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1. 发明申请

US20060088494A1 Method of treating hair with form memory polymers 审中-公开
标题翻译：用形态记忆聚合物处理毛发的方法
公开(公告)号：US20060088494A1
公开(公告)日：2006-04-27
申请号：US10510873
申请日：2003-04-10
申请人： Andreas Lendlein , Werner Grasser , Karl Kratz , Thomas Krause , Axel Kalbfleisch , Gunther Lang , Jurgen Allwohn , Johannes Burghaus , Gerhard Sendelbach , Detlef Mattinger , Stefan Uhl
发明人： Andreas Lendlein , Werner Grasser , Karl Kratz , Thomas Krause , Axel Kalbfleisch , Gunther Lang , Jurgen Allwohn , Johannes Burghaus , Gerhard Sendelbach , Detlef Mattinger , Stefan Uhl
IPC分类号： A61K8/81
CPC分类号： A61K8/86 , A61K8/046 , A61K8/416 , A61K8/8152 , A61K8/8182 , A61K8/88 , A61K2800/594 , A61Q5/06
摘要： A method for the provision of a recallable hair transformation using shape-memory polymers is disclosed. In this respect a composition which comprises a macromer or prepolymer which is cross-linkable to a shape-memory polymer is applied onto the hair and the hair is brought into a defined (permanent) shape and subsequently the permanent shape is fixed by means of the chemical cross-linking of the macromer or prepolymer under formation of the shape-memory polymer. The macromer or prepolymer contains segments which are cross-linkable by means of chemical bonds as well as thermoplastic segments which are not chemically cross-linkable. The shape-memory polymers do possess at least one transition temperature TTrans. In addition to the permanent shape of a hairdo a second (temporary) shape can be impressed. Furthermore, disclosed is a method for the recovery of a previously programmed, permanent shape of a hairdo, which has been temporarily brought into a temporary form or which has been deformed in a different manner.
摘要翻译：公开了使用形状记忆聚合物提供可召回的毛发转化的方法。在这方面，将包含可与形状记忆聚合物交联的大分子单体或预聚物的组合物施加到头发上，并将头发置于限定（永久）形状中，随后将永久形状通过形成记忆聚合物形成的大分子单体或预聚物的化学交联。大分子单体或预聚物含有通过化学键可交联的区段以及不可化学交联的热塑性区段。形状记忆聚合物确实具有至少一个转变温度T Trans。除了发型的永久形状之外，可以印象第二（暂时）形状。此外，公开了一种用于回收已经暂时形成或以不同方式变形的发型的先前编程的永久形状的方法。

2. 发明申请

US20060140892A1 Method for generation of memory effects on hair 审中-公开
标题翻译：产生对头发的记忆效应的方法
公开(公告)号：US20060140892A1
公开(公告)日：2006-06-29
申请号：US10511019
申请日：2003-04-10
申请人： Andreas Lendlein , Werner Grasser , Karl Kratz , Thomas Krause , Exel Kalbfleisch , Gunther Lang , Jurgen Allwohn , Johannes Burghaus , Gerhard Sendelbach , Detlef Mattinger , Stefan Uhl
发明人： Andreas Lendlein , Werner Grasser , Karl Kratz , Thomas Krause , Exel Kalbfleisch , Gunther Lang , Jurgen Allwohn , Johannes Burghaus , Gerhard Sendelbach , Detlef Mattinger , Stefan Uhl
IPC分类号： A61K8/81
CPC分类号： A61K8/046 , A61K8/416 , A61K8/8152 , A61K8/8182 , A61K8/86 , A61K8/88 , A61K2800/594 , A61Q5/06
摘要： Disclosed is a method for achieving a recallable hair deformation. A composition is applied onto hair, comprising at least one active agent, which, alone or in combination with further compounds, is able, after application to the hair and after carrying out the treatment of hair in accordance with the present invention, to provide a shape memory effect. The hair is brought into a defined (permanent) shape and the permanent shape is subsequently fixed by means of inducing a chemical or physical change of the applied agents, wherein after a desired or undesired deformation, the memory shape of the initial memory shape may be recovered by means of a physical stimulation. Suitable active agents are for example macromers which may be cross-linked to provide shape memory polymers, wherein the permanent shape is fixed by means of the chemical cross-linking of the macromer, providing a shape memory polymer, which possesses at least one transition temperature Ttrans. Suitable active agents are also shape memory polymers, which have hard segments which may be cross-linked by physical interactions having a first transition temperature T′trans, which preferably is at least 10° C. above room temperature, and soft segments having a second transition temperature which preferably is at least 10° C. below T′trans. In addition to the permanent hairdo, a second (temporary) shape can be impressed. Furthermore, disclosed is a method for the recovery of a once programmed permanent hairdo, which has been brought into a temporary shape or which has been deformed in any other way.
摘要翻译：公开了一种实现可召回的头发变形的方法。将组合物施用到头发上，其包含至少一种活性剂，其单独或与其他化合物组合可以在施用到毛发之后以及在进行根据本发明的毛发处理之后提供一种形状记忆效应。头发被带入限定的（永久）形状，并且随后通过引起所施加的药剂的化学或物理变化来固定永久形状，其中在所需或不期望的变形之后，初始记忆形状的记忆形状可以是通过物理刺激恢复。合适的活性剂是例如可以交联以提供形状记忆聚合物的大分子单体，其中永久形状通过大分子单体的化学交联固定，提供形状记忆聚合物，其具有至少一个转变温度 T 。合适的活性剂也是形状记忆聚合物，其具有可通过物理相互作用交联的硬链段，其具有第一转变温度T'反式，优选在室温以上至少10℃ ，和具有第二转变温度的软链段，其优选在T'反式以下至少10℃。除了永久发型，第二（暂时）形状可以印象深刻。此外，公开了一种用于恢复已经被暂时形成或以任何其它方式变形的一次编程的永久性发型的方法。

3. 发明申请

US20050244353A1 Method for achieving shape memory effects on hair by combining shape memory polymers with cationic active ingredients 审中-公开
标题翻译：通过将形状记忆聚合物与阳离子活性成分组合来实现头发形状记忆效应的方法
公开(公告)号：US20050244353A1
公开(公告)日：2005-11-03
申请号：US10510889
申请日：2003-04-10
申请人： Andreas Lendlein , Gunther Lang , Karl Kratz , Thomas Krause , Axel Kalbfleisch , Jurgen Allwohn , Johannes Burghaus , Gerhard Sendelbach , Angelika Beyer , Detlef Mattinger , Stefen Uhl , Susanne Birkel , Anja Duchscherer , Tareq Ali Abdull Hasson , Hong-Yan Jiang , Simone Morsheim , Yasmin Ghazlan
发明人： Andreas Lendlein , Gunther Lang , Karl Kratz , Thomas Krause , Axel Kalbfleisch , Jurgen Allwohn , Johannes Burghaus , Gerhard Sendelbach , Angelika Beyer , Detlef Mattinger , Stefen Uhl , Susanne Birkel , Anja Duchscherer , Tareq Ali Abdull Hasson , Hong-Yan Jiang , Simone Morsheim , Yasmin Ghazlan
IPC分类号： A61K8/00 , A61K8/04 , A61K8/40 , A61K8/41 , A61K8/64 , A61K8/73 , A61K8/81 , A61K8/86 , A61K8/88 , A61K8/89 , A61Q5/00 , A61Q5/04 , A61Q5/06 , A61K7/06
CPC分类号： A61K8/046 , A61K8/416 , A61K8/8152 , A61K8/8182 , A61K8/86 , A61K8/88 , A61K2800/594 , A61Q5/06
摘要： Disclosed is a method for achieving a recallable hair deformation. A composition is applied onto hair, comprising at least one first active principle or active complex, which, alone or in combination with further compounds, is able, after application to the hair and after carrying out the treatment of hair in accordance with the present invention, to provide a shape memory effect. The composition comprises at least one second active principle, which is a cationic agent. The hair is brought into a defined (permanent) shape and the permanent shape is subsequently fixed by means of inducing a chemical or physical change of the applied agents, wherein after a desired or undesired deformation, the memory shape of the initial memory shape may be recovered by means of a physical stimulation. In addition to the permanent hairdo, a second (temporary) shape can be impressed. Furthermore, disclosed is a method for the recovery of a once programmed permanent hairdo, which has been brought into a temporary shape or which has been deformed in any other way.
摘要翻译：公开了一种实现可召回的头发变形的方法。将组合物施用到头发上，其包含至少一种第一活性成分或活性复合物，其单独或与其它化合物组合可以在施用到毛发之后以及在进行根据本发明的毛发处理之后，提供形状记忆效应。该组合物包含至少一种第二活性成分，其为阳离子剂。头发被带入限定的（永久）形状，并且随后通过引起所施加的药剂的化学或物理变化来固定永久形状，其中在所需或不期望的变形之后，初始记忆形状的记忆形状可以是通过物理刺激恢复。除了永久发型，第二（暂时）形状可以印象深刻。此外，公开了一种用于恢复已经被暂时形成或以任何其它方式变形的一次编程的永久性发型的方法。

4. 发明申请

US20070275020A1 Method For Hair Treatment With Shape Memory Polymers 审中-公开
标题翻译：用形状记忆聚合物治疗头发的方法
公开(公告)号：US20070275020A1
公开(公告)日：2007-11-29
申请号：US10566232
申请日：2004-07-14
申请人： Andreas Lendlein , Axel Kalbfleisch , Anja Duchscherer , Angelika Beyer , Susanne Graner , Tareq Ali Abdulla Hasson , Thomas Krause , Karl Kratz , Hong-Yan Jiang , Simone Moersheim , Yasmin Ghazlan
发明人： Andreas Lendlein , Axel Kalbfleisch , Anja Duchscherer , Angelika Beyer , Susanne Graner , Tareq Ali Abdulla Hasson , Thomas Krause , Karl Kratz , Hong-Yan Jiang , Simone Moersheim , Yasmin Ghazlan
IPC分类号： A61K8/85
CPC分类号： A61Q5/06 , A61K8/90 , A61K2800/54 , C08G63/06 , C08G63/664 , C08G2261/126
摘要： A method for producing a retrievable hairstyling using shape memory polymers is described. Here a composition is applied to the hair, said composition containing a shape memory polymer P or a macromer M that can be cross-linked to a shape memory polymer, the hair is arranged into a given (permanent) shape and said permanent shape is then fixed by means of chemical cross-linking of the macromer M under the formation of a shape memory polymer and/or under physical cross-linking of the polymer P. The polymer P and the macromer M are formed from block copolymers, each of which comprises at least a first block and at least two additional blocks. The first block is a polyol and is selected from polyethers, dimerdiol and derivatives derived therefrom, as well as from polyesters of dicarboxylic acids with diols. The additional blocks are polyesters of hydroxycarboxylic acids or their lactones. The macromer M possesses cross-linkable regions, as well as thermoplastic regions that are not cross-linkable and, after cross-linking, has a transition temperature of Ttrans. The polymer P has a hard segment with a first transition temperature T′trans, which is above room temperature, and a soft segment with a second transition temperature Ttrans which is lower than T′trans.
摘要翻译：描述了使用形状记忆聚合物生产可回收发型的方法。这里将组合物施加到头发上，所述组合物含有可以与形状记忆聚合物交联的形状记忆聚合物P或大分子单体M，将毛发排列成给定（永久）形状，然后所述永久形状在形成记忆聚合物的形成和/或在物理交联聚合物P的情况下通过大分子单体M的化学交联固定。聚合物P和大分子单体M由嵌段共聚物形成，每个嵌段共聚物包含至少第一块和至少两个附加块。第一个嵌段是多元醇，选自聚醚，二聚二醇及其衍生物，以及二羧酸与二醇的聚酯。附加的嵌段是羟基羧酸或其内酯的聚酯。大分子单体M具有可交联的区域以及不可交联的热塑性区域，并且在交联之后具有T T的转变温度。聚合物P具有高于室温的第一转变温度T'>反式的硬链段和低于第二转变温度T lt反式的软链段比T'。

5. 发明申请

US20080311050A1 Method for Producing Shape Memory Effects in Hair in Connection with Hydrophobic Active Ingredients 审中-公开
标题翻译：在与疏水性活性成分相关的头发中产生形状记忆效应的方法
公开(公告)号：US20080311050A1
公开(公告)日：2008-12-18
申请号：US10566230
申请日：2004-07-14
申请人： Andreas Lendlein , Tareq Ali Abdulla Hasson , Karl Kratz , Leonid Kuper , Thomas Krause , Axel Kalbfleisch , Anja Duchscherer , Angelika Beyer
发明人： Andreas Lendlein , Tareq Ali Abdulla Hasson , Karl Kratz , Leonid Kuper , Thomas Krause , Axel Kalbfleisch , Anja Duchscherer , Angelika Beyer
IPC分类号： A61K8/06 , A61K9/107 , A61Q5/04
CPC分类号： A61K8/891 , A61K8/8152 , A61K8/86 , A61K8/87 , A61K8/892 , A61K2800/54 , A61Q5/06
摘要： A method for achieving a retrievable hair restyling is described. Here a composition is applied to the hair, said composition containing at least one first active ingredient or active ingredient complex which can provide a shape memory effect by itself or in combination with other substances after being applied to the hair and after the performance of the treatment of the hair according to the invention. The composition additionally contains at least one second active ingredient, namely a hydrophobic substance with a water solubility of ≦5 percent by weight at 20° C. The hair is arranged into a given (permanent) shape and said permanent shape is then fixed by inducing a chemical or physical modification of the applied active ingredients, wherein after a wanted or unwanted deformation of the shape memory, the original shape memory can be restored by means of a physical stimulation. In addition to the permanent hairstyle, a second (temporary) shape can be impressed. A method is also described for restoring a previously programmed permanent hairstyle that was temporarily transformed into a temporary shape or that was otherwise deformed.
摘要翻译：描述了一种用于实现可回收毛发修复的方法。这里将组合物施用于毛发，所述组合物含有至少一种第一活性成分或活性成分复合物，其可以在施用于毛发后自身或与其它物质组合提供形状记忆效应，并且在进行处理之后的根据本发明的头发。该组合物另外含有至少一种第二活性成分，即在20℃下水溶性为<= 5重量％的疏水性物质。毛发排列成给定（永久）形状，然后将所述永久形状固定在诱导所施加的活性成分的化学或物理改性，其中在形状记忆体的想要或不期望的变形之后，可以通过物理刺激来恢复原始形状记忆。除了永久发型之外，还可以留下第二（暂时）形状。还描述了一种用于恢复临时转变成临时形状或以其他方式变形的先前编程的永久性发型的方法。

6. 发明申请

US20070009465A1 Cosmetic compositions comprising polyol/polyester block polymers 审中-公开
标题翻译：包含多元醇/聚酯嵌段聚合物的化妆品组合物
公开(公告)号：US20070009465A1
公开(公告)日：2007-01-11
申请号：US10566231
申请日：2004-07-14
申请人： Andreas Lendlein , Tareq Ali Abdulla Hasson , Karl Kratz , Simone Moersheim , Yasmin Ghazlan , Susanne Birkel , Thomas Krause , Axel Kalbfleisch , Andrea Walter , Susanne Granner
发明人： Andreas Lendlein , Tareq Ali Abdulla Hasson , Karl Kratz , Simone Moersheim , Yasmin Ghazlan , Susanne Birkel , Thomas Krause , Axel Kalbfleisch , Andrea Walter , Susanne Granner
IPC分类号： A61K8/84
CPC分类号： C08G63/664 , A61K8/90 , A61K2800/54 , A61Q5/06 , C08G2261/126
摘要： A cosmetic composition is described, said composition having a content of a block polymer having at least a first block, which block is a polyol selected from polyethers, dimerdiol, derivatives derived from dimerdiol and polyesters of dicarboxylic acids with diols and at least two additional blocks, which blocks are polyesters of hydroxycarboxylic acids or lactones thereof.
摘要翻译：描述了一种化妆品组合物，所述组合物具有至少具有第一嵌段的嵌段聚合物的含量，该嵌段是选自聚醚，二聚二醇，衍生自二聚二醇的衍生物和二羧酸与二醇的聚酯和至少两个附加嵌段的多元醇，哪些嵌段是羟基羧酸或其内酯的聚酯。

7. 发明申请

US20090163664A1 BLENDS OF SHAPE MEMORY POLYMERS WITH THERMOPLASTIC POLYMERS 审中-公开
标题翻译：具有热塑性聚合物的形状记忆聚合物的混合物
公开(公告)号：US20090163664A1
公开(公告)日：2009-06-25
申请号：US12095256
申请日：2006-11-28
申请人： Andreas Lendlein , Ali Abdullah Tareq Hasson , Hongyan Jiang , Karl Kratz , Peter F.W. Simon , Jürgen Schulte , Steffen Kelch , Birgit Schnitter
发明人： Andreas Lendlein , Ali Abdullah Tareq Hasson , Hongyan Jiang , Karl Kratz , Peter F.W. Simon , Jürgen Schulte , Steffen Kelch , Birgit Schnitter
IPC分类号： C08G63/08
CPC分类号： C08L53/00 , B29C61/003 , C08G18/4266 , C08G18/73 , C08G2261/126 , C08G2280/00 , C08J3/005 , C08L23/06 , C08L27/06 , C08L67/04 , C08L75/06 , C08L101/00 , C08L2201/00 , C08L2666/06 , C08L2666/24 , C08L2666/02 , C08L2666/04 , C08L2666/18
摘要： The present invention concerns blends comprising at least one shape memory polymer and at least one thermoplastic polymer, wherein this thermoplastic polymer does not show shape memory properties. The present invention furthermore concerns methods for preparing such blends and the use of these blends in various applications, including additional products, household equipment etc.
摘要翻译：本发明涉及包含至少一种形状记忆聚合物和至少一种热塑性聚合物的共混物，其中该热塑性聚合物不显示形状记忆性质。本发明还涉及制备这种共混物的方法以及这些共混物在各种应用中的应用，包括额外的产品，家用设备等。

8. 发明授权

US06852825B2 Polyester urethanes 有权
标题翻译：聚酯聚氨酯
公开(公告)号：US06852825B2
公开(公告)日：2005-02-08
申请号：US10418615
申请日：2003-04-17
申请人： Andreas Lendlein , Annette Schmidt , Karl Kratz , Jürgen Schulte
发明人： Andreas Lendlein , Annette Schmidt , Karl Kratz , Jürgen Schulte
IPC分类号： C08G18/40 , C08G18/42 , C08G18/48 , C08G18/73 , A61K47/34 , C08J9/04 , C08J9/28 , C08L75/06
CPC分类号： C08G18/73 , C08G18/4018 , C08G18/4269 , C08G18/4854 , C08G2101/00 , C08G2280/00
摘要： The present invention relates to polyester urethanes comprising polypentadecalactone segments. These polyester urethanes do show good properties which may be adjusted in a controlled manner. In preferred embodiments the polyester urethanes display additionally polycaprolactone segments. Such polymer may show shape memory effects.
摘要翻译：本发明涉及包含多聚十六烷内酯片段的聚酯聚氨酯。这些聚酯聚氨酯确实显示出可以以可控方式调节的良好性能。在优选的实施方案中，聚酯聚氨酯另外显示出聚己内酯片段。这种聚合物可以显示形状记忆效应。

9. 发明申请

US20130053276A1 Method and kit for testing various selected materials and/or surface structures for culturing cells 有权
标题翻译：用于测试培养细胞的各种选择的材料和/或表面结构的方法和试剂盒
公开(公告)号：US20130053276A1
公开(公告)日：2013-02-28
申请号：US13508540
申请日：2010-09-24
申请人： Frank Klein , Thomas Weigel , Karl Kratz , Friedrich Jung , Bernhard Hiebl , Andreas Lendlein , Karola Lützow , Andreas Kurtz , Petra Reinke , Andy Römhild
发明人： Frank Klein , Thomas Weigel , Karl Kratz , Friedrich Jung , Bernhard Hiebl , Andreas Lendlein , Karola Lützow , Andreas Kurtz , Petra Reinke , Andy Römhild
IPC分类号： C40B30/06 , C40B40/00
CPC分类号： G01N33/5008
摘要： The present invention relates to a method for testing different selected materials and/or surface structures for the culture of cells and/or microorganisms, said method comprising the following steps: i) providing a plurality of different selected materials and/or surface structures to be tested in the form of beaker-shaped inserts, wherein the beaker-shaped inserts are dimensioned in such a way that a beaker-shaped insert can be inserted in a substantially accurately fitting manner into a well of a multiwell plate suitable for cell culture, wherein each beaker-shaped insert has walls, a base, and an opening in the side facing away from the base, wherein the walls and base of the beaker-shaped inserts are liquid-tight, and wherein each beaker-shaped insert has a selected material and/or a selected surface structure, at least on the inner face of the base; ii) inserting the beaker-shaped inserts into wells of multiwell plates of appropriate dimensioning so that the outer face of the beaker base points towards the inner face of the base of a well of the multiwell plate; iii) culturing the cells in the lumen of the beaker-shaped inserts, and to a kit for carrying out this method.
摘要翻译：本发明涉及一种用于测试用于培养细胞和/或微生物的不同选择的材料和/或表面结构的方法，所述方法包括以下步骤：i）提供多种不同的选择的材料和/或表面结构为以烧杯形插入物的形式进行测试，其中烧杯形插入件的尺寸设计使得可将烧杯形插入件以基本上精确适合的方式插入适合于细胞培养的多孔板的孔中，其中每个烧杯形插件具有壁，基部和在背离基部的一侧的开口，其中烧杯形插入件的壁和底部是液密的，并且其中每个烧杯形插入件具有选定的材料和/或选定的表面结构，至少在基底的内表面上; ii）将所述烧杯形插入物插入适合尺寸的多孔板的孔中，使得所述烧杯基底的外表面指向所述多孔板的孔的底部的内表面; iii）在烧杯形插入物的内腔中培养细胞，以及用于实施该方法的试剂盒。

10. 发明申请

US20080305545A1 Shape memory thermoplastics and polymer networks for tissue engineering 审中-公开
标题翻译：形状记忆热塑性塑料和组织工程的聚合物网络
公开(公告)号：US20080305545A1
公开(公告)日：2008-12-11
申请号：US12081104
申请日：2008-04-10
申请人： Andreas Lendlein , Ralf Knischka , Karl Kratz
发明人： Andreas Lendlein , Ralf Knischka , Karl Kratz
IPC分类号： C12N5/06
CPC分类号： A61L27/58 , A61L27/18 , A61L27/38 , B29C61/06 , B29K2995/006 , C08L67/04 , C08L2201/12 , C08L101/00
摘要： Methods and compositions are described herein for reconstruction of different functional tissues. Dissociated cells, differentiated cells, adult mesenchymal stem cells or embryonic stem cells are seeded on a scaffold. The scaffold will consist of a biocompatible, biodegradable shape memory (“SM”) polymers. In addition bioactive substances may be incorporated in the scaffold. Thermoplastic as well as thermoset materials with SM-effect can be used. The shape memory effect will be applied as an interactive link between the cells and the used polymeric scaffold. The degradation kinetics as well as shape memory transition temperature will be tailored by adjusting to monomer ratios of the co-oligomers. The shape memory effect will be used to create a degradation or release of bioactive substances on demand, induce forces on seeded cells or induce proliferation and differentiation of cells.
摘要翻译：本文描述了用于重建不同功能组织的方法和组合物。将解离的细胞，分化细胞，成体间充质干细胞或胚胎干细胞接种在支架上。支架将由生物相容的，可生物降解的形状记忆（“SM”）聚合物组成。此外，生物活性物质可以并入支架中。可以使用热塑性以及具有SM效应的热固性材料。形状记忆效应将被用作细胞和使用的聚合物支架之间的交互式连接。降解动力学以及形状记忆转变温度将通过调节共低聚物的单体比来调整。形状记忆效应将用于根据需要产生生物活性物质的降解或释放，诱导种子细胞的力或诱导细胞的增殖和分化。

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