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1. 发明授权

US10082228B2 Cross-linked polyethylene pipe 有权
公开(公告)号：US10082228B2
公开(公告)日：2018-09-25
申请号：US13127036
申请日：2009-10-30
申请人： Anneli Pakkanen , Magnus Palmlöf , Jeroen Oderkerk
发明人： Anneli Pakkanen , Magnus Palmlöf , Jeroen Oderkerk
IPC分类号： B32B1/08 , B29C47/00 , B29C35/08 , F16L9/12 , F16L11/04
CPC分类号： F16L9/12 , F16L11/04 , Y10T428/139
摘要： A cross-linked polyethylene pipe comprising an ethylene polymer with a density of at least 948 kg/m3 obtained by polymerization with a single-site catalyst and having a shear thinning index SHI2.7/210 of less than 10; and wherein said pipe has a pressure test at 4.8 MPa and 95° C. of at least 500 h and at 12.4 MPa and 20° C. of at least 500 h.

2. 发明授权

US08530580B2 Polymer compositions having improved homogeneity and odour, a method for making them and pipes made thereof 有权
标题翻译：具有改进的均匀性和气味的聚合物组合物，制造它们的方法和由其制成的管
公开(公告)号：US08530580B2
公开(公告)日：2013-09-10
申请号：US12995978
申请日：2009-05-25
申请人： Mats Bäckman , Carl-Gustaf Ek , Anneli Pakkanen , Magnus Palmlöf
发明人： Mats Bäckman , Carl-Gustaf Ek , Anneli Pakkanen , Magnus Palmlöf
IPC分类号： C08L23/08 , C08F4/6592
CPC分类号： C08L23/06 , C08L23/0815 , C08L2205/02 , Y10T428/139 , C08L2666/06
摘要： The present invention deals with polymer compositions suitable for making pipes. The compositions comprise a multimodal copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms wherein the multimodal ethylene copolymer has a density of from 924 to 960 kg/m3, a melt index MFR5 of from 0.5 to 6.0 g/10 min, a melt index MFR2 of from 0.1 to 2.0 g/10 min and a shear thinning index SHI2.7/210 of from 2 to 50. The compositions further have a level of volatile compounds of at most 100 ppm by weight and/or a homogeneity rating of at most 3. In addition the multimodal copolymer comprises: (A) from 35 to 60% by weight, based on the combined amount of components (A) and (B), of a low molecular weight ethylene polymer selected from ethylene homopolymer and a copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms and having a weight average molecular weight of from 5000 to 100000 g/mol and a density of from 945 to 975 kg/m3; and (B) from 40 to 65% by weight, based on the combined amount of components (A) and (B), of a high molecular weight copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms and having a weight average molecular weight of from 100000 to 1000000 g/mol and a density of from 890 to 935 kg/m3.
摘要翻译：本发明涉及适于制造管道的聚合物组合物。组合物包含乙烯和一种或多种具有4至10个碳原子的α-烯烃的多峰共聚物，其中多峰乙烯共聚物的密度为924至960kg / m 3，熔体指数MFR 5为0.5至6.0g / 10分钟，熔体指数MFR 2为0.1至2.0g / 10min，剪切稀化指数SHI2.7 / 210为2至50.组合物还具有至多100重量ppm的挥发性化合物和/ 或均一性等级至多为3.另外，多峰共聚物包含：（A）35至60重量％，基于组分（A）和（B）的组合量，选择低分子量乙烯聚合物来自乙烯均聚物和乙烯与一种或多种具有4至10个碳原子的α-烯烃的共聚物，其重均分子量为5000至100000g / mol，密度为945至975kg / m 3; 和（B）40至65重量％，基于组分（A）和（B）的组合量，乙烯和一种或多种具有4至10个碳原子的α-烯烃的高分子量共聚物和重均分子量为100000〜1000000g / mol，密度为890〜935kg / m 3。

3. 发明授权

US08557924B2 Polymer compositions and pressure-resistant pipes made therefrom 有权
标题翻译：由其制成的聚合物组合物和耐压管
公开(公告)号：US08557924B2
公开(公告)日：2013-10-15
申请号：US12995604
申请日：2009-05-25
申请人： Mats Bäckman , Carl-Gustaf Ek , Anneli Pakkanen , Magnus Palmlöf
发明人： Mats Bäckman , Carl-Gustaf Ek , Anneli Pakkanen , Magnus Palmlöf
IPC分类号： C08L23/04 , C08L23/08 , C08F4/6592
CPC分类号： F16L9/12 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2314/06 , Y10T137/0318 , Y10T428/139 , C08L2666/06
摘要： The present invention deals with polymer compositions suitable for making pipes. The compositions comprise a multimodal copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms wherein the multimodal ethylene copolymer has a density of from 924 to 935 kg/m3, a melt index MFR5 of from 0.5 to 6.0 g/10 min, a melt index MFR2 of from 0.1 to 2.0 g/10 min and a shear thinning index SHI2.7/210 of from 2 to 50. In addition the multimodal copolymer comprises: (A) from 30 to 70% by weight, based on the combined amount of components (A) and (B), of a low molecular weight ethylene polymer selected from ethylene homopolymer and a copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms and having a weight average molecular weight of from 5000 to 100000 g/mol and a density of from 945 to 975 kg/m3; and (B) from 30 to 70% by weight, based on the combined amount of components (A) and (B), of a high molecular weight copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms and having a weight average molecular weight of from 100000 to 1000000 g/mol and a density of from 890 to 929 kg/m3.
摘要翻译：本发明涉及适于制造管道的聚合物组合物。组合物包含乙烯和一种或多种具有4至10个碳原子的α-烯烃的多峰共聚物，其中多峰乙烯共聚物的密度为924至935kg / m 3，熔体指数MFR 5为0.5至6.0g / 10分钟，熔体指数MFR 2为0.1至2.0g / 10min，剪切稀化指数SHI2.7 / 210为2至50.此外，多峰共聚物包含：（A）30至70重量％基于组分（A）和（B）的组合量，选自乙烯均聚物和乙烯与一种或多种具有4至10个碳原子并且具有重均分子的α-烯烃的共聚物的低分子量乙烯聚合物分子量为5000至100000g / mol，密度为945至975kg / m 3; 和（B）30至70重量％，基于组分（A）和（B）的组合量，乙烯和一种或多种具有4至10个碳原子的α-烯烃的高分子量共聚物和重均分子量为100000〜1000000g / mol，密度为890〜929kg / m 3。

4. 发明申请

US20110108121A1 Polymer Compositions and Pressure-Resistant Pipes Made Therefrom 有权
标题翻译：聚合物组合物和耐压管道
公开(公告)号：US20110108121A1
公开(公告)日：2011-05-12
申请号：US12995604
申请日：2009-05-25
申请人： Mats Backman , Carl-Gustaf Ek , Anneli Pakkanen , Magnus Palmlöf
发明人： Mats Backman , Carl-Gustaf Ek , Anneli Pakkanen , Magnus Palmlöf
IPC分类号： F17D1/00 , C08F10/14 , C08F10/04 , C08L23/20 , C08L23/24 , B32B1/08
CPC分类号： F16L9/12 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2314/06 , Y10T137/0318 , Y10T428/139 , C08L2666/06
摘要： The present invention deals with polymer compositions suitable for making pipes. The compositions comprise a multimodal copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms wherein the multimodal ethylene copolymer has a density of from 924 to 935 kg/m3, a melt index MFR5 of from 0.5 to 6.0 g/10 min, a melt index MFR2 of from 0.1 to 2.0 g/10 min and a shear thinning index SHI27/210 of from 2 to 50. In addition the multimodal copolymer comprises: (A) from 30 to 70% by weight, based on the combined amount of components (A) and (B), of a low molecular weight ethylene polymer selected from ethylene homopolymer and a copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms and having a weight average molecular weight of from 5000 to 100000 g/mol and a density of from 945 to 975 kg/m3; and (B) from 30 to 70% by weight, based on the combined amount of components (A) and (B), of a high molecular weight copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms and having a weight average molecular weight of from 100000 to 1000000 g/mol and a density of from 890 to 929 kg/m3.
摘要翻译：本发明涉及适于制造管道的聚合物组合物。组合物包含乙烯和一种或多种具有4至10个碳原子的α-烯烃的多峰共聚物，其中多峰乙烯共聚物的密度为924至935kg / m 3，熔体指数MFR 5为0.5至6.0g / 10分钟，熔体指数MFR 2为0.1至2.0g / 10min，剪切稀化指数SHI27 / 210为2至50.此外，多峰共聚物包含：（A）30至70重量％，基于选自乙烯均聚物和乙烯与一种或多种具有4至10个碳原子并且具有重均分子量的α-烯烃的共聚物的低分子量乙烯聚合物的组分（A）和（B）的组合量为5000至100000g / mol，密度为945至975kg / m 3; 和（B）30至70重量％，基于组分（A）和（B）的组合量，乙烯和一种或多种具有4至10个碳原子的α-烯烃的高分子量共聚物和重均分子量为100000〜1000000g / mol，密度为890〜929kg / m 3。

5. 发明申请

US20120128912A1 POLYMER COMPOSITION FOR CROSSLINKED PIPES 审中-公开
标题翻译：交联管的聚合物组合物
公开(公告)号：US20120128912A1
公开(公告)日：2012-05-24
申请号：US13322261
申请日：2010-05-20
申请人： Carl-Gustaf Ek , Jeroen Oderkerk , Magnus Palmlöf , Tua Sundholm
发明人： Carl-Gustaf Ek , Jeroen Oderkerk , Magnus Palmlöf , Tua Sundholm
IPC分类号： B32B1/08 , C08F210/08 , C08J3/28 , C08F210/02 , C08F210/14 , C08F8/00
CPC分类号： F16L9/127 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , Y10T428/139 , C08L2666/06
摘要： The invention is directed to a use of a polymer composition comprising an ethylene polymer for producing a crosslinked pipe, a process for producing a crosslinked pipe and to a crosslinked pipe comprising a crosslinked polymer composition which comprises a crosslinked ethylene polymer.
摘要翻译：本发明涉及包含乙烯聚合物的聚合物组合物用于制备交联管的用途，一种制备交联管的方法和一种包含交联聚合物组合物的交联管的用途，所述交联聚合物组合物包含交联的乙烯聚合物。

6. 发明授权

US08519034B2 Polyethylene composition for water pipes with improved chlorine resistance 有权
标题翻译：具有改善耐氯性能的水管聚乙烯组合物
公开(公告)号：US08519034B2
公开(公告)日：2013-08-27
申请号：US13120929
申请日：2009-12-17
申请人： Magnus Palmlöf , Jeroen Oderkerk
发明人： Magnus Palmlöf , Jeroen Oderkerk
IPC分类号： C08K5/15 , C08K5/1545 , C08K5/13 , C07C37/14 , C09G1/04
CPC分类号： C08K5/13 , C08K5/1545 , C08L23/02
摘要： The present invention is directed to the use of compound (A) and compound (B) in a polyethylene composition for increasing the lifetime of a pipe made of said polyethylene composition which is in permanent contact with chlorinated water, wherein compound (A) has the following formula (I): wherein—R6, R7 and R8 independently are non-substituted or substituted aliphatic or aromatic hydrocarbyl radicals which may comprise OH-groups, X1, X2, and X3 independently are H or OH, with the proviso that at least one of X1, X2, and X3 is OH, and the entire molecule does not comprise an ester group; wherein compound (B) has the following formula (II): wherein R1, R2, R3, R4 and R5 independently are H, or non-substituted or substituted aliphatic or aromatic hydrocarbyl radicals which may comprise heteroatoms, and wherein the base resin of said polyethylene composition consists of a polyethylene homo- or copolymer.
摘要翻译：本发明涉及在聚乙烯组合物中使用化合物（A）和化合物（B）），以增加由与氯化水永久接触的所述聚乙烯组合物制成的管的使用寿命，其中化合物（A）具有下式（I）：其中-R 6，R 7和R 8分别是可以包含OH-基团的未取代或取代的脂族或芳族烃基，X 1，X 2和X 3独立地是H或OH，条件是至少 X1，X2和X3之一是OH，整个分子不包含酯基; 其中化合物（B）具有下式（II）：其中R 1，R 2，R 3，R 4和R 5独立地是H或可以包含杂原子的未取代或取代的脂族或芳族烃基，并且其中所述聚乙烯组合物由聚乙烯均聚物或共聚物组成。

7. 发明授权

US09562631B2 Polymer composition for crosslinked articles 有权
标题翻译：用于交联物品的聚合物组合物
公开(公告)号：US09562631B2
公开(公告)日：2017-02-07
申请号：US13322287
申请日：2010-05-20
申请人： Carl-Gustaf Ek , Magnus Palmlöf , Floran Prades
发明人： Carl-Gustaf Ek , Magnus Palmlöf , Floran Prades
IPC分类号： C08J3/24 , C08K5/14 , C08L23/04 , F16L9/12 , C08L23/08 , C08L23/06 , C08F2/38 , C08F220/06 , C08F220/18
CPC分类号： F16L9/12 , C08F2/38 , C08F220/06 , C08F220/18 , C08J3/24 , C08J2323/04 , C08K5/14 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2314/02 , C08L2666/06
摘要： The invention is directed to a use of a polymer composition comprising an ethylene polymer for producing a crosslinked article, a process for producing a crosslinked article and to a crosslinked article comprising a crosslinked polymer composition which comprises a crosslinked ethylene polymer.
摘要翻译：本发明涉及包含乙烯聚合物的聚合物组合物用于制备交联物品的用途，用于制备交联物品的方法和包含交联聚合物组合物的交联物品的用途，所述交联聚合物组合物包含交联的乙烯聚合物。

8. 发明申请

US20140069547A1 COATING COMPOSITION 有权
标题翻译：涂料组合物
公开(公告)号：US20140069547A1
公开(公告)日：2014-03-13
申请号：US14116091
申请日：2012-05-04
申请人： Tuomas Noopila , Erik Eriksson , Magnus Palmlöf , Jari Häönen , Michiel Bergstra , Leif Leiden , Martin Anker , Siw Bodil Fredriksen
发明人： Tuomas Noopila , Erik Eriksson , Magnus Palmlöf , Jari Häönen , Michiel Bergstra , Leif Leiden , Martin Anker , Siw Bodil Fredriksen
IPC分类号： C09D7/12 , F16L9/14
CPC分类号： C09D7/1216 , C09D7/61 , C09D123/0815 , F16L9/14 , F16L58/1027 , F16L58/1045 , C08L23/06 , C08L2203/18 , C08L2205/025 , C08L2205/035 , C08L2308/00
摘要： Coating composition comprising an ethylene copolymer containing not more than 5 mole-% comonomer, whereby the fraction of the ethylene copolymer having a molecular weight of 300 000 g/mol-600 000 g/mol has a methyl branching of more than 4.0 Methyl per 1000 C as determined by SEC/FT-IR analysis.
摘要翻译：包含含有不超过5摩尔％共聚单体的乙烯共聚物的涂料组合物，其中分子量为300000g / mol-600000g / mol的乙烯共聚物的分数具有大于4.0的甲基支链通过SEC / FT-IR分析测定。

9. 发明申请

US20110250374A1 ARTICLE COATED WITH A COMPOSITION COMPRISING POLYETHYLENE PREPARED WITH A SINGLE SITE CATALYST 有权
标题翻译：包含用单一催化剂制备聚乙烯的组合物的物品
公开(公告)号：US20110250374A1
公开(公告)日：2011-10-13
申请号：US13140342
申请日：2009-11-25
申请人： Bjöm Voigt , Martin Anker , Magnus Palmlöf , Solveig Johansson
发明人： Bjöm Voigt , Martin Anker , Magnus Palmlöf , Solveig Johansson
IPC分类号： B32B1/08 , C09D123/06 , B05D3/10 , C09D123/08
CPC分类号： C09D123/04 , C08L23/04 , C08L23/06 , C09D123/06 , Y10T428/1393 , C08L2666/06
摘要： The present invention relates to an article coated with a composition comprising (A) an ethylene homo- or copolymer resin which has been prepared by using a single-site catalyst further characterized in that component (A) has an MFR21, measured according to ISO 1133 at 190° C. and under a load of 21.6 kg, from 0.01 to 20 g/10 min. The present invention further relates to an article coated with a composition comprising (A) an ethylene homo- or copolymer resin which has been prepared by using a single-site catalyst further characterized in that component (A) has an impact strength at −40° C. of at least 80 kJ/m2 in a Charpy notched test according to ISO ISO 179-1/1eA:2000 with a pendulum energy of 15 J. The invention is furthermore directed to the use of the composition for the coating of an article.
摘要翻译：本发明涉及涂覆有组合物的制品，该组合物包含（A）通过使用单中心催化剂制备的乙烯均聚物或共聚物树脂，其特征在于组分（A）具有根据ISO 1133测量的MFR 21 在190℃和21.6kg的负荷下，0.01至20g / 10min。本发明还涉及涂覆有组合物的制品，该组合物包含（A）通过使用单中心催化剂制备的乙烯均聚物或共聚物树脂，其特征在于组分（A）的冲击强度在-40℃ 在根据ISO ISO 179-1 / 1eA：2000的摆锤能量为15J的夏比缺口试验中为至少80kJ / m 2的C.在本发明中还涉及该组合物用于制品的涂覆。

10. 发明授权

US09017784B2 Pipe having improved high temperature resistance 有权
标题翻译：管道具有改善的耐高温性能
公开(公告)号：US09017784B2
公开(公告)日：2015-04-28
申请号：US12517107
申请日：2007-11-21
申请人： Magnus Palmlöf , Solveig Johansson , Markku Vähteri
发明人： Magnus Palmlöf , Solveig Johansson , Markku Vähteri
IPC分类号： B29C47/00 , C08L23/06 , C08L23/08
CPC分类号： C08L23/06 , C08L23/08 , C08L23/0815 , C08L2205/02 , C08L2314/06 , Y10T428/139 , C08L2666/06
摘要： The present invention relates to a pipe made of a polyethylene composition comprising a polyethylene base resin, which comprises c. an ethylene copolymer as fraction (A), and d. an ethylene homo- or copolymer as fraction (B), with fraction (A) having a lower molecular weight than fraction (B), wherein the polyethylene base resin is obtainable in a polymerization process in which a single-site catalyst (SSC) is used in the polymerization of at least one of fractions (A) and (B), the base resin having (i) a density of below 940 kg/m3, and (ii) a MFR5 at 190° C./5.00 kg of at least 0.20 g/10 min, and the polyethylene composition having a time to failure of at least 250 h measured according to ISO 1167 at 95° C. and 4.3 MPa.
摘要翻译：本发明涉及一种由包含聚乙烯基树脂的聚乙烯组合物制成的管，其包括c。作为级分（A）的乙烯共聚物，和d。乙烯均聚物或共聚物作为级分（B），其中级分（A）的分子量低于级分（B），其中聚乙烯基树脂可以在其中单位点催化剂（SSC）为用于聚合组分（A）和（B）中的至少一种，基础树脂具有（i）密度低于940kg / m 3，和（ii）190℃下的MFR 5 / 至少0.20g / 10min，聚乙烯组合物根据ISO 1167在95℃和4.3MPa下具有至少250小时的破坏时间。

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