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1. 发明授权

US4980080A Process of making a cathode material for a secondary battery including a lithium anode and application of said material 失效
标题翻译：制造包括锂阳极的二次电池的阴极材料和所述材料的应用的方法
公开(公告)号：US4980080A
公开(公告)日：1990-12-25
申请号：US359333
申请日：1989-05-31
申请人： Andre Lecerf , Michel Broussely , Jean-Paul Gabano
发明人： Andre Lecerf , Michel Broussely , Jean-Paul Gabano
IPC分类号： C01G53/00 , H01M4/52 , H01M4/525 , H01M10/052 , H01M10/36
CPC分类号： H01M10/052 , C01G51/42 , C01G53/42 , H01M4/525 , C01P2002/54 , C01P2002/72 , C01P2002/74 , C01P2006/40
摘要： A process of making a cathode material for a secondary battery including a lithium anode and application of said material.A process of making a cathode material for a secondary electrochemical battery including a lithium anode, wherein said material corresponds to one of the formulas Li.sub.y Ni.sub.2-y O.sub.2 or LiNi.sub.1-x Co.sub.x O.sub.2, wherein y is a number ranging from 0.84 to 1.22 and x is a number ranging from 0.09 to 0.5, wherein the base is lithium hydroxide, nickel oxide or possibly cobalt oxide, in a powdered form in the desired stoichiometric ratio, and wherein it is heated in air at a temperature ranging from approximately 600.degree. C. to 800.degree. C.
摘要翻译：制造包括锂阳极的二次电池的阴极材料和所述材料的应用的方法。一种制备用于包括锂阳极的二次电化学电池的阴极材料的方法，其中所述材料对应于式Li y Ni 2-y O 2或LiNi 1-x CO 2 O 2之一，其中y为0.84至1.22的数，x为数字范围从0.09至0.5，其中碱为氢氧化锂，氧化镍或可能的氧化钴，粉末形式为所需化学计量比，并且其在空气中在约600℃至800℃的温度下加热。

2. 发明授权

US4158723A High specific energy battery 失效
标题翻译：高比能量电池
公开(公告)号：US4158723A
公开(公告)日：1979-06-19
申请号：US942291
申请日：1978-09-14
申请人： Jean-Paul Gabano , Michel Broussely
发明人： Jean-Paul Gabano , Michel Broussely
IPC分类号： H01M4/56 , H01M4/48 , H01M6/16
CPC分类号： H01M4/56 , H01M4/483 , H01M6/16
摘要： A high specific energy electric cell having a lithium negative active material, an electrolyte solution of which the solvent is an aprotic liquid, and the positive active material is a derivative of divalent lead oxide, PbO. The lead oxide derivation is a compound of said PbO and an oxide selected from the group comprising the oxides of bismuth, Bi.sub.2 O.sub.3, antimony, Sb.sub.2 O.sub.3, and tin, SnO.sub.2.
摘要翻译：具有锂负极活性物质的高比能量电池，溶剂为非质子性液体的电解质溶液，正极活性物质为二价氧化铅PbO的衍生物。铅氧化物衍生物是所述PbO和选自铋，Bi 2 O 3，锑，Sb 2 O 3和锡，SnO 2的氧化物的氧化物的化合物。

3. 发明授权

US4690877A Electrochemical cell having a non-aqueous electrolyte 失效
标题翻译：具有非水电解质的电化学电池
公开(公告)号：US4690877A
公开(公告)日：1987-09-01
申请号：US821157
申请日：1986-01-21
申请人： Jean-Paul Gabano , Michel Broussely , Jean-Pierre Pereira-Ramos , Richard Messina , Jacques Perichon
发明人： Jean-Paul Gabano , Michel Broussely , Jean-Pierre Pereira-Ramos , Richard Messina , Jacques Perichon
IPC分类号： H01M4/36 , H01M6/16 , H01M6/36 , H01M6/14
CPC分类号： H01M6/164 , H01M6/36
摘要： A cell operable at temperatures between 100.degree. C. and 200.degree. C. includes a non-aqueous electrolyte which comprises at least one solvent belonging to the class of aromatic or aliphatic linear sulfones. The negative active material of the cell may be lithium, for example, and its positive active material is selected from the group constituted by oxides, oxisalts, and sulfides. The electrolyte includes as a solvent, in particular, dimethylsulfone alone or mixed with other aromatic or aliphatic linear sulfones.
摘要翻译：可在100℃至200℃的温度下操作的电池包括非水电解质，其包含至少一种属于一类芳族或脂族线性砜的溶剂。电池的负极活性物质例如可以是锂，其正极活性物质选自氧化物，氧化锡和硫化物。电解质包括单独的二甲基砜或与其它芳族或脂肪族线性砜混合的溶剂，特别是二甲基砜。

4. 发明授权

US4271244A High specific energy battery having an improved positive active material 失效
标题翻译：具有改进的正极活性物质的高比能量电池
公开(公告)号：US4271244A
公开(公告)日：1981-06-02
申请号：US87926
申请日：1979-10-25
申请人： Jean-Paul Gabano , Michel Broussely
发明人： Jean-Paul Gabano , Michel Broussely
IPC分类号： C01G21/02 , H01M4/56 , H01M6/16
CPC分类号： C01G21/02 , H01M4/56 , H01M6/16
摘要： A battery having a lithium anode, an electrolyte solution in which the solvent is an aprotic composition, and cathode in which the positive active material is formed from particles of a lead oxide having the formula PbO.sub.x, where x has values from 1.5 to 1.87. The PbO.sub.x positive active material produces a battery with a high specific energy and a single discharge level.
摘要翻译：具有锂阳极的电池，其中溶剂是非质子组合物的电解质溶液，以及阴极，其中正极活性物质由具有式PbO x的氧化铅颗粒形成，其中x具有1.5至1.87的值。 PbO x正极活性物质产生具有高比能量和单次放电水平的电池。

5. 发明授权

US4228229A Lithium primary cell containing thionyl chloride 失效
标题翻译：含有亚硫酰氯的锂一次电池
公开(公告)号：US4228229A
公开(公告)日：1980-10-14
申请号：US4544
申请日：1979-01-18
申请人： Jean-Paul Gabano , Jean-Yves Grassien
发明人： Jean-Paul Gabano , Jean-Yves Grassien
IPC分类号： H01M4/58 , H01M6/14
CPC分类号： H01M6/14
摘要： An electrical primary cell using lithium as its negative active material and whose positive active material includes thionyl chloride. The electrolyte of the cell is a solution including the thionyl chloride as a solvent. The solute is a complex salt resulting from the reaction of at least one of the following compounds with aluminum chloride:lithium oxide Li.sub.2 O;lithium sulphide Li.sub.2 S;calcium oxide CaO; andbarium oxide BaO.
摘要翻译：使用锂作为其负极活性物质并且其正极活性物质包括亚硫酰氯的电原电池。电池的电解质是包含亚硫酰氯作为溶剂的溶液。溶质是由至少一种以下化合物与氯化铝反应产生的复合盐：氧化锂Li 2 O; 硫化锂Li2S; 氧化钙CaO; 和氧化钡BaO。

6. 发明授权

US4375502A Electrolyte for a lithium/thionyl chloride electric cell, a method of preparing said electrolyte and an electric cell which includes said electrolyte 失效
标题翻译：用于锂/亚硫酰氯电池的电解质，制备所述电解质的方法和包括所述电解质的电池
公开(公告)号：US4375502A
公开(公告)日：1983-03-01
申请号：US259186
申请日：1981-04-30
申请人： Jean-Paul Gabano
发明人： Jean-Paul Gabano
IPC分类号： H01M6/14
CPC分类号： H01M6/14
摘要： An electrolyte for an electric cell whose negative active material (4) is constituted by lithium and whose positive active material is constituted by thionyl chloride. The electrolyte contains at least one solvent and at least one solute, said solvent being thionyl chloride and said solute being chosen from the group which includes lithium tetrachloroaluminate and lithium hexachloroantimonate. According to the invention said electrolyte further includes a complex chosen from the group which includes AlCl.sub.3,So.sub.2 and SbCl.sub.5,SO.sub.2.The voltage rise of electric cells which include such an electrolyte takes negligible time. Figure to be published: FIG. 1.
摘要翻译：一种电池的电解质，其负极活性物质（4）由锂构成，其正极活性物质由亚硫酰氯构成。电解质含有至少一种溶剂和至少一种溶质，所述溶剂为亚硫酰氯，所述溶质选自四氯铝酸锂和六氯锑酸锂。根据本发明，所述电解质还包括选自包括AlCl 3，So 2和SbCl 5，SO 2的基团的络合物。包括这种电解质的电池的电压上升可以忽略不计。图将被公布： 1。

7. 发明授权

US4069374A High energy density electric cells 失效
标题翻译：高能密度电池
公开(公告)号：US4069374A
公开(公告)日：1978-01-17
申请号：US769343
申请日：1977-02-16
申请人： Jean-Paul Gabano
发明人： Jean-Paul Gabano
IPC分类号： H01M6/16 , H01M6/14
CPC分类号： H01M6/164
摘要： High energy density electric cells have lithium as the negative active material, a silver salt or a silver oxide as the positive material and a solution comprising one solute and at least two solvents as the electrolyte. According to the invention, the first solvent is chosen from the group of esters and the second is chosen from the group formed by benzene and its substituted derivatives.

8. 发明授权

US4478920A Lithium cell having a solid electrolyte constituted by a conductive vitreous compound 失效
标题翻译：具有由导电玻璃质化合物构成的固体电解质的锂电池
公开(公告)号：US4478920A
公开(公告)日：1984-10-23
申请号：US484688
申请日：1983-04-13
申请人： Jean-Paul Gabano , Jean-Pierre Duchange
发明人： Jean-Paul Gabano , Jean-Pierre Duchange
IPC分类号： H01M6/18
CPC分类号： H01M6/18
摘要： The electrolyte is constituted by a conductive vitreous compound having the formula aP.sub.2 S.sub.5, bLi.sub.2 S, cLiX, where X represents chlorine, bromine, or iodine, and where a, b, and c are numbers chosen so that the ratio b/(a+b) lies between 0.61 and 0.70, and so that the ratio c/(a+b+c) is less than or equal to a limit corresponding to the solubility in vitreous phase of LiX in the compound aP.sub.2 S.sub.5, bLi.sub.2 S, with the positive active material comprising 20% to 80% by volume solid electrolyte together with an electron conductor, the improvement wherein a substance chosen from the halogens and the chalcogens is included in the electrolyte in order to produce an in situ chemical reaction at the lithium electrolyte interface thereby creating an ionically conductive bonding layer comprising a lithium halogenide or chalcogenide.
摘要翻译：电解质由具有式aP2S5，bLi2S，cLiX的导电玻璃质化合物构成，其中X表示氯，溴或碘，其中a，b和c是选择的数字，使得b /（a + b）在0.61和0.70之间，因此比率c /（a + b + c）小于或等于对应于化合物aP2S5，bLi2S中LiX的玻璃相中的溶解度的极限，正极活性物质包含 20％至80％体积的固体电解质与电子导体一起，其中选自卤素和硫属元素的物质被包括在电解质中，以便在锂电解质界面处产生原位化学反应，从而产生离子导电结合层包含卤化锂或硫族化物。

9. 发明授权

US4444857A Electrochemical cell including a solid electrolyte made from a cation conductive vitreous compound 失效
标题翻译：包括由阳离子导电玻璃质化合物制成的固体电解质的电化学电池
公开(公告)号：US4444857A
公开(公告)日：1984-04-24
申请号：US386228
申请日：1982-06-08
申请人： Jean-Pierre Duchange , Jean-Paul Gabano
发明人： Jean-Pierre Duchange , Jean-Paul Gabano
IPC分类号： H01M4/36 , H01M4/58 , H01M6/18
CPC分类号： H01M6/18 , H01M4/36 , H01M4/58
摘要： An electrochemical cell having a lithium based negative active material, an electrolyte in the form of a vitreous cation conductive compound having a formula: aP.sub.2 S.sub.5, bLi.sub.2 S, cLiX, where X stands for chlorine, bromine or iodine, and a, b, and c are numbers chosen in such a manner that b/(a+b) lies in the range 0.61 to 0.70 and c/(a+b+c) is less than or equal to the maximum solubility in the vitreous phase of LiX in the compound aP.sub.2 S.sub.5, bLi.sub.2 S, and a positive active material in the form of a compressed powder with particles of the electrolyte dispersed throughout said positive active material. The positive active material is chosen from the group constituted by: (CH.sub.x ; Cu.sub.d O(PO.sub.4).sub.2 ; V.sub.6 O.sub.13 ; V.sub.2 S.sub.5 ; MoS.sub.3 ; CuS; S; CuO; Cu.sub.3 B.sub.2 O.sub.6 ; FeS.sub.2 ; Pb.sub.3 O.sub.4 ; Bi.sub.2 O.sub.3 ; PbO; BiO(CrO.sub.4).sub.2 ; AgBi(CrO.sub.4).sub.2 ; I.sub.2 ; MoO.sub.3 ; WO.sub.3 ; TiS.sub.2 ; NiPS.sub.3 ; copper bismuthate; and lead bismuthate.
摘要翻译：一种具有锂基负极活性材料的电化学电池，具有下列化学式的玻璃质阳离子导电化合物形式的电解质：aP2S5，bLi2S，cLiX，其中X代表氯，溴或碘，a，b和c分别为 b /（a + b）位于0.61〜0.70的范围内，c /（a + b + c）小于或等于化合物aP2S5中LiX的玻璃相的最大溶解度，bLi2S和以压电粉末形式的正极活性材料，其中电解质颗粒分散在整个所述正极活性材料中。正极活性物质选自：（CHx; CudO（PO4）2; V6O13; V2S5; MoS3; CuS; S; CuO; Cu3B2O6; FeS2; Pb3O4; Bi2O3; PbO; BiO（CrO4）2; AgBi （CrO4）2; I2; MoO3; WO3; TiS2; NiPS3;铋酸铜;和铋酸铅。

10. 发明授权

US4371592A Primary cell of high energy density in which the anode active material is an alkali metal 失效
标题翻译：高能量密度的初级电池，其中阳极活性材料是碱金属
公开(公告)号：US4371592A
公开(公告)日：1983-02-01
申请号：US243796
申请日：1981-03-16
申请人： Jean-Paul Gabano
发明人： Jean-Paul Gabano
IPC分类号： H01M6/14 , H01M4/58
CPC分类号： H01M6/14
摘要： A primary cell of high specific energy in which the anode active material (16) is an alkali metal and the cathode active material is sulphur oxychloride which simultaneously acts as an electrolyte solvent, said electrolyte further containing a dissolved salt and a co-solvent. The co-solvent is chosen from among phosphoryl chloride and benzoyl chloride; the dissolved salt is lithium tetrachloroaluminate.
摘要翻译：高比能量的初级电池，其中负极活性材料（16）是碱金属，正极活性材料是同时作为电解质溶剂的硫氧化氯，所述电解质还含有溶解盐和共溶剂。共溶剂选自磷酰氯和苯甲酰氯; 溶解的盐是四氯铝酸锂。

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