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    • 7. 发明授权
    • Nanocomposite material for the production of index of refraction gradient films
    • 用于生产折射率梯度膜的纳米复合材料
    • US07473721B2
    • 2009-01-06
    • US10500194
    • 2003-01-03
    • Takamasa HaradaFumio KitaAndreas ZimmermannUlrike DellwoMartin MennigPeter W. OliveiraHelmut SchmidtHeike Schneider
    • Takamasa HaradaFumio KitaAndreas ZimmermannUlrike DellwoMartin MennigPeter W. OliveiraHelmut SchmidtHeike Schneider
    • C08K9/12
    • C08L83/06C08K3/013C09D183/06G02B1/04G03H2260/12C08L2666/04
    • The invention relates to solid or gel-type nanocomposite material which can be polymerised, containing a) 4.9 95.9 wt. % of a soluble polymer; b) 4-95 wt. % of a partially or totally condensed silane selected from the group of epoxyalkoxysilanes, alkoxysilanes and alkylalkoxysilanes, the silane having an inorganic condensation degree of between 33-100% and an organic conversion degree of between 0-95%; c) 0-60 wt. % of an acrylate; d) 0.1-50 wt. % of surface modified nanometric particles selected from the group of oxides, sulphides, selenides, tellurides, halogenides, carbides, arsenides, antimonides, nitrides, phosphides, carbonates, carboxylates, phosphates, sulphates, silicates, titanates, zirconates, aluminates, stannates, plumbates and a mixed oxides; e) 0-50 wt.-% of a plasticizer; f) 0-5 wt. % of a thermal or photochemical cross-linking initiator, sensitizer, auxiliary wetting agent, adhesive agent, antioxidant, stabiliser, coloring agent, photochrome material and thermochrome material in relation to the total weight (dry weight) of the nanocomposite material.
    • 本发明涉及可以聚合的固体或凝胶型纳米复合材料,其包含a)4.9 95.9wt。 %的可溶性聚合物; b)4-95wt。 选自环氧烷氧基硅烷,烷氧基硅烷和烷基烷氧基硅烷的部分或全部冷凝的硅烷的%,硅烷的无机缩合度在33-100%之间,有机转化度在0-95%之间; c)0-60wt。 %的丙烯酸酯; d)0.1-50wt。 选自氧化物,硫化物,硒化物,碲化物,卤化物,碳化物,砷化物,锑化物,氮化物,磷化物,碳酸盐,羧酸盐,磷酸盐,硫酸盐,硅酸盐,钛酸盐,锆酸盐,铝酸盐,锡酸盐,铅酸铅的表面改性纳米颗粒的% 和混合氧化物; e)0-50重量%的增塑剂; f)0-5wt。 相对于纳米复合材料的总重量(干重),热或光化学交联引发剂,敏化剂,辅助润湿剂,粘合剂,抗氧化剂,稳定剂,着色剂,感光材料和热变色材料的%。