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1. 发明申请

US20070004903A1 Method for the separation of monomers from a composition containing a monomer 审中-公开
标题翻译：从含有单体的组合物中分离单体的方法
公开(公告)号：US20070004903A1
公开(公告)日：2007-01-04
申请号：US10551050
申请日：2004-03-26
申请人： Andreas Hoff , Axel Kobus , Dennis Thong , Ralf Goedecke , Martin Roos , Torsten Balduf
发明人： Andreas Hoff , Axel Kobus , Dennis Thong , Ralf Goedecke , Martin Roos , Torsten Balduf
IPC分类号： C08F6/00
CPC分类号： C07C51/50 , C07C57/04
摘要： The present invention concerns a process for separation of a monomer including at least one double bond, hereafter referred to as “monomer,” in particular (meth)acrylic acid, from a composition Z including this monomer and at least one impurity different to the monomer, including the steps of bringing into contact of the composition Z with an additive by forming a separation phase. The additive has a melting point of at most about 150° C. and a vapour pressure at a temperature of 20° C. of at most about 1 mbar. The monomer is then separated from the separation phase. A device for producing a monomer, the use of additives in the separation of a monomer from a monomer-comprising composition, the monomer obtainable by the process according to the invention, chemical products comprising the monomer as well as the use of the monomer in or for production of chemical products.
摘要翻译：本发明涉及从包含该单体的组合物Z和至少一种与单体不同的杂质分离包含至少一个双键的单体（以下称为“单体”，特别是（甲基）丙烯酸）的方法）包括通过形成分离相使组合物Z与添加剂接触的步骤。该添加剂的熔点至多约150℃，蒸气压在20℃至多约1毫巴。然后将单体与分离相分离。用于制备单体的装置，在从单体组合物分离单体中使用添加剂的方法，通过本发明的方法获得的单体，包含单体的化学产物以及单体在或用于生产化学产品。

2. 发明授权

US07495129B2 Purification of a monomer by extraction with a phase former and crystallization 失效
标题翻译：通过用相变器萃取并结晶来纯化单体
公开(公告)号：US07495129B2
公开(公告)日：2009-02-24
申请号：US10541647
申请日：2004-01-13
申请人： Torsten Balduf , Stefan Nordhoff , Dennis Thong Yu-Chiang , Axel Kobus , Martin Roos
发明人： Torsten Balduf , Stefan Nordhoff , Dennis Thong Yu-Chiang , Axel Kobus , Martin Roos
IPC分类号： C07C51/42
CPC分类号： C07C51/43 , C07C51/48 , C07C57/04
摘要： The invention concerns a process for purification of an acidic monomer having a double bond, as well as a device for synthesis of an acidic monomer having a double bond, a process for producing an acidic monomer having a double bond, an acid monomer having a double bond and obtainable by this process, fibers, formed bodies, films, foams, superabsorbent polymers and other special polymers based on or containing this acidic monomer, the use of this acidic monomer in or for producing fibers, formed bodies, films, foams, superabsorbent polymers or other special polymers.
摘要翻译：本发明涉及一种用于纯化具有双键的酸性单体的方法，以及用于合成具有双键的酸性单体的方法，制备具有双键的酸性单体的方法，具有双键的酸单体的方法通过该方法获得的纤维，成形体，膜，泡沫，超吸收性聚合物和基于或含有该酸性单体的其它特殊聚合物，该酸性单体在纤维，成形体，膜，泡沫，超吸收剂中的用途聚合物或其他特殊聚合物。

3. 发明申请

US20060116532A1 Purification of a monomer by extraction with a phase-separating agent and crystallisation 失效
标题翻译：通过用分相剂萃取并结晶纯化单体
公开(公告)号：US20060116532A1
公开(公告)日：2006-06-01
申请号：US10541647
申请日：2004-01-13
申请人： Torsten Balduf , Stefan Nordhoff , Dennis Thong Yu-Chiang , Axel Kobus , Martin Roos
发明人： Torsten Balduf , Stefan Nordhoff , Dennis Thong Yu-Chiang , Axel Kobus , Martin Roos
IPC分类号： C07C51/42
CPC分类号： C07C51/43 , C07C51/48 , C07C57/04
摘要： The invention concerns a process for purification of an acidic monomer having a double bond, as well as a device for synthesis of an acidic monomer having a double bond, a process for producing an acidic monomer having a double bond, an acid monomer having a double bond and obtainable by this process, fibres, formed bodies, films, foams, superabsorbent polymers and other special polymers based on or containing this acidic monomer, the use of this acidic monomer in or for producing fibres, formed bodies, films, foams, superabsorbent polymers or other special polymers.
摘要翻译：本发明涉及一种用于纯化具有双键的酸性单体的方法，以及用于合成具有双键的酸性单体的方法，制备具有双键的酸性单体的方法，具有双键的酸单体的方法通过该方法获得的纤维，成形体，膜，泡沫，超吸收性聚合物和基于或含有该酸性单体的其它特殊聚合物，该酸性单体在纤维，成形体，膜，泡沫，超吸收剂中的用途聚合物或其他特殊聚合物。

4. 发明授权

US09533933B2 Process for preparing cyclododecanone 有权
标题翻译：制备环十二酮的方法
公开(公告)号：US09533933B2
公开(公告)日：2017-01-03
申请号：US14815014
申请日：2015-07-31
申请人： Kevin Micoine , Ralf Meier , Juergen Herwig , Martin Roos , Harald Haeger , Luca Cameretti , Jens Doering
发明人： Kevin Micoine , Ralf Meier , Juergen Herwig , Martin Roos , Harald Haeger , Luca Cameretti , Jens Doering
IPC分类号： C07C45/51 , C07C45/58 , C07D201/04 , B01J23/44 , C07C45/82 , C07C249/04 , C07D225/02 , C07D301/12 , C08G69/16 , C07C29/52 , C07C45/00 , C07C45/28 , C07C49/413
CPC分类号： C07C45/512 , B01J23/44 , C07C29/52 , C07C45/002 , C07C45/28 , C07C45/58 , C07C45/82 , C07C49/413 , C07C249/04 , C07D201/04 , C07D225/02 , C07D301/12 , C08G69/16 , C07C35/205
摘要： Cyclododecanone (CDON) is prepared by epoxidizing cyclododecene (CDEN) to epoxycyclododecane (CDAN epoxide), and rearranging the CDAN epoxide to CDON to obtain a mixture comprising said CDON and CDEN, wherein CDEN is separated from the CDON-containing mixture and sent to the epoxidation to CDAN epoxide in step a.
摘要翻译：通过环环十二碳烯（CDEN）环氧环十二烷（CDAN环氧化物）制备环十二烷酮（CDON），并将CDAN环氧化物重排为CDON，得到包含所述CDON和CDEN的混合物，其中CDEN与含CDON的混合物分离并送至在步骤a中对CDAN环氧化物进行环氧化。

5. 发明授权

US08399658B2 Method for isolation of laurolactam from a laurolactam synthesis process stream 有权
标题翻译：从十二内酰胺合成工艺流中分离十二内酰胺的方法
公开(公告)号：US08399658B2
公开(公告)日：2013-03-19
申请号：US12951289
申请日：2010-11-22
申请人： Axel Hengstermann , Ralf Meier , Daniel Demicoli , Martin Roos , Bernd Guenzel , Frank Huebner
发明人： Axel Hengstermann , Ralf Meier , Daniel Demicoli , Martin Roos , Bernd Guenzel , Frank Huebner
IPC分类号： C07D201/16
CPC分类号： C07D225/02
摘要： A process for purifying laurolactam by means of integrated connection of distillation and crystallization is provided. The crystallization is performed as a solution or melt crystallization. The process reduces thermal stress applied to the laurolactam stream and improved yields are obtained. Raw materials are recovered and recycled in the production sequence.
摘要翻译：提供了通过蒸馏和结晶的整体连接来提纯月桂内酰胺的方法。结晶作为溶液或熔融结晶进行。该方法降低了施加到月桂内酰胺流上的热应力，并获得了提高的产率。原料按生产顺序回收和回收。

6. 发明申请

US20120245375A1 SYNTHESIS OF ALPHA,OMEGA-DICARBOXYLIC ACIDS AND ESTERS THEREOF FROM UNSATURATED FATTY ACID DERIVATIVES 失效
标题翻译：从不饱和脂肪酸衍生物合成ALPHA，欧米二酸和其酯
公开(公告)号：US20120245375A1
公开(公告)日：2012-09-27
申请号：US13424548
申请日：2012-03-20
申请人： Peter HANNEN , Harald Haeger , Martin Roos
发明人： Peter HANNEN , Harald Haeger , Martin Roos
IPC分类号： C07C67/44
CPC分类号： C07C67/333 , C07C51/285 , C07C51/34 , C07C51/373 , C07C67/313 , C07C69/48 , C07C69/716 , C07C53/126 , C07C59/147 , C07C55/02
摘要： A process for preparing an alpha, omega-dicarboxylic acid or an ester thereof, which includes (a) subjecting at least one unsaturated fatty acid or fatty acid derivative to ozonolysis to obtain an ozonolysis reaction mixture; and (b) oxidizing the ozonolysis reaction mixture with an oxidizing agent in the presence of an acid catalyst to obtain an oxidized reaction mixture comprising at least one alpha, omega-dicarboxylic acid or ester; wherein the process is performed using a solvent and the acid catalyst has a pKa of less than or equal to zero, as measured at 25° C.
摘要翻译：一种制备α，ω-二羧酸或其酯的方法，其包括（a）使至少一种不饱和脂肪酸或脂肪酸衍生物进行臭氧分解以获得臭氧分解反应混合物; 和（b）在酸催化剂存在下用氧化剂氧化臭氧分解反应混合物，得到包含至少一种α，ω-二羧酸或酯的氧化反应混合物; 其中所述方法使用溶剂进行，并且所述酸催化剂的pKa小于或等于零，如在25℃下测量的。

7. 发明申请

US20110124855A1 METHOD FOR ISOLATION OF LAUROLACTAM FROM A LAUROLACTAM SYNTHESIS PROCESS STREAM 有权
标题翻译：用于从LAUROLACTAM合成过程流分离LAUROLACTAM的方法
公开(公告)号：US20110124855A1
公开(公告)日：2011-05-26
申请号：US12951289
申请日：2010-11-22
申请人： Axel HENGSTERMANN , Ralf Meier , Daniel Demicoli , Martin Roos , Bernd Guenzel , Frank Huebner
发明人： Axel HENGSTERMANN , Ralf Meier , Daniel Demicoli , Martin Roos , Bernd Guenzel , Frank Huebner
IPC分类号： C07D225/02
CPC分类号： C07D225/02
摘要： A process for purifying laurolactam by means of integrated connection of distillation and crystallization is provided. The crystallization is performed as a solution or melt crystallization. The process reduces thermal stress applied to the laurolactam stream and improved yields are obtained. Raw materials are recovered and recycled in the production sequence.
摘要翻译：提供了通过蒸馏和结晶的整体连接来提纯月桂内酰胺的方法。结晶作为溶液或熔融结晶进行。该方法降低了施加到月桂内酰胺流上的热应力，并获得了提高的产率。原料按生产顺序回收和回收。

8. 发明申请

US20110015434A1 METHOD FOR PRODUCING DODECA-2,10-DIENE-1,12-DICARBOXYLIC ACID OR 1,12-DODECANE-DICARBOXYLIC ACID BY WAY OF RING-OPENING CROSS METATHESIS (ROCM) OF CYCLOOCTENE WITH ACRYLIC ACID 有权
标题翻译：通过旋转开环方式通过丙烯酸的环己烷的交联（ROCM）方法生产多卡那-2,10-二烯-1,12-二羧酸或1,12-十二烷基二羧酸的方法
公开(公告)号：US20110015434A1
公开(公告)日：2011-01-20
申请号：US12922807
申请日：2009-04-16
申请人： Peter Hannen , Martin Roos , Harald Haeger
发明人： Peter Hannen , Martin Roos , Harald Haeger
IPC分类号： C07C51/36 , C07C51/347
CPC分类号： C07C51/353 , C07C51/36 , C07C51/43 , C07C51/44 , C07C57/13 , C07C55/21
摘要： The invention relates to a method for producing 1,2-dodeca-2,10-diene diacid and 1,12-dodecanoic acid whereby cyclooctene and acrylic acid are reacted with a ruthenium catalyst by way of a metathesis reaction at high substrate concentrations until the reaction takes place in substance, the resulting unsaturated dicarboxylic acid being precipitated and being hydrated in a second reaction step.
摘要翻译：本发明涉及一种1,2-十二碳-2,10-二烯二酸和1,12-十二烷酸的制备方法，其中环辛烯和丙烯酸通过在高底物浓度下的复分解反应与钌催化剂反应，直到反应发生在物质中，所得的不饱和二羧酸在第二反应步骤中沉淀并水合。

9. 发明授权

US07608738B2 Coammoxidation of ketones 有权
标题翻译：酮的共氧化反应
公开(公告)号：US07608738B2
公开(公告)日：2009-10-27
申请号：US10572594
申请日：2004-08-02
申请人： Juergen Herwig , Martin Roos , Georg Oenbrink , Bernd Guenzel , Dirk Kuppert
发明人： Juergen Herwig , Martin Roos , Georg Oenbrink , Bernd Guenzel , Dirk Kuppert
IPC分类号： C07C251/32 , C07C249/04
CPC分类号： C07C249/04 , C07C2601/14 , C07C2601/20 , C07C251/44
摘要： The present invention relates to a process for the coammoximation, that is to say for the simultaneous ammoximation, of ketones, in particular of cyclic ketones such as cyclododecanone and cyclohexanone. Ammoximation is taken to mean here the preparation of oximes from ketones or aldehydes together with hydrogen peroxide and ammonia and in the presence of a catalyst which essentially consists of silicon, titanium and oxygen, for example titanium silicalite.
摘要翻译：本发明涉及一种用于协同肟化的方法，也就是说用于同时氨基肟化酮，特别是环状酮如环十二烷酮和环己酮。在这里，将肟从酮或醛与过氧化氢和氨一起制备，并且在催化剂的存在下，基本上由硅，钛和氧组成的催化剂（例如钛硅沸石）制备方法。

10. 发明授权

US06422615B1 Closure device with shutting aid 失效
标题翻译：带关闭辅助装置的关闭装置
公开(公告)号：US06422615B1
公开(公告)日：2002-07-23
申请号：US09369042
申请日：1999-08-04
申请人： Martin Roos , Jürgen Ehret
发明人： Martin Roos , Jürgen Ehret
IPC分类号： E05C306
CPC分类号： E05B81/20 , E05B81/21 , E05B83/16 , Y10S292/23 , Y10T292/1047 , Y10T292/1082
摘要： A closure device, especially for vehicle doors, possesses a rotary latch interacting with a closure pin, a releasable ratchet for arresting the door, and a motor-driven shutting aid, which moves the door into the closed position. A problem from safety aspects is activating the shutting aid if fingers or articles are still located between the door and the bodywork. In order to reduce the risk of injury or damage, when the release mechanism is actuated, the force flow between the drive of the shutting aid and the door to be closed is simultaneously mechanically interrupted. As a result of this measure, the rotary latch is immediately released and the door springs open.
摘要翻译：闭合装置，特别是用于车门的闭合装置具有与闭合销相互作用的旋转闩锁，用于阻止门的可释放棘轮以及将门移动到关闭位置的马达驱动的关闭辅助装置。如果手指或物品仍然位于门和车身之间，安全方面的问题是激活关闭辅助。为了减少受伤或损坏的风险，当释放机构被致动时，关闭辅助装置的驱动和被关闭的门之间的力流同时机械地中断。作为这种措施的结果，旋转闩锁立即释放并且门弹簧打开。

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