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    • 9. 发明申请
    • Process for the preparation of alkylarylsulfonates
    • 烷基芳基磺酸盐的制备方法
    • US20060167308A1
    • 2006-07-27
    • US11385773
    • 2006-03-22
    • Heiko MaasThomas NarbeshuberMichael Roper
    • Heiko MaasThomas NarbeshuberMichael Roper
    • C07C309/00
    • C07C303/32C07C2/08C07C2/66C07C6/04C07C303/06C11D1/22C11D11/04C07C309/31C07C11/02C07C11/10C07C11/107C07C15/107
    • The invention relates to a process for the preparation of alkylarylsulfonates by a) reaction of a C4-olefin mixture over a metathesis catalyst for the preparation of an olefin mixture comprising 2-pentene and/or 3-hexene, and optional removal of 2-pentene and/or 3-hexene, b) dimerization of the 2-pentene and/or 3-hexene obtained in stage a) over a dimerization catalyst to give a mixture containing C10-12-olefins, and optional removal of the C10-12-olefins, c) reaction of the C10-12-olefin mixtures obtained in stage b) with an aromatic hydrocarbon in the presence of an alkylating catalyst to form alkylaromatic compounds, where, prior to the reaction, additional linear olefins may be added, d) sulfonation of the alkylaromatic compounds obtained in stage c), and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, linear alkylbenzenes may additionally be added, e) optional mixing of the alkylarylsulfonates obtained in stage d) with linear alkylarylsulfonates.
    • 本发明涉及一种通过以下步骤制备烷基芳基磺酸盐的方法:a)在复分解催化剂上反应C 4/4烯烃混合物,用于制备包含2-戊烯和/或3-己烯的烯烃混合物 并且任选地除去2-戊烯和/或3-己烯,b)在二级催化剂中在阶段a)中获得的2-戊烯和/或3-己烯的二聚化,得到含有C 10-12 并且任选地除去C 10-12 - 烯烃,c)在步骤b)中获得的C 10-12α-烯烃混合物的反应, 在烷基化催化剂存在下用芳族烃形成烷基芳族化合物,其中在反应之前可以加入另外的直链烯烃,d)在步骤c)中获得的烷基芳族化合物的磺化,并中和得到烷基芳基磺酸盐,其中 在磺化之前,可以另外加入直链烷基苯,e)任选地将在sta中获得的烷基芳基磺酸盐 ge d)与直链烷基芳基磺酸盐。