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1. 发明申请

US20050065229A1 Process for oxidizing a fluoropolymer and multilayer structures comprising this oxidized fluoropolymer 审中-公开
标题翻译：用于氧化含氟聚合物和包含该氧化的含氟聚合物的多层结构的方法
公开(公告)号：US20050065229A1
公开(公告)日：2005-03-24
申请号：US10900940
申请日：2004-07-28
申请人： Anthony Bonnet , Barbara Ramfel , Pascal Sebire , Michael Werth , Thierry Pascal
发明人： Anthony Bonnet , Barbara Ramfel , Pascal Sebire , Michael Werth , Thierry Pascal
IPC分类号： C08F8/06 , C08J3/28
CPC分类号： B82Y30/00 , B32B7/10 , B32B7/12 , B32B27/08 , B32B27/304 , B32B27/32 , C08F8/06 , C08J3/28 , C08J7/123 , C08J2327/16 , C08F114/22
摘要： The present invention relates to a process for oxidizing a fluoropolymer, comprising the steps of: a) forming a fluoropolymer is into a film, a sheet, granules or powder; b) exposing the products from step a), in the presence of oxygen, to photon (γ) or electron (β) irradiation with a dose of between 1 and 15 Mrad; and c) optionally treating the product obtained in b) in order to remove all or some of the by-product impurities. The oxidized fluoropolymer thus obtained may be used as such or in a blend with at least one polymer. Structures comprising at least one layer of this oxidized fluoropolymer and at least one layer of another material may be formed into bottles, tanks, containers, pipes, hoses and vessels of all sorts. They may also be converted into films with which packaging is made. The invention also relates to the oxidized fluoropolymer.
摘要翻译：本发明涉及一种氧化含氟聚合物的方法，包括以下步骤：a）将含氟聚合物形成薄膜，片，颗粒或粉末; b）以1至15Mrad的剂量将来自步骤a）的产物在氧的存在下暴露于光子（γ）或电子（β）照射; 和c）任选地处理b）中获得的产物以除去所有或一些副产物杂质。由此获得的氧化含氟聚合物可以原样使用或与至少一种聚合物共混使用。包含至少一层该氧化含氟聚合物和至少一层其它材料的结构可以形成为各种瓶，罐，容器，管，软管和各种容器。它们也可以转换为制成包装的薄膜。本发明还涉及氧化的含氟聚合物。

2. 发明授权

US07241817B2 Process for grafting a fluoropolymer and multilayer structures comprising this grafted polymer 有权
标题翻译：用于接枝包含该接枝聚合物的含氟聚合物和多层结构的方法
公开(公告)号：US07241817B2
公开(公告)日：2007-07-10
申请号：US10859300
申请日：2004-06-02
申请人： Anthony Bonnet , Barbara Ramfel , Fabrice Chopinez , Karine Triballier , Michael Werth , Thierry Pascal
发明人： Anthony Bonnet , Barbara Ramfel , Fabrice Chopinez , Karine Triballier , Michael Werth , Thierry Pascal
IPC分类号： C08F2/46
CPC分类号： B32B27/08 , B32B27/304 , B32B27/308 , B32B27/34 , B32B2250/24 , B32B2250/246 , B32B2250/40 , B32B2270/00 , B32B2307/202 , B32B2307/7265 , B32B2439/00 , B32B2439/60 , B32B2597/00 , C08F259/08 , C08F291/18 , C08J7/18 , Y10T428/31855 , Y10T428/31891 , Y10T428/31909 , Y10T428/31913 , C08F222/06
摘要： The present invention relates to a process for grafting an unsaturated monomer onto a fluoropolymer, having the steps of: a) melt blending the fluoropolymer with the unsaturated monomer; b) forming the blend obtained in a) into films, sheets, granules or powder; c) exposing the products from step b), in the absence of air, to photon (γ) or electron (β) irradiation with a dose of between 1 and 15 Mrad; and d) optionally treating the product obtained at c) in order to remove all or part of the unsaturated monomer that has not been grafted onto the fluoropolymer. Structures made with these materials are barriers to many fluids and in particular to petrol and to air-conditioning fluids and may be formed into bottles, tanks, containers, pipes, hoses and vessels of all sorts. They may also be converted into films with which packaging is made.
摘要翻译：本发明涉及将不饱和单体接枝到含氟聚合物上的方法，具有以下步骤：a）将含氟聚合物与不饱和单体熔融共混; b）将a）中得到的共混物形成薄膜，薄片，颗粒或粉末; c）在没有空气的情况下将来自步骤b）的产物以1至15Mrad的剂量暴露于光子（γ）或电子（β）照射; 和d）任选地处理在c）获得的产物，以便除去未接枝到含氟聚合物上的全部或部分不饱和单体。用这些材料制成的结构是许多流体的障碍，特别是汽油和空调流体的障碍，并且可以形成瓶，罐，容器，管，软管和各种容器。它们也可以转换为制成包装的薄膜。

3. 发明申请

US20050203203A1 Process for grafting a fluoropolymer and multilayer structures comprising this grafted polymer 有权
标题翻译：用于接枝包含该接枝聚合物的含氟聚合物和多层结构的方法
公开(公告)号：US20050203203A1
公开(公告)日：2005-09-15
申请号：US10859300
申请日：2004-06-02
申请人： Anthony Bonnet , Barbara Ramfel , Fabrice Chopinez , Karine Triballier , Michael Werth , Thierry Pascal
发明人： Anthony Bonnet , Barbara Ramfel , Fabrice Chopinez , Karine Triballier , Michael Werth , Thierry Pascal
IPC分类号： C08J3/28
CPC分类号： B32B27/08 , B32B27/304 , B32B27/308 , B32B27/34 , B32B2250/24 , B32B2250/246 , B32B2250/40 , B32B2270/00 , B32B2307/202 , B32B2307/7265 , B32B2439/00 , B32B2439/60 , B32B2597/00 , C08F259/08 , C08F291/18 , C08J7/18 , Y10T428/31855 , Y10T428/31891 , Y10T428/31909 , Y10T428/31913 , C08F222/06
摘要： The present invention relates to a process for grafting an unsaturated monomer onto a fluoropolymer, having the steps of: a) melt blending the fluoropolymer with the unsaturated monomer; b) forming the blend obtained in a) into films, sheets, granules or powder; c) exposing the products from step b), in the absence of air, to photon (y) or electron (β) irradiation with a dose of between 1 and 15 Mrad; and d) optionally treating the product obtained at c) in order to remove all or part of the unsaturated monomer that has not been grafted onto the fluoropolymer. Structures made with these materials are barriers to many fluids and in particular to petrol and to air-conditioning fluids and may be formed into bottles, tanks, containers, pipes, hoses and vessels of all sorts. They may also be converted into films with which packaging is made.
摘要翻译：本发明涉及将不饱和单体接枝到含氟聚合物上的方法，具有以下步骤：a）将含氟聚合物与不饱和单体熔融共混; b）将a）中得到的共混物形成薄膜，薄片，颗粒或粉末; c）在没有空气的情况下将来自步骤b）的产物以1至15Mrad的剂量暴露于光子（y）或电子（β）照射; 和d）任选地处理在c）获得的产物，以便除去未接枝到含氟聚合物上的全部或部分不饱和单体。用这些材料制成的结构是许多流体的障碍，特别是汽油和空调流体的障碍，并且可以形成瓶，罐，容器，管，软管和各种容器。它们也可以转换为制成包装的薄膜。

4. 发明申请

US20050069778A1 Structure comprising a modified fluoropolymer and electrode based on this structure 审中-公开
标题翻译：包含基于该结构的改性含氟聚合物和电极的结构
公开(公告)号：US20050069778A1
公开(公告)日：2005-03-31
申请号：US10900817
申请日：2004-07-28
申请人： Anthony Bonnet , Barbara Ramfel , Benoit Barriere , Thierry Pascal
发明人： Anthony Bonnet , Barbara Ramfel , Benoit Barriere , Thierry Pascal
IPC分类号： B32B15/082 , B32B15/08 , C08F8/06 , C08F259/08 , C08J3/12 , C08J5/18 , C08J7/18 , C09D127/16 , C09D127/22 , C09D151/06 , C09J127/16 , H01M2/16 , H01M4/60 , H01M4/62 , H01M4/66 , H01M10/02 , H01M10/0525 , H01M10/36
CPC分类号： H01M4/623 , H01M4/621 , H01M4/661 , H01M10/0525 , Y10T428/31692
摘要： The present invention relates to a structure comprising, in succession: a metal layer L1, optionally a fluorinated primer L2, which is a blend comprising, by weight, 1 to 100% of at least one modified fluoropolymer per 0 to 99% of fluoropolymer, respectively, and a layer of a fluoropolymer L3; such that, if the primer layer L2 is absent, the fluoropolymer L3 is a blend comprising, by weight, 1 to 100% of at least one modified fluoropolymer per 0 to 99% of fluoropolymer, respectively; the said modified fluoropolymer being chosen from: fluoropolymers grafted with an unsaturated monomer, the grafting being carried out in the absence of oxygen by irradiation of the unsaturated monomer and of the fluoropolymer that are melt-blended beforehand, and fluoropolymers irradiated in the presence of oxygen (also referred to as oxidized fluoropolymers). The structure is useful as a positive electrode for a lithium-ion battery.
摘要翻译：本发明涉及一种结构，其包括：连续地包含金属层L1，任选的氟化底漆L2，其是共混物，其包含按重量计1至100％的至少一种改性含氟聚合物，每0至99％的含氟聚合物，和一层氟聚合物L3; 使得如果不存在底漆层L2，则含氟聚合物L3是共混物，其分别包含0至99％的含氟聚合物中的至少一种改性含氟聚合物1至100重量％所述改性含氟聚合物选自：用不饱和单体接枝的含氟聚合物，接枝在不存在氧的情况下通过不预先熔融共混的不饱和单体和含氟聚合物的照射和在氧气存在下照射的含氟聚合物进行（也称为氧化含氟聚合物）。该结构可用作锂离子电池的正极。

5. 发明申请

US20120077937A1 Method For Preparing A Suspension Of PVC Grafted Onto An Elastomer 审中-公开
标题翻译：制备粘合在弹性体上的PVC悬浮液的方法
公开(公告)号：US20120077937A1
公开(公告)日：2012-03-29
申请号：US13320377
申请日：2010-05-06
申请人： Thierry Pascal , Bruno Brechard
发明人： Thierry Pascal , Bruno Brechard
IPC分类号： C08F8/18
CPC分类号： C08F265/04 , C08F291/02 , C08F214/06 , C08F2/18
摘要： The invention pertains to the field of PVC production. More particularly, the invention relates to a method for preparing a polymer including vinyl chloride monomers that are polymerized and grafted onto acrylic, styrene, and/or ethylene monomers polymerized in the form of an elastomer.
摘要翻译：本发明涉及PVC生产领域。更具体地，本发明涉及一种制备聚合物的方法，所述聚合物包括聚合并接枝到以弹性体形式聚合的丙烯酸，苯乙烯和/或乙烯单体上的氯乙烯单体。

6. 发明授权

US5064934A Thermosetting polyimide schiff base resins, their preparation and their applications 失效
标题翻译：热固性聚酰亚胺席夫碱树脂，其制备及应用
公开(公告)号：US5064934A
公开(公告)日：1991-11-12
申请号：US502275
申请日：1990-04-02
申请人： Regis Mercier , Thierry Pascal , Bernard Sillion
发明人： Regis Mercier , Thierry Pascal , Bernard Sillion
IPC分类号： C07D209/48 , C08F38/00
CPC分类号： C07D209/48 , C08F38/00
摘要： Thermosetting Schiff base resins, their preparation and their applicationsre described.These thermosetting Schiff base resins can be defined as responding to the general formula: ##STR1## Radicals Ar.sub.1, Ar.sub.2 and Ar.sub.3 are chosen so that the softening temperature of the resins is less than about 150.degree. C.The resins can be prepared by direct condensation of an ethynyl benzaldehyde or acetophenone on a telechelic diamine oligomer obtained by reaction of a diamine containing flexibilizing groups on a derivative of benzhydrol tetracarboxylic acid. These Schiff base resins can be used by bulk thermal polymerization particularly to prepare adhesives or composite matrices.
摘要翻译：描述了热固性席夫碱树脂及其制备及其应用。这些热固性希夫碱树脂可以定义为响应于以下通式：选择Ar1，Ar2和Ar3的自由基，使得树脂的软化温度低于约150℃。树脂可以通过直接冷凝通过在二苯甲醇四羧酸的衍生物上使含有柔性基团的二胺反应得到的遥爪二胺低聚物上的乙炔基苯甲醛或苯乙酮。这些席夫碱树脂可以通过本体热聚合使用，特别是制备粘合剂或复合基质。

7. 发明申请

US20050084230A1 Polymers based on CTFE/VCA/HFP or TFE/VCA/HFP 审中-公开
标题翻译：基于CTFE / VCA / HFP或TFE / VCA / HFP的聚合物
公开(公告)号：US20050084230A1
公开(公告)日：2005-04-21
申请号：US10847963
申请日：2004-05-18
申请人： Thierry Pascal , Bernard Boutevin , Georges Kostov , Alain Rousseau , Jerome Alric , Jerome Fournier
发明人： Thierry Pascal , Bernard Boutevin , Georges Kostov , Alain Rousseau , Jerome Alric , Jerome Fournier
IPC分类号： G02B6/00 , C08F210/02 , C08F214/00 , C08F234/02
CPC分类号： C08F234/02 , C08F214/00
摘要： A subject-matter of the invention is a copolymer comprising at least 3 units, P1, P2 and P3, with the following general formulae: with X1, X2 and X3, which are identical or different, taken from the group of atoms consisting of H, F, Cl and Br; with R1 taken from the group of atoms consisting of H, F, Cl and Br; with R2 a carbonaceous group comprising from 1 to 10 partially or completely fluorinated carbon atoms; with Y1 and Y2, which are identical or different, taken either from the group of atoms consisting of H, F, Cl and Br or from the family of the carbonaceous groups comprising from 1 to 10 carbon atoms; with Y3 a carbonyl group or a divalent carbonaceous group; the content of P2 unit in the copolymer being between 30 and 70 mol % for respectively a content of P1 and P3 units in the copolymer of between 70 and 30 mol % and the weight-average molar mass (Mw) of the said copolymer being between 103 and 106 g/mol. Preferably, the copolymer is of CTFE/VCA/HFP or TFE/VCA/HFP type.
摘要翻译：本发明的主题是包含至少3个单元的共聚物，P1，P2和P3，具有以下通式：X 1，X 2和X 2 相同或不同的取代自H，F，Cl和Br组成的原子团; 其中R 1取自H，F，Cl和Br组成的原子团; R 2是含有1至10个部分或完全氟化的碳原子的碳质基团; Y 1和Y 2相同或不同，取自H，F，Cl和Br组成的原子团或来自碳质物质的族包含1至10个碳原子的基团; 具有Y 3或X 2的羰基或二价碳质基团; 共聚物中P2单元的含量分别为30-70mol％，共聚物中P1和P3单元的含量为70-30mol％，所述共聚物的重均摩尔质量（Mw）介于 10 3和106μg/ mol。优选共聚物为CTFE / VCA / HFP或TFE / VCA / HFP型。

8. 发明申请

US20110077342A1 METHOD FOR THE MULTI-STEP PREPARATION OF HALOGEN-CONTAINING COMPOSITE LATEX HAVING ASSOCIATIVE GROUPS 审中-公开
标题翻译：具有相关组合的含有氢的复合材料的多步法制备方法
公开(公告)号：US20110077342A1
公开(公告)日：2011-03-31
申请号：US12995768
申请日：2009-05-11
申请人： Manuel Hidalgo , Thierry Pascal
发明人： Manuel Hidalgo , Thierry Pascal
IPC分类号： C08L13/02 , C08L19/02 , C09J113/02 , C09J119/02
CPC分类号： C08F259/00 , C08F2/20 , C08F2/22 , C08F14/06 , C08F259/04 , C08F259/08 , C08L51/003 , C09D5/02 , C08F2/16 , C08F2/18 , C08L2666/02
摘要： “The invention relates to a method for preparing a composite latex, including(a) a first step of free radical emulsion or microsuspension polymerization or copolymerization, leading to the production of a first polymer latex, and(b) a second step of free radical microsuspension, emulsion, or suspension polymerization or copolymerization in the presence of the first polymer latex obtained in the first step (a), characterized in that the first polymer forming the latex obtained in step (a) is a halogen-containing vinyl polymer and the polymer formed in step (b) is an associative copolymer, preferably compatible with the halogen-containing vinyl polymer, which contains units from a first monomer (A) and units from a second monomer (B) having at least one associative group; however the nature of both polymers are capable of being reversed. The invention also relates to a latex or polymer suspension obtained by said method and to a polymer composition obtained from the latter, as well as to the use of said latex, from said suspension or said polymer composition, for manufacturing rigid or plasticized materials.”
摘要翻译： “本发明涉及一种制备复合胶乳的方法，包括（a）自由基乳液或微悬浮聚合或共聚的第一步骤，导致制备第一聚合物胶乳，和（b）第二步自由基在第一步骤（a）中获得的第一聚合物胶乳存在下进行微悬浮，乳液或悬浮聚合或共聚反应，其特征在于，形成步骤（a）中获得的胶乳的第一聚合物是含卤乙烯基聚合物，在步骤（b）中形成的聚合物是优选与含卤素的乙烯基聚合物相容的缔合共聚物，其含有来自第一单体（A）的单元和具有至少一个缔合基团的第二单体（B）的单元; 然而，两种聚合物的性质都能够被逆转。本发明还涉及通过所述方法获得的胶乳或聚合物悬浮液和由后者获得的聚合物组合物，以及所述悬浮液或所述聚合物组合物用于制造刚性或增塑材料的所述胶乳的用途。

9. 发明申请

US20110065860A1 METHOD FOR PREPARING A BLEND OF HALOGENATED POLYMER AND OF COPOLYMER BEARING ASSOCIATIVE GROUPS 审中-公开
标题翻译：制备聚合物共聚物和共聚物轴承相关组合物的方法
公开(公告)号：US20110065860A1
公开(公告)日：2011-03-17
申请号：US12991220
申请日：2009-05-05
申请人： Manuel Hidalgo , Thierry Pascal
发明人： Manuel Hidalgo , Thierry Pascal
IPC分类号： C08L27/06 , C08F114/06
CPC分类号： C08J3/16 , C08F2/24 , C08J2327/06 , C08J2333/06 , C08L27/06 , C08L33/14 , C08L2666/04
摘要： The present invention relates to a method of preparing a polymer resin based on a halogenated vinyl polymer and a copolymer bearing associative groups, comprising the steps that consist in forming a latex of each of these polymers, blending said latices, then isolating and drying the polymers contained in said latices in order to form a pulverulent resin. The present invention also relates to said resin, to a pulverulent composition containing said resin, and also to the use of this composition for manufacturing rigid or plasticized materials.
摘要翻译：本发明涉及一种制备基于卤代乙烯基聚合物和携带缔合基团的共聚物的聚合物树脂的方法，其包括以下步骤：形成这些聚合物中的每一种的胶乳，混合所述胶乳，然后分离和干燥聚合物包含在所述胶乳中以形成粉状树脂。本发明还涉及所述树脂，含有所述树脂的粉状组合物，以及该组合物用于制造刚性或增塑材料的用途。

10. 发明授权

US4508639A Polymers containing heterocycles and aromatic nuclei, and conductive organic materials made from such polymers 失效
标题翻译：含有杂环和芳香核的聚合物，以及由这些聚合物制成的导电有机材料
公开(公告)号：US4508639A
公开(公告)日：1985-04-02
申请号：US497234
申请日：1983-05-23
申请人： Marcel Camps , Alain Douillard , Jean-Claude Dubois , Maryse Gazard , Jean-Pierre Montheard , Thierry Pascal , Gerard Seytre
发明人： Marcel Camps , Alain Douillard , Jean-Claude Dubois , Maryse Gazard , Jean-Pierre Montheard , Thierry Pascal , Gerard Seytre
IPC分类号： C08K3/00 , C08G61/00 , C08G61/10 , C08G61/12 , C08K3/02 , C08K3/16 , C08L65/00 , H01B1/12 , H01M4/60 , C08G75/00 , C08G83/00
CPC分类号： C08G61/123 , H01B1/127 , H01G11/48 , H01M4/60 , Y02E60/13
摘要： The polymer material is made from a first monomer and from a second monomer. The first monomer Ar includes at least one aromatic nucleus and the second monomer is a five links conjugated heterocyclic ring. The polymer material has the following general chemical formula: ##STR1## in which: X represents the group constituted by sulphur and selenium; R.sub.1 and R.sub.2 are chosen from the group constituted by hydrogen, and by the alkyl, alkoxyl, and hydroxyl groups; and n is the degree of polymerization. Such materials can be made conductive by adding a doping agent, and they can then be used for manufacturing electrodes, junctions, Schottky barriers, etc.
摘要翻译：聚合物材料由第一单体和第二单体制成。第一单体Ar包括至少一个芳香核，第二单体是五链共轭杂环。聚合物材料具有以下一般化学式：其中：X表示硫和硒构成的基团; R1和R2选自氢，烷基，烷氧基和羟基构成的基团; n为聚合度。这样的材料可以通过添加掺杂剂而导电，然后它们可以用于制造电极，结，肖特基势垒等。

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