在重力作用下向下流动，离开所述下降管并重新引入提升管，从所述第一聚合区域排出的气体循环物流经历其低于其露点的冷却，然后返回到所述第一聚合区，其特征在于所述气体再循环流在低于其露点的范围为0.05℃至3℃的温度Tc下冷却。

5. 发明申请

US20050234217A1 Method for removing volatile components from polymer compositions 有权
标题翻译：从聚合物组合物中除去挥发性组分的方法
公开(公告)号：US20050234217A1
公开(公告)日：2005-10-20
申请号：US10518693
申请日：2003-06-17
申请人： Daniele Bigiavi , Nicolo Arich De Finetti , Gabriele Mei , Giuseppe Penzo , Massimo Covezzi , Pietro Baita , Maria Silvia Tonti
发明人： Daniele Bigiavi , Nicolo Arich De Finetti , Gabriele Mei , Giuseppe Penzo , Massimo Covezzi , Pietro Baita , Maria Silvia Tonti
IPC分类号： C08F6/06 , C08F6/00 , C08F6/10 , C08G2/00
CPC分类号： C08F6/003 , Y02P20/544 , C08L23/20
摘要： Method for continuously removing the unreacted butene-1, and optionally other volatile components, from a polymeric solution obtained by liquid phase (co)polymerization of butene-1, the method comprising the steps of: subjecting the polymeric solution to heating and mixing conditions such that a mixture is formed consisting substantially of: (1) a polybutene melt containing entrapped butene-1 and (2) supercritical gaseous butene-1; subjecting the above mixture to a sequence of devolatilization steps operating at decreasing pressures.
摘要翻译：从通过丁烯-1的液相（共）聚合获得的聚合物溶液中连续除去未反应的丁烯-1和任选的其它挥发性组分的方法，所述方法包括以下步骤：将聚合物溶液加热和混合条件如形成的混合物基本上由以下组成：（1）含有截留的丁烯-1和（2）超临界气态丁烯-1的聚丁烯熔体; 使上述混合物经历在降低的压力下操作的一系列脱挥发分步骤。

6. 发明申请

US20090156758A1 Gas-Phase Process for the Poymerization of Olefins 审中-公开
标题翻译：用于烯烃聚合的气相方法
公开(公告)号：US20090156758A1
公开(公告)日：2009-06-18
申请号：US11992032
申请日：2006-09-15
申请人： Joachim Pater T.M. , Pietro Baita , Gabriele Mei , Antonio Mazzucco
发明人： Joachim Pater T.M. , Pietro Baita , Gabriele Mei , Antonio Mazzucco
IPC分类号： C08F2/01 , B01J19/24
CPC分类号： B01J8/1827 , B01J8/002 , B01J8/0035 , B01J8/1872 , B01J19/2415 , B01J2208/00256 , B01J2208/00274 , B01J2208/0053 , B01J2208/00752 , B01J2219/00006 , B01J2219/00033 , B01J2219/0004 , C08F10/00 , C08F110/02 , C08F2/34 , C08F2/01 , C08F2500/05 , C08F2500/12 , C08F2500/24
摘要： A process for the gas-phase polymerization of one or more alpha-olefins in the presence of a polymerization catalyst system, the process comprising: a) contacting in a continuous way a gas comprising one or more of said alpha-olefins with said catalyst system in a gas-phase tubular reactor at a temperature from 30° C. to 130° C. in order to obtain a polymerization degree up to 500 grams per gram of catalyst system; b) feeding in continuous the prepolymer from step a) to a successive gas-phase polymerization reactor; wherein said gas-phase tubular reactor has a length/diameter ratio higher than 100.
摘要翻译：一种在聚合催化剂体系存在下气相聚合一种或多种α-烯烃的方法，该方法包括：a）以连续的方式使包含一种或多种所述α-烯烃的气体与所述催化剂体系在气相管式反应器中，在30℃至130℃的温度下，以获得高达500克/克催化剂体系的聚合度; b）将预聚物从步骤a）连续进料到连续的气相聚合反应器; 其中所述气相管式反应器具有高于100的长度/直径比。

7. 发明申请

US20100004408A1 PROCESS FOR THE POLYOLEFIN FINISHING 有权
标题翻译：聚烯烃饰面工艺
公开(公告)号：US20100004408A1
公开(公告)日：2010-01-07
申请号：US12309894
申请日：2007-08-01
申请人： Pietro Baita , Giuseppe Penzo , Gabriele Mei
发明人： Pietro Baita , Giuseppe Penzo , Gabriele Mei
IPC分类号： C08F6/00
CPC分类号： B01J8/24 , B01J8/003 , B01J2219/00006 , C08F6/005 , C08F6/02 , C08F210/16 , C08L23/00 , C08F210/14 , C08F2500/12 , C08F2500/24
摘要： A process to perform the finishing of polyolefins produced by gas-phase catalytic polymerization of one or more α-olefins in the presence of a polymerization diluent selected from a C3-C5 alkane, wherein the polyolefin granules discharged from the gas-phase reactor are subjected to: (1) a first degassing step in which said polyolefin is counter-currently contacted with a gaseous stream containing at least 85% by mol of a stripping agent selected from a C3-C5 alkane, said gaseous stream being continuously derived from the monomer recovery section of the polymerization plant; (2) a second degassing step in which said polyolefin is counter-currently contacted with steam, the amount of steam being from 10 to 200 Kg per 1000 kg of polyolefin.
摘要翻译：在选自C3-C5烷烃的聚合稀释剂存在下进行一种或多种α-烯烃的气相催化聚合制备的聚烯烃的精制方法，其中从气相反应器排出的聚烯烃颗粒经（1）第一脱气步骤，其中所述聚烯烃与包含至少85摩尔％选自C 3 -C 5烷烃的汽提剂的气流反向接触，所述气流连续地衍生自单体聚合厂的回收段; （2）第二脱气步骤，其中所述聚烯烃与蒸汽相反地接触，蒸汽的量为10-200Kg / 1000kg聚烯烃。

8. 发明授权

US07786254B2 Process for the polyolefin finishing 有权
标题翻译：聚烯烃整理工艺
公开(公告)号：US07786254B2
公开(公告)日：2010-08-31
申请号：US12309894
申请日：2007-08-01
申请人： Pietro Baita , Giuseppe Penzo , Gabriele Mei
发明人： Pietro Baita , Giuseppe Penzo , Gabriele Mei
IPC分类号： C08F6/00 , C08F2/34
CPC分类号： B01J8/24 , B01J8/003 , B01J2219/00006 , C08F6/005 , C08F6/02 , C08F210/16 , C08L23/00 , C08F210/14 , C08F2500/12 , C08F2500/24
摘要： A process to perform the finishing of polyolefins produced by gas-phase catalytic polymerization of one or more α-olefins in the presence of a polymerization diluent selected from a C3-C5 alkane, wherein the polyolefin granules discharged from the gas-phase reactor are subjected to: (1) a first degassing step in which said polyolefin is counter-currently contacted with a gaseous stream containing at least 85% by mol of a stripping agent selected from a C3-C5 alkane, said gaseous stream being continuously derived from the monomer recovery section of the polymerization plant; (2) a second degassing step in which said polyolefin is counter-currently contacted with steam, the amount of steam being from 10 to 200 Kg per 1000 kg of polyolefin.
摘要翻译：在选自C3-C5烷烃的聚合稀释剂的存在下进行由一种或多种α-烯烃的气相催化聚合制备的聚烯烃的精制方法，其中从气相反应器排出的聚烯烃颗粒经受（1）第一脱气步骤，其中所述聚烯烃与包含至少85摩尔％选自C 3 -C 5烷烃的汽提剂的气流反向接触，所述气流连续地衍生自单体聚合厂的回收段; （2）第二脱气步骤，其中所述聚烯烃与蒸汽相反地接触，蒸汽的量为10-200Kg / 1000kg聚烯烃。

9. 发明授权

US07160964B2 Liquid phase process for the polymerization of α-olefins 失效
标题翻译：用于α-烯烃聚合的液相方法
公开(公告)号：US07160964B2
公开(公告)日：2007-01-09
申请号：US10518885
申请日：2003-06-17
申请人： Daniele Bigiavi , Gabriele Mei , Nicolo' Arich De Finetti , Giuseppe Penzo , Gianni Vitale , Massimo Covezzi
发明人： Daniele Bigiavi , Gabriele Mei , Nicolo' Arich De Finetti , Giuseppe Penzo , Gianni Vitale , Massimo Covezzi
IPC分类号： C08F4/44
CPC分类号： C08F110/08 , Y10S526/903 , C08F2/001 , C08F2/06 , C08F2/42 , C08F2500/12 , C08F2/01 , C08F2/00
摘要： A liquid-phase process for polymerizing α-olefins of the formula CH2═CHR, where R is H or an alkyl radical C1–C6, to produce a polymer that is soluble in the reaction medium, comprising the steps of: a) continuously polymerizing in liquid phase the α-olefin in the presence of a catalyst system based on a transition metal compound; b) continuously withdrawing from step a) a solution of polymer in the liquid reaction medium; c) mixing in one or more mixing stages said solution of polymer in the reaction medium with an organic deactivator having: at least a hydroxy group, a boiling point higher than 150° C., and a ratio between the molecular weight (MW) and the number of hydroxy groups (OH) comprised between 20 and 100.
摘要翻译：用于聚合式CH 2 -CHR的α-烯烃的液相方法，其中R是H或烷基C1-C6，以产生可溶于反应介质的聚合物，包括步骤：a）在基于过渡金属化合物的催化剂体系的存在下，在液相中连续聚合α-烯烃; b）连续地从步骤a）中取出聚合物在液体反应介质中的溶液; c）在一个或多个混合阶段将所述聚合物在反应介质中的溶液与有机失活剂混合，所述有机失活剂具有至少羟基，沸点高于150℃，分子量（MW）和羟基（OH）的数目在20和100之间。

10. 发明申请

US20070004879A1 Gas-phase olefin polymerization process 有权
标题翻译：气相烯烃聚合工艺
公开(公告)号：US20070004879A1
公开(公告)日：2007-01-04
申请号：US10553476
申请日：2004-04-01
申请人： Giuseppe Penzo , Gabriele Mei , Gerben Meier
发明人： Giuseppe Penzo , Gabriele Mei , Gerben Meier
IPC分类号： C08F2/00
CPC分类号： B01J8/1827 , B01J8/1872 , B01J2208/00256 , B01J2208/00274 , B01J2208/003 , C08F10/00 , Y10S526/901 , Y10S526/918 , C08F2/01 , C08F2/34
摘要： A continuous process for the olefin polymerization in a fluidized bed reactor, said process comprising continuously passing a gaseous stream comprising one or more α-olefin monomers through the fluidized bed in the presence of a polymerization catalyst under reactive conditions, withdrawing polymeric product and unreacted fluids from the reactor, cooling part of said unreacted fluids below the dew point to form a two-phase mixture of gas and condensed liquid and reintroducing said two-phase mixture into the reactor, the process being characterized in that said twophase mixture is reintroduced under the distribution plate of the reactor so that a part of condensed liquid is separated from the gas and is successively fed above the fluidized bed through an external pipe connecting the bottom of the reactor to a point situated above the upper limit of the fluidized bed of polymer particles.
摘要翻译：在流化床反应器中烯烃聚合的连续方法，所述方法包括在反应条件下，在聚合催化剂存在下连续地通过包含一种或多种α-烯烃单体的气流通过流化床，将聚合物和未反应的流体从反应器中将所述未反应流体的部分部分冷却至低于露点以形成气体和冷凝液体的两相混合物，并将所述两相混合物重新引入反应器中，其特征在于将所述两相混合物重新引入到分配板，使得一部分冷凝液体与气体分离，并通过将反应器底部连接到位于聚合物颗粒流化床上限之上的点连续地供入到流化床上方。

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