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1. 发明授权

US08440152B2 Process for recovering metals from a stream rich in hydrocarbons and carbonaceous residues 有权
标题翻译：从富含烃和碳质残渣的物流中回收金属的方法
公开(公告)号：US08440152B2
公开(公告)日：2013-05-14
申请号：US13377036
申请日：2010-06-01
申请人： Andrea Bartolini , Ugo Cornaro , Paolo Pollesel , Paul Dominique Oudenne
发明人： Andrea Bartolini , Ugo Cornaro , Paolo Pollesel , Paul Dominique Oudenne
IPC分类号： C22B3/00
CPC分类号： C10G47/26 , B01J23/28 , B01J23/92 , B01J38/02 , B01J38/72 , C10G49/12 , C10G49/22 , C10G2300/1025 , C10G2300/205 , C10G2300/301 , C10G2300/4006 , C10G2300/4081 , C22B3/20 , C22B7/001 , Y02P10/214 , Y02P10/234
摘要： A process for recovering metals from a stream rich in hydrocarbons and carbonaceous residues by means of a treatment section, characterized in that it comprises the following steps: sending said stream to a primary treatment, effected in one or more steps, wherein said stream is treated in the presence of a fluxant agent in a suitable apparatus, at a temperature ranging from 80 to 180° C., preferably from 100 to 160° C., and subjected to liquid/solid separation in order to obtain a clarified product essentially consisting of liquids and a cake (oilcake); possibly subjecting the separated cake to drying, in order to remove the hydrocarbon component having a boiling point lower than a temperature ranging from 300 to 350° C. from the cake; sending the cake, possibly dried, to a secondary thermal treatment comprising: a flameless pyrolysis of the cake effected between 400 and 800° C., preferably between 500 and 670° C.; an oxidation of the pyrolysis residue effected in an oxidizing environment and at temperatures ranging from 400 to 800° C., preferably from 500 to 700° C.
摘要翻译：一种通过处理部分从富含烃和碳质残余物的物流中回收金属的方法，其特征在于其包括以下步骤：将一个或多个步骤中的所述物流送入初级处理，其中所述物流被处理在合适的装置中，在80至180℃，优选100至160℃的温度下，在助流剂存在下进行液/固分离，以获得基本上由液体和蛋糕（油饼）; 可能使分离的饼干经历干燥，以便从饼中除去沸点低于300-350℃的沸点的烃成分; 将可能干燥的蛋糕送到二次热处理中，其包括：在400和800℃之间，优选在500和670℃之间进行无蛋白质的热解。在氧化环境中和在400至800℃，优选500至700℃的温度下进行热解残留物的氧化。

2. 发明申请

US20120134899A1 PROCESS FOR RECOVERING METALS FROM A STREAM RICH IN HYDROCARBONS AND CARBONACEOUS RESIDUES 有权
标题翻译：从碳氢化合物和碳氢化合物中回收金属的方法
公开(公告)号：US20120134899A1
公开(公告)日：2012-05-31
申请号：US13377036
申请日：2010-06-01
申请人： Andrea Bartolini , Ugo Cornaro , Paul Dominique Oudenne , PAOLO POLLESEL
发明人： Andrea Bartolini , Ugo Cornaro , Paul Dominique Oudenne , PAOLO POLLESEL
IPC分类号： C01G1/02
CPC分类号： C10G47/26 , B01J23/28 , B01J23/92 , B01J38/02 , B01J38/72 , C10G49/12 , C10G49/22 , C10G2300/1025 , C10G2300/205 , C10G2300/301 , C10G2300/4006 , C10G2300/4081 , C22B3/20 , C22B7/001 , Y02P10/214 , Y02P10/234
摘要： A process for recovering metals from a stream rich in hydrocarbons and carbonaceous residues by means of a treatment section, characterized in that it comprises the following steps: sending said stream to a primary treatment, effected in one or more steps, wherein said stream is treated in the presence of a fluxant agent in a suitable apparatus, at a temperature ranging from 80 to 180° C., preferably from 100 to 160° C., and subjected to liquid/solid separation in order to obtain a clarified product essentially consisting of liquids and a cake (oilcake); possibly subjecting the separated cake to drying, in order to remove the hydrocarbon component having a boiling point lower than a temperature ranging from 300 to 350° C. from the cake; sending the cake, possibly dried, to a secondary thermal treatment comprising: a flameless pyrolysis of the cake effected between 400 and 800° C., preferably between 500 and 670° C.; an oxidation of the pyrolysis residue effected in an oxidizing environment and at temperatures ranging from 400 to 800° C., preferably from 500 to 700° C.
摘要翻译：一种通过处理部分从富含烃和碳质残余物的物流中回收金属的方法，其特征在于其包括以下步骤：将所述物流送入初级处理，一个或多个步骤进行，其中所述物流被处理在合适的装置中，在80至180℃，优选100至160℃的温度下，在助流剂存在下进行液/固分离，以获得基本上由液体和蛋糕（油饼）; 可能使分离的饼干经历干燥，以便从饼中除去沸点低于300-350℃的沸点的烃成分; 将可能干燥的蛋糕送到二次热处理中，其包括：在400和800℃之间，优选在500和670℃之间进行无蛋白质的热解。在氧化环境中和在400至800℃，优选500至700℃的温度下进行热解残留物的氧化。

3. 发明授权

US08236171B2 Process for improving quality as a fuel of hydrotreated hydrocarbon blends 有权
标题翻译：用于提高作为加氢处理的烃共混物的燃料的质量的方法
公开(公告)号：US08236171B2
公开(公告)日：2012-08-07
申请号：US11480369
申请日：2006-07-05
申请人： Roberto Giardino , Vincenzo Calemma , Ugo Cornaro
发明人： Roberto Giardino , Vincenzo Calemma , Ugo Cornaro
IPC分类号： C10G45/62 , C10G45/64
CPC分类号： B01J35/1061 , B01J21/12 , B01J23/40 , B01J29/7469 , B01J29/7669 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1057 , C10G2300/1044 , C10G2300/1051 , C10G2300/1055 , C10G2300/307 , C10G2300/4018 , C10G2400/04
摘要： A process is described for improving the quality as a fuel of hydrotreated hydrocarbon blends by reaction with hydrogen in the presence of a bifunctional catalytic system comprising one or more metals selected from Pt, Pd, Ir, Ru, Rh and Re, and a silico-aluminate of an acidic nature, selected from a micro-mesoporous silico-alumina and a zeolite belonging to the MTW family. The process of the invention produces an increase in the cetane index and a decrease in the density and T95.
摘要翻译：描述了一种方法，用于在包含一种或多种选自Pt，Pd，Ir，Ru，Rh和Re的金属的双功能催化体系存在下，通过与氢反应，提高作为加氢处理的烃共混物的燃料的质量，酸性的铝酸盐，选自微孔介质硅 - 氧化铝和属于MTW族的沸石。本发明的方法产生十六烷指数的增加和密度的降低以及T95。

4. 发明授权

US08940802B2 Method for optimizing the operation of a hydrocarbon synthesis unit starting from synthesis gas, by controlling the partial pressure of CO 有权
标题翻译：通过控制CO的分压来优化从合成气开始的烃合成单元的操作的方法
公开(公告)号：US08940802B2
公开(公告)日：2015-01-27
申请号：US13377193
申请日：2010-05-18
申请人： Marie Claire Marion , Andrea Tasso , Ugo Cornaro
发明人： Marie Claire Marion , Andrea Tasso , Ugo Cornaro
IPC分类号： C07C1/04 , C10G2/00 , B01J23/75
CPC分类号： C10G2/332 , B01J23/75 , C10G2300/802
摘要： A method is described for optimizing the operation of a reaction section for the synthesis of hydrocarbons from a feed comprising synthesis gas, operated in the presence of a catalyst comprising cobalt, said method comprising the following steps: a) determining the theoretical partial pressure of CO in the reaction section; b) optionally, adjusting the partial pressure of CO determined in step a) to a value of 4 bar or higher; c) determining a new value for the theoretical partial pressure of CO in the reaction section.
摘要翻译：描述了一种用于优化用于从包含合成气的原料合成烃的反应段的操作的方法，所述合成气在包含钴的催化剂存在下操作，所述方法包括以下步骤：a）确定CO的理论分压在反应部分; b）任选地，将步骤a）中测定的CO的分压调节至4巴或更高的值; c）确定反应段中CO的理论分压的新值。

5. 发明申请

US20120129961A1 METHOD FOR OPTIMIZING THE OPERATION OF A HYDROCARBON SYNTHESIS UNIT STARTING FROM SYNTHESIS GAS, BY CONTROLLING THE PARTIAL PRESSURE OF CO 有权
标题翻译：通过控制CO的部分压力来优化从合成气开始的烃合成装置的运行的方法
公开(公告)号：US20120129961A1
公开(公告)日：2012-05-24
申请号：US13377193
申请日：2010-05-18
申请人： Marie Claire Marion , Andrea Tasso , Ugo Cornaro
发明人： Marie Claire Marion , Andrea Tasso , Ugo Cornaro
IPC分类号： C07C1/04
CPC分类号： C10G2/332 , B01J23/75 , C10G2300/802
摘要： A method is described for optimizing the operation of a reaction section for the synthesis of hydrocarbons from a feed comprising synthesis gas, operated in the presence of a catalyst comprising cobalt, said method comprising the following steps: a) determining the theoretical partial pressure of CO in the reaction section; b) optionally, adjusting the partial pressure of CO determined in step a) to a value of 4 bar or higher; c) determining a new value for the theoretical partial pressure of CO in the reaction section.
摘要翻译：描述了一种用于优化用于从包含合成气的原料合成烃的反应段的操作的方法，所述合成气在包含钴的催化剂存在下操作，所述方法包括以下步骤：a）确定CO的理论分压在反应部分; b）任选地，将步骤a）中测定的CO的分压调节至4巴或更高的值; c）确定反应段中CO的理论分压的新值。

6. 发明申请

US20070187295A1 Process for improving the quality as a fuel of hydrotreated hydrocarbon blends 有权
标题翻译：用于提高作为加氢处理的烃共混物的燃料的质量的方法
公开(公告)号：US20070187295A1
公开(公告)日：2007-08-16
申请号：US11480369
申请日：2006-07-05
申请人： Roberto Giardino , Vincenzo Calemma , Ugo Cornaro
发明人： Roberto Giardino , Vincenzo Calemma , Ugo Cornaro
IPC分类号： C10G45/00
CPC分类号： B01J35/1061 , B01J21/12 , B01J23/40 , B01J29/7469 , B01J29/7669 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1057 , C10G2300/1044 , C10G2300/1051 , C10G2300/1055 , C10G2300/307 , C10G2300/4018 , C10G2400/04
摘要： A process is described for improving the quality as a fuel of hydrotreated hydrocarbon blends by reaction with hydrogen in the presence of a bifunctional catalytic system comprising one or more metals selected from Pt, Pd, Ir, Ru, Rh and Re, and a silico-aluminate of an acidic nature, selected from a micro-mesoporous silico-alumina and a zeolite belonging to the MTW family. The process of the invention produces an increase in the cetane index and a decrease in the density and T95.
摘要翻译：描述了一种方法，用于在包含一种或多种选自Pt，Pd，Ir，Ru，Rh和Re的金属的双功能催化体系存在下，通过与氢反应，提高作为加氢处理的烃共混物的燃料的质量，酸性的铝酸盐，选自微孔介质硅 - 氧化铝和属于MTW族的沸石。本发明的方法产生十六烷指数的增加和密度的降低以及T95。

7. 发明授权

US5767166A Process for producing mixtures of methanol and higher alcohols 失效
标题翻译：制备甲醇和高级醇混合物的方法
公开(公告)号：US5767166A
公开(公告)日：1998-06-16
申请号：US732597
申请日：1996-10-15
申请人： Giambattista Antonelli , Ugo Cornaro
发明人： Giambattista Antonelli , Ugo Cornaro
IPC分类号： C07C29/153 , C10L1/02 , C07C1/04
CPC分类号： C07C29/153 , C10L1/02
摘要： Process for producing mixtures of methanol and higher alcohols comprising feeding, into the reaction zone equipped with a catalytic system, H.sub.2, CO and possibly inert products with a molar ratio H.sub.2 /CO of between 0.2 and 10, at a temperature of between 200.degree. and 460.degree. C., at a pressure of between 2,000 and 30,000 KPa, and at a space velocity of between 1,000 and 40,000 GHSV, wherein the catalytic system corresponds to the following empirical formula: Zn.sub.x Cr.sub.y O.sub.t +z%M.sub.2 O wherein the x/y ratio is greater than 0.5 and less than 1, t is what is necessary for satisfying the valence with which the various elements appear in the catalyst, M is an alkaline metal selected from potassium and cesium, z, representing the percentage of alkaline oxide of the final catalyst, when the metal is potassium, is between 0.01 and 8 and, when the metal is cesium, between 0.01 and 20.6.
摘要翻译：制备甲醇和高级醇的混合物的方法，包括在装有催化体系的反应区中，在H 2 / CO和H 2 / CO摩尔比为0.2至10之间的温度下，在200°和 460℃，压力为2,000至30,000KPa，空间速度为1,000至40,000 GHSV，其中催化体系对应于以下经验式：Zn x CryOt + z％M 2 O其中x / y比为大于0.5且小于1，t是满足各种元素在催化剂中出现的化合价所必需的，M是选自钾和铯的碱金属，z代表最终催化剂的碱性氧化物的百分比当金属为钾时，为0.01〜8，当金属为铯时，为0.01〜20.6。

8. 发明授权

US5600054A Process for the skeleton isomerization of linear olefins 失效
标题翻译：线性烯烃骨架异构化方法
公开(公告)号：US5600054A
公开(公告)日：1997-02-04
申请号：US381062
申请日：1995-01-31
申请人： Roberta Miglio , Ugo Cornaro
发明人： Roberta Miglio , Ugo Cornaro
IPC分类号： B01J21/02 , C07C5/27
CPC分类号： B01J21/02 , C07C5/277
摘要： Process for the skeleton isomerization of linear olefins, preferably n-butenes or n-pentenes, which consists in putting said olefins in contact with a catalyst comprising alumina on whose surface boron oxide is deposited in a quantity which is lower than 2.1.times.10.sup.-4 g/m.sup.2 of the surface of the alumina.
摘要翻译：线性烯烃，优选正丁烯或正戊烯骨架异构化的方法，其包括将所述烯烃与包含氧化铝的催化剂接触，所述催化剂在其表面上沉积氧化硼，其量低于2.1×10 -4 g / m2的氧化铝表面。

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