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    • 2. 发明授权
    • Modification of (co)polymers employing organic peroxides
    • 使用有机过氧化物改性(共)聚合物
    • US5202386A
    • 1993-04-13
    • US703965
    • 1991-05-22
    • Andreas H. HogtJohn MeijerPeter HopeJernej Jelenic
    • Andreas H. HogtJohn MeijerPeter HopeJernej Jelenic
    • C07C409/16C07C409/18C08F8/08
    • C07C409/16C07C407/00C08F8/08
    • Organic (co)polymers, including saturated (co)polymers, are modified by contacting them with an organic peroxide and decomposing the peroxide. Use is made of an organic peroxide having the general formula R--(O--O--CHR.sup.1 --CR.sup.2 .dbd.CR.sup.3 R.sup.4)N, wherein N is 1, 2 or 3; R.sup.1 is H, C.sub.1 -C.sub.4 alkyl or C.sub.2 -C.sub.4 alkylene; R.sup.2, R.sup.3 and R.sup.4 are, independently, H or C.sub.1 -C.sub.4 alkyl; two of the substituents R.sup.1 -R.sup.4 together may form C.sub.3 -C.sub.12 alkylene; and, when N is 1, R is an optionally hydroxyl substituted C.sub.4 -C.sub.18 T.alkyl, P-menth-8-yl, C.sub.5 -C.sub.18 T.alkenyl, 1-vinylcyclohexyl or a group of the formula: --C(CH.sub.3)2--C.sub.6 HJ(5--M)--R.sup.5 (M), wherein M is 0, 1 or 2 and R.sup.5 is isopropenyl or 2-hydroxyisopropyl; when N is 2, R is a C.sub.8 -C.sub.12 alkylene or alkynylene group having a tertiary structure at both ends, or a group having the formula --(C)CH.sub.3)2)2--C.sub.6 H(4--X)--R.sup.5 (X), wherein X is 0 or 1; and when N is 3, R is 1,2,4- or 1,3,5-triisopropylbenzene-alpha, alpha"-triyl, i.a., 3-allylperoxy-3,3-dimethylpropene according to a preferred embodiment the modification is carried out in the presence of a coagent, whereby the advantageous polymer properties, such as adhesion to polar materials, are further enhanced.
    • 包括饱和(共)聚合物在内的有机(共)聚合物通过与有机过氧化物接触并分解过氧化物而被改性。 使用具有通式R-(O-O-CHR 1 -CR 2 = CR 3 R 4)N的有机过氧化物,其中N为1,2或3; R1是H,C1-C4烷基或C2-C4亚烷基; R2,R3和R4独立地是H或C1-C4烷基; 两个取代基R 1 -R 4一起可以形成C 3 -C 12亚烷基; 当N为1时,R为任选羟基取代的C 4 -C 18烷基,P-menth-8-yl,C 5 -C 18 T链烯基,1-乙烯基环己基或下式的基团-C(CH 3) 2-C6HJ(5-M)-R5(M),其中M是0,1或2,R5是异丙烯基或2-羟基异丙基; 当N为2时,R为在两端具有三级结构的C 8 -C 12亚烷基或亚炔基或具有式(C)CH 3)2)2 -C 6 H(4-X)-R 5(X)的基团, 其中X为0或1; 当N为3时,根据优选实施方案,R为1,2,4-或1,3,5-三异丙基苯-α,α“ - 三基,ia,3-烯丙基过氧-3,3-二甲基丙烯, 在助剂的存在下进行,由此有利的聚合物性质,例如对极性材料的粘附性进一步增强。
    • 4. 发明授权
    • Modification of (co)polymers employing organic peroxides
    • 使用有机过氧化物改性(共)聚合物
    • US5037892A
    • 1991-08-06
    • US283676
    • 1988-12-13
    • Andreas H. HogtJohn MeijerPeter HopeJernej Jelenic
    • Andreas H. HogtJohn MeijerPeter HopeJernej Jelenic
    • C07C409/16C07C409/18C08F8/08
    • C08F8/00
    • Organic (co)polymers, including saturated (co)polymers, are modified by contacting them with an organic peroxide and decomposing the peroxide. Use is made of an organic peroxide having the general formula: R--(O--O--CHR.sup.1 --CR.sup.2 .dbd.CR.sup.3 R.sup.4)N, wherein N is 1, 2 or 3; R.sup.1 is H, C.sub.1 -C.sub.4 alkyl or C.sub.2 -C.sub.4 alkylene; R.sup.2, R.sup.3 and R.sup.4 are, independently, H or C.sub.1 -C.sub.4 alkyl; two of the substituents R.sup.1 -R.sup.4 together may form C.sub.3 -C.sub.12 alkylene; and, when N is 1, R is an optionally hydroxyl substituted C.sub.4 -C.sub.18 T.alkyl, P-menth-8-yl, C.sub.5 -C.sub.18 T.alkenyl, 1-vinylcyclohexyl or a group of the formula: --C(CH.sub.3)2--C.sub.6 HJ(5--M)--R.sup.5 (M), wherein M is 0, 1 or 2 and R.sup.5 is isopropenyl or 2-hydroxyisopropyl; when N is 2, R is a C.sub.8 -C.sub.12 alkylene or alkynylene group having a tertiary structure at both ends, or a group having the formula: --(C)CH.sub.3)2)2--C.sub.6 H(4--X)--R.sup.5 (X), wherein X is 0 or 1; and when N is 3, R is 1,2,4-or 1,3,5-triisopropylbenzene-alpha, alpha"-triyl, i.a., 3-allylperoxy-3,3-dimethylpropene according to a preferred embodiment the modification is carried out in the presence of a coagent, whereby the advantageous polymer properties, such as adhesion to polar materials, are further enhanced.